TY - JOUR A1 - Lee, J.J. A1 - Buurman, Merwe A1 - Rice, C.A. A1 - Suhm, M.A. A1 - Stamm, A. A1 - Zimmer, M. A1 - Gerhards, M. T1 - Adaptive aggregation of peptide model systems JF - The journal of physical chemistry / A N2 - Jet-cooled infrared spectra of acetylated glycine, alanine, and dialanine esters and their dimers are reported in the amide A and amide I–III regions. They serve as particularly simple peptide aggregation models and are found to prefer a single backbone conformation in the dimer that is different from the most stable monomer backbone conformation. In the case of alanine, evidence for topology-changing chirality discrimination upon dimer formation is found. The jet spectroscopic results are compared to gas phase spectra and quantum chemical calculations. They provide reliable benchmarks for the evaluation of the latter in the field of peptide interactions. KW - Jet-cooled infrared spectra KW - Peptide aggregation KW - Quantum chemical calculations PY - 2013 DO - https://doi.org/10.1021/jp400056n SN - 1089-5639 SN - 1520-5215 N1 - Geburtsname von Buurman, Merwe: Albrecht, M. - Birth name of Buurman, Merwe: Albrecht, M. VL - 117 IS - 32 SP - 7050 EP - 7063 PB - Soc. CY - Washington, DC AN - OPUS4-29025 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -