TY - CONF A1 - Vasiliou, Eleni A1 - Schmidt, Wolfram A1 - Stefanidou, Maria A1 - Kühne, Hans-Carsten A1 - Rogge, Andreas ED - Amziane, Sofiane ED - Sonebi, Mohammed ED - Charlet, Karine T1 - Effectiveness of starch ethers as rheology modifying admixtures for cement based systems N2 - Polysaccharides are important rheology modifying admixtures in the building material sector. The use of starch is becoming increasingly important, due to many ecological and economic advantages. In the construction sector, starch ethers are being used as thickeners and as means to increase the yield stress. The starch ethers that are available on the market differ in their behaviour, which can vary greatly depending upon the binder system and mortar composition, e.g. solid volume content, binder type, additional admixtures. In view of the limited knowledge about the influence of molecular modifications associated with cement based systems, some fundamental rheological functional mechanisms were analysed in this study. The differently modified starch ethers used were derived from potatoes. They varied in their charges and degrees of hydroxypropylation. The setting and the flow behaviour of all examined variations of starch ethers were analysed in cement pastes. In order to illustrate the effects of the starch ethers that were used, the water-cement ratio (w/c) was held constant in all the mixtures [Schmidt 2012]. The results indicated significant differences in setting and flow behaviour. T2 - Second International RILEM Conference on Bio-based Building Materials CY - Clermont-Ferrand, France DA - 21.06.2017 KW - Rheology KW - Polysaccharides KW - Cement KW - Concrete KW - Starch KW - Polycarboxylate PY - 2017 SN - 978-2-35158-192-6 SP - 81 EP - 85 PB - RILEM S.A.R.L CY - Paris, France AN - OPUS4-43548 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Govin, A. A1 - Schmidt, Wolfram A1 - Bartholin, M. C. A1 - Grosseau, P. ED - Amziane, Sofiane ED - Sonebi, M. T1 - Effect of Guar Gum Derivatives Combined with Superplasticizers on Properties of Portland Cement-Pastes N2 - Chemical admixtures allow to the create a variety of fresh and hardened state properties in cementitious materials. In the case of self-compacting concrete, plasticizers or superplasticizers are introduced with the aim to decrease the yield stress and the viscosity of the materials. However, in order to prevent segregation and bleeding, and to improve the water retention of cement-based system, stabilizing agents or viscosity agents are often introduced in addition. Among these admixtures, polysaccharides are most commonly used. The aim of this study is to provide an understanding of competitive or synergetic effects induced by the combination of hydroxypropyl guar stabilizing agents (HPG) and superplasticizers on cement pastes. Two polycarboxylate superplasticizers (PCE) exhibiting different charge densities and one HPG were studied. It was found that the combination of HPG with PCE superplasticizer strongly affects the rheological behavior of cement pastes. Despite the presence of HPG, the viscosity of the pastes strongly decreased with increasing dosage of PCE until it became close to the viscosity of a cement paste with PCE only. However, the use of HPG in combination with PCE allows maintaining a significant yield stress in the cement paste compared to PCE alone. The increase in the charge density of the PCE seemed to amplify the drop of the viscosity and to reduce the gain on the yield stress induced by HPG. The results also highlight a delay in the setting-time of the cement paste by adding HPG and PCE. The delay induced by HPG is significantly lower than that generated by PCEs. However, the combination of the both kind of admixtures leads to a slightly shorter setting-time compared to the PCE alone. T2 - 2nd International Conference on Bio-based Building Materials & 1st Conference on ECOlogical valorisation of GRAnular and FIbrous materials CY - Clermont-Ferrand, France DA - 21.06.2017 KW - Guar gum KW - Polysaccharides KW - Superplasticizer KW - Cement KW - Rheology PY - 2017 VL - PRO 119 SP - 55 EP - 61 PB - RILEM Publications S.A.R.L. CY - Paris AN - OPUS4-41038 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -