TY - JOUR A1 - Raschpichler, C. A1 - Goroncy, C. A1 - Langer, B. A1 - Antonsson, E. A1 - Wassermann, B. A1 - Graf, C. A1 - Klack, Patrick A1 - Lischke, T. A1 - Rühl, E. T1 - Surface Properties and Porosity of Silica Particles Studied by Wide-Angle Soft X-ray Scattering N2 - Wide-angle soft X-ray scattering on free silica particles of different porosity prepared in a beam is reported. The explored q region is mostly dominated by features due to surface roughness and bulk porosity. A comprehensive experimental and theoretical analysis of silica particles of different porosity is presented for various incident photon energies. A correlation analysis, based on the theory of Porod, is used to test the validity of exact Mie theory in different pore density limits. The ability of the discrete dipole scattering model (DDSCAT) to resolve local effects, caused by various pore distributions, is discussed. Characteristic differences between the soft X-ray scattering patterns of the particle samples of different surface properties and porosity are detected. For all mentioned cases, it was confirmed that the effective radius concept of the Guinier model can be successfully extended to Mie theory and DDSCAT in describing the additive contributions of the primary particles, including a thin inhomogeneous solvent-rich surface shell and empty bulk pores. Close agreement, within ±15%, between the calculated and observed pore sizes and porosity values is reached. The influence of pores is alternatively described either in terms of secondary Mie scattering, which is modulated by the local internal electrical field within the particles, or by an independent Mie scattering process induced by the incident field on isolated pores. It is found that for the typical pore/particle size ratios the latter approach presents the best choice. KW - Wide-Angle Soft X‑ray Scattering KW - Silica KW - Porosity PY - 2020 DO - https://doi.org/10.1021/acs.jpcc.0c04308 SN - 1932-7447 SN - 1932-7455 VL - 124 SP - 16663 EP - 16674 AN - OPUS4-51089 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schlegel, Moritz-Caspar A1 - Russina, M. A1 - Günther, G. A1 - Grzimek, V. A1 - Gainov, R. A1 - Drescher, L. A1 - Kaulich, T. A1 - Graf, W. A1 - Urban, B. A1 - Daske, A. A1 - Grotjahn, K. A1 - Hellhammer, R. A1 - Buchert, G. A1 - Kutz, H. A1 - Rossa, L. A1 - Sauer, O.-P. A1 - Fromme, M. A1 - Wallacher, D. A1 - Kiefer, K. A1 - Klemke, B. A1 - Grimm, N. A1 - Gerischer, S. A1 - Tsapatsaris, N. A1 - Rolfs, K. T1 - Upgrade project NEAT02016 at Helmholtz Zentrum Berlin – What can be done on the medium power neutron source N2 - The neutron time-of-flight spectrometer NEAT has a long history of successful applications and is best suited to probe dynamic phenomena directly in the large time domain 10(-14) - 10(-10) s and on the length scale ranging from 0.05 to up to about 5 nm. To address user community needs for more powerful instrumental capabilities, a concept of the full upgrade of NEAT has been proposed. The upgrade started in 2010 after a rigorous internal and external selection process and resulted in 300-fold neutron count rate increase compared to NEAT01995. Combined with new instrumental and sample environmental capabilities the upgrade allows NEAT to maintain itself at the best world class level and provide an outstanding experimental tool for a broad range of scientific applications. The advanced features of the new instrument include an integrated guide-chopper system that delivers neutrons with flexible beam properties: either highly homogeneous beam with low divergence suitable for single crystals studies or "hot-spot" neutron distribution serving best small samples. Substantial increase of the detector angle coverage is achieved by using 416 He-3 position sensitive detectors. Placed at 3m from the sample, the detectors cover 20m(2) area and are equipped with modern electronics and DAQ using event recording techniques. The installation of hardware has been completed in June 2016 and on January 23, 2017 NEAT has welcomed its first regular users who took advantage of the high counting rate, broad available range of incoming neutron wavelengths and high flexibility of NEAT. Here we present details of NEAT upgrade, measured instrument characteristics and show first experimental results. KW - Neutron scattering KW - Neutron spectroscopy KW - Instrumentation KW - Time-of-flight neutron spectroscopy KW - Nanoscale dynamics PY - 2017 DO - https://doi.org/10.1016/j.physb.2017.12.026 SN - 0921-4526 VL - 551 SP - 506 EP - 511 PB - Elsevier B.V. AN - OPUS4-43514 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - El-Sari, B. A1 - Biegler, M. A1 - Graf, B. A1 - Rethmeier, Michael T1 - Distortion-based validation of the heat treatment simulation of Directed Energy Deposition additive manufactured parts N2 - Directed energy deposition additive manufactured parts have steep stress gradients and an anisotropic microstructure caused by the rapid thermo-cycles and the layer-upon-layer manufacturing, hence heat treatment can be used to reduce the residual stresses and to restore the microstructure. The numerical simulation is a suitable tool to determine the parameters of the heat treatment process and to reduce the necessary application efforts. The heat treatment simulation calculates the distortion and residual stresses during the process. Validation experiments are necessary to verify the simulation results. This paper presents a 3D coupled thermo-mechanical model of the heat treatment of additive components. A distortion-based validation is conducted to verify the simulation results, using a C-ring shaped specimen geometry. Therefore, the C-ring samples were 3D scanned using a structured light 3D scanner to compare the distortion of the samples with different post-processing histories. KW - Directed Energy Deposition KW - Additive Manufacturing KW - Heat Treatment KW - Numerical Simulation KW - Finite Element Method PY - 2020 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-513153 DO - https://doi.org/10.1016/j.procir.2020.09.146 VL - 94 SP - 362 EP - 366 PB - Elsevier B.V. AN - OPUS4-51315 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Biegler, M. A1 - Elsner, B. A1 - Graf, B. A1 - Rethmeier, Michael T1 - Geometric distortion-compensation via transient numerical simulation for directed energy deposition additive manufacturing N2 - Components distort during directed energy deposition (DED) additive manufacturing (AM) due to the repeated localised heating. Changing the geometry in such a way that distortion causes it to assume the desired shape – a technique called distortion-compensation – is a promising method to reach geometrically accurate parts. Transient numerical simulation can be used to generate the compensated geometries and severely reduce the amount of necessary experimental trials. This publication demonstrates the simulation-based generation of a distortioncompensated DED build for an industrial-scale component. A transient thermo-mechanical approach is extended for large parts and the accuracy is demonstrated against 3d-scans. The calculated distortions are inverted to derive the compensated geometry and the distortions after a single compensation iteration are reduced by over 65%. KW - DED KW - Welding simulation KW - Dimensional accuracy KW - Additive manufacturing KW - Laser metal deposition KW - LMD PY - 2020 DO - https://doi.org/10.1080/13621718.2020.1743927 SP - 1 EP - 8 PB - Taylor & Francis AN - OPUS4-50877 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - El-Sari, B. A1 - Biegler, M. A1 - Graf, B. A1 - Rethmeier, Michael T1 - Numerische Simulation einer AM-Prozesskette im DED Auftragschweißen N2 - Das DED Auftragschweißen ist ein additives Fertigungsverfahren für Metalle, bei dem das Material schichtweise auf ein Substrat aufgetragen wird. Die schnellen Temperaturzyklen rufen Spannungsgradienten im Bauteil hervor. Der schichtweise Aufbau der Bauteile verursacht eine anisotrope Mikrostruktur. Mittels nachgelagerter Wärmebehandlung können diese Effekte verringert werden. Im anschließenden Schritt der Prozesskette wird das additiv hergestellte Bauteil mittels Drahterodieren von dem Substrat abgetrennt. In diesem Beitrag wird eine thermo-mechanische Simulation der gesamten Prozesskette vorgestellt, welche den additiven Aufbau, Wärmebehandlung und das Abtrennen vom Substrat beinhaltet. Anstelle der in der Literatur üblichen schichtweisen Modellierungsstrategie für die DED Simulation wird das gesamte Bauteil in einem Stück vernetzt und der vollständig transiente, schichtweise Materialauftrag über Elementgruppen realisiert. Im Gegensatz zu früheren Simulationen muss der nichtlineare Kontakt zwischen den Schichten nicht berücksichtigt werden, was die Rechenzeiten deutlich verkürzt. Das Modell wurde validiert mittels Abgleiches des Verzugs aus Simulation und Experiment. Die Proben, bestehend aus DIN 1.4404 (AISI 316L), wurden nach jedem Prozessschritt 3D gescannt um den Verzug zu quantifizieren. Zusätzlich wurden Querschnitte und Härtetests nach Vickers von unterschiedlich behandelten Proben durchgeführt, um den Effekt der Wärmebehandlung auf die Mikrostruktur und die Härte des Bauteils zu untersuchen. T2 - 20. Roundtable Simulating Manufacturing CY - Marburg, Germany DA - 22.05.2019 KW - Numerische ISmulation KW - DED KW - AM KW - Laser-Pulver-Auftragschweißen PY - 2019 SP - 1 EP - 14 AN - OPUS4-50046 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Petrat, T. A1 - Graf, B. A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Laser-Pulver-Auftragschweißen zum additiven Aufbau komplexer Formen N2 - Das Laser-Pulver-Auftragschweißen als additives Fertigungsverfahren ermöglicht einen endformnahen Aufbau von Bauteilen. Ein Zielkonflikt besteht zwischen der Forderung nach hoher Aufbaurate und hoher Endformnähe, welcher von der Schweißraupengröße wesentlich beeinflusst wird. In dieser Veröffentlichung wird das Laser-Pulver-Auftragschweißen eingesetzt, um komplexe Formen additiv aufzubauen. Am Beispiel eines Tannenbaumprofiles werden unterschiedliche Einflussfaktoren dargestellt. Dazu gehören die Raupengeometrie, die Überlappung einzelner Raupen, die Verwendung unterschiedlicher Aufbaustrategien und die Teilung des Gesamtkörpers in Teilkörper. Der Zielkonflikt wird durch die Herstellung von Probekörpern mit unterschiedlichen Steigungswinkeln an den Seitenflächen verdeutlicht. Die Ergebnisse zeigen eine verbesserte Endformnähe in Bereichen flacher Steigung beim Einsatz kleiner Schweißraupen. Im Vergleich dazu erlauben die Schweißparameter der großen Raupen eine 5-fach höhere Aufbaurate. Bei einer Raupenüberlappung kleiner und großer Raupengeometrien innerhalb einer Lage treten Anbindungsfehler auf. Strategien zur Behebung dieses Fehlers durch Anpassung der Schweißreihenfolge werden in dieser Veröffentlichung aufgezeigt. Diese Erfahrungen werden genutzt, um einen Gesamtkörper aus Teilkörpern unterschiedlicher Raupengeometrien zu fertigen. T2 - DVS Congress 2015 - Große Schweißtechnische Tagung CY - Nuremberg, Germany DA - 14.09.2015 PY - 2015 SN - 978-3-945023-46-4 N1 - Serientitel: DVS-Berichte – Series title: DVS-Berichte IS - 315 SP - 126 EP - 129 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-34770 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Petrat, Torsten A1 - Graf, B. A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - Build-up strategies for generating components of cylindrical shape with laser metal deposition N2 - Laser Metal Deposition LMD) as additive manufacturing process offers the potential to produce near net shape components. This reduces the amount of material and post-processing. The components are composed of individual layers. Already mall irregularities within a layer can add up over multiple layers and lead to error propagation. This paper deals with the issue of build-up strategies to minimize irregularities and prevent error propagation. Different travel paths and the influence of a changing starting point regarding to error propagation are discussed. Different deposition rates between core and peripheral area are detected and successfully compensated by adjusting the build-up sequence. Stainless steel and titanium alloy Ti-6Al-4V are used in the experiments. The results are intended to illustrate the potential of an adjusted build-up strategy and provide basic information on the way to an automated deposition process. This paper is of interest for engineers in industry or science using LMD as additive manufacturing process. T2 - Lasers in Manufacturing Conference 2015 CY - Munich, Germany DA - 22.06.2015 KW - Ti - 6Al - 4V KW - Additive Manufacturing KW - Build - up Strategy KW - Laser Metal Deposition KW - Stainless Steel PY - 2015 UR - http://www.wlt.de/lim/Proceedings/Stick/sessions.html SP - 1 EP - 6 AN - OPUS4-37829 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Graf, B. T1 - 3D laser metal deposition in an additive manufacturing process chain N2 - Laser metal deposition is described with its applications for additive manufacturing. The necessary process chain is discussed, with regard to weld bead dimensions and 3D build-up strategy. Metallurgical cross sections, x-ray and tensile tests are conducted. As demonstrative components, a gas turbine burner and a turbine blade are shown T2 - 1st International Congress on Welding, Additive Manufacturing and Associated Non-Destructive Testing CY - Metz, France DA - 17.05.2017 KW - Additive manufacturing KW - Ti-6Al-4V KW - Process chain KW - Turbine industry KW - Laser metal deposition PY - 2017 AN - OPUS4-44477 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Graf, B. A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael T1 - 3D laser metal deposition in an additive manufacturing process chain N2 - Laser metal deposition is described with its applications for additive manufacturing. The necessary process chain is discussed, with regard to weld bead dimensions and 3D build-up strategy. Metallurgical cross sections, x-ray and tensile tests are conducted. As demonstrative components, a gas turbine burner and a turbine blade are shown. T2 - 1st International Congress on Welding, Additive Manufacturing and Associated Non- CY - Metz, France DA - 17.05.2017 KW - Laser metal deposition KW - Additive manufacturing KW - Ti-6Al-4V KW - Turbine industry KW - Process chain PY - 2017 UR - https://icwam.com/sites/default/files/Abstract%20book.pdf SP - AM 34-2 EP - 3 AN - OPUS4-43190 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Petrat, T. A1 - Marko, A. A1 - Graf, B. A1 - Gumenyuk, Andrey A1 - Rethmeier, Michael ED - Mayr, P. ED - Berger, M. T1 - Baustrategien zur Beeinflussung von Materialauftrag und Temperaturentwicklung bei der additiven Fertigung mittels Laser-Pulver-Auftragschweißen N2 - Die Weiterentwicklung des Laser-Pulver-Auftragschweißens im Bereich der additiven Fertigung stellt dieses Verfahren vor neue Herausforderungen. Bauteile können schnell und endformnah hergestellt werden, was diese Technik für den Prototypenbau sowie Kleinserienfertigung interessant macht. Die Vielzahl an Varianten, um ein Volumen aus einzelnen Schichten aufzubauen, erhöhen die Möglichkeiten die Eigenschaften des entstehenden Bauteils zu beeinflussen. Hierfür müssen Strategien entwickelt werden, welche einen gleiclunäßigen Materialauftrag bei gleichzeitig optimalen Materialeigenschaften gewährleisten. Die durchgeführten Untersuchungen behandeln den Einfluss von Pendelstrategien sowie Spiralstrategien auf die Temperaturentwicklung und stellen diese vergleichend gegenüber. Um den unterschiedlichen Bedingungen bei der Bauteilfertigung Rechnung zu tragen, wurden Versuche in Randbereichen sowie im zentralen Bereich des Testobjekts untersucht. Die Ergebnisse verdeutlichen die Notwendigkeit angepasste Baustrategien zu entwickeln, um durch einen stabilen Fertigungsprozess Qualität und Eigenschaften eines Bauteils gewährleisten zu können. T2 - FüMoTec 2017 CY - Chemnitz, Germany DA - 14.11.2017 KW - Laser-Pulver-Auftragschweißen KW - Additiv KW - Pendelstrategie KW - Spiralstrategie KW - Temperaturentwicklung PY - 2017 SN - 978-3-96100-034-0 SN - 2365-8096 SN - 2365-810X VL - 2017/2 SP - 27 EP - 36 PB - readbox unipress CY - Münster AN - OPUS4-43104 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Marko, A. A1 - Graf, B. A1 - Rethmeier, Michael T1 - Statistical analysis of weld bead geometry in Ti6Al4V laser cladding N2 - The process of laser cladding has become more important during recent years because of its broad application for cladding, repair or additive manufacturing. In the field of mechanical engineering, one use is the repair of turbine blades. For high quality and reliability of the repaired components, it is necessary to adjust the weld bead geometry to the specific repair task. The bead geometry influences the metallurgical bonding and the degree of dilution as well as the formation of defects like pores or cracks. Therefore, it is important to know the effects of the different parameters on the welding bead. A valuable tool to meet this industrial challenge is the design of experiments (DoE). In this context, the user can choose between a huge number of test plans. Greater Profit of information is expected by a larger test range. In order to confirm the acceptance, a five-step full factorial test plan is compared to a central composite design in this paper. Moreover, the limits of the experimental range are indicated and restrictions can be derived. As the results show, the essential effects are detected with a full factorial test plan as well as with a central composite design. Merely the effect strength could not always be specified unambiguously. On this account and in consideration of cost efficiency, the use of central compound design is recommended in industrial applications. KW - Laser metal deposition KW - Design of experiments KW - Laser cladding KW - Cladding parameter KW - Additive manufacturing PY - 2017 DO - https://doi.org/10.3139/120.111077 SN - 0025-5300 SN - 2195-8572 VL - 59 IS - 10 SP - 837 EP - 843 PB - Carl Hanser Verlag CY - München AN - OPUS4-42882 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -