TY - THES A1 - Schempp, Philipp T1 - Grain refinement in aluminium GTA welds N2 - Grain refinement is an important opportunity to improve mechanical properties of fusion welds and the weldability (cracking sensitivity) of the base metal. In this thesis, grain refinement was achieved for aluminium welds by additions of a grain refiner. For this purpose, inserts consisting of aluminium base metal and small additions of commercial Al Ti5B1 grain refiner were cast, deposited in base metal plates, and fused in a gas tungsten arc (GTA) welding process. As a result, higher grain refiner additions increased the weld’s titanium and boron content resulting in a significant decrease in the weld metal mean grain size up to 86%. This grain size reduction led to a transition from predominantly columnar to equiaxed grain shape (columnar to equiaxed transition CET). The grain refinement was thereby found to be strongly dependent upon the base metal chemical composition. Accordingly, the grain refining efficiency was the highest in commercial pure Al (Alloy 1050A, Al 99.5), followed by Alloy 6082 (Al Si1MgMn) and Alloy 5083 (Al Mg4.5Mn0.7). In this regard, the parameters P and Q were applied to investigate the influence of alloying elements on the supply of constitutional undercooling during solidification and on final grain size. Also, WDS (wavelength dispersive x-ray spectroscopy) and TEM (transmission electron microscopy) analysis found an increasing number of particles rich in Ti and B. These substrates are probably TiB2 particles coated by Al3Ti likely nucleating Al grains during solidification. The variation in torch speed showed that increasing torch speeds support the CET effect leading to many small and equiaxed grains at high torch speed. To give explanations for this observation, the thermal conditions, that are controlled by welding parameters such as torch speed, were determined with temperature measurements via thermocouples. These measurements revealed that solidification parameters like solidification growth rate, cooling rate, (local) thermal gradient and solidification time vary significantly along the solidification front (from weld centreline to weld fusion line). In a further step, the solidification parameters were related to the corresponding grain size and shape. On the basis of this comparison, an analytical approach was used to model the CET. This allowed the prediction of critical values for both solidification growth rate and thermal gradient, at which the CET occurs in aluminium weld metal. The influence of grain refinement on the weld mechanical properties was investigated in tensile tests. Accordingly, the ductility of Alloy 5083 welds was increased through grain refinement whereas no improvement in weld metal strength was observed. Furthermore, tear tests with notched specimens revealed for Alloy 1050A that the resistance against initiation and propagation of cracks in the weld metal can be enhanced through grain refinement. In addition, when welding Alloy 6082, weld metal grain refinement prevented the formation of centreline solidification cracking that was present only in welds with unrefined grain structure. On the basis of the above experiments, the Ti/B contents needed in commercial filler wires or rods to allow optimum weld metal grain refinement were estimated. Accordingly, this work gives specific recommendations to filler material producers through a simple calculation that considers the influence of base alloy and welding process. The results show that the Ti/B contents defined by the corresponding standards for filler alloys are too low to allow weld metal grain refinement. T3 - BAM Dissertationsreihe - 111 KW - Aluminium KW - Kornfeinung KW - WIG-Schweißen PY - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-477 SN - 978-3-9815944-4-7 SN - 1613-4249 VL - 111 SP - 1 EP - 121 PB - Bundesanstalt für Materialforschung und -prüfung (BAM) CY - Berlin AN - OPUS4-47 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schempp, Philipp A1 - Cross, C.E. A1 - Häcker, Ralf A1 - Pittner, Andreas A1 - Rethmeier, Michael T1 - Influence of grain size on mechanical properties of aluminium GTA weld metal N2 - Grain refinement is an important possibility to enhance the mechanical properties such as strength, ductility and toughness of aluminium weld metal. In this study, grain refinement was achieved through the addition of commercial grain refiner Al Ti5B1 to gas tungsten arc weld metal of the aluminium alloys 1050A (Al 99.5) and 5083 (Al Mg4.5Mn0.7). The grain refiner additions led to a significant reduction of the weld metal mean grain size (Alloy 1050A, 86 %; Alloy 5083, 44 %) with a change in grain shape from columnar to equiaxed. Tensile tests showed for Alloy 5083 that the weld metal's ductility can be increased through grain refinement. No improvement in weld metal strength (i.e. yield strength and ultimate tensile strength) was observed. Furthermore, tear tests with notched specimens revealed that the resistance against initiation and propagation of cracks in the weld metal can be enhanced through grain refinement. The toughness was observed to increase clearly by grain refinement in weld metal of commercial pure Al (Alloy 1050A). In Alloy 5083 weld metal, the toughness was not improved through grain refinement, likely because of a semi-continuous network of brittle intermetallic phases that facilitate crack propagation. KW - GTA welding KW - Aluminium KW - Grain size KW - Tensile tests KW - Dynamic fracture tests PY - 2013 U6 - https://doi.org/10.1007/s40194-013-0026-6 SN - 0043-2288 SN - 1878-6669 VL - 57 IS - 3 SP - 293 EP - 304 PB - Springer CY - Oxford AN - OPUS4-28065 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schempp, Philipp A1 - Pittner, Andreas A1 - Rethmeier, Michael A1 - Tang, Z. A1 - Seefeld, T. A1 - Cross, C.E. ED - Babu, S. S. ED - Bhadeshia, H.K. ED - Cross, C.E. ED - David, S.A. ED - DebRoy, T. ED - DuPont, J.N. ED - Koseki, T. ED - Liu, S. T1 - Influence of alloy and solidification parameters on grain refinement in aluminium weld metal due to inoculation N2 - Refinement of the weld metal grain structure can improve the mechanical properties of the weld and decrease the susceptibility to solidification cracking of the weld metal. In this study, commercial Al Ti5B1 grain refiner was used to refine the microstructure of LB (laser beam) and GTA (gas tungsten arc) aluminum welds by inoculation. The grain refiner additions led to a significant decrease in the weld metal mean grain size whereby a transition from columnar to equiaxed grain structure (Columnar to Equiaxed Transition, CET) was observed. The development of both grain size and shape depended upon the base metal (Al alloys 1050A, 5083 and 6082) and upon the welding process. The GTA welding process allowed a more pronounced and a more efficient refinement than in LB welds. Furthermore, the influence of the solidification conditions on the CET was investigated through temperature measurements in the weld metal. The temperature profiles revealed a faster solidification of LB welds than in GTA welds. The results from the temperature measurements were also used to estimate (according to an existing model) the critical thermal gradient at which the CET occurs. T2 - 9th International conference on trends in welding research CY - Chicago, Illinois, USA DA - 04.06.2012 KW - Aluminium KW - LBW KW - GTAW KW - Grain refinement KW - Alloy 1050A KW - Alloy 5083 KW - Alloy 6082 KW - Al Ti5B1 PY - 2013 SN - 978-1-62708-998-2 SP - 98 EP - 107 PB - ASM international AN - OPUS4-27907 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schempp, Philipp A1 - Cross, C.E. A1 - Pittner, Andreas A1 - Rethmeier, Michael T1 - Influence of solute content and solidification parameters on grain refinement of aluminum weld metal N2 - Grain refinement provides an important possibility to enhance the mechanical properties (e.g., strength and ductility) and the weldability (susceptibility to solidification cracking) of aluminum weld metal. In the current study, a filler metal consisting of aluminum base metal and different amounts of commercial grain refiner Al Ti5B1 was produced. The filler metal was then deposited in the base metal and fused in a GTA welding process. Additions of titanium and boron reduced the weld metal mean grain size considerably and resulted in a transition from columnar to equiaxed grain shape (CET). In commercial pure aluminum (Alloy 1050A), the grain-refining efficiency was higher than that in the Al alloys 6082 and 5083. Different welding and solidification parameters influenced the grain size response only slightly. Furthermore, the observed grain-size reduction was analyzed by means of the undercooling parameter P and the growth restriction parameter Q, which revealed the influence of solute elements and nucleant particles on grain size. KW - Aluminium KW - GTA welding KW - Grain refinement KW - Alloy 1050A KW - Alloy 5083 KW - Alloy 6082 KW - Al Ti5B1 PY - 2013 U6 - https://doi.org/10.1007/s11661-013-1649-3 SN - 1073-5623 SN - 1543-1940 VL - 44A IS - 7 SP - 3198 EP - 3210 PB - The Minerals, Metals and Materials Society CY - Warrendale AN - OPUS4-28656 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Tang, Z. A1 - Schempp, Philipp A1 - Seefeld, T. A1 - Schwenk, Christopher A1 - Vollertsen, F. T1 - Kornfeinung beim WIG- und Laserstrahlschweißen von Aluminiumlegierungen N2 - Die Kornfeinung beim Schweißen ist mit einem Übergang von groben, stängeligen Körnern zu kleineren, globulitischen Körnern im Schweißgut verbunden. Die Feinung der Korngröße und Form führt sowohl zu einer wesentlichen Verbesserung der Schweißeignung als auch zu verbesserten mechanischen Eigenschaften. Heute gebräuchliche Schweißzusatzwerkstoffe enthalten zum Teil bereits geringe Mengen kornfeinender Zusätze, deren Wirksamkeit jedoch von einer Reihe weiterer Randbedingungen abhängt. Durch Zugabe definierter Mengen an Keimbildnern (AlTi5B1) in das Schmelzbad wurde die Abhängigkeit der Korn-größe und –form vom Titan/Bor-Gehalt untersucht. Weiterhin wurde der zur vollständigen Kornfeinung notwendige Mindestgehalt an Keimbildner für unterschiedliche Legierungen und unter unterschiedlichen Schweißbedingungen, sowohl beim WIG-Schweißen als auch beim Laserstrahlschweißen bestimmt. Die Ergebnisse zeigen, dass sich die Korngröße im Schweißgut bis auf ein Minimum von ca. 20µm verringern lässt und zugleich der Anteil der globulitischen Körner zunimmt. Der Mindestgehalt an Keimbildner für vollständige Korn-feinung hängt stark von Schweißgeschwindigkeit und Legierungszusammensetzung ab. Der Einfluss der Kornfeinung auf die Festigkeit, Duktilität sowie die Heißrissempfindlichkeit der Schweißverbindungen wird an ausgewählten Bespielen aufgezeigt. T2 - DVS Congress 2011 - Große Schweißtechnische Tagung CY - Hamburg, Deutschland DA - 27.09.2011 KW - Kornfeinung KW - WIG-Schweißen KW - Laserstrahlschweißen KW - Aluminium PY - 2011 SN - 978-3-87155-267-0 VL - 275 SP - 153 EP - 160 PB - DVS Media GmbH CY - Düsseldorf AN - OPUS4-24607 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schempp, Philipp A1 - Cross, Carl Edward A1 - Schwenk, Christopher A1 - Rethmeier, Michael T1 - Influence of Ti and B additions on grain size and weldability of aluminium alloy 6082 N2 - Grain refinement is an important possibility to enhance the weldability of aluminium weld metal that is usually defined by its susceptibility to solidification cracking. In this study, grain refinement was achieved through the addition of commercial grain refiner containing titanium and boron to the GTA weld metal of aluminium alloy 6082. The weld metal mean grain size could be reduced significantly from about 70 µm to a saturated size of 21 µm with a change in grain shape from columnar to equiaxed. The grain refinement prevented the formation of centreline solidification cracking that was present only in welds with unrefined grain structure. A variation of torch speed led to a strong change of solidification parameters such as cooling rate that was measured in the weld metal and the corresponding solidification rate and thermal gradient. The ratio thermal gradient/growth rate (G/R) decreased from 50 K s/mm² (high torch speed) to 10 K s/mm² (low torch speed). However, the variation of torch speed did not change the tendency for solidification cracking. The microstructure of unrefined and completely refined weld metal was compared. The observed change in size and distribution of the interdendritic phases was related to the change in susceptibility to solidification cracking. KW - Aluminium KW - WIG-Schweißen KW - Kornfeinung KW - Schweißeignung KW - Heißrisse KW - Aluminium alloy KW - Solidification cracking KW - Weldability KW - GTA welding PY - 2012 SN - 0043-2288 SN - 1878-6669 VL - 56 IS - 09/10 SP - 95 EP - 104 PB - Springer CY - Oxford AN - OPUS4-26992 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schempp, Philipp A1 - Häcker, Ralf A1 - Pittner, Andreas A1 - Cross, C.E. A1 - Rethmeier, Michael T1 - Influence of grain size on mechanical properties of aluminium GTA weld metal N2 - Surface modification of mild steel was undertaken using two covered electrodes and two tubular electrodes. The two covered electrodes are DIN 8555: E6-UM-60 and E10-UM-60GR; however, the two tubular electrodes are E10-GF-60GR1 and E10-GF-60GR2. Chemical analysis for the weld metal and XRD of the flux covering for covered electrodes and flux core for tubular electrodes were conducted. The most important factor in determining the wear resistance is the microstructure of the deposit layers. In similar carbon equivalent electrodes E10-UM-60GR and E10-GF-60GR1, electrode E10-GF-60GR1 (tubular) shows larger carbides area fraction and better wear resistance than electrode E10-UM-60GR (covered). This could be attributed to a lower dilution associated with tubular electrode compared with covered electrode. The two tubular electrodes showed higher wear resistance than the covered electrodes which is mainly due to the larger Fe-Cr carbide precipitation area fraction. KW - GTA welding KW - Aluminium KW - Grain refinement KW - Tensile tests KW - Tear tests PY - 2014 U6 - https://doi.org/10.1007/s40194-014-0132-0 SN - 0354-7965 VL - 58 IS - 4 SP - 491 EP - 497 PB - Drustvo za Unapredjivanje Zavarivanja u Srbiji CY - Beograd AN - OPUS4-35103 LA - srp AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schempp, Philipp A1 - Cross, C.E. A1 - Pittner, Andreas A1 - Oder, Gabriele A1 - Neumann, R.S. A1 - Rooch, Heidemarie A1 - Dörfel, Ilona A1 - Österle, Werner A1 - Rethmeier, Michael T1 - Solidification of GTA aluminium weld metal: Part I - Grain morphology dependent upon alloy composition and grain refiner content KW - Aluminium KW - Gas tungsten arc welding (GTAW) KW - Grain refinement KW - Columnar to equiaxed transition (CET) KW - Epitaxial nucleation KW - Duplex nucleation theory PY - 2014 SN - 0043-2296 SN - 0096-7629 VL - 93 SP - 53-s - 59-s PB - American Welding Society CY - New York, NY AN - OPUS4-30413 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Schempp, Philipp A1 - Cross, C.E. A1 - Pittner, Andreas A1 - Rethmeier, Michael T1 - Solidification of GTA aluminium weld metal: Part 2 - Thermal conditions and model for columnar-to-equiaxed transition KW - Aluminium KW - Gas tungsten arc welding (GTAW) KW - Columnar to equiaxed transition (CET) KW - Thermal analysis PY - 2014 SN - 0043-2296 SN - 0096-7629 VL - 93 IS - March SP - 69-s - 77-s PB - American Welding Society CY - New York, NY AN - OPUS4-30415 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -