TY - JOUR A1 - Hioki, A. A1 - Kurahashi, M. A1 - Turk, G. A1 - Matschat, Ralf A1 - Recknagel, Sebastian T1 - CCQM-K33 Final Report - Determination of minor elements in steel N2 - The key comparison CCQM-K33 was organized by the Inorganic Analysis Working Group of the CCQM to test the abilities of the national metrology institutes to measure the mass fractions of minor elements in steel. Elements to be analysed were Cr, Mn, Ni and Mo in low alloy steel. The National Metrology Institute of Japan (NMIJ), the National Institute of Standards and Technology (NIST) and the Federal Institute for Materials Research and Testing (BAM) acted as the coordinating laboratories. The participants used various measurement methods, though many of them used ICP-AES. Generally speaking, the agreement of the results was very good for each measurand. PY - 2006 U6 - https://doi.org/10.1088/0026-1394/43/1A/08007 SN - 0026-1394 SN - 1681-7575 VL - 43 IS - Technical Supplement 1A 08007 SP - 1 EP - 15 PB - Inst. of Physics Publ. CY - Bristol AN - OPUS4-12349 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kipphardt, Heinrich A1 - Matschat, Ralf A1 - Vogl, Jochen A1 - Gusarova, Tamara A1 - Czerwensky, Michael A1 - Heinrich, Hans-Joachim A1 - Hioki, A. A1 - Konopelko, L.A. A1 - Methven, B. A1 - Miura, T. A1 - Petersen, O. A1 - Riebe, Gundel A1 - Sturgeon, R. A1 - Turk, G.C. A1 - Yu, L. L. T1 - Purity determination as needed for the realisation of primary standards for elemental determination: status of international comparability N2 - Within the National Metrology Institutes (NMIs) and designated laboratories, an interlaboratory comparison, CCQM-P107, was conducted to verify the degree of international comparability concerning the results of purity analysis. The mass fractions of Ag, Bi, Cd, Cr, Ni, Tl at the lower mg/kg-level in a high purity zinc material were determined, but the real measurand in metrological sense was the sum of the six mass fractions. Homogeneity was investigated by glow discharge mass spectrometry, reference values were obtained using isotope dilution mass spectrometry. Six NMIs participated, contributing eight independent data sets. The agreement amongst the results of the participants, their median and the agreement with the reference values were usually excellent and in almost all cases below the target uncertainty of 30% relative. In this manner, the accuracy of results and the comparability between the participants was demonstrated to be established. KW - Interlaboratory comparison KW - Purity analysis KW - High purity metals KW - CCQM-P107 KW - Zinc PY - 2010 U6 - https://doi.org/10.1007/s00769-009-0557-0 SN - 0949-1775 SN - 1432-0517 VL - 15 IS - 1 SP - 29 EP - 37 PB - Springer CY - Berlin AN - OPUS4-20767 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -