TY - CONF A1 - Bäßler, Ralph A1 - Schmidt, C. A1 - Alves, H. T1 - Suitability of Nickel-based alloys and titanium for applications in acids at 200 °C N2 - In the literature there are not much data available to describe the corrosion behavior of titanium, nickel alloys and special stainless steels in acids at high temperature, in particular above the boiling point. Therefore, a laboratory testing program was performed with two titanium alloys (grade 2 - UNS R50400 and grade 12 - UNS R53400) to obtain corrosion data in formic acid, acetic acid, phosphoric acid, polyphosphoric acid, p-toluene sulfonic acid and lactic acid at 200 °C. Results were compared to previously published ones obtained on alloy 31 (UNS N08031), alloy 59 (UNS N06059) and B-2 (UNS N10665). From the results it can be concluded that titanium does not always Show better corrosion resistance than Ni-based alloys, Alloy 59 was the best choice for formic and acetic acids at temperatures of 200°C. Both Ti-alloys are resistant in acetic acid. Some slight differences were observed for formic acid, where Ti grade 2 is only resistant up to a 20 % solution and grade 12 in concentrated acid too. The phosphoric acid is extremely corrosive and none of the investigated materials was resistant. In the diluted acid (5 %) only Ti grade 12 is resistant, whereas in 1 % solution all investigated materials withstand. Alloy B-2 and alloy 59 showed the best behavior in polyphosphoric acid. In 30 % concentrated p-toluene sulfonic acid at 200 °C all alloys tested were unsuitable. In very diluted acid (0.1 %) both Ti-alloys and the other three alloys behaved well. In lactic acid at 180 °C increased corrosion underneath deposits was detected; the best performance was observed for alloy 59 and Ti grade 2. T2 - VDM Symposium "Nickel alloys, titanium and zirconium in the chemical process industry" CY - Frankfurt am Main, Germany DA - 17.06.2015 KW - Titanium grade 2 (UNS 50400) KW - grade 12 (UNS 53400) KW - Alloy 59 (UNS N06059) KW - Alloy 31 (UNS N08031) KW - Alloy B-2 (UNS N10665) KW - Inorganic acids KW - Organic acids KW - Corrosion PY - 2015 SP - paper 3 AN - OPUS4-34752 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weltschev, Margit A1 - Bäßler, Ralph A1 - Werner, H. A1 - Behrens, R. T1 - Assessment of the corrosion resistance of high-alloyed metallic tank materials in the BAM-list-requirements for tanks for the transport of dangerous goods T2 - EUROCORR 2003 CY - Budapest, Hungary DA - 2003-09-28 KW - BAM-List KW - Dangerous goods KW - Compatibility evaluations KW - High-alloyed metallic tank materials KW - Corrosion tests PY - 2003 N1 - Serientitel: EFC-Event – Series title: EFC-Event IS - 261 SP - 1 EP - 12 PB - European Federation of Corrosion CY - Budapest AN - OPUS4-2683 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Weltschev, Margit A1 - Bäßler, Ralph A1 - Werner, H. A1 - Behrens, R. T1 - Suitability of High-Alloyed Metallic Materials for Tanks for the Transport of Dangerous Goods - BAM-List T2 - 11th International Symposium "Loss Prevention 2004" CY - Prague, Czech Republic DA - 2004-05-31 KW - BAM-List KW - Dangerous goods KW - Compatibility evaluations KW - High-alloyed metallic tank materials KW - Corrosion tests KW - Korrosion KW - Höherlegierte metallische Tankwerkstoffe KW - BAM-Liste PY - 2004 SN - 80-0201574-6 SP - PG4478 EP - PG4489 PB - Ceská Spolecnost Chemického Inzenýrství CY - Prag AN - OPUS4-3576 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weltschev, Margit A1 - Bäßler, Ralph A1 - Werner, H. A1 - Behrens, R. T1 - Suitability of More Noble Materials for Tanks for Transport of Dangerous Goods T2 - Corrosion 2004 ; 59th NACExpo 2004 ; 59th Annual conference & exposition. NACE International - The Corrosion Society CY - New Orleans, LA, USA DA - 2004-03-28 KW - BAM-List KW - Dangerous goods KW - Compatibility evaluations KW - High-alloyed metallic tank materials KW - Corrosion tests PY - 2004 IS - CD-ROM, Paper 04228 SP - 04228-1-04228-13 PB - NACE International CY - New Orleans, La. AN - OPUS4-3476 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Keserović, A. A1 - Sobetzki, J. A1 - Sarmiento-Klapper, H. A1 - Boduch, A. A1 - Aristia, G. A1 - Faes, W. A1 - Stoljarova, A. A1 - Zimmer, S. T1 - Metallene Werkstoffe in Geothermieanlagen - nicht nur aus Sicht der Korrosion N2 - Um Konstrukteuren und Nutzern geothermischer Anlagen grundlegende Informationen über die Korrosionsbeständigkeit zur Verfügung zu stellen, wurden verschiedene metallene Werkstoffe, darunter nichtrostende Duplex- und austenitische Stähle sowie eine Nickellegierung, in künstlichen Geothermalwässern, die die Bedingungen an verschiedenen Standorten mit geothermischem Potenzial simulieren, mit Hilfe von elektrochemischen und Langzeittests hinsichtlich ihrer Eignung bewertet. In hochsalinaren Umgebungen erwies sich Spaltkorrosion als der entscheidende Mechanismus. Die Nickellegierung zeigt eine ausgezeichnete Beständigkeit gegenüber Lochkorrosion. Abgesehen von ihren hohen Kosten eignet sie sich sehr gut für den Bau von Geothermieanlagen mit stark salzhaltigen Fluiden. Rostfreie Stähle und Duplexstähle weisen eine begrenzte Korrosionsbeständigkeit gegen Loch- und Spaltkorrosion auf. Daher sind sie für stark salzhaltige Fluide nicht geeignet. Der Superaustenit zeigt ein temperaturabhängiges Verhalten. In nichtsalinaren Umgebungen könnten niedriglegierte Stähle (neben den höherlegierten Werkstoffen) als Konstruktionsmaterial für Geothermieanlagen eingesetzt werden, sofern eine ausreichende Wandstärke des Materials berücksichtigt wird. Neben Korrosionsaspekten erwies sich auch die Ausfällung von Fluidbestandteilen als interessantes Thema. Beim Betrieb der Forschungsanlage in Groß Schönebeck wurden Kupfer- und Bleieffekte im Bohrloch festgestellt. Die auftretenden Mechanismen und Maßnahmen zur Verhinderung von Ausfällungen und Abscheidungen wurden ebenso untersucht, wie deren mögliche Einflüsse auf die Korrosionsbeständigkeit metallener Werkstoffe für Anlagenkomponenten. Der Beitrag beschreibt die Wechselwirkungen zwischen Geothermalwässern und Ausrüstungskomponenten. T2 - 57. Kraftwerktechnisches Kolloquium CY - Dresden, Germany DA - 07.10.2025 KW - Örtliche Korrosion KW - Edelstahl KW - Ni-Legierungen KW - Geothermie KW - Abscheidung PY - 2025 SN - 978-3-00-082651-1 SN - 978-3-00-082652-8 SP - 551 EP - 568 PB - IKS-Verlag CY - Freiberg AN - OPUS4-64320 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rütters, H. A1 - Stadler, S. A1 - Bäßler, Ralph A1 - Bettge, Dirk A1 - Jeschke, S. A1 - Kather, A. A1 - Lempp, C. A1 - Lubenau, U. A1 - Ostertag-Hennig, C. A1 - Schmitz, S. A1 - Schütz, S. A1 - Waldmann, S. T1 - Towards an optimization of the CO2 stream composition - A whole-chain approach N2 - CO2 streams captured from power stations or industrial plants may contain impurities that impact the consecutive steps of the CO2 capture and storage (CCS) chain. As the basis for an optimization of CO2 purity over the whole CCS chain, impacts of different impurities were investigated at key steps including studies on (i) corrosion of metallic materials in CO2 streams and brine, (ii) fluid and interfacial properties as a function of pressure, temperature and CO2 stream composition and their implications for CO2 transport, injection and geological storage, (iii) costs of different pipeline design options, (iv) geochemical alterations at typical reservoir conditions and their implications for geomechanical rock properties. Major findings are synthesized for two exemplary single source-single sink CCS chain scenarios involving CO2 stream compositions typical for pre-combustion capture and oxyfuel combustion. Recommendations for material selection for compression, transport and injection were derived for various CO2 stream compositions. To reliably control corrosion, a limitation of water contents to 50 ppmv is recommended for pipeline transportation of all CO2 streams. At geological storage conditions, the presence of either O2, NOx or SO2 only weakly affected fluid-mineral/rock interactions that still impacted geomechanical rock properties. KW - CCS KW - Impurities KW - Associated incidental substances KW - Pipeline design KW - Corrosion KW - Fluid-rock interactions PY - 2016 UR - http://www.sciencedirect.com/science/article/pii/S1750583616305047 DO - https://doi.org/10.1016/j.ijggc.2016.08.019 SN - 1750-5836 SN - 1878-0148 VL - 54 IS - 2 SP - 682 EP - 701 PB - Elsevier AN - OPUS4-38401 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Alves, H. A1 - Behrens, R. A1 - Kurumlu, D. A1 - Bäßler, Ralph T1 - High performance alloys to mitigate corrosion in the energy industry - a contribution to a clean environment N2 - In order to evaluate materials for components in geothermal brines with high salt content a range of corrosion resistant materials has been selected for corrosion testing, comprising the materials alloy 31, 625, 59, 2120 and titanium Ti Gr. 2. Testing was done in an artificial brine simulating the natural conditions of the North German Basin at the Groß Schönebeck location with high salt content (165 g/l Cl-) and a test temperature of 150 °C. Pitting corrosion had occurred on alloys 31 and 625 after potentiodynamic polarization. The results obtained on the alloys 59, 2120 and Ti Gr.2 indicate that these materials are offering sufficient resistance to the various forms of corrosive attack as they might occur in geothermal saline services of this kind. For the most aggressive service conditions as they may occur in flue gas desulfurization, waste incineration, other aspects of environmental engineering and beyond, a new nickel alloy with 21 % Cr and 19 % Mo has been developed recently. The new alloy 2120 is the first Ni-Cr-Mo alloy to contain nitrogen as an alloying constituent. Together with the chromium and the increased molybdenum content the alloying with nitrogen results in a pitting resistance equivalent number (PREN) of about 86 and a corresponding high resistance to pitting and crevice corrosion, surpassing the nickel-chromium-molybdenum alloys being commonly in use so far. The alloy is easily manufactured into the various shapes which are needed in flue gas desulfurization, waste incineration and other industrial equipment. Depending on the wall thickness welding can be done using a matching filler or without filler metal. T2 - EUROCORR 2013 - The European corrosion congress CY - Estoril, Portugal DA - 01.09.2013 KW - Alloy 31 (EN 1.4562, UNS N08031) KW - Alloy 31 plus KW - Alloy 625 (EN 2.4856, UNS N06625) KW - Alloy C-276 (EN 2.4819, UNS N10276) KW - Alloy 59 (EN 2.4605, UNS N06059) KW - Alloy 2120 (EN 2.4700, UNS N06058) KW - Titanium Ti Gr. 2 (DIN 3.7035, UNS R50400) KW - Geothermal brines KW - Flue gas desulfurization KW - Pitting corrosion KW - Crevice corrosion PY - 2013 SN - 978-989-8601-31-5 SP - 1 EP - 13 (Paper 1238) AN - OPUS4-29478 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mundhenk, N. A1 - Huttenloch, P. A1 - Bäßler, Ralph A1 - Kohl, T. A1 - Steger, H. A1 - Zorn, R. T1 - Electrochemical study of the corrosion of different alloys exposed to deaerated 80 °C geothermal brines containing CO2 N2 - Corrosion of metallic engineering materials accounts for problems during geothermal operation in the Upper Rhine Graben (URG). Herein, we study the electrochemical behaviour of various metal alloys in an 80 °C simulated geothermal environment by using potentiodynamic polarisation and open-circuit potential measurements. Two different natural geothermal waters from URG geothermal sites were used for the experiments. The measurements reveal spontaneous passivation to be a key process for all alloys. This ennoblement protects more noble alloys from significant corrosion (e.g. titanium gr. 2, alloy 625) and brings less noble alloys to failure, mostly due to pitting corrosion (e.g. 316L). KW - A. Alloy KW - B. Polarization KW - C. Passivity KW - C. Pitting corrosion KW - C. Repassivation KW - C. Thermodynamic diagrams PY - 2014 DO - https://doi.org/10.1016/j.corsci.2014.03.027 SN - 0010-938X VL - 84 SP - 180 EP - 188 PB - Elsevier Ltd. CY - Orlando, Fla. AN - OPUS4-30634 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Yevtushenko, Oleksandra A1 - Hattendorf, H. T1 - Electrochemical characterization of high alloyed materials in molten salts for solar energy applications N2 - Within the last years the use of feasible alternative energy sources has risen and is going to replace fossil resources more and more. Nevertheless, service conditions in solar facilities are due to the chemical composition of heat transmission media and temperatures, in many cases, extreme in terms of corrosion. Since the construction of power plants shall be economical with maximum life service, materials selection based on preliminary material qualification is essential to guarantee a secure and reliable operation of those facilities. The materials selection depends on the operation temperature of a power plant on the chemical composition of the transmission fluid used. In high corrosive environments Ni-based alloys are often used as an all-round solution for the construction of corrosion resistant parts, because of their good corrosion properties. However, there might be limits for their use regarding their corrosion behavior, with which this contribution deals. Experiences from the electrochemical characterization of materials in aqueous solutions are transferred to molten salts, providing a good addition to common exposure tests at temperatures from 450 0C to 600 0C. By means of electrochemical measurements and exposure tests the suitability of high alloyed materials in molten nitrate salt (60 % NaNO3/40 % KNO3) can be characterized. The method was verified on different Ni-based alloys (UNS N08810, UNS N06600) and Titanium (UNS R50250). T2 - NACE International Corrosion Conference 2015 CY - Dallas, TX, USA DA - 15.03.2015 KW - Localized corrosion KW - Nickel based alloys KW - Solar energy KW - Renewables KW - Electrochemical characterization KW - UNS N08810 KW - UNS N06600 KW - UNS R50250 PY - 2015 SP - paper 5659, S. 1 EP - 9 AN - OPUS4-34748 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bäßler, Ralph A1 - Sobetzki, Joana A1 - Sarmiento Klapper, H. T1 - Korrosionsbeständigkeit: Beurteilung von Werkstoffen für den Einsatz in Geothermieanlagen N2 - Aufgrund der extremen Betriebsbedingungen in Geothermieanlagen des Norddeutschen Beckens ist die Werkstoffauswahl für ober- und untertägige Komponenten entscheidend für einen sicheren und zuverlässigen Betrieb. Im Rahmen der Werkstoffqualifizierung wurden mittels klassischer Auslagerung und elektrochemischen Untersuchungen an zwei hochlegierten Stählen deren Einsatzgrenzen für die Förderung von hochsalinarem Aquiferfluid der geothermischen Tiefbohrung in Groß Schönebeck ermittelt. Die Ergebnisse und daraus resultierende Schlussfolgerungen werden hier vorgestellt. KW - Korrosion KW - Geothermie PY - 2013 SN - 1611-1478 VL - 64 IS - 1 SP - 92 EP - 96 PB - WVGW, Wirtschafts- u. Verl.Ges. Gas und Wasser CY - Bonn AN - OPUS4-27681 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bäßler, Ralph A1 - Sarmiento Klapper, H. A1 - Burkert, Andreas T1 - Korrosionsbeständigkeit von Werkstoffen für den Einsatz in Geothermieanlagen N2 - Für den sicheren und zuverlässigen Betrieb von Geothermieanlagen ist, aufgrund der extremen Betriebsbedingungen, die Werkstoffauswahl für bohr- und verfahrenstechnische Einrichtungen entscheidend. Es werden die im Rahmen der Werkstoffqualifizierung für zwei hochlegierte Stähle durch elektrochemische Untersuchungen und klassische Auslagerungsversuche ermittelten Einsatzgrenzen im Bereich geothermischer Tiefenbohrungen für die Förderung des hochsalinen Aquiferfluids von Groß Schönbeck dargestellt. KW - Korrosion KW - Geothermie PY - 2012 SN - 0948-6615 VL - 21 IS - 74 SP - 26 EP - 29 PB - GtV-Service GmbH CY - Berlin AN - OPUS4-27620 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ackermann, H. A1 - Bäßler, Ralph T1 - Entwicklung einer Prüfmethode zur Bewertung der Materialbeständigkeit von Bauteilen in Mitteldestillatanwendungen N2 - Damit stehen neben den klassischen (Massenänderung der Werkstoffprüfkörpern und metallographischer Bewertung) neue Auswertemethoden für die Werkstoffbewertung zur Verfügung. T2 - DGMK Projekttreffen CY - Hamburg, Germany DA - 28.02.2018 KW - Korrosion KW - Brennstoff PY - 2018 AN - OPUS4-44932 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Schmidt, C. A1 - Alves, H. T1 - Recent experiences on suitability of titanium and high alloyed materials in acids at 200°C N2 - In the literature there are not much data available to describe the corrosion behavior of titanium, nickel alloys and special stainless steels in acids at high temperature, in particular above the boiling point. Therefore, a laboratory testing program was performed with two titanium alloys (UNS R50400 and UNS R53400) to obtain corrosion data in formic acid, acetic acid, phosphoric acid, polyphosphoric acid, p-toluene sulfonic acid and lactic acid at 200 °C. Results were compared to previously published ones obtained on UNS N08031, UNS N06059 and UNS N10665. From the results it can be concluded that titanium does not always show better corrosion resistance than Ni-based alloys. UNS N06059 was the best choice for formic and acetic acids at temperatures of 200 °C. Both Ti-alloys are resistant in acetic acid. Some slight differences were observed for formic acid, where UNS R50400 is only resistant up to a 20 % solution and UNS R53400 in concentrated acid too. The phosphoric acid is extremely corrosive and none of the investigated materials was resistant. In the diluted acid (5 %) only UNS R53400 is resistant, whereas in 1 % solution all investigated materials performed satisfactory. UNS N10665 and UNS N06059 showed the best behavior in polyphosphoric acid. In 30 % concentrated p-toluene sulfonic acid at 200 °C all alloys tested were unsuitable. In very diluted acid (0.1 %) both Ti-alloys and the other three alloys behaved well. In lactic acid at 180 °C increased corrosion underneath deposits was detected; the best performance was observed for UNS N06059 and UNS R50400. T2 - NACE International Corrosion Conference 2015 CY - Dallas, TX, USA DA - 15.03.2015 KW - Titanium grade 2 (UNS 50400) KW - grade 12 (UNS 53400) KW - alloy 59 (UNS N06059) KW - alloy 31 (UNS N08031) KW - alloy B-2 (UNS N10665) KW - Inorganic acids KW - Organic acids KW - Corrosion PY - 2015 SP - paper 5658, S. 1 EP - 13 AN - OPUS4-34749 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -