TY - JOUR A1 - Duewer, D. L. A1 - Murray, J. A. A1 - Wood, L. J. A1 - Wise, S. A. A1 - Hein, Sebastian A1 - Koch, Matthias A1 - Philipp, Rosemarie A1 - Werneburg, Martina A1 - Hackenberg, R. A1 - Polzer, J. A1 - Avila, M. A. A1 - Serrano, V. A1 - Kakoulides, E. A1 - Alexopoulos, C. A1 - Giannikopoulou, P. A1 - Gui, E. M. A1 - Lu, T. A1 - Teo, T. L. A1 - Hua, T. A1 - Dazhou, C. A1 - Chunxin, L. A1 - Changjun, Y. A1 - Hongmei, L. A1 - Nammoonnoy, J. A1 - Sander, L. C. A1 - Lippa, K. A1 - Quinn, L. A1 - Swiegelaar, C. A1 - Fernandes-Whaley, M. A1 - Gören, A. C. A1 - Gökcen, T. T1 - CCQM-K95.1 Low-polarity analytes in a botanical matrix: Polycyclic aromatic hydrocarbons (PAHs) in tea JF - Metrologia N2 - Extraction, chromatographic separation, and quantification of low-concentration organic compounds in complex matrices are core challenges for reference material producers and providers of calibration services. Evidence of successful participation in formal, relevant international comparisons is needed to document measurement capability claims made by national metrology institutes (NMIs) and designated institutes (DIs). To enable NMIs and DIs to update or establish their claims, in 2014 the Organic Analysis Working Group (OAWG) initiated CCQM-K95.1 "Low-Polarity Analytes in a Botanical Matrix: Polycyclic Aromatic Hydrocarbons (PAHs) in Tea". This was a follow-on comparison from CCQM-K95 which was completed in 2014. The polycyclic aromatic hydrocarbons (PAHs) benz[a]anthracene (BaA) and benzo[a]pyrene (BaP) are considered priority pollutants by U.S. Environmental Protection Agency and are regulated contaminants in food, pose chromatographic separation challenges, and for which exist well-characterized measurement procedures and standard materials. BaA and BaP in a smoked tea were therefore selected as representative target measurands for CCQM-K95.1. Ten NMIs participated in CCQM-K95.1. The consensus summary mass fractions for the two PAHs are in the range of (50 to 70) ng/g with relative standard deviations of (6 to 10) %. Successful participation in CCQM K95.1 demonstrates the following measurement capabilities in determining mass fraction of organic compounds, with molar mass of 100 g/mol to 500 g/mol and having polarity pKow −2, in a botanical matrix ranging in mass fraction from 10 ng/g to 1000 ng/g: (1) value assignment of primary reference standards (if in-house purity assessment carried out), (2) value assignment of single and/or multi-component organic solutions, (3) extraction of analytes of interest from the matrix, (4) cleanup and separation of analytes of interest from interfering matrix or extract components, and (5) separation and quantification using gas chromatography or liquid chromatography. KW - Benz[a]anthracene (BaA) KW - Benzo[a]pyrene (BaP) KW - Gas chromatography (GC) KW - Isotope dilution (ID) KW - Liquid chromatography (LC) KW - Mass spectrometry (MS) KW - Polycyclic aromatic hydrocarbon (PAH) KW - Yerba mate tea PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-471430 DO - https://doi.org/10.1088/0026-1394/56/1A/08002 SN - 0026-1394 SN - 1681-7575 VL - 56 IS - 1 A SP - 08002, 1 EP - 89 PB - IOP Science AN - OPUS4-47143 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Duewer, D. L. A1 - Sander, L. C. A1 - Wise, S. A. A1 - Philipp, Rosemarie A1 - Hein, Sebastian A1 - Hackenberg, R. A1 - Polzer, J. A1 - Avila, M. A. A1 - Serrano, V. A1 - Kakoulides, E. A1 - Alexopoulos, C. A1 - Giannikopoulou, P. A1 - Chan, P. A1 - Lee, H. A1 - Tang, H. A1 - Tang, P. A1 - Yip, Y. A1 - Lu, T. A1 - Cheow, P. S. A1 - Teo, T. L. A1 - Sega, M. A1 - Rolle, F. A1 - Baek, S. A1 - Kim, B. A1 - Lee, S. A1 - Cabillic, J. A1 - Fallot, C. A1 - Hua, T. A1 - Dazhou, C. A1 - Changjun, Y. A1 - Chunxin, L. A1 - Hongmei, L. A1 - Lippa, K. A1 - Itoh, N. A1 - Quinn, L. A1 - Prevoo-Franzsen, D. A1 - Fernandes-Whaley, M. A1 - Gören, A. C. A1 - Gökcen, T. A1 - Gündüz, S. A1 - Krylov, A. A1 - Mikheeva, A. A1 - Baldan, A. A1 - van der Hout, J. W. A1 - van der Veen, A. M. H. T1 - CCQM-K131 Low-polarity analytes in a multicomponent organic solution: Polycyclic aromatic hydrocarbons (PAHs) in acetonitrile JF - Metrologia N2 - Solutions of organic analytes of known mass fraction are typically used to calibrate the measurement processes used to determine these compounds in matrix samples. Appropriate value assignments and uncertainty calculations for calibration solutions are critical for accurate measurements. Evidence of successful participation in formal, relevant international comparisons is needed to document measurement capability claims (CMCs) made by national metrology institutes (NMIs) and designated institutes (DIs). To enable NMIs and DIs to update or establish their claims, in 2015 the Organic Analysis Working Group (OAWG) sponsored CCQM-K131 "Low-Polarity Analytes in a Multicomponent Organic Solution: Polycyclic Aromatic Hydrocarbons (PAHs) in Acetonitrile". Polycyclic aromatic hydrocarbons (PAHs) result from combustion sources and are ubiquitous in environmental samples. The PAH congeners, benz[a]anthracene (BaA), benzo[a]pyrene (BaP), and naphthalene (Nap) were selected as the target analytes for CCQM-K131. These targets span the volatility range of PAHs found in environmental samples and include potentially problematic chromatographic separations. Nineteen NMIs participated in CCQM-K131. The consensus summary mass fractions for the three PAHs are in the range of (5 to 25) μg/g with relative standard deviations of (2.5 to 3.5) %. Successful participation in CCQM-K131 demonstrates the following measurement capabilities in determining mass fraction of organic compounds of moderate to insignificant volatility, molar mass of 100 g/mol up to 500 g/mol, and polarity pKow < −2 in a multicomponent organic solution ranging in mass fraction from 100 ng/g to 100 μg/g: (1) value assignment of primary reference standards (if in-house purity assessment carried out), (2) value assignment of single and/or multi-component organic solutions, and (3) separation and quantification using gas chromatography or liquid chromatography. KW - Benz[a]anthracene (BaA) KW - Benzo[a]pyrene (BaP) KW - Gas chromatography (GC) KW - Isotope dilution (ID) KW - Liquid chromatography (LC) KW - Mass spectrometry (MS) KW - Naphthalene (Nap) KW - Organic calibration solution KW - Polycyclic aromatic hydrocarbon (PAH) PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-471442 DO - https://doi.org/10.1088/0026-1394/56/1A/08003 SN - 0026-1394 SN - 1681-7575 VL - 56 IS - 1A SP - 08003, 1 EP - 102 PB - IOP Science AN - OPUS4-47144 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Busse, F. A1 - Heidrich, C. A1 - Kleine, M. A1 - Sander, C. A1 - Ünal, Murat T1 - BEGLARES II Protection and restoration of monumental concrete-glazing with cathodic protection systems T2 - 9th Forum for the conservation and technology of historic stained-glass (Proceedings) N2 - Since the 1950's, art has been fascinated by concrete glazing. In countless buildings of the post-war period they determine the lighting effect of the space by its function as luminous walls. A peculiar kind of stained glass from partially filigree compositions of two such contrasting materials: delicate, luminous glass and rough, austere concrete. Artistically designed components, which are equipped with a range of stylistic subtleties. But even after o short time of exposure a whole catalogue of damage patterns has been revealed, which documents the decay processes, such as the carbonation initiated corrosion of reinforcement. Cathodic protection is already used in a wide range of repair of concrete structures. Taking into account technical and historical preservation requirements, this research project aims to transfer these techniques to the conservation of concrete-glazing under less health risk, cost and work effort. T2 - 9th Forum for the conservation and technology of historic stained-glass CY - Paris, France DA - 08.07.2015 KW - Concrete-glazing KW - Dalles de verres KW - Cathodic corrosion protection KW - Heritage KW - Restoration KW - Maintenance PY - 2015 SN - 978-2-9543731-1-9 SP - 82 EP - 90 AN - OPUS4-34286 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sander, C. A1 - Kühne, Hans-Carsten A1 - Ünal, Murat A1 - Kleine, M. A1 - Köhler, A. A1 - Kriesten, V. T1 - Betondickglasfenster - Schadensmechanismen und Instandsetzungsprinzipien zur Erhaltung JF - Restauro N2 - Errichtet aus Glas und Beton prägen heute unzählige Sakralbauten der 1950er- und 60er-Jahre unsere Stadtbilder. Nicht selten sind in diesen Kirchen erhebliche Schäden an den Betonglasfenstern zu verzeichnen. Diese fachgemäß zu erhalten, erfordert spezielles technisches und denkmalpflegerisches Know-how. An der Entwicklung geeigneter Instandsetzungsstrategien arbeitet derzeit ein interdisziplinäres Projektteam. KW - Betonglasrestaurierung KW - Schadensmechanismen KW - Instandsetzungsprinzipien KW - Glass KW - (Reinforced) concrete KW - Church windows KW - Churches KW - Structural analysis KW - Concrete block technique KW - Reinforcement KW - Dalle de verre PY - 2011 SN - 0933-4017 VL - 7 SP - 48 EP - 53 PB - Callwey CY - München AN - OPUS4-24834 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Torge, Manfred A1 - Krug, Sonja A1 - Bücker, Michael A1 - Feldmann, Ines A1 - Scharf, Holger A1 - Witthuhn, Heike A1 - Sander, C. T1 - Flüchtiges Quecksilber - Emission von Quecksilber aus historischen Zinnamalgamspiegeln JF - Restauro N2 - Mit der Erfindung des Glas-Guß-Walzverfahrens eröffnete sich die Möglichkeit, größere Spiegelflächen als zuvor herzustellen. Diese sogenannten Quecksilberspiegel sind mit Zinnamalgam beschichtet. Wenn Restauratoren mit Zinnamalgamspiegeln arbeiten, müssen sie strenge Sicherheitsvorkehrungen einhalten. Häufig finden sich im Spiegelrahmen Quecksilberkugeln, die beim Öffnen herausfallen und damit gesundheitsschädliches Quecksilber freisetzen können. In einem Forschungsprojekt wurden die Quecksilberemissionen aus Zinnamalgamspiegeln gemessen und Möglichkeiten entwickelt, diese zu verringern. KW - Quecksilber KW - Emission KW - Zinnamalgamspiegel PY - 2012 SN - 0933-4017 VL - 118 IS - 3 SP - 30 EP - 37 PB - Callwey CY - München AN - OPUS4-25846 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kühne, Hans-Carsten A1 - Hüsken, Götz A1 - Mundra, Shishir A1 - Sander, C. A1 - Obermann, S. T1 - Die Betondickglasfenster des Glockenturms am Eiermannbau der Kaiser-Wilhelm-Gedächtniskirche T2 - N.i.Ke. Schriftenreihe des Netzwerks zur interdisziplinären Kulturguterhaltung N2 - Die Kaiser-Wilhelm-Gedächtniskirche (KWG) gilt als eine der wichtigsten Sehenswürdigkeiten Berlins in der City West und als ein herausragendes Beispiel für die „Dalle de Verre“ Verglasungen in sakralen Gebäuden. Der vorliegende Beitrag widmet sich der Fassade und den Glasfenstern des neuen Glockenturms, wobei die beschriebenen Szenarien aufgrund der annähernd gleichen Bauweise der restlichen neuen Baukörper in weiten Teilen starke Analogien aufweisen und insofern übertragbar sind. T2 - Workshop Kulturguterhaltung - Vom Dampfkessel zu Nanomaterialien CY - Berlin, Germany DA - 17.11.2021 KW - Kaiser-Wilhelm-Gedächtniskirche KW - Betondickglasfenster KW - Instandsetzung KW - Elektrochemische Realkalisierung PY - 2021 VL - 3 SP - 125 EP - 140 PB - Druckerei G. Bohm CY - Berlin AN - OPUS4-57092 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Torge, Manfred A1 - Krug, Sonja A1 - Bücker, Michael A1 - Feldmann, Ines A1 - Scharf, Holger A1 - Witthuhn, Heike A1 - Sander, C. A1 - Fraenkler-Balhorn, K. ED - Roemich, H. T1 - Mercury emissions from historical tin amalgam mirrors T2 - Interim Meeting of the ICOM-CC Working Group - Glass & Ceramics Conservation (Proceedings) T2 - Interim Meeting of the ICOM-CC Working Group - Glass & Ceramics Conservation CY - Corning, New York, USA DA - 2010-10-03 KW - Mirrors KW - Mercury KW - Tin amalgam KW - Deterioration PY - 2010 SN - 978-0-87290-182-7 SP - 156 EP - 163 AN - OPUS4-22175 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ünal, Murat A1 - Kühne, Hans-Carsten A1 - Kleine, M. A1 - Sander, C. T1 - Development and design of repair and protection principles and a concrete repair mortar for the conservation of slab glass set in concrete from the 20th century T2 - GLASSAC 11 - 3rd GLASSAC Conference 'Glass science in art and conservation' N2 - Main topics of the research project BEGLARES are the restoration of "dalle de verre" concrete Windows and the development of repair techniques and mortars. This project is executed in Cooperation between Glasmalerei Peters GmbH, the University of York and the BAM Federal Institute for Materials Research and Testing. It is funded by the Federal Ministry of Economics and Technology. The main mechanism of damages, the development of repair mortar and special test specimens are presented. T2 - GLASSAC 11 - 3rd GLASSAC Conference 'Glass science in art and conservation' CY - Wertheim, Bronnbach Monastery, Germany DA - 10.05.2011 KW - Concrete glazing KW - Carbonation KW - Maintenance planning KW - Actual state analysis PY - 2011 SN - 978-3-8396-0255-3 SP - 43 EP - 46 PB - Fraunhofer Verlag AN - OPUS4-23730 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -