TY - JOUR A1 - Skopp, André A1 - Klaffke, Dieter A1 - Buchkremer-Hermanns, H. A1 - Ren, H. A1 - Weiß, H. T1 - Tribological behavior of MW PACVD diamond coatings in vibrating contacts KW - Diamond coatings KW - Chemical vapour deposition KW - MW PACVD KW - Vibrating contacts KW - Steel/diamond pairings KW - Running-in KW - Wear KW - SEM KW - EDX KW - LRS KW - AFM KW - Surfaces KW - Wear scar KW - Transfer layer KW - Debris PY - 1997 SN - 1354-4063 SN - 1557-685X VL - 4-1 SP - 3 EP - 27 PB - Coppin CY - Deal AN - OPUS4-2429 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Skopp, André A1 - Klaffke, Dieter A1 - Buchkremer-Hermanns, H. A1 - Ren, H. A1 - Weiß, W. ED - Bartz, Wilfried J. T1 - Oscillating sliding behavior of MW PACVD diamond coatings T2 - 10th International Colloquium CY - Esslingen, Germany DA - 1996-01-09 PY - 1996 SN - 3-924813-34-5 N1 - Serientitel: Internationales Kolloquium / Technische Akademie Esslingen – Series title: Internationales Kolloquium / Technische Akademie Esslingen IS - 10 SP - 1943 EP - 1959 PB - Techn. Akad. Esslingen CY - Ostfildern AN - OPUS4-2419 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Skopp, André A1 - Klaffke, Dieter A1 - Buchkremer-Hermanns, H. A1 - Ren, H. A1 - Weiß, W. T1 - Tribotest journalTribological behavior of MW PACVD diamond coatings in vibrating contacts PY - 1997 SN - 1354-4063 SN - 1557-685X VL - 4-1 SP - 3 EP - 27 PB - Coppin CY - Deal AN - OPUS4-2420 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schartel, Bernhard A1 - Weiß, André A1 - Sturm, Heinz A1 - Kleemeier, M. A1 - Hartwig, A. A1 - Vogt, C. A1 - Fischer, R.X. T1 - Layered silicate epoxy nanocomposites: formation of the inorganic-carbonaceous fire protection layer N2 - The layered silicate (LS) modification and processing parameters applied control the morphology of the LS/polymer composites. Here, increasing the surface area of the LS particles by using alternative drying processes increases dispersion towards a more typical nanocomposite morphology, which is a basic requirement for promising flame retardancy. Nevertheless, the morphology at room temperature does not act itself with respect to flame retardancy, but serves as a prerequisite for the formation of an efficient surface protection layer during pyrolysis. The formation of this residue layer was addressed experimentally for the actual pyrolysis region of a burning nanocomposite and thus our results are valid without any assumptions or compromises on the time period, dimension, surrounding atmosphere or temperature. The formation of the inorganic-carbonaceous residue is influenced by bubbling, migration, reorientation, agglomeration, ablation, and perhaps also delamination induced thermally and by decomposition, whereas true sintering of the inorganic particles was ruled out as an important mechanism. Multiple, quite different mechanisms are relevant during the formation of the residue, and the importance of each mechanism probably differs from one nanocomposite system to another. The main fire protection effect of the surface layer in polymer nanocomposites based on non-charring or nearly non-charring polymers is the increase in surface temperature, resulting in a substantial increase in reradiated heat flux (heat shielding). KW - Nanocomposite KW - Fire retardancy KW - Epoxy resin KW - Fire behavior KW - Flammability PY - 2011 DO - https://doi.org/10.1002/pat.1644 SN - 1042-7147 SN - 1099-1581 VL - 22 IS - 12 SP - 1581 EP - 1592 PB - John Wiley & Sons, Ltd. CY - Chichester AN - OPUS4-24916 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weiß, André T1 - Epoxy layered silicate nanocomposites: Modified cone calorimeter tests in order to investigate barrier formation and its mode of action T2 - FRPM07 11th European Meeting on Fire Retardant Polymers CY - Bolton, England DA - 2007-07-04 PY - 2007 AN - OPUS4-15040 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sturm, Heinz A1 - Schartel, Bernhard A1 - Weiß, André A1 - Braun, Ulrike T1 - SEM/EDX: Advanced investigation of structured fire residues and residue formation N2 - Heterogeneous, gradual or structured morphology of fire residues plays an important role in fire retardancy of polymers. A scanning electron microscope with an attached energy dispersive X-ray spectrometer (SEM/EDX) is highlighted as a powerful tool for the advanced characterization of such complex fire residues, since it offers high resolution in combination with both good depth of field and analysis of chemical composition. Two examples are presented: First, comprehensive SEM/EDX investigation on a complex structured fire residue of glass fibre reinforced polyamide 6,6 (PA 66-GF) flame retarded by diethylaluminium phosphinate, melamine polyphosphate and some zinc borate. A multilayered surface crust (thickness ~ 24 µm) covers a rather hollow area stabilized by GF glued together. The resulting efficient thermal insulation results in self-extinguishing before pyrolysis is completed, even under forced-flaming combustion. Second, sophisticated, quasi online SEM/EDX imaging of the formation of residual protection layer in layered silicate epoxy resin nanocomposites (LSEC). Burning specimens were quenched in liquid nitrogen for subsequent analyses. Different zones were distinguished in the condensed phase characterized by distinct processes such as melting and ablation of organic material, as well as agglomeration, depletion, exfoliation and reorientation of the LS. KW - Fire residue KW - SEM/EDX KW - Fire retardancy KW - PA 66 KW - Layered silicate KW - Diethylaluminium phosphinate PY - 2012 DO - https://doi.org/10.1016/j.polymertesting.2012.03.005 SN - 0142-9418 VL - 31 IS - 5 SP - 606 EP - 619 PB - Elsevier CY - Amsterdam AN - OPUS4-25802 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -