TY - CONF A1 - Recknagel, Sebastian A1 - Kipphardt, Heinrich A1 - Lange, Britta A1 - Hoppe, Marion T1 - Traceable analysis of impurities in metallic reference materials using GD-MS N2 - The traceabiiity requirements for certification analyses of reference materials are much more stringent than for routine analysis, where certified matrix reference materials (CRM) can be used for calibration and to establish traceabiiity. Although the ISO-Guides related to CRM production and certification are not fully clear concerning calibration, many established CRM-producers do not accept matrix-CRMs for calibration in case of certification analyses, e.g. to avoid circular reasoning. These requirements limit the methods used for certification to those that can be calibrated using Standards of known high purity and stoichiometry or mixtures of such Standards. Powerful solid sampling techniques such as glow discharge mass spectrometry (GD-MS) or spark-optical emission spectrometry (SOES), where usually compact CRMs are used for calibration, seem not be applicable for certification analyses. Especially GD-MS is a powerful tool for trace element determination of solid samples. Beside metallic impurities the use of specific gas mixtures enables also the determination of interesting nonmetallic impurities such as sulfur and phosphorus. Within BAM a calibration approach, was developed which enables to use mixtures of Standards of known high purity and stoichiometry also for GD-MS. Analogue to matrix adaption in solution based techniques, the calibration approach is based on doped pressed powder pellets. Approach and application on the certification analyses of copper and Steel CRMs are presented. T2 - CETAS 2011 - 8th International workshop on progress in analytical chemistry & materials characterisation in the steel and metal industries CY - Luxembourg, Luxembourg DA - 17.05.2011 PY - 2011 IS - OC53 SP - 361 EP - 365 AN - OPUS4-23762 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - ICP-Sektorfeld-MS zur Bestimmung von Elementspuren in Reinstmetallen T2 - Canas CY - Freiberg, Germany DA - 2005-03-06 PY - 2005 AN - OPUS4-10970 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Element GD-Herausforderung Kalibration T2 - GDS-Anwendertreffen CY - Hanau, Germany DA - 2006-09-11 PY - 2006 AN - OPUS4-13477 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Calibration of glow discharge mass spectrometry for the analysis of pure copper T2 - 13th International Conference on ultra high-purity base metals CY - Berlin, Germany DA - 2006-09-11 PY - 2006 AN - OPUS4-13484 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - ICP-Sektorfeld-MS zur Bestimmung von Elementspuren in Reinstmetallen T2 - IGAS CY - Berlin, Germany DA - 2006-11-08 PY - 2006 AN - OPUS4-13774 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Recknagel, Sebastian A1 - Lange, Britta T1 - Neues zertifiziertes Referenzmaterial für die Analyse von Verunreinigungen in Reinzink KW - Zertifizierung KW - Referenzmaterial KW - Zink KW - Feinzink PY - 2006 SN - 0026-0746 VL - 60 IS - 12 SP - 799 EP - 803 PB - Giesel Verlag GmbH CY - Isernhagen AN - OPUS4-14428 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Bestimmung von Nichtmetallen in Kupfer mittels Glimmentladungsmassenspektrometrie T2 - CANAS '07, Colloquium Analytische Atomspektroskopie CY - Konstanz, Germany DA - 2007-03-18 PY - 2007 AN - OPUS4-14629 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Signal enhancement in GD-MS analysis of pure matals by application of Argon- Helium mixtures as discharge gas T2 - ECASIA '07, GDS-Sitzung CY - Brussels, Belgium DA - 2007-09-13 PY - 2007 AN - OPUS4-14860 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Spurenanalytik in Reinkupfer mittels Glimmentladungsmassenspektrometrie T2 - ANAKON 2007 CY - Jena, Germany DA - 2007-03-27 PY - 2007 AN - OPUS4-14641 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Possibilities of signal enhancement in GD-MS analysis of pure metals T2 - EuroAnalysis XIV CY - Antwerp, Belgium DA - 2007-09-09 PY - 2007 AN - OPUS4-14859 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Zertifizierung von Referenzmaterial am Beispiel des Kalibrationssatzes Reinkupfer T2 - CANAS '05 CY - Freiberg, Germany DA - 2005-03-06 PY - 2005 AN - OPUS4-6701 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Zertifizierung von Referenzmaterial am Beispiel des Kalibrationssatzes Reinkupfer T2 - IGAS CY - Berlin, Germany DA - 2006-11-08 PY - 2006 AN - OPUS4-13772 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lange, Britta T1 - Zertifizierung von Referenzmaterial am Beispiel des Kalibrationssatzes Reinkupfer T2 - Tag der Chemie, Freie Universität Berlin CY - Berlin, Germany DA - 2005-06-08 PY - 2005 AN - OPUS4-11904 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -