TY - JOUR A1 - Steinborn, Gabriele A1 - Gemeinert, Marion A1 - Schmidt, Wolfram T1 - Vergleich verschiedener Messverfahren zur Partikelgrößenanalyse am Beispiel von nanodispersem ZrO2-Pulver N2 - Fünf verschiedene Messverfahren wurden zur Partikelgrößenanalyse von nanodispersen ZrO₂-Pulver verglichen. Mit der Laserstreulichtanalyse, der dynamischen Lichtstreuung (heterodyne DLS und homodyne DLS-PCS), der Sedimentationsanalyse im Zentrifugalfeld und der Ultraschallspektrometrie wurden wässrige ZrO₂-Suspensionen mit verschiedenen Feststoffkonzentrationen hinsichtlich ihrer Partikelgrößenverteilung analysiert. Als Referenz diente die REM-Analyse zur Ermittlung der Primärpartikelgröße (ca. 40 nm). Mit den hier vorgestellten Messverfahren konnten in den entsprechenden Suspensionen nur Sekundärpartikel im Bereich von 105 nm bis 224 nm detektiert werden, die somit auf das Vorhandensein von Aggregaten bzw. harten Agglomeraten hinweisen. T2 - Tagung, Produktgestaltung in der Partikeltechnologie CY - Berlin, Germany DA - 23.04.2015 KW - Agglomeration KW - Nanopulver KW - Partikelgröße KW - Suspension PY - 2016 DO - https://doi.org/10.1002/cite.201500164 SN - 0009-286 X VL - 88 IS - 7 SP - 984 EP - 994 PB - WILEY-VCH CY - Weinheim AN - OPUS4-36960 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Wolfram T1 - Cement proficiency testing scheme for Africa T1 - Programm zur Eignungsprüfung von Zement in Afrika N2 - The German BAM Federal Institute for Materials Research and Testing in collaboration with the German Metrology Institute (PTB) are organising an Africa wide Proficiency Testing Scheme for the year 2014 on the testing of cement. The Pan-African Cement Proficiency Testing Scheme PACE-PTS is the second Africa-wide proficiency testing scheme after a first transaction in 2012/2013, where 26 private and public constniction materials testing laboratories from 20 African nations were registered. The testing Programme comprises testing of the major Chemical and physical properties of cement. The testing is conducted according to EN 196. The PACE-PTS is open for private and public laboratories in Africa and the registration is open until March 15, 2014. PY - 2014 SN - 0373-4331 SN - 1865-6528 N1 - Sprachen: Deutsch/Englisch - Languages: German/English VL - 80 IS - 3 SP - 4 PB - Bauverl. CY - Gütersloh AN - OPUS4-30828 LA - mul AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Einfluss der Partikelvolumenfraktion auf die Rheologie und die Effektivität von Polysaccharid-Stabilisierern in Gegenwart von Polycarboxylatether-Fließmitteln T2 - 19. Internationale Baustofftagung (ibausil) CY - Weimar DA - 2015-09-16 PY - 2015 AN - OPUS4-34499 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Correlation between setting, heat evolution, and deformations of cementitious binder systems depending on type and amount of superplasticizer T2 - XIII ICCC - International Congress on the Chemistry of Cement CY - Madrid, Spain DA - 2011-07-03 PY - 2011 AN - OPUS4-24019 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Process Control of the Rheology of Self-Compacting Concrete Based on Cusum Control Charts T2 - 23. Workshop und Kolloquium "Rheologische Messungen an Baustoffen", Regensburg 2015 CY - Regensburg, Germany DA - 2015-03-11 PY - 2015 AN - OPUS4-33565 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Priebe, Nsesheye Susan A1 - Schmidt, Wolfram A1 - Mota, Berta A1 - Leinitz, Sarah A1 - Kühne, Hans-Carsten A1 - Rogge, Andreas T1 - The effect of superplasticizers on rheology and early hydration kinetics of rice husk ash-blended cementitious systems N2 - Superplasticizers (SPs) have been employed in concrete technology for decades to improve the workability of concrete in its fresh state. The addition of SPs in cement-based systems affects the early properties. Although the interaction of the cement particles with various SPs has been extensively researched, there still exists limited research on the interaction of SPs with supplementary cementitious materials such as rice husk ash (RHA). This paper investigates the rheological properties and early hydration kinetics of RHA-blended systems with three types of SPs, a polycarboxylate ether (PCE) and two lignosulphonates (LS-acc and LS-ret). In rheological properties, the addition of SP causes an initial improvement of workability as the yield stress is significantly reduced. The pastes with PCE and LS-acc show a slight increase of yield stress over time whereas pastes with LS-ret tend to lower the yield stress slightly over time, further improving the workability. Without SP, pastes with RHA show a lower yield stress but an increase in plastic viscosity as cement is further replaced with RHA. The addition of the LS SPs is observed to lower the plastic viscosity but remains constant with further replacement of cement with RHA. This indicates that LS SPs further adsorbs on RHA particles and hydration products produced causing dispersion of the particles within the system. In early hydration kinetics, pastes with PCE retard hydration and the degree of retardation is further increased with LS SPs. In the presence of RHA, the retardation of LS SP systems is significantly reduced. The pastes with PCE show more ettringite in the SEM micrographs, but is observed to be shorter needles. This indicates an initial good workability for PCE. However, C-S-H and CH were observed to be low in quantity, whereby the pastes with LS show more nucleation sites for C-S-H and CH. The ettringite needles in the LS systems were similar in quantity and more elongated in some cases but not abundant as in the PCE systems. KW - Plastic viscosity KW - Cement KW - CO2 reduction KW - Supplementary cementitious materials KW - Rice husk ash KW - Superplasticizers KW - Hydration KW - Rheology KW - Yield stress KW - Slump flow PY - 2017 UR - http://www.sciencedirect.com/science/article/pii/S0950061817310978?via%3Dihub DO - https://doi.org/10.1016/j.conbuildmat.2017.05.197 SN - 0950-0618 SN - 1879-0526 N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. VL - 150 SP - 511 EP - 519 PB - Elsevier Ltd. AN - OPUS4-41036 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Promising bio-based material solutions for more sustainable concrete N2 - Today, concrete engineers can vary consistencies between very stiff and self-compacting. At the same time engineers can opt for a vast variety of binders. The possibility to use optimised mineral binders and to tailor rheological properties of concrete eventually opened up the path to multiple new technologies, where design criteria are no longer limited to the Young’s modulus and the compressive strength, but often comprise additional added value. It can therefore be concluded that the capability to control the rheology and the interactions particles can be considered as the catalyst for concrete innovations such as polymer modified cementitious composites (PCC) self-compacting concrete (SCC), high-performance concrete (HPC), ultra-high performance concrete (UHPC) or strain hardening cement based composites (SHCC). In the same way rheology modifying additions, SCMs and admixtures will become key parameters in mastering the challenges of the next decades such as: - Additive manufacturing/3D-printing - Overcoming pumping height limitations - Casting at extreme temperatures - Tailored rheology at delivery In many regions in the Southern hemisphere the effective use of SCMs, additions and chemical admixtures for concrete could significantly contribute to solve problems induced by the challenging climatic conditions, but particularly in many countries with challenging climatic conditions, it is difficult to use them, due to lacking local supply and supply infrastructure, and often the awareness of the value of local mineral resources is missing. However, the long distance transportation of mineral resources and chemicals is not very environmentally friendly and the economic consequences are dramatic. However, bio-based constituents and chemicals have been used in construction for ages effectively. Due to the enormous relevance of binders, fillers and rheology modifying admixtures it is worthwhile to recollect that nature provides an enormous variety of products that can be used readily or with low processing. Today, the use of petrol based polycarboxylate ether superplasticizers has become quite common in concrete technology due to their versatility, but their uncomplicated and cost efficient availability is limited in many countries in the world. However, alternatives are available, which can be found locally. In addition many agricultural wastes today are dumped, although they could be converted to reactive ashes easily. Plant extracts have been used to modify the properties of concrete for long time. These plants are typically regionally abundantly available, cheap, and they are environmental friendly. They do not require special caring for seedlings, weeding or manuring to grow since they grow wildly. The talk will present an overview of various options for binders, fillers and rheology modifying admixtures, that can be found in nature, and that may become a real alternative, once their interaction within the complex cementitious system is well understood. T2 - Peak Forum on Sustainable Civil Engineering Materials CY - Shanghai, China DA - 18.05.2017 KW - Cement KW - Concrete KW - Sustainability KW - Bio-based materials KW - Polysaccharides KW - Supplementary cementitious materials PY - 2017 AN - OPUS4-41031 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Influence of nano scale effects on the macroscopic rheology N2 - Chemical admixtures like superplasticisers or stabilising agents are of ever increasing importance for modern concrete technology. They liberate the workability of concrete from its dependency on water content, and thus, open the gate towards innovative and future oriented concrete technologies. Meanwhile admixtures have become common practice in concrete technology, but the understanding of these highly complex polymers in the entire concrete system lags far behind their application. Due to its complex time-dependent, multi-phase and multi-scale behaviour, flowable concrete systems are highly complicated and cannot be described comprehensively by simple models. It is therefore extremely challenging to identify the relevant parameters that predominantly control flow phenomena on different size scales, since these may occur on any scale between the nano scale (e.g. superplasticizer adsorption) and macro scale (e.g. grading of the aggregates). The present study discusses fundamental mechanisms at the interface between particle or hydrate surfaces and the fluid phase at a very early stage of concrete formation, and links these effects to macroscopic flow phenomena. Based on the observations of the nano scale effects, it seems that higher sensitivity against variations in the constituents, the handling, or the boundary condition are the inevitable price for higher performances. However, eventually a very effective method is introduced that helps to maintain stable processes regardless of the root cause for performance changes based on an efficient in-situ process control scheme and superplasticizer and stabilising agents as counter actions. T2 - International Workshop on Nano-Engineered Meta-materials for Civil Infrastructures CY - Jinan, China DA - 20.5.2017 KW - Rheology KW - Meta materials KW - Nano engineering KW - Admixtures KW - Cement KW - Ettringite PY - 2017 AN - OPUS4-41032 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram A1 - Priebe, Nsesheye Susan A1 - Pirskawetz, Stephan A1 - Kühne, Hans-Carsten ED - Amziane, Sofiane ED - Sonebi, M. ED - Charlet, K. T1 - Efficiency of high performance concrete types incorporating bio-materials like rice husk ashes, cassava starch, lignosulfonate, and sisal fibres N2 - Over the last decades concrete has evolved from a simple mass construction material towards a sophisticated multi-component system. The design parameters for the mixture composition of concrete have significantly increased from strength based towards overall or specific performance based. As a result the variety of concrete has increased yielding a number of special concrete technologies such as Self-Compacting Concrete (SCC), High-Performance Concrete (HPC), Strain Hardening Cement Based Composites (SHCC), and many others. Due to their complex mixture compositions and a multitude of possible interactions between constituents, these concrete types are preferably composed of special components like well-defined powders and sophisticated chemical admixtures. This makes such concrete technology expensive and limits their application to regions with the required material supply chains. The paper puts focus on materials, which are less well studied in conjunction with high performance concrete, but which are available in many developing countries, and in particular sub-Saharan Africa. The paper shows how sec can be designed without polycarboxylate ether superplasticizer and well defined fillers, but with lignosulphonate, cassava starch and rice husk ash. The positive effect of well processed rice husk ashes is demonstrated. Furthermore results are presented of SHCC where typical components like polyvinyl alcohol fibres and fluy ash are replaced by sisal fibres and limestone filler, respectively. The results point out that high performance concrete applications do not have to be limited to a boundary framework with availability of well-defined raw material supply structures and sophisticated admixtures or fibres. Concepts are presented how innovative concrete technologies can be developed based on indigenous materials. T2 - ICBBM 2015 - 1st International conference on bio-based building materials CY - Clermont-Ferrand, France DA - 22.06.2015 KW - Corrosion potential KW - Chloride migration KW - Electrical resistivity KW - Water absorption KW - Freeze-thaw PY - 2015 SN - 978-2-35158-154-4 N1 - Serientitel: Rilem proceedings – Series title: Rilem proceedings N1 - Geburtsname von Priebe, Nsesheye Susan: Msinjili, N. S. - Birth name of Priebe, Nsesheye Susan: Msinjili, N. S. IS - PRO 99 SP - 208 EP - 214 AN - OPUS4-33583 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schmidt, Wolfram T1 - Einsparpotenziale bei der Produktion von selbstverdichtendem und hochfestem Beton für Betonfertigteile N2 - Im Betonbau hat sich im Laufe der vergangenen Jahrzehnte ein grundlegender Wandel von einer Massenanwendung hin zu einer innovativen, zukunftsorientierten und leistungsbasierten Baustofftechnologie vollzogen. Heute besteht Beton nicht mehr lediglich aus Zement, Wasser und Gesteinskörnungen, sondern kann durch die Verwendung von Zusatzstoffen und chemischen Zusatzmitteln signifikant verbessert werden. Der im Bereich der Zusatzmittel erzielte Fortschritt ebnete zudem den Weg für die Entwicklung neuer Betontypen wie zum Beispiel selbstverdichtender Beton (SVB) und Hochleistungsbeton (HLB), indem die Verarbeitbarkeit vom Wasser-Zement-Wert (w/z) abgekoppelt wurde. Während der w/z und die Sieblinie der Gesteinskörnungen bei herkömmlichen Betontypen die für die Verarbeitbarkeit relevanten Mischungsparameter darstellten, weisen SVB und HLB komplexere Leistungsparameter auf; in puncto Leistungsfähigkeit fallen hier insbesondere die Mehlkornkomponenten ins Gewicht. Dadurch wird das System komplexer und zugleich anfälliger für Abweichungen bei der Produktion. Erschwert wird die Identifizierung möglicher Einsparpotenziale durch die Schwierigkeit der Vorhersage der Auswirkungen von Veränderungen im Produktionsprozess und bei der Mischung. KW - Selbstverdichtender Beton KW - Hochfester Beton KW - Packungsdichte KW - Fließmittel KW - Rheologie PY - 2016 VL - 2016 IS - 02 SP - 80 EP - 83 PB - Ad-Media CY - Köln AN - OPUS4-36884 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Barthel, Maria A1 - Schmidt, Wolfram A1 - Kühne, Hans-Carsten A1 - Meng, Birgit ED - Rogge, A. ED - Meng, B. T1 - Betonpflastersteine mit erweiterten Leistungsmerkmalen T2 - 52. DAfStb-Forschungskolloquium CY - Berlin, Deutschland DA - 2011-11-07 PY - 2011 SN - 978-3-9814281-0-0 N1 - Geburtsname von Barthel, Maria: Meinel, M. - Birth name of Barthel, Maria: Meinel, M. SP - 194 EP - 203 PB - BAM Bundesanstalt für Materialforschung und -prüfung CY - Berlin AN - OPUS4-25182 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Bio-based additives, resins and polymers roles and performances T2 - ICBBM Pre-Conference Seminar: Sustainable Bio-materials from Bio-mass for Use in Construction CY - Clermont-Ferrand, France DA - 2015-06-21 PY - 2015 AN - OPUS4-33561 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram T1 - Supplementary Cementitious Materials an Admixtures - Part I: Supplementary Cementitious Materials T2 - Totally Concrete East Africa 2014 CY - Dar es Salaam, Tansania DA - 2014-10-28 PY - 2014 AN - OPUS4-32333 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -