TY - CONF A1 - Crasselt, Claudia A1 - Schmidt, Wolfram A1 - Sturm, Heinz T1 - Influence of rheology modifying admixtures on early hydration of cementitious suspensions T2 - PAPERS AND POSTERS PROCEEDINGS 15th International Congress on the Chemistry of Cement N2 - The presence of polycarboxylate ether (PCE) based superplasticizers (SPs) has enormous influence on the early hydration of cement. C3A as the most reactive phase of Portland cement plays a significant role in early hydration reactions and affects the rheological performance. Therefore, this paper presents experimental results about the influence of delayed addition of PCEs on the Hydration of cement and C3A-gypsum pastes investigated by isothermal heat flow calorimetry. Complementary in-situ XRD was carried out on C3A pastes to analyze hydration and phase changes related to the addition of PCE. Cement pastes with a delayed addition of PCE showed less Retardation compared to simultaneous addition. The alteration caused by PCE is much more pronounced for C3A-gypsum mixes. With a delayed addition of SP, the hydration of C3A is less retarded or even accelerated. It is obvious that there is less retardation the later the addition of SP. Furthermore, the PCE alter the hydration of C3A when added delayed and exhibit changes in kinetics and hydration rates. XRD results showed that more C3A is dissolved in the presence of PCE. Also, the gypsum depletion occurs earlier in the presence of PCE and even faster with delayed addition. Without PCE AFm starts to form just after the gypsum depletion. However, in the presence of PCE AFm already starts to form at the beginning of the hydration. Due to the faster gypsum depletion in the presence of PCE, also the transformation from ettringite into AFm begins earlier, but takes longer as without SP. T2 - 15th International Congress on the Chemistry of Cement CY - Prague, Czech Republic DA - 16.09.2019 KW - Cement KW - C3A KW - Early hydration KW - Polycarboxylate ether (PCE) KW - Delayed addition PY - 2019 SP - 1 EP - 8 AN - OPUS4-49104 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schmidt, Wolfram ED - Schmidt, Wolfram T1 - Engineering skill requirements to cope with the local and global challenges of the future T2 - ISEE Africa - Innovation, Science, Engineering, Education N2 - In the 21st century, adequate habitat and functioning infrastructure are critical for global societal and economic stability. In addition, growing urbanisation and environmental pollution cause challenges to societies. With increasing velocity, humanity faces that the current way of living is not sustainable. Thus, habitat,infrastructure, urbanisation, environment and sustainability are definitively among the most striking challenges of the 21st century. By consulting, planning, building, maintaining, exploiting and processing of global resources, civil engineers contribute significantly to the existence of these challenges. This is a high responsibility, but due to the heavy involvement, together with adjacent disciplines such as architecture, geosciences, chemistry, physics, environmental sciences and economics, civil engineers also hold the key to mitigate these challenges and provide a brighter global future. Solutions towards greener, more sustainable and economically viable materials do exist, and there is ongoing research on how greener technologies can contribute to better livelihood and economic growth, but their level of implementation is limited, a major reason for which is that these approaches require more fundamental understanding rather than standard application. T2 - ISEE Africa - Innovation, Science, Engineering, Education CY - Nairobi, Kenya DA - 30.01.2019 KW - Civil Engineering KW - Education KW - Sustainability KW - Materials KW - Sciences PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-484895 UR - http://isee-africa.com/wp-content/uploads/2019/07/Innovation-Science-Engineering-Education_High-Quality.pdf SN - 978-3-9818564-2-2 SP - 16 EP - 19 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-48489 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -