TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph A1 - Carrillo Salgado, I. T1 - Material challenge for carbon capture and storage - Crevice corrosion susceptibility of super austenitic stainless steel UNS NO8031 (alloy 31) and duplex stainless steel S32101 in CO2 saturated saline brine N2 - Corrosion resistance of duplex stainless Steel UNS S32101 and super austenitic stainless Steel UNS NO8031 (alloy 31) was investigated in crevice conditions in a corrosive environment (saline brine, T = 60 °C, C02-flow rate 3-5 L/h, normal pressure) using electrochemical and metallographic techniques. Rectangular rubber was used to form a metal/non-metal-crevice configuration. Potentiodynamic measurements have been carried out in order to determine critical pitting and repassivation potentials. Potentiostatic measurements at different Potentials have been performed and the dependence of pit depth on the potential applied in crevice conditions was investigated. It was shown that the repassivation potential of duplex stainless Steel S32101 coincides with its corrosion potential. Strang pitting corrosion occurred after potentiodynamic measurements with pit depths up to 100 pm. Otherwise, stainless Steel UNS NO8031 shows about 0.5 V difference between the free corrosion potential and the repassivation potential and did not show any signs of pitting corrosion after polarization measurements. Slight rouging effects have been observed. By potentiostatic measurements on duplex stainless Steel S32101 potentials slightly more positive than the corrosion Potentials causing strong pitting corrosion, and pit depths up to 650 pm were measured. Super austenitic stainless Steel UNS NO8031 did not exhibit any signs of pitting corrosion even by applying potentials much more positive than the corrosion potential. T2 - NACE International Corrosion Conference 2013 CY - Orlando, FL, USA DA - 17.03.2013 KW - CO2 KW - Saturated saline brine KW - Crevice corrosion KW - Pitting corrosion KW - Electrochemical measurements PY - 2013 SN - 978-1-627-48145-8 SP - 1 EP - 8 (Paper 2427) PB - Curran CY - Red Hook, NY AN - OPUS4-28964 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph A1 - Carrillo-Salgado, I. T1 - Corrosion stability of piping steels in a circulating supercritical impure CO2 environment N2 - Within the project COORAL (German acronym for ''C02 purity for capture and storage") studies on pipeline steels exposed to circulating supercritical impure C02 have been carried out. For this purpose, a loop consisting of compressors, flow meter and two autoclaves was constructed. In order to simulate the real conditions in pipelines, impurities such as H20, CO, S02, N02 and 02 were added to the C02 stream before compression. Exposure experiments were carried out with Steel specimens placed in the autoclaves. Carbon Steel L360NB, pure iron X20Cr13, X46Cr13, X2CrMnNiN22-5-2 and alloy 31 have been exposed to circulating (flow rate 4 L/min) supercritical impure C02 for one week at 60 °C and 10 MPa Surface analysis and weight loss experiments in order to determine the corrosion products and the corrosion rates showed that the impurities cause corrosion problems. Slight general corrosion by L360NB and soft iron was observed. The initiation of pitting corrosion was observed at the surfaces of the materials X20Cr13, X46Cr13, X2CrMnNiN22-5-2. No visible signs of corrosion have been observed on alloy 31. T2 - NACE International Corrosion Conference 2013 CY - Orlando, FL, USA DA - 17.03.2013 KW - Supercritical circulating CO2 KW - Impurities KW - Exposure test KW - Corrosion PY - 2013 SN - 978-1-627-48145-8 SP - 1 EP - 11 (Paper 2372) PB - Curran CY - Red Hook, NY AN - OPUS4-28965 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph A1 - Carrillo-Salgado, I. T1 - Corrosion resistance of piping steels in circulating supercritical impure CO2 environment due to moisture, SO2 and NO2 impurities T2 - EUROCORR 2013 CY - Estoril, Portugal DA - 2013-09-01 PY - 2013 AN - OPUS4-28968 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph A1 - Carrillo-Salgado, I. T1 - Corrosion of pipeline steels due tot the condensation effects caused by SO2 and NO2 impurities in CO2 T2 - EUROCORR 2012 CY - Istanbul, Turkey DA - 2012-09-09 PY - 2012 AN - OPUS4-27064 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph A1 - Carrillo-Salgado, I. T1 - Corrosion stability of piping steels in a circulating supercritical impure CO2 environment T2 - NACE 2013 CY - Orlando, FL, USA DA - 2013-03-17 PY - 2013 AN - OPUS4-27065 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph A1 - Carrillo-Salgado, I. T1 - Material challenge for CCS - crevice corrosion susceptibility of alloy 31 and duplex steel S32101 in CO2 saturated saline brine T2 - NACE 2013 CY - Orlando, FL, USA DA - 2013-03-17 PY - 2013 AN - OPUS4-27066 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Bäßler, Ralph A1 - Yevtushenko, Oleksandra A1 - Carrillo Salgado, I. T1 - Corrosion behavior of highly alloyed steels in artificial saline aquifer fluids containing carbon dioxide KW - Highly alloyed steels KW - Carbon dioxide KW - Pitting corrosion PY - 2012 SN - 0430-6252 VL - 9 IS - 2 SP - 393 EP - 396 CY - L'viv, Ukrainian national academy of science AN - OPUS4-26056 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph ED - Lexow, J. ED - Kishi, T. ED - Kitagawa, M. ED - Böllinghaus, T. T1 - Electrochemical studies on pitting corrosion on Cr13 steel exposed to CO2 and artificial brine with high chloride concentration N2 - Within the project COORAL (German acronym for 'CO2 purity for capture and storage') first studies on piping steels exposed to CO2 and artificial brine with high chloride concentration have been carried out. Corrosion behavior of martensitic Cr13 steel (1.4034) was investigated in a corrosive environment (artificial saline brine, T = 60 °C, CO2-flow rate 3 – 5 L/h, atmospheric pressure, exposure times from 1 h up to 14 days) using electrochemical and metallographic techniques. Different corrosion kinetics were observed as a function of exposure times and chloride concentration in the artificial brine. In CO2-saturated brine pitting corrosion was observed at free corrosion potential, whereas in the brine without addition of NaCl a stable passive layer built up. Predictions about corrosion mechanism are made and verified by means of surface analytical techniques. KW - Stainless steel KW - Pitting corrosion KW - Electrochemistry KW - Carbon dioxide PY - 2012 SN - 978-3-642-23347-0 SN - 978-3-642-23348-7 SP - 45 EP - 53 PB - Springer CY - Berlin Heidelberg AN - OPUS4-27393 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yevtushenko, Oleksandra A1 - Bäßler, Ralph T1 - Elektrochemische Untersuchungen in Nitratsalzschmelzen T2 - GfKorr Arbeitskreissitzung Korrosion und Korrosionsschutz von Eisen und Stahl CY - Duisburg, Germany DA - 2013-12-03 PY - 2013 AN - OPUS4-29686 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bäßler, Ralph A1 - Yevtushenko, Oleksandra A1 - Hattendorf, H. T1 - Suitability of high alloyed materials in molten salts at 600 °C N2 - Within the last years the use of feasible alternative energy sources has risen and is going to replace fossil resources more and more. Nevertheless, service conditions in solar facilities are due to the chemical composition of heat transmission media and temperatures, in many cases, extreme in terms of corrosion. Since the construction of power plants shall be economical with maximum life service, materials selection based on preliminary material qualification is essential to guarantee a secure and reliable operation of those facilities. The materials selection depends on the operation temperature of a power plant on the chemical composition of the transmission fluid used. In high corrosive environments Ni-based alloys are often used as an all-round solution for the construction of corrosion resistant parts, because of their good corrosion properties. However, there might be limits for their use regarding their corrosion behavior, with which this contribution deals. By means of electrochemical measurements and exposure tests the suitability of two high alloyed materials X8NiCrSi38 18 and NiCr25FeAlYB in molten nitrate salt (60 % NaNO3/40 % KNO3) was characterized at 600 °C. T2 - NACE International Corrosion Conference CY - Vancouver, BC, Canada DA - 06.03.2016 KW - Localized corrosion KW - Nickel based alloys KW - Solar energy KW - Renewables KW - Electrochemical characterization KW - X8NiCrSi38-18 KW - NiCr25FeAlYB PY - 2016 SP - 7363-1 EP - 7363-9 CY - Houston, USA AN - OPUS4-36988 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -