TY - CONF A1 - Kannengießer, Thomas A1 - Florian, Wolfgang A1 - Böllinghaus, Thomas T1 - Einfluss des Einspanngrades auf die Beanspruchung beim Schweißen eingespannter Bauteile T2 - 18. Tagung Werkstoffprüfung 2000 ; 18. Vortrags- und Diskussionstagung Werkstoffprüfung 2000 CY - Bad Nauheim, Deutschland DA - 2000-12-07 PY - 2000 SP - 95 EP - 102 PB - Dt. Verband für Materialforschung CY - Berlin AN - OPUS4-980 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Xu, Ping A1 - Weber, Gert A1 - Krause, Hans-Joachim A1 - Böllinghaus, Thomas T1 - Bewertung und Vereinheitlichung von gefügten Dünnblechproben für Schwingversuche im Zeitfestigkeitsbereich PY - 2002 SN - 0933-050X IS - 169 SP - 1 EP - 77 PB - Verband der Automobilindustrie CY - Frankfurt a. M. AN - OPUS4-1758 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kannengießer, Thomas A1 - Mc Inerney, T. A1 - Florian, Wolfgang A1 - Böllinghaus, Thomas A1 - Cross, C.E. ED - Cerjak, H. T1 - The influence of local weld deformation on hot cracking susceptibility T2 - 6th International Seminar on the Numerical Analysis of Weldability CY - Seggauberg, Austria DA - 2001-10-01 PY - 2002 SN - 1-902653-56-4 N1 - Serientitel: Books of IOM3 – Series title: Books of IOM3 IS - 784 SP - 803 EP - 818 PB - Maney CY - London AN - OPUS4-1793 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas A1 - Jochum, C. A1 - Stiebe-Springer, I. T1 - Effect of filler material selection on stress strain build up and stress corrosion cracking resistance of welded supermartensitic stainless steel pipes T2 - Corrosion 2002 CY - Denver, CO, USA DA - 2002-04-07 KW - Supermartensitic stainless steel KW - Filler material KW - Orbital TIG welding KW - Duplex stainless steel KW - Hydrogen assisted cracking KW - Stress strain distribution KW - Shrinkage restraint KW - Formation water PY - 2002 SP - Paper 02061, 1 EP - 20 PB - NACE International CY - Houston, Tex. AN - OPUS4-1794 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Viyanit, Ekkarut ED - Cerjak, H. T1 - Numerical Simulations of Hydrogen-Assisted Cracking in Girth Welds of Supermartensitic Stainless Steel Pipelines - Report I T2 - 6th International Seminar on the Numerical Analysis of Weldability CY - Seggauberg, Austria DA - 2001-10-01 PY - 2002 SN - 1-902653-56-4 N1 - Serientitel: Books of IOM3 – Series title: Books of IOM3 IS - 6 SP - 839 EP - 855 PB - Maney CY - London AN - OPUS4-1795 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Noack, Volker A1 - Böllinghaus, Thomas A1 - Michael, Thomas T1 - Untersuchungen zur Prozeßbeherrschung des Weichplasmaschweißens an Überlappverbindungen von hochlegierten CrNi-Stählen PY - 2002 SN - 3-934238-50-5 N1 - Serientitel: Forschung für die Praxis – Series title: Forschung für die Praxis VL - P 387 IS - P387 SP - 1 EP - 98 PB - Verl. und Vertriebsges. mbH CY - Düsseldorf AN - OPUS4-1864 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Xu, Ping A1 - Böllinghaus, Thomas T1 - Fatigue testing for spot welds - problems, solutions and new development N2 - Engineering design of spot-welded components as well as computational analyses of the local stress in the weld zone require relevant fatigue test data. Those test data, however, are dependent on the applied specimens, on the specimen restraint, on the load introduction into the weld zone as well as on the definition of the specimen failure. The discussion of the advantages and drawbacks as well as of the influence of these factors shows that a deliberate selection of specimens is necessary for different test purposes. For the comparability of the test results it is essential in addition to specify comparable test conditions, e.g., specimen fixturing, load introduction and definition of the specimen failure. On account of the variety of variants, a standardization of suitable specimens and respective test conditions hence constitutes an approach to the determination of relevant and comparable test results. T2 - SAE world congress CY - Detroit, MI, USA DA - 2003-03-03 PY - 2003 UR - http://www.sae.org/technical/papers/2003-01-0976 SN - 0-7680-1191-4 SN - 0099-5908 N1 - Serientitel: SAE-SP – Series title: SAE-SP IS - 1766 SP - 87 EP - 94 PB - Society of Automotive Engineers CY - Warrendale, Pa. AN - OPUS4-2299 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas T1 - Steps to more conclusive testing of welded supermartensitic stainless steel pipes T2 - 2nd International Conference Supermartensitic Stainless Steels 2002 CY - Brussels, Belgium DA - 2002-10-03 KW - Component testing KW - Conclusive test sequences KW - Hydrogen assisted cracking KW - Supermartensitic stainless steels KW - Martensite transformation KW - Welded pipelines PY - 2002 SP - 71 EP - 76 PB - KCI Publ. CY - Zutphen AN - OPUS4-2301 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Schobbert, Helmut A1 - Lammers, Marco A1 - Michael, Thomas A1 - Skopp, André T1 - Laser-Plasma-Pulver-Schweißen hochlegierter austenitischer Stähle T2 - 5. Konferenz "Strahltechnik" CY - Halle (Saale), Deutschland DA - 2001-11-27 PY - 2001 SP - 67 EP - 76 CY - Halle (Saale) AN - OPUS4-2428 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Seeger, Dirk A1 - Böllinghaus, Thomas T1 - Hydrogen Permeation in Supermartensitic Stainless Steels Exposed to Realistic Formation Water Compositions T2 - Corrosion 2003 CY - San Diego, CA, USA DA - 2003-03-16 KW - hydrogen permeation KW - Supermartensitic stainless steel KW - Formation water KW - Realistic environments KW - diffusion coefficient KW - HDss PY - 2003 IS - 03098 SP - 03098-1-03098-15 PB - NACE International CY - Houston, Tex. AN - OPUS4-2898 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas A1 - Neuhaus, Mathias A1 - Florian, Wolfgang T1 - Analysis of Residual Stress Distribution in Welded Joints Depending on the Restraint Intensity T2 - Euromat 2003 CY - Lausanne, Switzerland DA - 2003-09-01 PY - 2003 AN - OPUS4-2905 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas A1 - Neuhaus, Mathias T1 - Effects of the Structural Restraint Intensity on the Stress Strain Build up in Butt Joints T2 - 7th International Seminar: Numerical Analysis of Weldability CY - Graz, Austria DA - 2003-09-29 PY - 2003 AN - OPUS4-2906 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Viyanit, Ekkarut A1 - Hoffmeister, H. T1 - Numerical modelling of hydrogen assisted cracking N2 - Hydrogen might be introduced during fabrication welding or might be taken up from an environment during sour service or cathodic protection. Thus, hydrogen assisted stress corrosion and cold cracking is still a major topic regarding the reliability of welded steel components, as for instance offshore platforms and pipelines. In order to support conclusive testing and life time evaluation of welded steel components, a numerical model for hydrogen assisted cracking has been developed, particularly taking into consideration the geometrical effects of crack propagation on the respective hydrogen distribution alongside and ahead of the crack. Numerical calculations were based on finite element analysis of the hydrogen and stress-strain distribution by using a commercially available program. The model has been verified experimentally by slow strain rate experiments of supermartensitic stainless steels which are intended to be used more extensively as materials for welded flowlines in North Sea oil and gas production. As first results of such simulations the influence of the subsurface concentration provided by different H2S saturation levels in the NACE TM 0177-96 standard solution on crack propagation and the effect of crack shape on the hydrogen distribution profile are presented in this contribution. T2 - Corrosion 2001 CY - Houston, TX, USA DA - 2001-03-11 KW - Hydrogen assisted cracking KW - Numerical simulation KW - Welded steel components KW - Low carbon martensitic stainless steel KW - Sour service KW - Slow strain rate test KW - Crack propagation PY - 2001 UR - http://www.nace.org/nacestore/department.asp?ID=671 IS - Paper 01226 PB - NACE International CY - Houston, Tex. AN - OPUS4-1015 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Seeger, Dirk A1 - Böllinghaus, Thomas A1 - Hoffmeister, H. ED - Olive, J. M. ED - Puiggali, M. ED - Zielinski, A. T1 - Hydrogen permeation in supermartensitic stainless steels T2 - 2nd International Conference on Environmental Degradation of Engineering Materials CY - Bordeaux, France DA - 2003-06-29 KW - Hydrogen permeation KW - Supermartensitic stainless steel KW - Diffusion coefficient KW - Subsurface concentration KW - Heat treatment PY - 2003 SN - 1-904350-07-0 N1 - Serientitel: Event of the European Federation of Corrosion – Series title: Event of the European Federation of Corrosion IS - 264 SP - 1 EP - 8(?) PB - Universite de Bordeaux 1, Laboratoire de Mécanique-Physique AN - OPUS4-3111 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Schobbert, Helmut A1 - Böllinghaus, Thomas A1 - Skopp, André ED - Sepold, G. T1 - Kurzzeitmetallurgische Phänomene bei schnellen Umschmelzprozessen im System Fe-Cr-Ni in der Nähe der eutektischen Rinne PY - 2002 SN - 3-933762-08-1 N1 - Serientitel: Strahltechnik – Series title: Strahltechnik IS - 18 SP - 201 EP - 217 PB - BIAS CY - Bremen AN - OPUS4-2065 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Schobbert, Helmut T1 - Laser Weld Metallurgy of Austenitic Stainless Steels T2 - Stainless Steel World Conference & Expo 2003 CY - Maastricht, The Netherlands DA - 2003-11-11 KW - Laser Welding KW - Hybrid Welding KW - Austenitic Stainless Steels KW - Weld Metallurgy KW - Primary Solidification Mode KW - Nitrogen Content KW - Hot Cracking KW - Stress Corrosion Cracking PY - 2003 SN - 90-73168-20-1 SP - 243 EP - 257 PB - KCI Publ. CY - Zutphen AN - OPUS4-2646 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas A1 - Zimmer, Peter T1 - Investigations of Cold Cracking by the CTS-Test at Various Cooling Conditions T2 - 56th IIW International Conference Welded Construction for Urban Infrastructure CY - Bucharest, Romania DA - 2003-07-10 KW - Kaltrisstests KW - Schweißsicherheit PY - 2003 SN - 0043-2288 SN - 1878-6669 VL - 47 SP - 1(?) EP - 12(?) PB - Springer CY - Oxford AN - OPUS4-2630 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas A1 - Schobbert, Helmut T1 - Neue werkstofftechnische Erkenntnisse und Ergebnisse aus der BAM PY - 2003 SN - 0935-0292 VL - 18.2004 SP - 80 EP - 90 PB - Verl. für Schweißen u. Verwandte Verfahren DVS-Verl. CY - Düsseldorf AN - OPUS4-2656 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Xu, Ping A1 - Weber, Gert A1 - Böllinghaus, Thomas A1 - Krause, Hans-Joachim ED - Blom, A. F. T1 - Determination of relevant fatigue characteristics for joined thin sheet metal structures on suitable specimens with appropriate test methods T2 - 8th FATIGUE 2002 ; 8th International Fatigue Congress CY - Stockholm, Sweden DA - 2002-06-03 PY - 2002 SN - 1-901537-30-7 VL - 2 SP - 1103 EP - 1110 PB - EMAS, Engineering Materials Advisory Services CY - Cradley Heath, West Midlands AN - OPUS4-1385 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Seeger, D.M. A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas T1 - Risssicherheit von Schweißnähten an Pipelines der Offshore-Industrie aus supermartensitischem Stahl T2 - Schweißen und Schneiden 2005 CY - Essen, Deutschland DA - 2005-09-12 KW - Supermartensit KW - Risssicherheit KW - Geschlossene Prüfkette PY - 2005 SN - 3-87155-695-5 N1 - Serientitel: DVS-Berichte – Series title: DVS-Berichte IS - 237 SP - 85 EP - 91 PB - DVS-Verl. CY - Düsseldorf AN - OPUS4-11083 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Zimmer, Peter A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas T1 - Kaltrissprüfverfahren nach der DVS Richtlinie 1006 T2 - Schweißen und Schneiden 2005 CY - Essen, Deutschland DA - 2005-09-12 KW - Kaltriss KW - Kaltrissprüfung KW - DVS-Richtlinie 1006 PY - 2005 SN - 3-87155-695-5 N1 - Serientitel: DVS-Berichte – Series title: DVS-Berichte IS - 237 SP - 275 EP - 280 PB - DVS-Verl. CY - Düsseldorf AN - OPUS4-11084 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stelling, Karen A1 - Schobbert, Helmut A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas T1 - Vertical-up and -down laser plasma powder hybrid welding of a high nitrogen austenitic stainless steel KW - Laser welding KW - Photon beam welding KW - Radiation welding KW - Plasma welding KW - Arc Welding KW - Gas shielded arc welding KW - Vertical down KW - Vertical position KW - Welding position KW - Vertical up KW - Process parameters KW - Process conditions KW - Speed KW - Austenitic stainless steels KW - Stainless steels KW - Steels PY - 2005 SN - 0043-2288 SN - 1878-6669 VL - 49 IS - 5/6 SP - 45 EP - 49 PB - Springer CY - Oxford AN - OPUS4-11885 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Zimmer, Peter A1 - Kannengießer, Thomas A1 - Florian, Wolfgang A1 - Böllinghaus, Thomas T1 - Kaltrissprüfungen für hochfeste Feinkornbaustähle T2 - Große Schweißtechnische Tagung "Schweißen und Schneiden" 2004 CY - Magdeburg, Deutschland DA - 2004-09-22 PY - 2004 SN - 3-87155-689-0 SN - 0418-9639 N1 - Serientitel: DVS-Berichte – Series title: DVS-Berichte IS - 232 SP - 207 EP - 214 PB - DVS-Verl. CY - Düsseldorf AN - OPUS4-4634 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Neuhaus, Mathias A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas A1 - Herold, H. A1 - Hoffmeister, H. T1 - Beurteilung der Kaltrisssicherheit von Schweißverbindungen in realen Konstruktionen mit der Finite-Elemente-Methode T2 - Große Schweißtechnische Tagung "Schweißen und Schneiden" 2004 CY - Magdeburg, Deutschland DA - 2004-09-22 PY - 2004 SN - 3-87155-689-0 SN - 0418-9639 N1 - Serientitel: DVS-Berichte – Series title: DVS-Berichte IS - 232 SP - 195 EP - 200 PB - DVS-Verl. CY - Düsseldorf AN - OPUS4-4635 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas A1 - Neuhaus, M. T1 - Effects of the load history on the residual stress distribution in welded components KW - Loading KW - Residual stresses KW - Stress distribution KW - Influencing factors KW - Practical investigations KW - Measurement KW - Cooling KW - Hardness KW - Mechanical properties KW - Temperature distribution KW - Heat affected zone KW - Weld zone KW - Yield strength KW - Strength KW - Parent material KW - Restraint PY - 2006 SN - 0043-2288 SN - 1878-6669 VL - 50 IS - 7/8 SP - 11 EP - 17 PB - Springer CY - Oxford AN - OPUS4-12516 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wolf, Martin A1 - Böllinghaus, Thomas A1 - Schobbert, Helmut ED - Böllinghaus, T. ED - Herold, H. T1 - Influence of the Weld Pool Geometry on Solidification Crack Formation N2 - Numerous externally loaded as well as self-restraint hot cracking test procedures have been developed over the years to evaluate soldidification crack phenomena. But the interpretation and the subsequent transfer of test results towards component weldments has still to be regarded as a decisive challenge. Some progress has been achieved by hypothesizing crack / no crack criteria referring to uniform and uniaxial loading of the solidification front during welding. But, as the present results show, solidification cracking significantly depends on the geometry of the solidification front, which has so far not been considered in the respective criteria. In this contribution, the position of solidification cracks is correlated with the positiondependent strain rates along the solidification front and with the positiondependent curvature of the weld pool. Especially at positions of high curvature, an increased rate of shrinkage can be predicted on the basis of a geometrical Rate of Feeding (ROF) Rate of Shrinkage (ROS) model, corresponding to the measured positions of the solidification cracks. The assumption of position-dependent strain and strain rates along the solidification front during Varestraint-Testing has been confirmed by means of numerical simulations. T2 - International Workshop "Hot Cracking Phenomena in Welds" CY - Berlin, Germany DA - 2004-03-04 PY - 2005 SN - 3-540-22332-0 U6 - https://doi.org/10.1007/b139103 SP - 245 EP - 268 PB - Springer CY - Berlin AN - OPUS4-7275 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schobbert, Helmut A1 - Böllinghaus, Thomas A1 - Wolf, Martin ED - David, S. A. T1 - Hot Cracking Resistance of Laser and Hybrid Welded Austenitic Stainless Steels T2 - 6th International Conference on Trends in Welding Research (TWR) CY - Pine Mountain, GA, USA DA - 2002-04-15 KW - Heißrisse KW - Nichtrostende Stähle PY - 2003 SN - 0-87170-780-2 SP - 76 EP - 81 PB - ASM international CY - Materials Park, Ohio AN - OPUS4-7283 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wongpanya, Pornwasa A1 - Böllinghaus, Thomas A1 - Lothongkum, G. T1 - Effects of hydrogen removal heat treatment on residual stresses in high strength structural steel welds T2 - International Conference "Tubular structures" CY - Quebec, Canada DA - 2006-08-31 KW - Hydrogen KW - Simulation KW - High strenght structural steel KW - Restraint intensity KW - Heat treatment PY - 2006 UR - http://www.iiw-iis.org/ SN - 0043-2288 SN - 1878-6669 VL - 50 IS - Special Issue SP - 96 EP - 103 PB - Springer CY - Oxford AN - OPUS4-13932 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Müller, Christina A1 - Gaal, Mate T1 - Reliability Tests for Demining T2 - BAM-DLR Visit to GICHD CY - Geneva, Switzerland DA - 2004-02-05 PY - 2004 AN - OPUS4-5589 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas ED - Richard, H. A. T1 - Sicherheit von Schweißverbindungen gegen wasserstoffunterstützte Rissbildung T2 - 32. Tagung des DVM-Arbeitskreises Bruchvorgänge CY - Berlin, Deutschland DA - 2000-02-22 PY - 2000 SN - 0943-3473 SP - 173 EP - 182 PB - DVM CY - Berlin AN - OPUS4-11843 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Hoffmeister, H. T1 - Hydrogen permeation in supermartensitic stainless steels dependent on heat treatment and chemical composition N2 - Hydrogen might cause severe degradation of supermartensitic stainless steels, if they are activated during exposure to sour environments. Consistent and comprehensive data for hydrogen transport in these materials are thus required to support, in particular, modelling of hydrogen assisted cracking as a part of life time assessment of welded steel components. In addition to previously published diffusion coefficients and subsurface concentrations of a supermartensitic stainless steel further data dependent on heat treatment are provided by this contribution. Furthermore, a higher alloyed material has been investigated in the state as received and also in the quenched condition, in order to approach the influences of chemical composition on hydrogen transport in supermartensitic stainless steels. With respect to welding it turned out that the diffusion coefficient and the subsurface concentration are markedly dependent on heat treatment of the materials. T2 - Corrosion 2000 CY - Orlando, FL, USA DA - 2000-03-26 PY - 2000 SP - Paper 00141, 1 EP - 19 PB - NACE International CY - Houston, Tex. AN - OPUS4-11844 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Hoffmeister, H. T1 - A numerical model for hydrogen assisted cracking PY - 2000 U6 - https://doi.org/10.5006/1.3280564 SN - 0010-9312 SN - 1938-159X VL - 56 IS - 6 SP - 611 EP - 622 PB - National Association of Corrosion Engineers CY - Houston, Tex. AN - OPUS4-11845 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kannengießer, Thomas A1 - Florian, Wolfgang A1 - Böllinghaus, Thomas A1 - Herold, H. ED - Miannay, D. P. T1 - Analysis of welding reaction stresses and welding reaction moments in component tests - Stress characteristics dependent on the intensity of restraint N2 - Up to the present, the thermomechanical loads during welding and subsequent cooling under design-specific shrinkage restraint resulting from the interaction between the materials and the structure have often not been taken into consideration approperiately for weldability assessment of components. As compared to previous investigations using small specimens this report presents component weld tests under varying intensities of restraint. Online records of the reaction forces and moments demonstrate in which way the intensity of restraint affects the reaction stresses and moments and their meaning for the evaluation of the load level in welded components. T2 - EUROMAT Topical 2000 CY - Tours, France DA - 07.11.2000 PY - 2000 SN - 0-08-042815-0 VL - 1 SP - 145 EP - 150 PB - Elsevier CY - Amsterdam AN - OPUS4-11847 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Schobbert, Helmut A1 - Böllinghaus, Thomas A1 - Schöler, Annett T1 - Heißrißsicherheit hochlegierter austenitischer Stähle beim Laser- und Hybridschweißen N2 - Eine Reihe nichtrostender austenitischer Cr-Ni-Stähle in der Nähe der eutektischen Rinne können beim Laserschweißen sowohl primär ferritisch als auch primär austenitisch erstarren. Speziell konzipierte Heißrißprüfungen zeigen eine Rißanfälligkeit der im Unterschied zum WIG-Schweißen mit großen Streckenenergien beim Laserschweißen mit kleinen Streckenenergien primär austenitisch erstarrenden Gefügebereiche. Die Ursache dafür ist, daß im Unterschied zu einer langsamen primär ferritischen Erstarrung bei einer schnellen Erstarrung über metastabile primär austenitische Zustände Restschmelzen entstehen können, die gegenüber dem Grundwerkstoff erhebliche temperaturabhängige Zähigkeitsverluste aufweisen. Es wird gezeigt, wie sich durch die Wahl auf den Werkstoff gezielt abgestimmter Schweißparameter die Heißrißsicherheit beim Laserschweißen weitestgehend sicherstellen läßt. Darüber hinaus werden Perspektiven vorgestellt, wie die Heißrißsicherheit bei Hybridschweißen durch die Auswahl vom Zusatzwerkstoffen und durch eine geeignete Prozeßführung zu erreichen ist. T2 - 12. Jahrestagung Schadensanalyse CY - Würzburg, Germany DA - 18.10.2000 PY - 2000 SN - 3-18-091556-0 SN - 0083-5560 N1 - Serientitel: VDI-Berichte – Series title: VDI-Berichte IS - 1556 SP - 225 EP - 240 PB - VDI-Verl. CY - Düsseldorf AN - OPUS4-11849 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas A1 - Neuhaus, Mathias ED - Cerjak, H. ED - Bhadeshia, H. K. D. H. T1 - Effects of the structural restraint intensity on the stress strain build up in butt joints T2 - 7th International Seminar on Numerical Analysis of Weldability CY - Graz, Austria DA - 2003-09-29 PY - 2005 SN - 3-901351-99-X SP - 651 EP - 669 PB - Techn. Univ., TUG CY - Graz AN - OPUS4-11850 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Zimmer, Peter A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas T1 - Effects of hydrogen on weld microstructure mechanical properties of the high strength steels S 690Q and S 1100QL PY - 2004 UR - http://www.china-weldnet.com/English/information/II-1525-04.htm IS - II-1525-04 SP - 1 EP - 16 PB - International Institute of Welding CY - Paris AN - OPUS4-11851 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Stelling, Karen A1 - Böllinghaus, Thomas A1 - Wolf, Martin A1 - Schöler, Annett A1 - Burkert, Andreas A1 - Isecke, Bernd ED - Böllinghaus, T. ED - Herold, H. T1 - Hot cracks as stress corrosion cracking initiation sites in laser welded corrosion resistant alloys N2 - Although hot cracks at weld surfaces of corrosion resistant alloys (CRAs) might provide access to respective aggressive media and thus, might provide the conditions for a local potential and pH drop, the interaction between hot cracking and corrosion phenomena has not been investigated up to the present. This particularly concerns the initiation of stress corrosion cracking inside such crevices. As a first approach to clarify the influence of hot cracks on corrosion resistance, considering particularly stress corrosion cracking, hot crack afflicted laser welds of three different CRAs have been subjected to a series of different corrosion tests. Besides the fact that the Drop Evaporation (DE) Test represents a more realistic procedure than standard immersion tests it turned out that hot cracks can obviously represent an initiation site of stress corrosion cracking in the austenitic stainless steel AISI 309 (German No. 1.4828). The susceptibility of such hot crack afflicted laser welds to stress corrosion cracking (SCC) significantly depends on temperature and chloride concentration of the test environment In comparison, the high nitrogen austenitic stainless steel AISI S 34565 (German No. 1.4565) did not exhibit any stress corrosion cracking associated with hot cracking. This material exhibited pitting corrosion and stress corrosion only in the base material. The Alloy 50 (German No. 2.4850), a Nickel based material, was susceptible to pitting corrosion, but showed no tendency towards stress corrosion cracking at all. T2 - International Workshop "Hot Cracking Phenomena in Welds" CY - Berlin, Germany DA - 2004-03-04 KW - Ni-Base Alloy KW - Stress corrosion Cracking KW - Hot Cracking KW - Laser Welding KW - Austenitic Stainless Steel KW - Drop Evaporation Test PY - 2005 SN - 3-540-22332-0 U6 - https://doi.org/10.1007/3-540-27460-X_10 SP - 165 EP - 182 PB - Springer CY - Berlin AN - OPUS4-11852 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas ED - Cerjak, H. T1 - Modelling of Hydrogen Diffusion and Cracking in Steel Welds N2 - Hydrogen assisted steel corrosion and cold cracking is still a major topic regarding the reliability of welded steel components, such as offshore platforms and pipelines. Measurement of local and crack critical hydrogen concentrations in a specific weld is difficult and not very precise. Numerical simulations of hydrogen uptake and diffusion developed within the last twenty years have to be regarded as much more effective to determine local hydrogen concentrations in crack critical regions of welds. As an overview of existing theories of the state of the art in modelling of hydrogen cracking in steels, the present contribution shows that the development of a comprehensive numerical model for both types of hydrogen assisted cracking in welds, hydrogen assisted stress corrosion cracking and cold cracking, is still a major research task. As a first step towards that direction, a basic procedure for numerical simulation of crack initiation and propagation has been developed and experimentally verified. The approach can be extended to a comprehensive quantitative model for life time prediction and risk based inspection of welded steel components. (Steel specimen used was S355 along with other materials such as AISI 321, Incoloy 800, Inconel 690 and 600.) T2 - Fifth International Seminar on the 'Numerical Analysis of Weldability' CY - Graz, Austria DA - 1999-09-01 PY - 2000 SN - 1-86125-115-7 N1 - Serientitel: Book / The Institute of Materials – Series title: Book / The Institute of Materials IS - 738 SP - 1019 EP - 1059 PB - IOM Communications CY - London AN - OPUS4-11841 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas A1 - Florian, Wolfgang A1 - Herold, H. T1 - Effect of weld metal strength and welding conditions on reaction forces and stress distribution of restrained components N2 - Düring the past decades, weldability studies have predominantly been concentrated on the material and the welding process. In order to achieve a closer insight into the structural effects, component weldability tests have been performed by online monitoring of the reaction forces and moments. As a particular item, the effects of different strengths of the base and filier material on the reaction force and stress build up transverse to the welding direction have been studied at a specific structural restraint. As a most relevant result for practical welding it is demonstrated that the final reaction force and also the reaction stress level in the multilayer butt welds decreases with overmatch of the weld metal. PY - 2000 IS - IX-1971-00 SP - 1 EP - 18 PB - International Institute of Welding CY - Paris AN - OPUS4-11842 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tal-Gutelmacher, E. A1 - Eliezer, Dan A1 - Viyanit, Ekkarut A1 - Böllinghaus, Thomas ED - Carpinteri, A. T1 - Numerical Simulation of Hydrogen-Induced Cracking in Titanium Based Alloys T2 - 11th International Conference on Fracture CY - Turin, Italy DA - 2005-03-20 PY - 2005 SN - 978-88-903188-1-8 PB - CCI CY - Turin AN - OPUS4-11853 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eliezer, Dan A1 - Tal-Gutelmacher, E. A1 - Böllinghaus, Thomas T1 - Hydrogen embrittlement in hydride- and non hydride-forming systems - microstructural/phase changes and cracking mechanisms, effects of high fugacity and internal hydrogen on beta-21S titanium alloy T2 - EUROCORR 2005 CY - Lisbon, Portugal DA - 2005-09-04 PY - 2005 PB - Fundação para a Ciência e a Tecnologia CY - Lisbon AN - OPUS4-11854 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Zimmer, Peter A1 - Seeger, Dirk A1 - Böllinghaus, Thomas ED - Cerjak, H. T1 - Hydrogen permeation and related material properties of high strength steels T2 - Conference on High Strength Steels for Hydropower Plants CY - Graz, Austria DA - 2005-07-05 PY - 2005 SN - 3-902465-21-2 SP - Paper 17, 1 EP - 18 PB - Verl. der Techn. Univ. Graz CY - Graz AN - OPUS4-11855 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Dorsch, T. A1 - Saarinen, K. A1 - Roos, E. A1 - Böllinghaus, Thomas A1 - Cerjak, H. A1 - Enzinger, N. ED - Cerjak, H. T1 - Results of stress corrosion investigation on steel and weldments on steels S890 and S690 T2 - Conference on High Strength Steels for Hydropower Plants CY - Graz, Austria DA - 2005-07-05 PY - 2005 SN - 3-902465-21-2 SP - Paper 04, 1 EP - 49 PB - Verl. der Techn. Univ. Graz CY - Graz AN - OPUS4-11856 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - The Effect of Restraint on weld Solidification Cracking in Aluminium T2 - IIW Conference 2005 CY - Prague, Czech Republic PY - 2005 PB - IIW CY - Prag AN - OPUS4-11857 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stelling, Karen A1 - Schobbert, Helmut A1 - Böllinghaus, Thomas T1 - Vertical-Up and Down Laser Plasma Powder Hybrid Welding of a High Nitrogen Austenitic Stainless Steel PY - 2005 SN - 0043-2288 SN - 1878-6669 VL - 49 IS - 5/6 SP - 45 EP - 49 PB - Springer CY - Oxford AN - OPUS4-11858 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Schobbert, Helmut A1 - Böllinghaus, Thomas A1 - Wolf, Martin ED - Herlach, D. M. T1 - Metastable Primary Solidification Modes in the Fe-Cr-Ni System During Laser Welding T2 - 8th EUROMAT 2003 CY - Lausanne, Switzerland DA - 2003-01-01 PY - 2004 SN - 3-527-31011-8 VL - 8 SP - 213 EP - 226 PB - Wiley-VCH CY - Weinheim AN - OPUS4-4988 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Vermeidung von Rissen beim Schweißen von Rohrleitungen T2 - DVM-Tag 2011 "Bauteilzuverlässigkeit - Schäden und ihre Vermeidung" CY - Berlin, Germany DA - 2012-05-04 PY - 2012 AN - OPUS4-26033 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Schadensfälle geschweißter Rohrleitungen und Maßnahmen zur Vermeidung N2 - Aus wirtschaftlich-technischer Perspektive ergeben sich in den letzten zehn Jahren hinsichtlich der Werkstoffinnovation und -auswahl für geschweißte Rohrleitungen im Wesentlichen zwei Entwicklungsrichtungen: Im Bereich der niedriglegierten Stähle werden immer höher festere Feinkombaustähle mit Streckgrenzen von inzwischen über 900 MPa verwendet. Wirtschaftliches Ziel ist hierbei eine möglichst hohe Kosteneinsparung durch Reduktion der Wanddicke. Für korrosionsbeanspruchte Komponenten, unter anderem im Petrochemie- und Energieanlagenbau besteht das wirtschaftliche Ziel primär darin, eine höhere Kosteneinsparung durch neue Legierungskonzepte zu erzielen und zwar möglichst so, dass bei mindestens gleicher Festigkeit auf die Verwendung von teuren Elementen, wie beispielsweise Nickel, verzichtet werden kann. Beispiele hierfür sind insbesondere hochlegierte martensitische Cr-V-Stähle, supermartensitische Stähle, Lean-Duplexstähle, superaustenitische Stähle und austenitische Cr-Mn-Stähle. Für einige der neu eingeführten Grundwerkstoffe sind die Zusatzwerkstoffe noch in der Entwicklung. In jedem Fall stellen diese Werkstoffinnovationen besondere Ansprüche hinsichtlich einer Rissvermeidung während der schweißtechnischen Verarbeitung, um von vornherein riss- bzw. fehlerfreie Rohrleitungen herzustellen, die eine hohe Sicherheit gegen ein Versagen während der Inbetriebnahme und im Verlauf der vorgesehenen Lebensdauer aufweisen. Fast alle dieser neu eingeführten Rohrleitungswerkstoffe weisen eine reduzierte Heiß- oder Kaltrissresistenz vor allem während des Schweißens mit modernen Hochleistungsprozessen, bspw. Laserhybridschweißen, auf. Dabei besteht nach wie vor Forschungsbedarf hinsichtlich der jeweiligen Entstehungsmechanismen. Da es in den letzten zehn Jahren immer häufiger zu Produktionsausfällen und Schadensfällen mit teilweise katastrophalen Konsequenzen gekommen ist, werden die Ursachen und die Vermeidung fertigungsbedingter Heiß- und Kaltrisse im Folgenden zusammengefasst. T2 - 14. Sommerkurs Werkstoffe und Fügen CY - Magdeburg, Germany DA - 23.09.2011 PY - 2011 SN - 978-3-940961-56-3 SP - 45 EP - 54 CY - Magdeburg AN - OPUS4-26196 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dabah, Eitan A1 - Kannengießer, Thomas A1 - Eliezer, D. A1 - Böllinghaus, Thomas T1 - In situ synchrotron X-ray radiation analysis of hydrogen behavior in stainless steel subjected to continuous heating N2 - Hydrogen generally causes lattice distortions and phase transformations when introduced into a metallic crystal lattice. For the investigations reported in this contribution, hydrogen thermal desorption analysis has been carried out to observe the influence of hydrogen desorption on the lattice of super martensitic stainless steel during continuous heating. The lattice expansion parameter and the phase transformations have been monitored during the thermal desorption process, and the influence of hydrogen on such characteristics has been evaluated. It was found that hydrogen has a significant influence on both the lattice parameter and on the thermal expansion. However, hydrogen has no influence on phase transformation during thermal desorption. The hydrogen's desorption behavior in this process was also observed and it turned out that hydrogen desorbs in two stages, i.e., firstly diffusible hydrogen and trapped hydrogen afterward. KW - Synchrotron radiation KW - In situ KW - Hydrogen PY - 2012 U6 - https://doi.org/10.1007/s10853-012-6489-9 SN - 0022-2461 SN - 1573-4803 VL - 47 IS - 15 SP - 5879 EP - 5885 PB - Springer Science + Business Media B.V. CY - Norwell, Mass. AN - OPUS4-26179 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Steppan, Enrico A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - Numerical investigations on cold cracking avoidance in fillet welds of high-strength steels N2 - Industry faces a growing demand for high-strength structural steels with yield strengths of up to 1,300 MPa in order to cope with increasingly higher strength requirements in engineering. Higher strength levels are achieved by a special coordinated production process and an adapted chemical composition. Nevertheless, disastrous damage cases with high-strength steels have occurred in the past. The sensitivity to mechanical property degradation by hydrogen increases dramatically with strength. This phenomenon leads to hydrogen-assisted cold cracking. T-joints with fillet welds made from one side with an included angle of 60° were examined for their cold cracking behavior. Based on the T-joint, a modified heat input, even interpass temperature, plate thickness, and length ones were examined. The diffusion behavior and the effectiveness of different post-weld heat treatments in joints were simulated. The results of post-weld heat treatments are illustrated in practical hydrogen removal heat treatment diagrams. It is noticed that the T-joint is subject to a very high risk of hydrogen-assisted cold cracking (HACC). Contrary to other joints, its most critical area for cracking is not the weld metal but the heat-affected zone surrounding area of the root pass. The simulation shows that HACC in the T-joint can only be avoided by applying a sufficient post-weld heat treatment. KW - High-strength structural steels KW - Hydrogen diffusion KW - Numerical simulation KW - Hydrogen-assisted cold cracking (HACC) KW - T joints KW - Fillet welds KW - Post-weld heat treatment KW - Hydrogen removal heat treatment diagramm (HRHT) PY - 2013 U6 - https://doi.org/10.1007/s40194-013-0036-4 SN - 0043-2288 SN - 1878-6669 VL - 57 IS - 3 SP - 359 EP - 371 PB - Springer CY - Oxford AN - OPUS4-27952 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Gumenyuk, Andrey A1 - Quiroz Penaranda, Vanessa ED - Lippold, J. ED - Böllinghaus, T. ED - Cross, C.E. ED - et al., T1 - Short Term Metallurgy and Hot Cracking During Laser Beam Welding of Austenitic Stainless Steels N2 - Industrial application of high alloyed austenitic stainless steel laser welding has grown significantly in the recent time due to the continuous improvement of compact and high power density lasers systems. The application of such processes meanwhile ranges from pipeline or railway car body manufacturing to the production of household wares. The largest advantages of the laser application to welding production are much higher welding speeds, reduction or complete exclusion of welding consumables, easy design of the weld joints, decrease of thermal distortions and thus, costs saving. In contrast to arc welding, laser beam welding might particularly be associated with metallurgical defects, like the formation of hot cracks. Such phenomena are related to an order of magnitude higher temperature gradients and cooling rates in the solidification zone, providing rapid solidification kinetics which may cause significant segregation of alloying elements such as Ni and Cr and respective undercooling of the solute at the solidification front. In specific metastable austenitic stainless steels alloys in vicinity of the so called eutectic rim of the Fe-Cr-Ni constitutional diagram, such effects might entail a change of solidification mode from primary ferrite to austenite, providing an increased risk of solidification cracking. Previous studies has shown that the primary solidification mode change during laser beam welding of Cr-Ni austenitic stainless steels such alloys could be effectively influenced by nitrogen absorption as well as by the laser plasma type and also proved the occurrence of metastable primary ferritic solidification. In the present contribution, such results are compared to recent investigations of laser welding newer austenitic Fe-Cr-Mn-Ni steel grades by identification of respective hot cracking critical welding parameter intervals and strain rates in the Controlled Thermal Weldability (CTW) Test. PY - 2011 SN - 978-3-642-16863-5 U6 - https://doi.org/10.1007/978-3-642-16864-2_7 IS - Part 2 SP - 103 EP - 129 PB - Springer CY - Berlin, Heidelberg AN - OPUS4-24348 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Trends in investigating hydrogen cracking and diffusion in steel welds N2 - ♦ Elongation of the Service life of existent components ♦ Inovative light weight design ♦ Higher strength of the applied materials ♦ Increasingly aggressive environments T2 - 64th IIW Annual assembly and international conference CY - Chennai, India DA - 17.07.2011 PY - 2011 AN - OPUS4-24349 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eliezer, Dan A1 - Böllinghaus, Thomas T1 - Hydrogen trapping mechanisms in structural materials T2 - Effects of hydrogen on materials - 2008 International hydrogen conference CY - Jackson, Wyoming, USA DA - 2008-09-07 PY - 2008 SN - 1615030034 SP - 438 EP - 447 PB - ASM international AN - OPUS4-24543 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Wongpanya, Pornwasa T1 - Modeling of hydrogen assisted cold cracking in high strength steel welds T2 - Effects of hydrogen on materials - 2008 International hydrogen conference CY - Jackson, Wyoming, USA DA - 2008-09-07 PY - 2008 SN - 1615030034 SP - 588 EP - 595 PB - ASM international AN - OPUS4-24544 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wolf, Martin A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas ED - Carl E. Cross, ED - John C. Lippold, ED - Böllinghaus, T. ED - Herold, H. T1 - Determination of critical strain rate for solidification cracking by numerical simulation PY - 2008 SN - 978-3-540-78627-6 IS - Part I SP - 77 EP - 92 PB - Springer CY - Berlin AN - OPUS4-24488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - kModeling of hydrogen distribution in a duplex stainless steel N2 - Quite a number of models for hydrogen distribution in steels and welds have been developed in the past 20 years. They reach from simple analytical models to more complex two and three dimensional finite element simulations. So far, these models have been used to simulate hydrogen distribution in homogeneous microstructure. This paper contributes to numerical simulation of hydrogen distribution in heterogeneous microstructure, e. g. in a duplex stainless steel microstructure consisting of two phase fractions. Under appropriate conditions, such as cathodic protection, it is possible that hydrogen is absorbed leading to material embrittlement and possibly initiating hydrogen assisted cracking. In order to avoid hydrogen assisted cracking in duplex stainless steels, it is of great interest to know more about the diffusion behavior of the ferrite and austenite phase. A numerical model has been developed that operates on the mesoscale and enables simulation of hydrogen transport in the various phases of a metallic material. As a first application of this model, hydrogen distribution in a duplex stainless steel 1.4462, consisting of approximately equal portions of ferrite and austenite, was simulated using the finite element program package ANSYS. The results reflect the dependency of hydrogen distribution on the microstructural alignment of the ferrite and austenite phase fractions. Crack-critical areas can thus be identified, provided the critical strain-hydrogen combination is known for the respective microstructural phase. KW - Finite element KW - Simulation KW - Duplex stainless steel KW - Hydrogen KW - Diffusion KW - Weld metal KW - Microstructure PY - 2012 SN - 0043-2288 SN - 1878-6669 VL - 56 IS - 11/12 SP - 66 EP - 78 PB - Springer CY - Oxford AN - OPUS4-27483 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas T1 - Cold cracking tests - an overview of present technologies and applications N2 - This study provides an in-depth survey of current technologies and applications for assessing the cold cracking susceptibility of welded joints. From the large variety of existent cold cracking test procedures, the most important and internationally established tests are presented and evaluated in terms of their usefulness and application limits. According to the type of loading, the test procedures are classified into self-restraint and externally loaded tests. Apart from the merely metallurgical weldability tests for determining the cracking susceptibility of base materials, filler materials and weld metals, advanced test methods are presented for evaluating the cold cracking susceptibility of welded components. A salient point brought out in this respect is the fact that the level of external loading in such component weld tests can be applied independently of the welding parameters, reproducing as realistically as possible the practical application case, i.e. the level of the restraint intensity. This study includes a summarized comparison of the cold cracking procedures. It is emphasized that highly accurate consideration and reproduction of the design-specific stiffness conditions is essential in the tests for assessing the cold cracking behaviour of welded joints. Therefore, various numerical analyses are presented in a final chapter for calculating the restraint intensity as a definitive factor affecting cold cracking. KW - Cold cracking KW - Weldability tests KW - Testing KW - Restraint PY - 2013 U6 - https://doi.org/10.1007/s40194-012-0001-7 SN - 0043-2288 SN - 1878-6669 VL - 57 IS - 1 SP - 3 EP - 37 PB - Springer CY - Oxford AN - OPUS4-27634 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Böllinghaus, Thomas ED - Czichos, Horst T1 - Principles and concepts of technical failure analysis N2 - This chapter introduces conceptually Part C of the Handbook Technical Diagnostics of Machines and Plants. Although various prescriptions for organization and performing failure analyses are existing in literature [1–6], up to the present no approach is consistent to the concept of technical systems in the Sects 2.2 and 2.3 (Fig. 2.6) and thus, a comprehensive concept is outlined in this section, with a special attribute to the VDI-Guideline 3822 Failure Analysis. KW - Failure analysis PY - 2013 SN - 978-3-642-25849-7 SN - 978-3-642-25850-3 U6 - https://doi.org/10.1007/978-3-642-25850-3_17 IS - Chapter 17 SP - 341 EP - 353 PB - Springer CY - Berlin Heidelberg AN - OPUS4-27629 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Straub, Franka A1 - Unger, Wolfgang A1 - Mente, Tobias T1 - In-situ Detection of Deuterium in Duplex Stainless Steels Using Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) T2 - 2012 International Hydrogen Conference CY - Moran, WY, USA DA - 2012-09-09 PY - 2012 AN - OPUS4-27593 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Straub, Franka A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang A1 - Mente, Tobias ED - Somerday, B. P. ED - Sofronis, P. T1 - In-situ detection of Deuterium in duplex stainless steels by time-of-flight secondary ion mass spectrometry (TOF-SIMS) T2 - Hydrogen-materials interactions - 2012 International hydrogen conference CY - Moran, WY, USA DA - 2012-09-09 PY - 2014 SN - 978-0-7918-6029-8 SP - 505 EP - 512 PB - ASME CY - New York AN - OPUS4-27669 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Kurzzeitmetallurgische Phänomene bei schnellen Umschmelzprozessen im System Fe-Cr-Ni in der Nähe fer eutektischen Rinne T2 - DFG-Kolloquium Kurzzeitmetallurgie CY - Bremen, Germany DA - 2002-09-11 PY - 2002 AN - OPUS4-6322 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Effect of Filler Material Selction on Stress Strain Build Up an Stress Corrosion Cracking of Welded SMSS Pipes T2 - IIW-Intermediale Meeting SC II-E, Institute Du Soudure CY - Paris, France DA - 2002-03-20 PY - 2002 AN - OPUS4-6326 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Filler Material Selection for Orbital Supermatensitic Stainless Steel Pipeline Welds T2 - IIW-Intermediale Meeting SC II-E CY - Copenhagen, Denmark DA - 2002-06-27 PY - 2002 AN - OPUS4-6329 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Hydrogen Cracking of Supermartennsitic Stainless Steels T2 - 5th International Conference HCDI CY - Jackson, WY, USA DA - 2002-09-22 PY - 2002 AN - OPUS4-6332 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Viyanit, Ekkarut A1 - Hoffmeister, H. T1 - Numercial Simulation of Hydrogen-Assisted Cracking in Girth Welds of Supermartensitic Stainless Steel Pipelines - Report II T2 - 7th International Seminar: Numerical Analysis of Weldability CY - Graz, Austria DA - 2003-09-30 PY - 2003 AN - OPUS4-4685 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas ED - Moody, N. T1 - Hydrogen assisted cracking of supermartensitic stainless steels T2 - International Conference on Hydrogen Effects on Material Behavior and Corrosion Deformation Interactions CY - Moran, WY, USA DA - 2002-09-22 PY - 2003 SN - 0-87339-501-8 SP - 1009 EP - 1018 PB - TMS CY - Warrendale, Pa. AN - OPUS4-15488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Wongpanya, Pornwasa A1 - Böllinghaus, Thomas A1 - Lothongkum, G. ED - H.K.D.H. Bhadeshia, ED - H. Cerjak, ED - E. Kozeschnik, T1 - Numerical simulation of hydrogen removal heat treatment procedures in high strength steel welds KW - Hydrogen removal heat treatment KW - High strength steel KW - Numerical simulation KW - Hydrogen assisted cold cracking PY - 2007 SN - 978-3-902465-69-6 SP - 743 EP - 765 CY - Graz, Austria AN - OPUS4-16496 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas A1 - Florian, Wolfgang A1 - Herold, H. T1 - Effect of weld metal strength and welding conditions on reaction forces and stress distribution of restrained components PY - 2001 SN - 0043-2288 SN - 1878-6669 VL - 45 IS - 1-2 SP - 18 EP - 26 PB - Springer CY - Oxford AN - OPUS4-16544 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Pettersson, C.O. A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas T1 - Corrosion testing of welds, a review of methods KW - Austenitic stainless steels KW - Carbon steels KW - Corrosion KW - Corrosion tests KW - Crevice corrosion KW - Duplex stainless steels KW - Fatigue strength KW - Galvanic corrosion KW - Intergranular corrosion KW - Low alloy steels KW - Mechanical properties KW - Nickel alloys KW - Pitting corrosion KW - Stress corrosion KW - Stainless steels KW - Steels KW - Unalloyed steels KW - Welded joints KW - Weld metal PY - 2007 SN - 0043-2288 SN - 1878-6669 VL - 51 IS - 7/8 SP - 79 EP - 106 PB - Springer CY - Oxford AN - OPUS4-15727 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas T1 - An overview on cold cracking tests - Part 1: Externally loaded tests KW - Cold cracking KW - Hydrogen Induced Cracking KW - Tests KW - Weldability KW - Trinca a Frio KW - Trinca Induzida por Hidrogenio KW - Ensaios KW - Soldabilidade PY - 2007 SN - 0104-9224 SN - 1980-6973 VL - 12 IS - 2 SP - 160 EP - 166 PB - Associação Brasileira de Soldagem, ABS CY - Rio de Janeiro AN - OPUS4-15728 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas ED - Uwe Reisgen, T1 - Prüfen Sie noch oder bewerten Sie schon - Entwicklungen in der Untersuchung geschweißter Bauteile / Are You Still Testing or Already Evaluating - Developments in the investigation of Welded Components PY - 2007 SN - 978-3-8322-6644-8 SN - 0943-9358 SP - 41 EP - 57 PB - Shaker CY - Aachen AN - OPUS4-16270 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - The Effect of Restraint on weld Solidification Cracking in Aluminium KW - Aluminium alloys KW - Light metals KW - Solidification cracking KW - Cracking KW - Defects KW - Hot cracking KW - Crack initiation KW - Strain KW - Restraint PY - 2006 SN - 0043-2288 SN - 1878-6669 VL - 50 IS - 11/12 SP - 51 EP - 54 PB - Springer CY - Oxford AN - OPUS4-14220 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Eliezer, Dan A1 - Tal-Gutelmacher, E. A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - Hydrogen trapping in beta-21S titanium alloy N2 - Different characteristics of hydrogen's absorption/desorption behavior and trapping in ß-21S titanium alloy are studied by means of thermal desorption spectroscopy (TDS). Spectra analysis is supported by data from variety of other experimental techniques, such as LECO hydrogen determinator, XRD and microstructure investigations by means of optic and electronic microscopy. In contrast to many past considerations, the complex process of hydrogen evolution has been found to be significantly affected by the way hydrogen introduction into the alloy. The different trapping sites, as well as phase transformations, have to be considered as the reasons for the different hydrogen evolution behavior. KW - Titanium alloys KW - Hydrogen absorption KW - Hydrogen desorption KW - Thermally activated processes KW - Thermal desorption spectroscopy (TDS) PY - 2006 U6 - https://doi.org/10.1016/j.msea.2006.01.067 SN - 0921-5093 SN - 1873-4936 VL - 421 IS - 1-2 SP - 200 EP - 207 PB - Elsevier CY - Amsterdam AN - OPUS4-14423 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eliezer, Dan A1 - Tal-Gutelmacher, E. A1 - Kannengießer, Thomas A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - The effects of high fugacity and internal hydrogen on beta-21S titanium alloy T2 - EUROCORR 2005 CY - Lisbon, Portugal DA - 2005-09-04 KW - Titanium alloys KW - Beta-21S KW - Hydrogen desorption KW - Thermal Desorption Spectroscopy (TDS) PY - 2005 SP - 1 EP - 9 PB - Fundação para a Ciência e a Tecnologia CY - Lisbon AN - OPUS4-14451 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Eliezer, Dan A1 - Hamu, G.B. A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas ED - Galloway, T. T1 - Effect of grain refinement on the strength and corrosion of AZ31 magnesium alloy following severe plastic deformation N2 - Gas tungsten arc welds made on wrought magnesium AZ31 plate have been characterized for corrosion in saline solution (3.5% NaCl). Microstructural changes induced by the welding process resulted in different environmental behaviour of each zone (BM-base metal, HAZ-heat affected zone and FZ-fusion zone). The faster kinetics of corrosion in FZ and especially HAZ are attributed to (a) the coarse microstructure, consisting of large grains, and (b) very small amounts of ß-phase in the grain boundaries. Also, hardness traverses have shown that these zones are weaker than the base metal. Based on the significant effect of grain size on strength in magnesium alloys, the weld metal grains have been systematically refined using controlled oscillation during welding, and by adding a grain refiner to the weld pool. Detailed microstructure analyses have been carried out and the relationships between corrosion behaviour, mechanical properties and microstructure (grain refinement and second-phases formation) are highlighted. T2 - 135th Annual Meeting of the Minerals, Metals & Materials Society CY - San Antonio, TX, USA DA - 2006-03-12 PY - 2006 SN - 978-0-87339-619-6 VL - 135 SP - 1 EP - 4 PB - TMS, the Minerals, Metals & Materials Society CY - Warrendale AN - OPUS4-14452 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eliezer, Dan A1 - Tal-Gutelmacher, E. A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas ED - Gdoutos, E. T1 - Irreversible Hydrogen Trapping in Welded Beta-21S Titanium Alloy T2 - 16th European Conference of Fracture CY - Alexandroupoli, Greece DA - 2006-07-03 KW - Titanium alloys KW - Beta-21S KW - Hydrogen desorption KW - Thermal Desorption Spectroscopy (TDS) PY - 2006 VL - 16 IS - 803 SP - 1 EP - 8 CY - Alexandroupolis AN - OPUS4-14453 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Tal-Gutelmacher, E. A1 - Eliezer, Dan A1 - Böllinghaus, Thomas T1 - Hydrogen Behavior in GTA Welded Ti-6Al-4V and Beta-21S Aerospace Applicative Titanium Alloys T2 - 2006 Beijing International Materials Week CY - Beijing, China DA - 2006-06-25 KW - Titanium alloys KW - Ti-6Al-4V KW - Beta-21S KW - Hydrogen embrittlement KW - Hydrogen desorption PY - 2007 SN - 0-87849-432-4 SN - 0255-5476 VL - 546-549/3 SP - 1413 EP - 1420 PB - Trans Tech Publ. CY - Stafa-Zürich AN - OPUS4-14511 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eliezer, Dan A1 - Tal-Gutelmacher, E. A1 - Böllinghaus, Thomas ED - Carpinteri, A. T1 - Hydrogen embrittlement in hydride- and non hydride-forming systems - microstructural/phase changes and cracking mechanisms N2 - Hydrogen-assisted cracking (HAC) or hydrogen embrittlement (HE) are the most commonly used terms to describe a time-dependant failure process, characterized by mechanical properties degradation, mainly ductility reduction, and a change in the fracture mode. With almost no direct techniques for observing atomic-scale events at crack tips in bulk specimens, HE/HAC mechanisms are deduced mainly from fractography, microscopic investigation of microstructure changes, surface-science observations, and atomistic or continuum modeling. This paper addresses to HE/HAC mechanisms into two different systems; hydride-forming and non-hydride forming materials. As a representative example of the hydride-forming systems, the discussion focuses on the hydrogen-induced second phase formation (e.g. hydrides) phenomena in titanium based alloys. Due to the large differences in the behavior of hydrogen in α and β phases of titanium, the susceptibility of titanium-based alloys to the various forms and conditions of hydrogen embrittlement can vary markedly. The microstructural changes and hydrogen-induced second phase formation due to exposure at various charging conditions, as well as the difference in hydrogen absorption/desorption behavior as a function of the prior microstructure of titanium alloys, are highlighted. In non-hydride forming materials, where as representative examples stainless steels are chosen, the paper concentrates on the qualitatively same phenomena of hydrogen-induced second phase embrittlement. The phase transitions related to hydrogen-induced cracking, the hydrogen related failure sequences and fracture modes in austenitic and supermartensitic stainless steels and a potential modeling of hydrogen-assisted cracking in these structural metallic materials are discussed. T2 - 11th International Conference on Fracture CY - Turin, Italy DA - 2005-03-20 PY - 2005 UR - http://www.gruppofrattura.it/ocs/index.php/ICF/ICF11/paper/viewFile/10870/10199 SN - 978-88-903188-1-8 SP - Paper 5766, 1 EP - 6 PB - CCI CY - Turin AN - OPUS4-14513 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Stelling, Karen A1 - Lammers, Marco A1 - Böllinghaus, Thomas T1 - Qualification of Nd:YAG and CO2 laser plasma hybrid welding with filler material powder KW - Hybrid welding KW - Nickel base alloy KW - Laser arc KW - Out of position welding PY - 2006 SN - 1612-3433 VL - 5 IS - 6 SP - 330 EP - 334 PB - DVS - German Welding Society CY - Düsseldorf AN - OPUS4-14561 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Eliezer, Dan A1 - Tal-Gutelmacher, E. A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - Hydrogen absorption and desorption in a duplex-annealed Ti-6Al-4V alloy during exposure to different hydrogen-containing environments N2 - Based on its excellent combination of a high strength/weight ratio and good corrosion behavior, Ti–6Al–4V alloy is ranked among the most important advanced materials for a variety of industrial applications. However, in many of these technological applications, this alloy is exposed to environments which can act as sources of hydrogen, and severe problems may arise based on its susceptibility to hydrogen embrittlement. Even small hydrogen concentrations might lead to failure. Consequently, a comprehensive knowledge of hydrogen's absorption/desorption behavior and interactions between hydrogen and different microstructural features is necessary to better understand the desorption and trapping mechanisms, the types of the trap sites, and the trapped hydrogen content, in order to determine the safe service conditions of this alloy in the industry. In this paper, different characteristics of hydrogen's absorption/desorption behavior and trapping in a duplex-annealed Ti–6Al–4V alloy are studied by means of thermal desorption spectroscopy (TDS). Spectra analysis is supported by data from a variety of other experimental techniques, such as LECO hydrogen determinator, XRD and microstructure investigations by means of optical and electron microscopy. Hydrogen evolution is found to be a very complex process, being affected by the way hydrogen was initially introduced to the alloy, the phase transformations that may occur during the thermal analysis and the presence of potential trapping sites. KW - Titanium alloys KW - Hydrogen absorption KW - Hydrogen desorption KW - Ti-6Al-4V KW - Thermal desorption spectroscopy (TDS) PY - 2006 U6 - https://doi.org/10.1016/j.msea.2006.06.088 SN - 0921-5093 SN - 1873-4936 VL - 433 IS - 1-2 SP - 298 EP - 304 PB - Elsevier CY - Amsterdam AN - OPUS4-14484 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ben-Hamu, G. A1 - Eliezer, Dan A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - Microstructure and Corrosion Resistance of TIG Welded AZ31B Magnesium Sheet T2 - 2nd International Conference on Magnesium CY - Beijing, China DA - 2006-06-25 KW - AZ31B KW - TIG welded KW - Microstructure KW - Corrosion behavior PY - 2006 VL - 2 IS - A-044 SP - 1 EP - 8 CY - Beijing AN - OPUS4-14486 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Cross, Carl Edward A1 - Eliezer, Dan A1 - Böllinghaus, Thomas T1 - The Role of Hydrogen in Titanium Alloy Weldments T2 - Titanium Conference 2006 CY - San Diego, CA, USA DA - 2006-10-01 PY - 2006 VL - 22 SP - 1 EP - 9 CY - San Diego AN - OPUS4-14488 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Ben-Hamu, G. A1 - Eliezer, D. A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - The relation between microstructure and corrosion behavior of GTA welded AZ31B magnesium sheet N2 - Welding of AZ31B magnesium alloy was carried out using gas-tungsten arc (GTA) welding. The microstructure and the corrosion behavior of welded magnesium AZ31B alloy were investigated. ac and dc polarization tests were carried out on the welded Mg sheet. The microstructure was examined using optical and electron microscopy (TEM and SEM), X-ray analysis and EDS. Scanning Kelvin probe force microscopy (SKPFM) was used in order to measure the Volta potential of different phases relative to the matrix. The results showed that the GTA process effected both the microstructure and the corrosion behavior. These results can be explained by the effects of the process on microstructure of AZ31B Mg alloy sheet such as grain size and precipitates caused by the change in precipitation and recrystallization behavior. KW - AZ31B KW - GTA weld KW - Microstructure KW - Corrosion behavior KW - SKPFM KW - Intermetallics PY - 2007 U6 - https://doi.org/10.1016/j.msea.2006.12.122 SN - 0921-5093 SN - 1873-4936 VL - 452/453 SP - 210 EP - 218 PB - Elsevier CY - Amsterdam AN - OPUS4-15459 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas T1 - Cold Cracking Tests - Overview KW - High strength steel KW - Multi-pass weld KW - Numerical simulation KW - Intensity of restraint KW - IRc-Test KW - Preheating KW - Interpass temperature KW - Hydrogen assisted cold cracking PY - 2007 IS - II-1635-07 SP - 1 EP - 22 PB - International Institute of Welding CY - Paris AN - OPUS4-15755 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas T1 - An overview on cold cracking tests - Part 2: Self-restraint tests KW - Cold Cracking KW - Hydrogen induced cracking KW - Tests KW - Weldability PY - 2007 SN - 0104-9224 SN - 1980-6973 VL - 12 IS - 3 SP - 244 EP - 260 PB - Associação Brasileira de Soldagem, ABS CY - Rio de Janeiro AN - OPUS4-16415 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas A1 - Neuhaus, Mathias T1 - Effects of the load history on the residual stress distribution in welded components KW - Loading KW - Residual stresses KW - Stress distribution KW - Influencing factors KW - Practical investigations KW - Measurement KW - Cooling KW - Hardness KW - Mechanical properties KW - Temperature distribution KW - Heat affected zone KW - Weld zone KW - Yield strength KW - Strength KW - Parent material KW - Restraint PY - 2008 SN - 0043-2318 VL - 54 IS - 1 SP - 1 EP - 7 PB - Welding Research Council CY - New York, NY AN - OPUS4-17333 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wongpanya, Pornwasa A1 - Böllinghaus, Thomas A1 - Lothongkum, G. A1 - Kannengießer, Thomas T1 - Effects of Preheating and Interpass Temperature on Stresses in S 1100 QL Multi-Pass Butt-Welds KW - Cold cracking KW - Cracking KW - Defects KW - Heat treatment KW - High stength steels KW - Mathematical models KW - Multirun welding KW - Preheating KW - Residual stresses KW - Restraint KW - Steels KW - Structural steels KW - Temperature KW - Weldability tests PY - 2008 SN - 0043-2288 SN - 1878-6669 VL - 52 IS - 3/4 SP - 79 EP - 92 PB - Springer CY - Oxford AN - OPUS4-17334 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Wasserstoffunterstützte Rissbildung zweier Submarine Flowlines T2 - 39. VDI-Jahrestagung Schadensanalyse CY - Würzburg, Germany DA - 2013-10-08 PY - 2013 AN - OPUS4-29102 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Straub, Franka A1 - Wirth, Thomas A1 - Hertwig, Andreas A1 - Hodoroaba, Vasile-Dan A1 - Unger, Wolfgang A1 - Böllinghaus, Thomas T1 - Imaging the microstructure of duplex stainless steel samples with TOF-SIMS N2 - Time-of-flight secondary ion mass spectrometry (TOF-SIMS) mappings provide a visualization of the distribution of chemical elements and phases on polished duplex steel surfaces as element and fragment secondary ion signals. The advantage of TOF-SIMS, compared to optical microscopy, is its potential to analyze the chemical composition with a lateral resolution at a submicrometer scale. TOF-SIMS mappings allow distinguishing between ferritic and austenitic phases because of the phase selective detection method without any requirement of etching or other processing. KW - TOF-SIMS mappings KW - Duplex stainless steel KW - Surface analysis KW - Ferritic phase KW - Austenitic phase PY - 2010 UR - http://onlinelibrary.wiley.com/doi/10.1002/sia.3385/pdf U6 - https://doi.org/10.1002/sia.3385 SN - 0142-2421 SN - 1096-9918 VL - 42 IS - 6-7 SP - 739 EP - 742 PB - Wiley CY - Chichester AN - OPUS4-21818 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Hoffmeister, H. A1 - Stiebe-Springer, I. A1 - Florian, Wolfgang A1 - Michael, Thomas T1 - Component testing of welded supermartensitic stainless steel pipes T2 - EUROCORR 2000 CY - London, England, UK DA - 2000-09-10 PY - 2000 SP - 1 EP - 10 PB - IOM Communications CY - London AN - OPUS4-22138 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ben-Hamu, G. A1 - Eliezer, D. A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas T1 - Volta potential of second phase particles in TIG welded AZ31 magnesium sheet T2 - EUROCORR 2006 CY - Maastricht, The Netherlands DA - 2006-09-25 KW - TIG welding KW - AZ31 Magnesium Alloy KW - Corrosion behavior PY - 2006 N1 - Serientitel: EFC-Event – Series title: EFC-Event IS - 280 SP - 1 EP - 10 PB - European Federation of Corrosion CY - Maastricht AN - OPUS4-22134 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Tal-Gutelmacher, E. A1 - Eliezer, Dan A1 - Böllinghaus, Thomas T1 - Investigation of hydrogen-deformation interactions in beta-21S titanium alloy using thermal desorption spectroscopy KW - Titanium alloys KW - Hydrogen absorption KW - Thermally activated processes KW - Thermal desorption spectroscopy (TDS) PY - 2007 U6 - https://doi.org/10.1016/j.jallcom.2006.10.026 SN - 0925-8388 SN - 1873-4669 VL - 440 IS - 1-2 SP - 204 EP - 209 PB - Elsevier Sequoia CY - Lausanne AN - OPUS4-22098 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Schobbert, Helmut ED - David, S. A. T1 - Nd:YAG laser plasma powder hybrid welding of austenitic stainless steels T2 - 6th International Conference on Trends in Welding Research (TWR) CY - Pine Mountain, GA, USA DA - 2002-04-15 PY - 2003 SN - 0-87170-780-2 SP - 453 EP - 458 PB - ASM international CY - Materials Park, Ohio AN - OPUS4-22099 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas ED - David, S. A. T1 - Effect of filler material selection and shrinkage restraint on stress strain build up in component welds T2 - 6th International Conference on Trends in Welding Research (TWR) CY - Pine Mountain, GA, USA DA - 2002-04-15 PY - 2003 SN - 0-87170-780-2 SP - 906 EP - 911 PB - ASM international CY - Materials Park, Ohio AN - OPUS4-22082 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dabah, Eitan A1 - Kannengießer, Thomas A1 - Eliezer, D. A1 - Böllinghaus, Thomas T1 - In situ analysis of hydrogen behaviour in stainless steels by high energy synchrotron radiation N2 - Hydrogen generally causes lattice distortions and phase transformations when introduced into a metal matrix. The present contribution provides a report of first in situ investigations of hydrogen effects on the lattice of the austenite and the martensite phase in a supermartensitic stainless steel using hard synchrotron radiation for respective energy dispersion diffraction measurements. Lattice distortions, such as the planar spacing expansion, have been monitored during the complete hydrogen effusion process over 24 h and are directly correlated to the dissolved hydrogen in the metal matrix. Among other results, it turned out that hydrogen at the introduced concentration level causes a reversible lattice expansion and after hydrogen effusion the lattice nearly regained its original dimensions. Hydrogen much more significantly affects the austenite phase with respect to lattice expansion than the martensite phase, but no phase transformations occur during the hydrogen desorption process. KW - Hydrogen diffusion KW - Solubility KW - Lattice distortions KW - Energy dispersive X-ray diffraction PY - 2011 U6 - https://doi.org/10.1016/j.msea.2010.10.090 SN - 0921-5093 SN - 1873-4936 VL - 528 IS - 3 SP - 1608 EP - 1614 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-22849 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Vermeidung von Rissen beim Schweissen von Rohrleitungen N2 - Schadensfälle in den letzten zehn Jahren mit teilweise katastrophalen Folgen belegen, dass der Vermeidung von Rissen beim Schweißen von Rohrleitungen besondere Aufmerksamkeit zu schenken ist. In der Analyse solcher Schäden ist zu unterscheiden, ob die Risse bereits während oder kurz nach der schweißtechnischen Fertigung der Rohrkomponenten oder während des anschließenden Betriebes entstanden sind. Im vorliegenden Beitrag wird sich vor allem auf die Vermeidung einer Heiß- und Kaltrissbildung beim Schweißen von Rohrleitungen konzentriert und es werden weitere Forschungsperspektiven abgeleitet. T2 - DVM-Tag 2011 - Bauteilzuverlässigkeit - Schäden und ihre Vermeidung CY - Berlin, Germany DA - 04.05.2011 KW - Rissvermeidung KW - Heißrissbildung KW - Wasserstoffunterstützte Kaltrissbildung (HACC) KW - Pipelineschweißungen PY - 2011 SN - 0946-5987 N1 - Serientitel: DVM-Bericht – Series title: DVM-Bericht IS - 678 SP - 81 EP - 90 AN - OPUS4-26113 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias A1 - Dabah, Eitan ED - Kulkarni, D.V. ED - Samant, M. ED - Krishnan, S. ED - De, A. ED - Krishnan, J. ED - Patel, H. ED - Bhaduri, A.K. T1 - Trends in investigating hydrogen cracking and diffusion in steel welds N2 - The present contribution highlights recent trends in investigating hydrogen diffusion and cracking in steel welds. For such studies, supermartensitic stainless steels (SMSS) have exemplarily been selected. These materials have been used for offshore and marine constructions for about two decades now. They present a versatility of improved properties such as high strength to thickness ratio, good weldability and good corrosion resistance. However, as shown by respective failure cases, SMSS welds might become prone to hydrogen assisted cracking and the degradation phenomena are more easily to investigate due to the nearly homogeneous martensitic microstructure than in other materials. Generally, it has to be distinguished between cracking that occurs during or shortly after fabrication welding, or during subsequent operation of SMSS components. In order to achieve crack avoidance during fabrication and service, conclusive test sequences have to be applied, ranging from field tests at real components and full scale tests investigating the materials behavior under real service conditions to basic and small scale tests, such as tensile and corrosion tests, oriented more towards a materials ranking. Considerable testing of SMSS welds has been carried out and the present paper particularly summarizes spotlights on 1:1 scale component testing of welded tubulars, slow strain rate testing and basic tests oriented to elucidate the hydrogen behavior and degradation in SMSS weld microstructures. Also, permeation tests, hydrogen dependent degradation of mechanical properties and thermal desorption spectroscopy are adressed. As a specific item, first results of lately conducted investigations for tracking hydrogen movement in such weld microstructures by using high energy synchrotron radiation are elucidated. T2 - IIW International conference on global trends in joining, cutting and surfacing technology CY - Chennai, India DA - 21.07.2011 PY - 2011 SN - 978-81-8487-152-4 SP - 49 EP - 55 PB - Narosa Publ. House AN - OPUS4-26114 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - Heat treatment effects on the reduction of hydrogen in multi-layer high-strength weld joints KW - Cold cracking KW - Heat treatment KW - High strength steels KW - Hydrogen KW - Numerical simulation KW - Structural steels PY - 2012 SN - 0043-2288 SN - 1878-6669 VL - 56 IS - 7/8 SP - 26 EP - 36 PB - Springer CY - Oxford AN - OPUS4-26055 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Dabah, Eitan A1 - Kannengießer, Thomas A1 - Eliezer, D. A1 - Böllinghaus, Thomas T1 - Hydrogen interaction with residual stresses in steel studied by synchrotron X-ray diffraction N2 - The residual stress state in a material has an important role in the mechanism of cracking, induced or assisted by hydrogen. In this contribution, the beamline EDDI in BESSY II instrument in Berlin was used in order to investigate the influence of hydrogen upon the residual stresses state existing in a Supermartensitic stainless steel sample. The method used for investigating the residual stresses is the “sinus square ψ” method. This method involves the usage of high energy X-ray diffraction in order to measure the residual stress state and magnitude. It was found that hydrogen presence has a significant influence upon the magnitude of the residual stresses, as its value decreases with high hydrogen content. This effect is reversible, as hydrogen desorbs from the sample the residual stress magnitude gains its initial value before hydrogen charging. KW - Energy dispersive diffraction KW - Hydrogen embrittlement KW - Residual Stress KW - Supermartensitic Steel PY - 2014 U6 - https://doi.org/10.4028/www.scientific.net/MSF.772.91 SN - 0255-5476 VL - 772 SP - 91 EP - 95 PB - Trans Tech Publications CY - Aedermannsdorf, Switzerland AN - OPUS4-29673 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mente, Tobias A1 - Böllinghaus, Thomas ED - Sommitsch, C. ED - Enzinger, N. T1 - Numerical model for hydrogen assisted cracking in duplex stainless steel microstructures N2 - Duplex stainless steels (DSS) are used in various industrial applications, e.g. in offshore construction as well as in chemical industry. But, at specific conditions, as for instance arc welding fabrication, cathodic protection or exposure to sour service environments, such materials can take up hydrogen which may cause significant property degradation particularly in terms of ductility losses which, in turn, may entail hydrogen assisted cracking (HAC). If HAC occurs in a duplex stainless steel the cracking mechanism is different from steels having only one phase, because hydrogen diffusion, stress-strain distribution and crack propagation are totally different in the austenite or ferrite phase. Whereas, the mechanism of hydrogen assisted crack initiation and propagation as well as hydrogen trapping in DSS have not been fully understood up to the present, as in most two-phase microstructures. In order to better understand the mechanisms of hydrogen assisted cracking in duplex stainless steels, knowledge of the diffusion behavior and of the stress-strain distribution in the ferritic and austenitic phase is of great interest. A numerical mesoscale model was created with a view to studying the hydrogen transport and the stresses and strains in each phase of duplex stainless steel. The material investigated in this work was DSS 1.4462, consisting of approximately equal portions of ferrite and austenite. Hydrogen diffusion in the duplex base metal was studied using the finite element program ANSYS. Stress-strain distribution as well as hydrogen assisted cracking in the ferritic and austenitic phase fractions were additionally investigated. The results of numerical simulation of the hydrogen diffusion process as well as structural analyses enable the identification of crack critical areas in the DSS microstructure. Numerical simulations qualitatively reflect the crack initiation and propagation process in ferrite. Crack critical combinations of hydrogen concentrations and local mechanical loads initiating HAC can be identified. T2 - 10th International seminar numerical analysis of weldability CY - Leibnitz, Austria DA - 24.09.2012 KW - Schweißen KW - Mathematisches Modell KW - Numerische Mathematik PY - 2013 SN - 978-3-85125-293-4 VL - 10 SP - 337 EP - 356 PB - Verlag der Technischen Universität Graz AN - OPUS4-29987 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hoffmeister, H. A1 - Böllinghaus, Thomas T1 - Modeling of combined anodic dissolution / hydrogen assisted stress corrosion cracking of low alloyed power plant steels in high temperature water environments N2 - High temperature SSRT - ductility data from cathodic hydrogen charging of 10CrMo910 and 7CrMoVTiB1010 are implemented into a mathematical model of SCC at various operational conditions including temperatures, pH and dissolved hydrogen/oxygen contents as well as global stresses and material properties. The results show that, as a consequence of experimentally verified local acidification at initial anodic path corrosion, subsequent local hydrogen assisted cracking can be a controlling factor for SCC in high temperature water. As a particular effect at global stresses close to the yield point, operational temperatures around 270°C exhibit peak crack growth rates depending on dissolved hydrogen, oxygen, pH and global stress, which has been found to be consistent for both, experimental studies and mathematical modeling. KW - Slow strain rate testing KW - Iron oxide precipitation KW - Anodic acidification KW - Stress corrosion cracking KW - Hydrogen assisted cracking PY - 2014 U6 - https://doi.org/10.5006/1048 SN - 0010-9312 SN - 1938-159X VL - 70 IS - 6 SP - 563 EP - 578 PB - National Association of Corrosion Engineers CY - Houston, Tex. AN - OPUS4-30097 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - Mesoscale modeling of hydrogen-assisted cracking in duplex stainless steels N2 - Quite a number of numerical models for hydrogen-assisted cracking in different kind of steels are existing reaching from simple analytical models to more complex two- and three-dimensional finite element simulations. These numerical models have been used to simulate the processes of hydrogen-assisted cracking in homogeneous microstructure. This paper contributes to numerical simulation of hydrogen-assisted cracking in heterogeneous microstructure, e.g., in a duplex stainless steel microstructure consisting of two phase fractions. If hydrogen is absorbed during welding or during service, i.e., due to cathodic protection, hydrogen is leading to material embrittlement and leads to hydrogen-assisted cracking. In order to improve understanding of the mechanisms of hydrogen-assisted cracking in duplex stainless steels, a numerical model has been created that operates at the mesoscale and enables simulation of stress–strain distribution as well as cracking in the various phases of a metallic material. Stress–strain distribution and hydrogen-assisted cracking in the duplex stainless steel 1.4462, consisting of approximately equal portions of ferrite and austenite, was simulated using the finite element program ANSYS. It was shown by numerical simulation that higher local stresses and strains are present at ferrite and austenite than the global stresses and strains in the duplex stainless steel, while the highest plastic deformations occur at austenite and the highest stresses can be found in small ferrite bars surrounded by ductile austenitic islands. By analyzing the stress–strain distribution in the duplex microstructure, crack critical areas in the ferrite can be identified. Hydrogen-assisted cracking was modeled assuming high hydrogen concentrations and regarding the local mechanical load in each phase of the duplex stainless steel. The mesoscale model qualitatively reflects the crack initiation and propagation process in the ferritic and austenitic phase of the duplex stainless steel. KW - Finite element analysis KW - Simulating KW - Duplex stainless steels KW - Stress distribution KW - Strain KW - Mathematical models KW - Hydrogen-assisted cracking KW - Hydrogen PY - 2014 U6 - https://doi.org/10.1007/s40194-013-0106-7 SN - 0043-2288 SN - 1878-6669 VL - 58 IS - 2 SP - 205 EP - 216 PB - Springer CY - Oxford AN - OPUS4-29442 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Wentland, Eva A1 - Jaßmann, R. A1 - Keller, R. A1 - Wolfrum, Anne T1 - Conservation of the Shaft #1 Headgear at the Tsumeb Mine, Namibia: Corrosion Protection N2 - The Tsumeb Mine in Namibia represents one of the best-preserved mining sites in the world and is rapidly gaining cross-disciplinary interest among cultural and engineering scientists. Most of the open pit and the shaft mining equipment are still in place, including the ore processing units and the local power plant. The mining area thus deserves recognition as an industrial world heritage site, especially due to the rarity of such locations on the African continent. The Shaft #1 headgear, built in 1924, represents one of the oldest known riveted steel headgears of the Promnitz design worldwide. In contrast to similar steel structures located in the northern hemisphere, it has been exposed to a different rural semi-arid climate since it is located in the Otavi Mountain Land, characterized by semi-annual change of rainy and dry seasons. Parts of the Shaft #1 headgear have remained largely untouched for more than 70 years. Besides its outstanding heritage value, it thus also represents an interesting object for studying the composition of corrosion layers formed on mild steel surfaces when exposed to continental and industrial mining atmospheres. To find a suitable transparent corrosion prevention coating, various on-site coating samples were evaluated after 11 months of outdoor exposure, including Owatrol Oil®, which is based on natural oil and alkyd resin with strong wicking potential. The substance is frequently applied for the conservation of single components but is not yet widely used on large steel structures in the field of industrial heritage conservation. However, it represented the most stable anti-corrosion coating under the local atmospheric conditions in the on-site tests. Thus, the suitability of Owatrol Oil® as a transparent coating for corrosion protection of riveted mild steel structures in such climates was further investigated as a more recent approach for the conservation of large steel structures. Since the protective coatings are exposed to strong UV radiation in the local climate, the addition of a specific UV stabilizer mixture was also tested. For such laboratory tests, two mild steel samples were taken. The first one originated from a diagonal strut of the 1920s and the second one from a handrail mounted in the early 1960s. Using corresponding high-resolution scanning electron microscopy (HR-SEM) and energy-dispersive X-ray spectroscopy (EDX) it was found that the corrosion layers are predominantly composed of lepidocrocite and goethite. A weathering program simulating the specific environmental conditions at Tsumeb in a UV climate chamber was developed and the corrosion resistance of the mild steel surface was subsequently evaluated by potentiodynamic measurements. Such tests proved to be a fast and reliable procedure for ranking the corrosion resistance of the old mild steels. It was found that the long-term corrosion layers already provide significant protection against further corrosion in the simulated environment. However, the study also showed that this can be further improved by the application of the Owatrol Oil® as a protective coating that also seals crevices. The addition of the UV stabilizers, however, led to a significant deterioration in corrosion protection, even in comparison to that of the uncoated long-term corrosion layers on the surface. Regular overcoating seems more advisable for the long-term preservation of the Shaft #1 headgear than modifying the Owatrol Oil® Coating with the tested UV-stabilizing additives. KW - Potentiodynamic measurements KW - Mining head gear KW - Mild steels KW - Chemical composition KW - Characterization of corrosion layers KW - Alkyd resin-based coating KW - UV-blocker addition KW - Weathering tests PY - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-541476 SN - 0039-3630 SP - 1 EP - 15 PB - Taylor & Francis Online AN - OPUS4-54147 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sobol, Oded A1 - Holzlechner, Gerald A1 - Nolze, Gert A1 - Wirth, Thomas A1 - Eliezer, D. A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang T1 - Time-of-Flight secondary ion mass spectrometry (ToF-SIMS) imaging of deuterium assisted cracking in a 2205 duplex stainless steel microstructure N2 - In the present work, the influence of deuterium on the microstructure of a duplex stainless steel type EN 1.4462 has been characterized by Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) supported by scanning electron microscopy (SEM), focused ion beam (FIB), electron back scattered diffraction(EBSD) and energy dispersive x-ray (EDX) investigations. Characterization has been carried out before and after electrochemical charging with deuterium which has been used as a tracer, due to its similar behavior to hydrogen in the steel microstructure. In a first approach, the distribution of the deuterium occurring at temperatures above 58 °C has been visualized. Further it turned out that sub-surface micro blisters are formed in the ferrite-austenite interface, followed by the formation of needle shaped plates and subsequent cracking at the ferrite surface. In the austenite phase, parallel cracking alongside twins and hexagonal close packed (martensitic) regions has been observed. In both phases and even in the apparent interface, cracking has been associated with high deuterium concentrations, as compared to the surrounding undamaged microstructure. Sub-surface blistering in the ferrite has to be attributed to the accumulation and recombination of deuterium at the ferrite-austenite interface underneath the respective ferrite grains and after fast diffusing through this phase. Generally, the present application of chemometric imaging and structural analyses allows characterization of hydrogen assisted degradation at a sub-micron lateral resolution. KW - ToF-SIMS KW - Hydrogen assisted cracking KW - Hydrogen embrittlement KW - SEM KW - FIB KW - EBSD PY - 2016 UR - http://www.sciencedirect.com/science/article/pii/S0921509316310334 U6 - https://doi.org/10.1016/j.msea.2016.08.107 SN - 0921-5093 VL - 676 SP - 271 EP - 277 PB - Elsevier B.V. AN - OPUS4-37298 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sobol, Oded A1 - Holzlechner, Gerald A1 - Holzweber, Markus A1 - Lohninger, H. A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang T1 - First use of data fusion and multivariate analysis of ToF-SIMS and SEM image data for studying deuterium-assisted degradation processes in duplex steels N2 - Time-of-flight secondary ion mass spectrometry (ToF-SIMS) and high-resolution scanning electron microscopy are well-acknowledged tools in materials characterization. The ability to map chemical species on the surface of an investigated sample with often low mass detection limits makes ToF-SIMS an essential tool in fields where many question marks concerning Degradation processes and damage mechanisms exist. The aim of this paper is to describe the power of data fusion of ToF-SIMS and high-resolution scanning electron microscopy results employing computational methods for multivariate data Analysis such as principal component analysis. As a case study the investigation of hydrogen distribution in an artificially charged Duplex stainless steel microstructure is presented aiming on a better understanding of hydrogen embrittlement. T2 - 16th European Conference on Applications of Surface and Interface Analysis CY - Granada, Spain DA - 28.09.2015 KW - ToF-SIMS KW - HR-SEM KW - Data fusion KW - Duplex stainless steel KW - Hydrogen embrittlement PY - 2016 UR - http://onlinelibrary.wiley.com/doi/10.1002/sia.6015/full U6 - https://doi.org/10.1002/sia.6015 VL - 48 IS - 7 SP - 474 EP - 478 PB - John Wiley & Sons, Ltd CY - Surface and Interface Analysis AN - OPUS4-36832 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Falkenreck, Thora E. A1 - Böllinghaus, Thomas T1 - Blast resistance of high-strength structural steel welds N2 - As consequence for increasing threats by IEDs (Improvised Explosive Devices) on vehicles, the blast resistance of the welded frames and bodies becomes increasingly important. Considering vehicle welds subjected to blasting, the real configurations of the joints in the structure and the position of the blast loads have to be considered. The present contribution thus focuses on a weld joint at the explosion endangered wheel well of a tactical truck. The high-strength steel welds were subsequently impacted by explosion loads within the upper range from those experienced in practical military operation to cause not only deformation, but also to investigate the ultimate fracture behaviour of the high-strength weld. The interaction between cooling time t8/5 and displacement, crack path as well as fracture surface was analysed. The analyses of the fracture surfaces revealed ductile overload failure and also the size of the dimples was influenced by the cooling time t8/5. As a prominent feature, these investigations showed that the crack path of such high-strength steel welds under blasting is less influenced by the final hardness level in the respective weld microstructures but much more affected by the hardness gradient at the fusion line and inside the Heat Affected Zone (HAZ). KW - Explosions KW - High strength steels KW - MAG welding KW - Cooling rate PY - 2016 U6 - https://doi.org/10.1007/s40194-016-0307-y SN - 0043-2288 SN - 1878-6669 VL - 60 IS - 3 SP - 475 EP - 483 PB - Springer CY - Heidelberg, Germany AN - OPUS4-36378 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Thomas T1 - Numerical investigations on hydrogen-assisted cracking in duplex stainless steel microstructures T2 - 4th International Workshop "Cracking Phenomena in Welds" CY - Berlin, Germany DA - 2014-04-02 PY - 2014 AN - OPUS4-31227 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wolf, Marcus A1 - Heynert, Katharina A1 - Böllinghaus, Thomas A1 - Pfennig, A. T1 - First in-situ electrochemical measurement during fatigue testing of injection pipe steels to determine the reliability of a saline aquifer water CCS-site in the Northern German basin N2 - During carbon dioxide storage technology (carbon capture and storage, CCS) components are exposed to a corrosive environment and mechanical stress, which results in corrosion fatigue and inevitably followed by the a lifetime reduction of these components. In order to gain knowledge upon the corrosion fatigue strength of materials, Samples of high alloyed stainless injection-pipe steels AISI 420 X46Cr13, and X5CrNiCuNb16-4 AISI 630 were tested in a at T=60 °C and ambient pressure in a CO2-saturated synthetic aquifer environment similar to possible geological on-shore CCS-sites in the northern German Basin. Therefore a corrosion chamber applied to a resonant testing machine allowing for “in situ” test conditions was designed and successfully tested. In-situ tension compression experiments were established using a resonant testing machine at a frequency as low as 30 – 40 Hz. In addition technical CO2 was introduced into the closed system at a rate close to 9 L/h to keep stable environmental conditions. Simultaneously electrochemical testing was performed to get information on failure causes and the mechanism of failure during the injection of CO2 into deep geological layers. S-N plots, micrographic analysis, and surface analysis of the fracture surface were applied to obtain sustainable information on the corrosion fatigue behavior of injection pipe steels. Samples used have a surface roughness of Rz = 4, to simulate technically machined surfaces. X46Cr13 reached the maximum number of cycles (12.5 x 106) at a stress amplitude of 173 MPa. X5CrNiCuNb16-4 reached the maximum number of cycles (10 x 106) at a stress amplitude at 150 MPa. The scatter range of X5CrNiCuNb16-4 is very high (1:34); by comparison the scatter range of X46Cr13 is only 1:3.5. T2 - GHGT-12 - Greenhouse gas control technologies conference CY - Austin, TX, USA DA - 05.10.2014 KW - Steel KW - Corrosion fatigue KW - Electrochemistry KW - Reliability KW - CCS KW - CO2-storage PY - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-319426 SN - 1876-6102 N1 - Serientitel: Energy Procedia – Series title: Energy Procedia VL - 63 SP - 5773 EP - 5786 PB - Elsevier Ltd. AN - OPUS4-31942 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas T1 - Hot cracking tests - an overview of present technologies and applications N2 - Hot crack prevention in materials production and processing is an essential prerequisite for welded component safety. The causes of hot cracking can ultimately be attributed to the occurrence of metallurgical effects and to structural loads. More than 140 hot cracking test procedures have hitherto been developed for determining the hot cracking resistance. In principle, they are divided in self-restraint and externally loaded hot cracking tests with diverse process variants. Only some of the hot cracking tests are international standardized. Although various factors are known that encourage or prevent hot cracking, it is often not possible even with defined welding conditions to draw immediate conclusions about the hot cracking resistance of a welded component alone from a metallurgical composition of the base and filler materials. Based on an evaluation of the existing theories relating to hot cracking susceptibility assessment, this study summarizes the major hot cracking test procedures and highlights the application limits of the test procedures by presenting overviews along with explanations. It shows that weld hot cracking tests can generally be used to rank materials, welding consumables, and welding conditions. The evaluation of hot cracking test results and of their transferability among one another and to real components always requires consideration of the close relationships between metallurgy, welding process, and parameters, respectively, and prevailing restraint conditions. KW - Arc welding KW - Quality control KW - Weldability tests KW - Cracking KW - Hot cracking KW - Solidification cracking PY - 2014 U6 - https://doi.org/10.1007/s40194-014-0126-y SN - 0043-2288 SN - 1878-6669 VL - 58 IS - 3 SP - 397 EP - 421 PB - Springer CY - Oxford AN - OPUS4-30611 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Bauer, Margit T1 - Investigation of iron containers for storage of hydrogen gas – Translation of the Adolf Martens’ spectacular failure investigation report published in 1896 N2 - More than 400 iron hydrogen storage containers (also called bottles or cylinders exploded on the air strip Berlin-Tempelhof on May 25, 1894, leaving immense destruction. The Royal Prussian Materials Testing Institute was requested to investigate the material properties and to furnish an expertise, how an increased safety of such cylinders might be achieved for the future under protection of the interests of the air ship service, as for instance by improvement of delivery specifications or respective material inspections. The studies conducted personally by the director Prof. Adolf Martens and his deputy Prof. M. Rudeloff represent one of the first comprehensive failure case investigations in history and initiated BAMs long tradition in failure analysis. Martens and his colleague elaborated quite detailed specimen plans and investigated original failure parts with a special emphasis on conspicuous fracture appearance, but also made comparison experiments with hardened as well as annealed samples. Experienced investigators might identify some first routines how to conduct failure analyses and the importance of Adolf Martens as a pioneer in this field becomes evident. Martens publications about the original expertise Martens, 1896 [1] and [2] include detailed descriptions about the experimental procedures and specimen preparation. Also, quite modern materials testing technologies and machines have been utilized, as for instance light microscopy as well as the tensile testing machines developed by Werder and Pohlmeyer. As special features developed by Martens, precision strain measurements have been applied during respective tensile tests and the so-called micro-photographic apparatus has been adopted to produce photos of the investigated microstructures. Additionally, the publications contain at that time very valuable advices regarding appropriate materials selection for gas storage cylinders. The present contribution provides a nearly complete and as exact as possible translation of the original report Martens, 1896 [1] written in Old German language. Only little changes have been made in the text for a better understanding. KW - Explosion KW - Hydrogen storage cylinders KW - Microstructure KW - Tensile tests KW - Bend tests PY - 2014 U6 - https://doi.org/10.1016/j.engfailanal.2014.03.018 SN - 1350-6307 SN - 1873-1961 VL - 43 IS - Special Issue 'A Tribute to Prof. A. Martens' SP - 11 EP - 46 PB - Elsevier Ltd. CY - Oxford AN - OPUS4-31083 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Hydrogen-Assisted Cracking of a Subsea-Flowline T2 - Workshop "Hot Cracking Phenomena in Welds IV" CY - Berlin, Germany DA - 2014-04-02 PY - 2014 AN - OPUS4-31091 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Mechanisms of Stress Corrosion Cracking in Welds T2 - Workshop "Hot Cracking Phenomena in Welds IV" CY - Berlin, Germany DA - 2014-04-02 PY - 2014 AN - OPUS4-31092 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Kannengießer, Thomas A1 - Cross, Carl Edward A1 - Böllinghaus, Thomas ED - Karl-Heinrich Grote, ED - Erik K. Antonsson, T1 - Modern Joining Technology - Weld Simulation PY - 2009 SN - 978-3-540-49131-6 IS - Part B / 7.4.8 SP - 706 EP - 723 PB - Springer AN - OPUS4-19047 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Stelling, Karen A1 - Lammers, Marco A1 - Gumenyuk, Andrey A1 - Böllinghaus, Thomas A1 - Rethmeier, Michael T1 - Laser Plasma Hybrid Welding of Austenitic Stainless Steels - Phenomena of Process Instability N2 - Laser plasma hybrid welding has been proved to be a very stable hybrid welding process and welds of high quality can be produced, especially if high surface quality and low spattering is demanded such as in welding fabrication of high alloyed austenitic stainless steels. In particular cases, even though welds display high outer quality, X-ray examinations revealed weld defects which may range from low porosity to blowhole-like cavities. The phenomena and the main influencing parameters such as arc current, welding speed and focal point position are discussed. Parameter fields will be suggested for welding plates of different austenitic stainless steel grades with thicknesses ranging from 3 to 8 mm. The results are based on welding experiments carried out using a 4.4 kW diode pumped Nd:YAGlaser. Thus, also the influence of the feeding fibre diameter has been investigated and it was found that the resulting beam shape has a major effect on the welding performance. T2 - 60th IIW Annual Assembly CY - Dubrovnik, Croatia DA - 2007-07-01 KW - Laser KW - Plasma KW - Hybrid welding KW - Pores KW - Cavities KW - Root dropping KW - Austenitic steel PY - 2007 IS - IV-933-07 SP - 1 EP - 14 PB - International Institute of Welding CY - Paris AN - OPUS4-18677 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Wongpanya, Pornwasa T1 - Stress strain build-up during cooling of high strength structural steels welds T2 - IIW Meeting CY - Paris, France DA - 2008-03-12 PY - 2008 AN - OPUS4-23608 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Safety of welded tubular components against hydrogen assisted cracking T2 - WMRIF Young scientists workshop CY - Tsukuba, Japan DA - 2008-07-22 PY - 2008 AN - OPUS4-23611 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Ways to reduce the cold cracking risk in high strength structural steel welds T2 - The South African Institute of Welding 60th Anniversary Conference CY - Johannesburg, South Africa DA - 2008-05-28 PY - 2008 AN - OPUS4-23612 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Structure and task of modern research organisations T2 - WMRIF-Treffen (World Materials Research Institute Forum) CY - Gaithersburg, MD, USA DA - 2009-02-05 PY - 2009 AN - OPUS4-23614 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Keynote Lecture: Hot cracking in austenitic stainless steel welds T2 - Hot cracking workshop CY - Columbus, OH, USA DA - 2010-03-17 PY - 2010 AN - OPUS4-23615 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Wongpanya, Pornwasa T1 - Numerical modelling of cold cracking initiation and propagation in S 1100 QL steel root welds T2 - IIW Intermediate Meeting CY - Singapore DA - 2009-03-19 PY - 2009 AN - OPUS4-23598 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Wongpanya, Pornwasa T1 - Residual stress distribution in interacting steels welds T2 - IIW Annual Assembly CY - Singapore DA - 2009-07-14 PY - 2009 AN - OPUS4-23600 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Heat treatments for sufficient hydrogen removal in high strength steel T2 - IIW Annual Assembly CY - Istanbul, Turkey DA - 2010-07-14 PY - 2010 AN - OPUS4-23601 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Spotlight of crystallisation and solidification processes in solutions and melts T2 - Symposium "Frontiers in nanotechnology and materials" CY - Tsukuba, Japan DA - 2009-10-22 PY - 2009 AN - OPUS4-23602 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Hydrogen assisted cracking in welds T2 - FESI-NPL Workshop hydrogen meeting CY - London, England DA - 2008-02-12 PY - 2008 AN - OPUS4-23604 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Holzlechner, Gerald A1 - Sobol, Oded A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang ED - Udomkichdecha, W. ED - Mononukul, A. ED - Böllinghaus, Thomas ED - Lexow, Jürgen T1 - Imaging ToF-SIMS as a chemical metrology tool to support material and analytical science N2 - As a chemical metrology tool time-of-flight secondary ion mass spectrometry (ToF-SIMS) has become a very popular technique to monitor the elemental, isotopic and molecular distribution in two or three dimensions. Its reduced sampling depth, high sensitivity, great structural specificity and the direct detection of hydrogen thereby increase the emergence of ToF-SIMS for material and analytical surface science, particularly due to recent instrumental developments improving mass, depth and lateral resolution. For basic surface science, adsorption processes and surface reactivity thus can be investigated in high detail on organic as well as inorganic samples. The use of multivariate data analysis in addition can effectively assist to identify trends in the complex SIMS raw data set and define key co-variances between certain samples or mass spectra. In this contribution the essence of ToF-SIMS is illustrated by discussing two highly relevant energy applications. First, for piezoelectric electroceramics oxygen exchange active zones have been visualized to determine the impact of external field-load to the oxygen vacancy distribution between anode and cathode. As a second case study the interaction of hydrogen species with the microstructure of a duplex stainless steel was investigated. It was concluded that ToF-SIMS has a valuable essence for detailing hydrogen related degradation mechanisms. T2 - 4th WMRIF Young scientists workshop CY - Boulder, CO, USA DA - 08.09.2014 PY - 2016 SN - 978-981-287-723-9 SN - 978-981-287-724-6 U6 - https://doi.org/10.1007/978-981-287-724-6_7 SP - 63 EP - 72 PB - Springer AN - OPUS4-34881 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Hoffmeister, H. A1 - Böllinghaus, Thomas T1 - Modeling the effects of dissolved hydrogen, temperature, pH, and global stress on stress corrosion cracking of a Cr-Ni model alloy in high-temperature water N2 - As an extension of recently presented stress corrosion cracking (SCC) models for pure nickel and iron in high-temperature water, the anodic path, hydrogen-assisted stress corrosion cracking of a model Cr-Ni alloy is presented, utilizing Alloy 600 (UNS 06600) mechanical properties. With the local anodic path corrosion as the crack initiation phase, the respective oxides precipitate while the crack tip solution acidify and establish local hydrogen ion reduction conditions. Depending on the applied global stress, local plastic straining then provides an active crack tip surface that transfers atomic hydrogen to the plastic zone ahead of the crack tip. Hydrogen-assisted crack propagation is then controlled by the calculated local hydrogen ion reduction charge and the plastic strain distribution ahead of the crack tip. The results show that for global stress levels close to the yield stress and at constant dissolved oxygen contents, the increasing dissolved hydrogen contents provide peak crack growth rates at hydrogen levels that decrease both with increasing temperatures and bulk pH. The peak crack growth rates also decrease with decreasing global stress as well as with increasing temperature and increasing bulk pH. The results are in accordance with published experimental investigations and operational experiences regarding the effects of dissolved hydrogen on stress corrosion rates in high-temperature waters of nuclear reactors. They are explained by the interaction between the electrochemical parameters of the respective reactions. KW - Chromium-nickel alloy KW - Dissolved hydrogen KW - High-temperature water KW - Stress corrosion cracking PY - 2015 U6 - https://doi.org/10.5006/1443 SN - 0010-9312 SN - 1938-159X VL - 71 IS - 5 SP - 559 EP - 573 PB - National Association of Corrosion Engineers CY - Houston, Texas, USA AN - OPUS4-33114 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Mente, Tobias A1 - Böllinghaus, Thomas ED - Udomkichdecha, W. ED - Mononukul, A. ED - Böllinghaus, Thomas ED - Lexow, Jürgen T1 - Numerical investigations on hydrogen-assisted cracking (HAC) in duplex stainless steels N2 - Duplex stainless steels have been used for a long time in the offshore industry, since they have higher strength than conventional austenitic stainless steels and they exhibit a better ductility as well as an improved corrosion resistance in harsh environments compared to ferritic stainless steels. However, despite these good properties the literature shows some failure cases of duplex stainless steels in which hydrogen plays a crucial role for the cause of the damage. Numerical simulations can give a significant contribution in clarifying the damage mechanisms. Therefore, a numerical model of a duplex stainless steel microstructure was developed enabling simulation of crack initiation and propagation in both phases. The phase specific stress strain analysis revealed that local plastic deformation occurs in both austenite and δ-ferrite already in the macroscopically elastic range. Altogether, phase specific hydrogen-assisted material damage was simulated for the first time taking into account all main factors influencing hydrogen assisted cracking process. The results agree well with experimental observations and thus allow a better insight in the mechanism of hydrogen-assisted material damage. T2 - 4th WMRIF Young scientists workshop CY - Boulder, CO, USA DA - 2014-09-08 KW - Hydrogen-assisted cracking (HAC) KW - Numerical simulation KW - FEM KW - Duplex stainless steel (DSS) KW - Mesoscale model PY - 2016 SN - 978-981-287-723-9 SN - 978-981-287-724-6 U6 - https://doi.org/10.1007/978-981-287-724-6_3 SP - 21 EP - 31 PB - Springer AN - OPUS4-35075 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Schäden an Schweißverbindungen einer Ro-Ro-Fähre T2 - VDI-GME Fachausschuss "Expertenkreis Schadensanalyyse" CY - München DA - 2015-05-06 PY - 2015 AN - OPUS4-33160 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas T1 - Hydrogen assisted cracking in advanced steels T2 - First International Symposium on Structural Materials for Innovation CY - Tokyo, Japan DA - 2015-02-26 PY - 2015 AN - OPUS4-32758 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias T1 - Numerical investigation on hydrogen-assisted cracking in duplex stainless steel microstructures T2 - 4th International Workshop "Cracking Phenomena in Welds" CY - Berlin, Germany DA - 2014-04-02 PY - 2014 AN - OPUS4-32686 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Mente, Tobias A1 - Steppan, Enrico T1 - Numerical Modelling of Hydrogen Assisted Cracking in Steel Welds T2 - 4th International Workshop "Cracking Phenomena in Welds" CY - Berlin, Germany DA - 2014-04-02 PY - 2014 AN - OPUS4-32705 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - Modeling of hydrogen-assisted cracking (HAC) in duplex stainless steels (DSS) N2 - Modeling of Hydrogen-Assisted Cracking (HAC) in Duplex Stainless Steels (DSS): - Hydrogen causes significant degradation in DSS and consequently HAC - Mechanisms of HAC have not been fully understood in two-phase microstructures - Mesoscale numerical modeling for HAC in DSS was created, coupled to the macroscale, enabling simulation of HAC in both phases independent from predefined crack paths T2 - International Hydrogen Conference - Material Performance in Hydrogen Environments CY - Jackson Lake Lodge, Moran, Wyoming, USA DA - 11.09.2016 KW - Hydrogen KW - Numerical modeling KW - Duplex stainless steel KW - Hydrogen assisted cracking PY - 2016 AN - OPUS4-37404 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Holzweber, Markus A1 - Sobol, Oded A1 - Wirth, Thomas A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang T1 - Deuterium permeation and cracking in duplex steels as viewed by ToF-SIMS and HR-SEM with data fusion N2 - Better understanding of hydrogen assisted degradation and trapping mecha-nisms requires sufficient imaging techniques for respective hydrogen-microstructure interaction studies, in particular with multi-phase metallic micro-structures [1]. The present work is focusing on the elucidation of deuterium be-havior in two austenitic-ferritic duplex stainless steels (DSS) under the assumption that deuterium behaves in many ways similarly to hydrogen [2]. For case studies standard 2205 and lean 2101 DSSs were chosen due to the extensive use of these steels in industry [3]. The analyses were conducted by using a novel in-situ permeation and Time-of-Flight secondary ion mass spectrometry (ToF-SIMS) imaging technique or by ex-situ ToF-SIMS imaging following electrochemical charging experiments. Another pioneering procedure was data fusion (including chemometry) of results of powerful laterally resolved chemical analysis and high resolution structural characterization techniques . Results for the ex-situ observations showed a different influence of deuterium loading on the two steel grades as well as different damage mechanisms in each phase. Formation of sub-surface blisters between the ferrite and austenite were obtained in both the standard and the lean DSS. In both steels, an increased deuterium concentration was observed around deformed regions such as cracks, confirming that they originate from the presence of deuterium [4]. The formation of parallel cracks was obtained only in the austenite within the standard duplex whereas in the lean duplex the highest intensity of deuterium was obtained in the austenite along the ferrite-austenite interphase. In comparison, application of the novel in-situ permeation technique enabled to register and record the deuterium permeation through the material and the respective saturation sequence of the two phases as well as the interfaces. Faster diffusion of the deuterium was observed in the ferrite and a direct proof for deuterium enrichment at the austenite-ferrite interface has been given [1]. The integration of the specified techniques gives a better insight into the processes leading to hydrogen induced failure. These two experimental techniques provide very valuable tools for elucidation of respective metallurgical failure mechanisms that can be used for the validation of respective numerical models for hydrogen assisted cracking (HAC). T2 - 19. Arbeitstagung Angewandte Oberflächenanalytik CY - Soest, Germany DA - 05.09.2016 KW - ToF-SIMS KW - Hydrogen assisted cracking KW - Data fusion KW - SEM PY - 2016 AN - OPUS4-37484 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Silverstein, R. A1 - Sobol, Oded A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang A1 - Eliezer, D. T1 - Hydrogen behavior in SAF 2205 duplex stainless steel N2 - This paper describes austenitic-ferritic duplex stainless steels, SAF 2205, in the presence of hydrogen. The duplex stainless steels (DSS) properties include excellent resistance to stress corrosion cracking, high strength and good weldability. Those steels are preferably used in industries combining hydrogen and loads. Hydrogen location in addition to hydrogen binding energy with the steel's defects are of great importance for the analysis of hydrogen embrittlement model in that steel. It is known from previously published works that the susceptibility to hydrogen embrittlement will depend on the competition between reversible and irreversible traps; meaning a direct relation to the hydrogen's state and position in the steel. In this work, we examine the local hydrogen concentration, trapping and distribution by two modern and advanced techniques: thermal desorption spectrometry (TDS) and we support it by time of flight-secondary ion mass spectrometer (ToF-SIMS). In this paper, we support and give for the first time new insights and better understanding to the hydrogen embrittlement mechanism in SAF 2205. The trapping energies levels were calculated using TDS and Lee and Lee's model. This model revealed reversible in addition to irreversible trapping sites. Also the trapping controlling mechanism was found to be a combination of detrapping controlled mechanism and diffusion controlled mechanism. The use of ToF-SIMS for local imaging the distribution of hydrogen species supports the discussion of the different hydrogen traps in this type of steel. The hydrogen embrittlemet phenomenon in SAF 2205 will be discussed in details in that paper. KW - Hydrogen trapping KW - Duplex stainless steel KW - Thermal desorption spectrometry (TDS) KW - ToF-SIMS PY - 2017 U6 - https://doi.org/10.1016/j.jallcom.2016.11.184 SN - 0925-8388 SN - 1873-4669 VL - 695 SP - 2689 EP - 2695 PB - Elsevier B.V. AN - OPUS4-38856 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Münster, C. A1 - Mente, Tobias A1 - Rhode, Michael A1 - Böllinghaus, Thomas ED - Sommitsch, C. ED - Enzinger, N. ED - Mayr, P. T1 - Modelling of hydrogen diffusion in power station steels and influence of experimental conditions on the determination of diffusion coefficients N2 - In the field of modelling hydrogen assisted cracking (HAC) phenomenon, hydrogen diffusivity is an important input parameter for numerical simulation. In terms of hydrogen diffusion coefficients, they have great impact on realistic assessment of the evolution of possible crack critical hydrogen concentrations. In addition, the chemical compositions of steels can have a strong effect on hydrogen diffusion. Unfortunately, literature provides a wide range of available hydrogen diffusion coefficients even for similar microstructures and equal temperatures. The scattering of the data can lead to significant deviations in the results of simulating the evolving hydrogen concentrations due to hydrogen uptake (by fabrication or service). Thus, the application of such data to crack-models or for component life tie predictions can be realized up to the present only by considering envelope curves of such value, corresponding to a work or bench case scenario, respectively. For improved reliability of numerical simulaitons, it is necessary to minimize the mentioned deviation of these data. Hence, this work focuses on the validation of hydrogen diffusion coefficients obtained from permeation experiments at room temperature. Two baintic steels with different alloying concepts were investigated, the creep-resistant 7CrMoVTiB10-10 and the reactor pressure vessel grade 20MnMoNi4-5. A numerical model is presented for simulation of the corresponding hydrogen diffusion during permeation experiments using the finite element software ANSYS. Three different diffusion coefficients (obtained from different common calculation methods) are considered and compared to numerical results. The vases of thes calculation methods are permeation transients which are a direct measure for hydrogen. The results of the simulated hydrogen diffusion coefficients show that only one procedure for calculation of diffusion coefficitnes is suitable in comparision to the experimental values. Thus, it is suggested to use this method for analysis of experimental results in case of hydrogen diffusion during permeation experiments. Furthermore, this work supplies validated values for the hydrogen diffusion coefficients of both steel grades. KW - Hydrogen KW - Diffusion Coefficient KW - Numerical Simulation KW - Permeation KW - Creep-resistant Steel KW - Pressure Vessel Steel PY - 2016 SN - 978-3-85125-490-7 SN - 2410-0544 SP - 435 EP - 457 PB - Technische Universität Graz CY - Graz AN - OPUS4-38917 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Wolf, Marcus A1 - Afanasiev, Roman A1 - Böllinghaus, Thomas A1 - Pfennig, A. T1 - Investigation of Corrosion Fatigue of Duplex Steel X2CrNiMoN22-5 3 Exposed to a Geothermal Environment under Different Electrochemical Conditions and Load Types N2 - Corrosion fatigue (CF) of duplex stainless steel (DSS) X2CrNiMoN22-5-3 was investigated in in-situ geothermal conditions of the Northern German Basin (NGB). The influence of the load type on CF behavior of the alloy was examined by applying push/pull and rotating bending cyclic load to failure. The hour-glass shaped specimens with both polished and precisely turned surface finish were tested in corrosion chambers allowing for the permanent circulation of Northern German Basin electrolyte heated to 369 K. Additionally, the influence of a protective cathodic potential on the CF life expectancy was investigated by employing a potentiostat. The rotating bending cyclic load led to a higher CF life expectancy, which decreased with increasing duration of the experiment due to a higher deterioration rate of the material. The application of a cathodic potential caused a significant increase of the CF lifespan from 4.7 x 105 (open-circuit potential (OCP)) to 107 cycles (preset threshold cycle number) for the potential range from USHE = – 450 to – 900 mV. Microstructural analysis of the CF damage revealed horizontal grain attack within corrosion pit cavities, multiple fatigue cracks and preferable deterioration of the austenitic phase. T2 - 13th International Conference on Greenhouse Gas Control Technologies, GHGT-13 CY - Lausanne, Switzerland DA - 14.11.2016 KW - Different load cases KW - Corrosion fatigue KW - DSS KW - Geothermal environment KW - Different electrochemical conditions PY - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-439231 SN - 1876-6102 VL - 114 SP - 5337 EP - 5345 PB - Elsevier Science AN - OPUS4-43923 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Falkenreck, Thora E. A1 - Kromm, Arne A1 - Böllinghaus, Thomas T1 - Investigation of physically simulated weld HAZ and CCT diagram of HSLA armour steel N2 - The phase transformation under various cooling rates and in different HAZ regions for high-strength armour steel was analysed by dilatometry. To develop a continuous cooling transformation (CCT) diagram, the samples were heated up to a peak temperature of 1250 °C to achieve a coarse-grained microstructure and then cooled down with a cooling time t 8/5 varying from 3 to 240 s. Analysis of dilatation curves revealed the austenite decomposition process, during which transformation temperatures were determined. The results showed martensitic transformations for all welding-relevant cooling times. Furthermore, to analyse different heat-affected subzones of the weld, the peak temperature was varied between 550 and 1250 °C at a constant cooling time t 8/5 of 6 s. The simulated coarse-grained heat-affected zone (CGHAZ) and fine-grained-heat affected zone (FGHAZ) showed only martensitic transformations with transformation temperatures below 400 °C. The steel exhibited an inhomogeneous hardness with hardening in the CGHAZ and FGHAZ and softening in the intercritical and subcritical HAZ. The physically simulated microstructure was validated by a real hybrid laser-arc weld microstructure. KW - Dilatometry KW - High-strength steels KW - CCT diagrams KW - Heat-affected zone PY - 2018 U6 - https://doi.org/10.1007/s40194-017-0511-4 SN - 0043-2288 SN - 1878-6669 VL - 62 IS - 1 SP - 47 EP - 54 PB - Springer AN - OPUS4-44716 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael A1 - Böllinghaus, Thomas T1 - Hydrogen absorption and diffusion in T24 steel weld joints and effect on mechanical properties N2 - The present contribution summarizes results obtained from experiments with low-alloyed boiler steel grades T24 (CrMoV alloy), T22 (CrMo) and thermally simulated T24 HAZ microstructure and pure weld metal. The hydrogen absorption and diffusion behavior was investigated by permeation experiments and thermal desorption analysis (TDA). The results showed significant weld microstructure influence on diffusion by hydrogen trapping. Trapped hydrogen was determined in the T24 BM at temperatures up to 120 °C compared to 75 °C in the T22. In addition, the T24 HAZ showed decreased diffusion coefficients (at room temperature) of approximately one magnitude compared to the BM. For the mechanical properties, tensile tests were conducted with electrochemically hydrogen charged specimens and compared to results obtained from slow strain rate tests (SSRT) in high-temperature water up to 200 °C. The as-welded HAZ had remarkably increased susceptibility compared to the BM already at low hydrogen concentration of 1-2 ppm. The SSRT were conducted for free corrosion and acidic environment and confirmed this behavior at elevated temperatures for both HAZ microstructures of T24 and T22. Summarized, each weld microstructure has specific diffusion coefficients and shows different susceptibility to degradation of the mechanical properties, i.e. delayed hydrogen assisted cracking or stress corrosion cracking. T2 - NACE Italia - 2nd Conference & Expo 2018 CY - Genoa, Italy DA - 28.05.2018 KW - Hydrogen KW - Stress corrosion cracking KW - Welding KW - Creep-resistant steel PY - 2018 SP - Paper 10, 1 EP - 7 AN - OPUS4-45081 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mente, Tobias A1 - Böllinghaus, Thomas ED - Somerday, B. P. ED - Sofronis, P. T1 - Mesoscale Numerical Simulation of Hydrogen-Assisted Cracking in Duplex Stainless Steels N2 - A two-dimensional numerical mesoscale model has been created representing a microstructure of a typical 2205/1.4462 duplex stainless steel to further elucidate the mechanisms of hydrogen-assisted crack initiation and propagation in multiphase non-hydride forming metallic microstructures. Hydrogen-assisted cracking (HAC) was simulated by considering different stress and strain behavior as well as different diffusion behavior in both phases. For simulation of crack initiation and propagation, the element elimination technique has been applied. The model allows the simulation of path-free crack propagation which contributes to a better understanding of the HAC process in two-phase microstructures. As a particular result, the analyses revealed that a global macroscopic elastic deformation might already cause plastic deformation in both phases entailing respective HAC. T2 - International Hydrogen Conference CY - Jakson Lake Lodge, Wyoming, USA DA - 11.09.2016 KW - Computer simulation KW - Cracking (Materials) KW - Fracture (Process) KW - Hydrogen KW - Stainless steel PY - 2017 SN - 978-0-7918-6138-7 U6 - https://doi.org/10.1115/1.861387_ch67 SP - 589 EP - 596 PB - The American Society of Mechanical Engineers (ASME) CY - New York AN - OPUS4-45680 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Mente, Tobias A1 - Böllinghaus, Thomas ED - Böllinghaus, Thomas ED - Lippold, J. C. ED - Cross, C. E. T1 - Numerical investigations on hydrogen-assisted cracking in duplex stainless steel microstructures N2 - Duplex stainless steels (DSS) are used in various industrial applications, e.g. in offshore constructions as well as in chemical industry. DSS reach higher strength than commercial austenitic stainless steels at still acceptable ductility. Additionally, they exhibit an improved corrosion resistance against pitting corrosion and corrosion cracking in harsh environments. Nevertheless, at specific conditions, as for instance arc welding, cathodic protection or exposure to sour service environments, such materials can take up hydrogen which may cause significant property degradation particularly in terms of ductility losses which, in turn, may entail hydrogen-assisted cracking (HAC). The cracking mechanism in DSS is different from steels having only a single phase, because hydrogen diffusion, stress-strain distribution and crack propagation are different in the austenite or ferrite phase. Therefore, the mechanism of HAC initiation and propagation as well as hydrogen trapping in DSS have not been fully clarified up to the present, as for most of the two-phase microstructures. At this point the numerical simulation can bridge the gap to a better insight in the cracking mechanism regarding the stress-strain distribution as well as hydrogen distribution between the phases, both austenite and ferrite, of the DSS. For that purpose, a two dimensional numerical mesoscale model was created representing the microstructure of the duplex stainless steel 1.4462, consisting of approximately equal portions of austenite and ferrite. Hydrogen assisted cracking was simulated considering stresses and strains as well as hydrogen concentration in both phases. Regarding the mechanical properties of austenite and ferrite different statements can be found in the literature, dependent on chemical composition and thermal treatment. Thus, various stress-strain curves were applied for austenite and ferrite simulating the HAC process in the DSS microstructure. By using the element elimination technique crack critical areas can be identified in both phases of the DSS regarding the local hydrogen concentration and the local mechanical load. The results clearly show different cracking behavior with varying mechanical properties of austenite and ferrite. Comparison of the results of the numerical simulation to those of experimental investigations on DSS will improve understanding of the HAC process in two phase microstructures. KW - duplex stainless steel 1.4462 (2205) KW - numerical simulation KW - hydrogen assisted cracking KW - diffusion PY - 2016 UR - http://link.springer.com/chapter/10.1007%2F978-3-319-28434-7_16 UR - http://www.springer.com/us/book/9783319284323 SN - 978-3-319-28432-3 SN - 978-3-319-28434-7 U6 - https://doi.org/10.1007/978-3-319-28434-7_16 SP - Part V, 329 EP - 359 PB - Springer International Publishing CY - Switzerland ET - 1 AN - OPUS4-35591 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Steppan, Enrico A1 - Mente, Tobias ED - Böllinghaus, Thomas ED - Lippold, J. C. ED - Cross, C. E. T1 - Hydrogen assisted cracking of a subsea-flowline N2 - Since the mid-nineties, supermartensitic stainless steels (SMSS) have increasingly been applied to welded subsea-pipeline systems in the North Sea oil and gas fields, especially to flowlines at mild sour service conditions. However, in 2001 cracking and leaks occurred during installation and service start-up of two SMSS flowlines in the Norwegian Tune gas condensate field, welded with a new developed matching filler wire. Brittle transgranular cracking started especially at inter-run lack of fusion and propagated brittle, predominantly through the weld metal. The present paper provides a brief overview of the original failure case and respective sequence of events leading to complete replacement of the SMSS by carbon steel flowlines in 2002. Then, detailed investigations of a circumferential weld sample of the failed Tune flowline are highlighted, targeted at comparison of the failure appearance to previous investigations of this filler material type and to search for possible explanations for the brittle fracture at the crack initiation area. SEM investigations of the fracture surface revealed brittle areas only in the direction towards the top side of the weld while the major part of the investigated surface exhibited ductile fracture. As an approach to clarify, if the fracture was a consequence of hydrogen assisted cracking, five small sized specimens have been cut out of the original sample. Cracking has been introduced parallel to the original fracture surface in these specimens at respective saw cuts and bending. The results show that brittle transgranular cracking appeared only in the specimen cooled down to very low temperatures by liquid nitrogen and in the sample charged with hydrogen to an average concentration of about 15 ml/100 g. However, a fracture similar to the original surface was observed only in the hydrogenized specimen. As a further result, very similar fracture surfaces of supermartensitic stainless steel weld metals had been observed on specimens subjected to hydrogen assisted cold cracking (HACC) as well as to hydrogen assisted stress corrosion cracking (HASCC). In total, the results indicate that brittle fracture starting at the inter-run lack of fusion were not initiated by high notch tip deformation rates, but rather influenced by hydrogen, probably taken up during welding. KW - supermartensitic stainless steel KW - hydrogen assisted cracking KW - fracture topography PY - 2016 UR - http://link.springer.com/chapter/10.1007/978-3-319-28434-7_17 UR - http://www.springer.com/us/book/9783319284323 SN - 978-3-319-28432-3 SN - 978-3-319-28434-7 U6 - https://doi.org/10.1007/978-3-319-28434-7_17 SP - Part V, 361 EP - 379 PB - Springer International Publishing CY - Switzerland ET - 1 AN - OPUS4-35592 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - GEN A1 - Böllinghaus, Thomas A1 - Mente, Tobias A1 - Wongpanya, Pornwasa A1 - Viyanit, Ekkarut A1 - Steppan, Enrico ED - Böllinghaus, Thomas ED - Lippold, J. C. ED - Cross, C. E. T1 - Numerical modelling of hydrogen assisted cracking in steel welds N2 - Hydrogen assisted stress corrosion and cold cracking represent still a major topic regarding the safety of welded steel components against failure in many industrial branches. Hydrogen might be introduced during fabrication welding or might be taken up from an environment during sour service or at cathodic protection. Additionally, understanding and avoidance of hydrogen entry into weld microstructures from gaseous pressurized environments becomes increasingly important for renewable energy components. There are two types of metallurgical mechanisms associated with hydrogen assisted cracking, i.e. the cracking as well as hydrogen transport and trapping mechanisms. For numerical modelling, it has to be considered that both types are not independent of each other, that the mechanisms are not yet completely clarified and that validation of such models strongly depends on implementation of the correct hydrogen related materials properties. However, quite significant achievements have been made in modelling of hydrogen assisted cracking by indirect coupling of thermal, stress-strain as well as hydrogen uptake and diffusion analyses. After a brief introduction into the subject and by revisiting various proposed cracking mechanisms, the present contribution focuses on recent developments of a numerical model based on a comparison of actual hydrogen concentrations and mechanical loads with respective hydrogen dependent material properties as crack initiation and propagation criteria. The basic procedure for numerical simulation of crack initiation and propagation is outlined and it is shown how such numerical simulations can be validated experimentally. Furthermore, it is highlighted how such a procedure has been extended to a comprehensive model for life time prediction of welded steel pipeline components and experimentally verified. Finally, it is outlined how the model can be extended to simulate cracking in heterogeneous steel microstructures on the different scales. KW - hydrogen assisted cracking KW - numerical simulation KW - supermartensitic stainless steel KW - high strength low alloyed structural steel KW - duplex stainless steel PY - 2016 UR - http://link.springer.com/chapter/10.1007%2F978-3-319-28434-7_18 UR - http://www.springer.com/us/book/9783319284323 SN - 978-3-319-28432-3 SN - 978-3-319-28434-7 U6 - https://doi.org/10.1007/978-3-319-28434-7_18 SP - Part VI, 383 EP - 439 PB - Springer International Publishing CY - Switzerland ET - 1 AN - OPUS4-35593 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sobol, Oded A1 - Straub, F. A1 - Wirth, Thomas A1 - Holzlechner, G. A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang T1 - Real Time Imaging of Deuterium in a Duplex Stainless Steel Microstructure by Time-of-Flight SIMS N2 - For more than one century, hydrogen assisted degradation of metallic microstructures has been identified as origin for severe technical component failures but the mechanisms behind have not yet been completely understood so far. Any in-situ observation of hydrogen transport phenomena in microstructures will provide more details for further elucidation of these degradation mechanisms. A novel experiment is presented which is designed to elucidate the permeation behaviour of deuterium in a microstructure of duplex stainless steel (DSS). A hydrogen permeation cell within a TOF-SIMS instrument enables electrochemical charging with deuterium through the inner surface of the cell made from DSS. The outer surface of the DSS permeation cell exposed to the vacuum has been imaged by TOF-SIMS vs. increasing time of charging with subsequent chemometric treatment of image data. This in-situ experiment showed evidently that deuterium is permeating much faster through the ferrite phase than through the austenite phase. Moreover, a direct proof for deuterium enrichment at the austenite-ferrite interface has been found. KW - Characterization and analytical techniques KW - Corrosion KW - Imaging technique KW - Mass spectrometry PY - 2016 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-353872 UR - http://www.nature.com/articles/srep19929 SN - 2045-2322 VL - 6 IS - 19929 SP - 1 EP - 7 PB - nature publishing group CY - London, United Kingdom AN - OPUS4-35387 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rhode, Michael A1 - Steger, Jörg A1 - Böllinghaus, Thomas A1 - Kannengießer, Thomas ED - Lippold, J. ED - Böllinghaus, Thomas ED - Richardson, I. M. T1 - Hydrogen degradation effects on mechanical properties in T24 weld microstructures N2 - Spectacular failure cases of fossil power stations in the recent years exhibited severe cracking in T24 welds. The results show that hydrogen-assisted cracking up to 200 °C cannot be excluded. Hence, it is important to gain a basic understanding on how hydrogen might affect the basic material properties in the respective weld microstructures. The present study focuses on hydrogen degradation of the respective weld microstructures, i.e., the weld metal and the coarse grained heat affected zone, where actually cracking appeared in practice. Tensile tests were carried out for coarse grain heataffected zone (CGHAZ) and the weld metal in uncharged and electrochemically hydrogen-charged condition. It turned out that both microstructures show distinct tendency for gradual degradation of mechanical properties in the presence of increasing hydrogen concentration. Already for a hydrogen concentration about and above 2 ml/100 g Fe, a significant ductility reduction has been observed. SEM investigations revealed that the fracture topography changes from ductile topography in uncharged condition to intergranular topography for the CGHAZ and to ductile-brittle mix for the weld metal (WM) in hydrogen charged condition. Ti-rich inclusions were identified as central regions of quasi-cleavage fracture areas in the WM. An approximation procedure is applied to quantify the degradation intensity. KW - Low alloy steels KW - Hydrogen embrittlement KW - Heat affected zone KW - Microstructure KW - Creep resisting materials PY - 2016 UR - http://link.springer.com/article/10.1007/s40194-015-0285-5 U6 - https://doi.org/10.1007/s40194-015-0285-5 SN - 0043-2288 VL - 60 IS - 2 SP - 201 EP - 216 PB - Springer-Verlag GmbH CY - Heidelberg AN - OPUS4-35390 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lippold, J. C. A1 - Böllinghaus, Thomas A1 - Richardson, I. T1 - Welding in the world - Update 2018 N2 - In 2018, the Journal "Welding in the World" published 6 issues that contained 120 papers and over 1300 pages of fundamental and applied research associated with materials joining and allied technologies. KW - Journal KW - Editorial Board KW - Year in Review PY - 2019 U6 - https://doi.org/10.1007/s40194-018-00695-9 SN - 0043-2288 SN - 1878-6669 VL - 63 IS - 1 SP - 1 PB - Springer CY - Berlin AN - OPUS4-50064 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rhode, Michael A1 - Richter, Tim A1 - Mayr, P. A1 - Nitsche, A. A1 - Mente, Tobias A1 - Böllinghaus, Thomas T1 - Hydrogen diffusion in creep-resistant 9% Cr P91 multi-layer weld metal N2 - Welded components of P91 9% Cr steel demand for careful welding fabrication with necessary post weld heat treatment (PWHT). Before the PWHT, a hydrogen removal heat treatment is necessary for avoidance of hydrogen assisted cracking (HAC). In this context, the microstructure and temperature-dependent hydrogen diffusion is important, and reliable diffusion coefficients of P91 weld metal are rare. For that reason, the diffusion behavior of P91 multi-layer weld metal was investigated for as-welded (AW) and PWHT condition by electrochemical permeation experiments at room temperature and carrier gas hot extraction (CGHE) from 100 to 400 °C. Hydrogen diffusion coefficients were calculated, and the corresponding hydrogen concentration was measured. It was ascertained that both heat treatment conditions show significant differences. At room temperature the AW condition showed significant hydrogen trapping expressed by to seven times lower diffusion coefficients. A preferred diffusion direction was found in perpendicular direction expressed by high permeability. The CGHE experiments revealed lower diffusion coefficients for the AW condition up to 400 °C. In this context, a hydrogen concentration of approximately 21 ml/100 g was still trapped at 100 °C. For that reason, a certain HAC susceptibility of as-welded P91 weld metal cannot be excluded, and hydrogen removal should be done before PWHT. KW - Creep resisting materials KW - Diffusion KW - Hydrogen KW - Weld metal KW - Post weld heat treatment KW - Microstructure PY - 2020 U6 - https://doi.org/10.1007/s40194-019-00828-8 SN - 0043-2288 VL - 64 IS - 2 SP - 267 EP - 281 PB - Springer AN - OPUS4-50471 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Madigan, Maria A1 - Mente, Tobias A1 - Böllinghaus, Thomas ED - Sommitsch, C. ED - Enzinger, N. ED - Mayr, P. T1 - Numerical Simulation of Hydrogen Assisted Stress Corrosion Cracking Originating from Pits N2 - Supermartensitic stainless steels (SMSS) are a commonly used material nowadays for building offshore structures, i.e. pipelines in the oil and gas industry. The harsh and corrosive environments in oil and gas applications require the correct combination of alloys to attain the desired properties of steel, including high strength and good corrosion properties, even in severe sour service conditions. Welding is the most commonly used method in joining offshore components, depending on requirements requiring strength or fitting. It has been shown that the heat affected zone (HAZ) is more susceptible to certain types of corrosion, including pitting corrosion, especially during severe sour service where a high pH and lower H2S values in the flow medium can lead to pitting corrosion in the HAZ of welded structures. Subsequent hydrogen uptake in the pits can cause cracks to initiate and propagate, leading to rupture of pipelines or catastrophic failures of structures, even at low mechanical loads. Offshore standards allow a certain amount of corrosion, including pitting, to be present before action is required, however the extent of pitting corrosion is not identified by performing visual inspection alone as the subsurface pit diameter may be vastly greater than the pit diameter at the surface. The critical conditions which lead to crack initiation and propagation from a pit with hydrogen uptake are currently not known. Therefore, pitting corrosion and subsequent crack initiation are a danger to the safety of structures. The interest in this phenomenon has resulted in many experimental studies and numerical simulations. Several numerical models of pitting corrosion and hydrogen uptake resulting in crack initiation are already in existence, but these two phenomena are regularly modelled individually. Thus, a model enabling simulation of both phenomena simultaneously would be of great benefit. Hence, the goal of this study is to develop a model enabling simulation of pit growth and crack initiation, considering hydrogen uptake in the pit from a corrosive environment. As a first step, this paper presents an investigation into various parameters, which influence crack initiation at pits. These crack critical parameters include: pit geometry, pit location, mechanical load and hydrogen transport into the microstructure. The results will help to identify critical conditions for crack initiation starting at the pit and developing measures to avoid hydrogen assisted cracking (HAC). T2 - 12th International Seminar Numerical Analysis of Weldability CY - Graz, Austria DA - 23.09.2018 KW - Hydrogen Assisted Cracking (HAC) KW - Pitting KW - Supermartensitic Stainless Steel (SMSS) KW - Numerical Simulation PY - 2019 SN - 978-3-85125-615-4 SN - 978-3-85125-616-1 SN - 2410-0544 VL - 12 SP - 443 EP - 464 PB - Verlag der Technischen Universität Graz CY - Graz (Österreich) AN - OPUS4-48721 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Steffens, B. R. A1 - Rhode, Michael A1 - Shoales, G.A. T1 - Hydrogen Assisted Stress Corrosion Cracking Related Material Properties of ServiceApplied Landing Gear Ultra-High Strength Steels N2 - Aircraft main landing gear (MLG) components are commonly manufactured from low-alloyed, martensitic, ultra-high strength steels (UHSS) that have to be coated for corrosion protection, representing an expensive and environmentally harmful production step. To avoid already partly banned corrosion protection plating, the new high-alloyed UHSS, Ferrium S53 (UNS S10500), has been designed to replace lowalloyed legacy materials and has been subjected to a limited field test over five years. As with the legacy alloys, UNS S10500 has a fully hardened martensitic microstructure known to be susceptible to hydrogen assisted cracking, per se. Containing about 10 wt% Cr, steels such as S10500 are at the lower limit for corrosion resistant alloys. Similar to super-martensitic stainless steels used in the oil and gas industry, a common failure sequence in marine environments represents pitting and subsequent hydrogen assisted stress corrosion cracking (HASCC). For addressing such phenomena quantitively, as required for respective lifetime assessments of MLG components and systems, the tolerance of such materials dependent on the absorbed hydrogen concentration must be evaluated quantitatively. However, there is a lack of such valuable materials data, as well as of the fractographic behavior dependent on the hydrogen concentration that might be absorbed during HASCC. To provide an improved understanding of the hydrogen dependent mechanical and fractographic behavior, samples of the legacy AISI 4340 and the new S10500 MLG steels have electrochemically been hydrogen-saturated and subjected to tensile testing. In contrast to a previous study, this contribution for the first time focuses on materials that have been salvaged from real service used landing gear components. In this study, it has been demonstrated that the service-applied S10500 steel has not only a higher strength, but also an improved ductility in comparison to the legacy AISI 4340 steel after similar service durations that provides a higher tolerance against hydrogen concentrations that might be absorbed during potential pitting and HASCC in marine environments. In addition, it has been found that the absorbed hydrogen concentration significantly affects the fracture behavior. Interestingly, hardening of the hydrogen charged low-alloyed AISI 4340 steel changes the fracture topography from trans- toward intergranular, while hardening of the S10500 steel turned the fracture topography from inter- to transgranular at respectively high hydrogen concentrations. KW - Hydrogen assisted stress corrosion cracking KW - Ultra-high strength steel KW - Martensite KW - Modeling KW - Hydrogen dependent mechanical properties PY - 2019 U6 - https://doi.org/10.5006/3028 SN - 0010-9312 SN - 1938-159X VL - 75 IS - 5 SP - 513 EP - 524 PB - NACE International AN - OPUS4-49530 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Viyanit, E. A1 - Keawkumsaia, S. A1 - Wongpinkeawa, K. A1 - Bunchoo, N. A1 - Khonraeng, W. A1 - Trachoob, T. A1 - Böllinghaus, Thomas T1 - Hydrogen assisted cracking of an AISI 321 stainless steel seamless pipe exposed to hydrogen-containing hot gas at high pressure N2 - A seamless pipe made of AISI 321 stainless steel represented a part of a transportation Pipeline system for hydrogen-containing hot gas in a hydrocarbon cracking unit. After a service period of approximately 21 months, a segment of such pipe demonstrated the cracks, causing leakage and respective fire. For clarification of a failure root cause, various metallurgical investigations combined with numerical simulations have been applied. The results revealed that the rupture of seamless pipe was evidently influenced by hydrogen assisted cracking (HAC). An increased susceptibility of the alloy to HAC had to be attributed to its sensitive microstructure which was related to the occurrence of slip bands with a high quantity in austenite grains, particularly in the specific region underneath the outer wall surface. In addition, the intensity of restraint resulting from the T-joint weld configuration caused respectively higher triaxial stresses in the confined area on the outer wall surface where the crack started. The numerical simulations of hydrogen diffusion revealed that a uniform hydrogen concentration profile over the pipe wall thickness was reached when the service period was more than 20 months. This duration agreed well to the timeto-failure of the actual component. Considering additionally that the final stage of rupture by overload was preceded by severe HAC, as confirmed by the respective intergranular fracture topography. KW - Hydrogen-containing hot gas KW - AISI 321 stainless steel KW - Hydrogen assisted cracking KW - Intergranular cracking PY - 2019 U6 - https://doi.org/10.1016/j.engfailanal.2019.02.037 SN - 1350-6307 SN - 1873-1961 VL - 100 SP - 288 EP - 299 PB - Elsevier Ltd. AN - OPUS4-49617 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Böllinghaus, Thomas A1 - Rhode, Michael A1 - Falkenreck, T. ED - Bender, B. ED - Göhlich, D. T1 - Korrosion und Korrosionsschutz N2 - Das Kapitel beginnt mit einer kurzen Einführung über die Korrosion (Wechselwirkung zwischen einem Metall, einer korrosiven Umgebung und der der jeweiligen Konstruktion). Im zweiten Abschnitt werden die wichtigsten Formen der wässrigen elektrochemischen Korrosion (Flächenkorrosion, galvanische, selektive und interkristalline Korrosion sowie Loch- und Spaltkorrosion) betrachtet. Darüber hinaus wird die elektrochemische Korrosion unter mechanischer Belastung betrachtet (Spannungsrisskorrosion, wasserstoffunterstützte Rissbildung, Korrosionsermüdung), sowie Sonderformen der Korrosion (Erosion, Fretting und mikrobiologisch induzierte Korrosion). Der dritte Abschnitt befasst sich mit der chemischen und Hochtemperaturkorrosion (Oxidation, Aufkohlung, Hochtemperatur-Wasserstoffangriff, Aufschwefelung, Nitrierung, Halogenierung). Zusätzlich enthält das Kapitel Maßnahmen zur Vermeidung der Korrosion. KW - Korrosion KW - Korrosionsschutz KW - Spannungsrisskorrosion KW - Wasserstoff KW - Loch- u. Spaltkorrosion PY - 2021 SN - 978-3-662-59710-1 U6 - https://doi.org/10.1007/978-3-662-59711-8_34 VL - 1 SP - 691 EP - 725 PB - Springer-Verlag GmbH, ein Teil von Springer Nature CY - Berlin ET - 26 AN - OPUS4-52156 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Böllinghaus, Thomas A1 - Rhode, Michael A1 - Falkenreck, T. ED - Grote, K.-H. ED - Hefazi, H. T1 - 6. Corrosion and Corrosion Resistance N2 - The chapter starts with a brief introduction about corrosion, which is defined as the interdependency between a metal, a corrosive environment, and the respective component design. The second section introduces the most important forms of aqueous electrochemical corrosion (uniform corrosion, galvanic corrosion, selective and intergranular corrosion, and finally pitting and crevice corrosion in the case of passive layer forming metals). In addition, electrochemical corrosion under applied mechanical load is introduced (stress corrosion cracking, hydrogen-assisted cracking, corrosion fatigue), as well as special forms of corrosion (erosion, fretting, and microbiologically induced corrosion). The third section of this chapter introduces (mostly dry) chemical corrosion and high-temperature corrosion (oxidation, carburization, high-temperature hydrogen attack, sulfurization, nitriding, halogenation). As in the case of electrochemical corrosion, chemical corrosion can also be superimposed by mechanical loads. Finally, general facts on the testing of corrosion are introduced. KW - Corrosion KW - Corrosion testing KW - Handbook KW - Electrochemical corrosion KW - Chemical corrosion PY - 2021 SN - 978-3-030-47035-7 U6 - https://doi.org/10.1007/978-3-030-47035-7_6 VL - 2021 SP - 185 EP - 213 PB - Springer Nature Switzerland AG CY - Cham (CH) ET - 2nd Edition AN - OPUS4-52423 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böllinghaus, Thomas A1 - Holler, K. A1 - Kannengießer, Thomas A1 - Schobbert, H. T1 - Nd: YAG laser plasma powder hybrid welding of austenitic stainless steels N2 - As an approach towards more rough industrial laser welding applications, the Nd:YAG laser welding process has been coupled to the plasma powder welding process for the first time. Process stabilities have been achieved by such hybrid welding which are even better than those known from previous coupling of the laser process with gas metal arc welding (GMAW), for instance. The present contribution focuses on the technology and potentials of the novel laser hybrid welding technique and addresses the realisation and the perspectives for practical applications. The experimental results demonstrate that the new process coupling enables welding of austenitic stainless steels in the thickness range between 3 mm and 8 mm at various weld geometries and joint configurations and at welding speeds exceeding 2 m/min. In addition it has been proven that the laser plasma powder arc welding (LPPAW) technique can also be applied to out-of-position conditions. Continuous advancement of the welding equipment ensures a high gap bridging ability and levelling of misalignment due to higher powder feeding rates. The recent development of a new plasma powder torch even provides a higher efficiency of powder feeding and guarantees smoth weld surfaces. Up to the present, the investigations demonstrated that the novel laser plasma powder hybrid welding technique offers all perspectives for application in pipe fabrication, ship building and offshore as well as transportation industry. T2 - Seminar in Mechanical and Metallurgical Approaches to New Joining Process CY - Awaji Island, Japan DA - 20.07.2004 KW - Nd:YAG KW - Laser plasma KW - Powder KW - Hybrid KW - Welding KW - Austenitic stainless steels PY - 2004 SP - 140 EP - 145 CY - Japan AN - OPUS4-39261 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Sobol, Oded A1 - Nolze, Gert A1 - Saliwan Neumann, Romeo A1 - Eliezer, D. A1 - Böllinghaus, Thomas A1 - Unger, Wolfgang T1 - Novel approach to image hydrogen distribution and related phase transformation in duplex stainless steels at the sub-micron scale N2 - The effect of electrochemical charging of hydrogen on the structure of a lean duplex stainless steel LDX 2101® (EN 1.4162, UNS S32101) was examined by both Time-of-Flight secondary ion mass spectrometry and electron back-scatter diffraction. The goal is to correlate hydrogen concentration and induced structural changes. Chemical and structural characterizations were done for the same region at the sample's surface with sub-micron spatial resolution. Regions of interest were varying in size between 50 × 50 μm and 100 × 100 μm. The results show a phase transformation of austenite to mainly a defect-rich BCC and scarcely a HCP phase. The phase transformation occurred in deuterium rich regions in the austenite. KW - Time-of-flight secondary ion mass spectrometry KW - ToF-SIMS KW - Electron backscatter diffraction KW - EBSD KW - Hydrogen-assisted cracking KW - Data fusion KW - Lean duplex stainless steel PY - 2017 U6 - https://doi.org/10.1016/j.ijhydene.2017.08.016 SN - 0360-3199 VL - 42 IS - 39 SP - 25114 EP - 25120 AN - OPUS4-42022 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Rhode, Michael A1 - Münster, C. A1 - Mente, Tobias A1 - Böllinghaus, Thomas ED - Somerday, B.P. ED - Sofronis, P. T1 - Influence of experimental conditions and calculation method on hydrogen diffusion coefficient evaluation at elevated temperatures N2 - Literature provides a wide range of hydrogen diffusion coefficients for low alloyed steels used in power plants. In fact, experimental boundary conditions and calculation methods have influence on the determination of these coefficients. The diffusion and trapping behavior in creep-resistant steel 7CrMoVTiB10-10 has been studied. Based on experimental carrier gas hot extraction (CGHE) data, a numerical model has been developed to describe the hydrogen transport and respective hydrogen distribution at elevated temperatures. The numerical results suggest that common calculation methods for diffusion coefficients are limited for experimental data analysis. The sample preparation time before CGHE experiment influences the determined diffusion coefficients with the consequence that non-homogeneous hydrogen concentration profiles have to be considered in the simulations. KW - Temperature effect KW - Hydrogen diffusion KW - Creep-resistant steel KW - Hydrogen assisted cracking KW - Carrier gas hot extraction PY - 2017 SN - 978-0-7918-6138-7 U6 - https://doi.org/10.1115/1.861387_ch56 SP - 495 EP - 503 PB - ASME CY - New York, USA ET - 1 AN - OPUS4-42502 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Steffens, B. R. A1 - Böllinghaus, Thomas A1 - Shoales, G. A. A1 - Rhode, Michael ED - Somerday, B. P. ED - Sofronis, P. T1 - Hydrogen dependent material properties of UHSS for aerospace applications N2 - Quantitative investigations of hydrogen dependent properties of aircraft landing gear materials have only scarcely been carried out in the past. They are essential for respective component life time assessments. To better understand the behavior of these landing gear materials in a hydrogen rich environment, specimens were charged in the condition as delivered with known concentrations of hydrogen and then mechanically tested to evaluate the degradation effects. The present contribution is focused on evaluating the hydrogen concentration dependent material properties and the respective fracture topographies of the two investigated steels, and then continued by the comparison of the results with other previously investigated martensitic steels in order to better understand the thresholds for these materials to maintain structural integrity. T2 - International Hydrogen Conference 2016 CY - Jackson Lake Lodge, Moran, WY, USA DA - 11.09.2016 KW - Material properties KW - Hydrogen assisted cracking KW - Degradation KW - Aerospace materials KW - Ultra high strength steels PY - 2017 SN - 978-0-7918-6138-7 U6 - https://doi.org/10.1115/1.861387_ch12 SP - 123 EP - 131 PB - ASME CY - New York, USA AN - OPUS4-42504 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Silverstein, R. A1 - Eliezer, D. A1 - Böllinghaus, Thomas T1 - Hydrogen-trapping mechanisms of TIG-welded 316L austenitic stainless steels N2 - The interaction of hydrogen with various tungsten-inert-gas-welded austenitic stainless steels’ (AUSS) microstructure is studied by means of desorption/absorption analysis and microstructure observations. One of the limitations of welding is created by the presence of hydrogen in the weld, which can shorten the steel’s service life. The local hydrogen concentration, trapping, and its distribution along the welded samples were studied by thermal desorption spectrometry and were supported by X-ray diffraction (XRD) and electronic microstructural observations. Hydrogen content demonstrated a dependence on the welding zone. It was found that hydrogen distribution, and accepted microstructure during welding, played a significant role in the trapping mechanism of 316L AUSS. XRD analysis revealed residual stresses which were caused due to the presence of hydrogen in c-phase. It was shown that the austenite microconstituents inside 316L can have a crucial effect in preventing hydrogen-assisted cracking phenomenon. The effects of AUSS microstructure on hydrogen absorption and desorption behavior are discussed in detail. KW - Thermal-desorption spectroscopy KW - Ferritic steels KW - Strain rates KW - Duplex KW - Embrittlement KW - Diffusion KW - Titanium KW - Alloys KW - Behavior PY - 2018 U6 - https://doi.org/10.1007/s10853-018-2349-6 SN - 1573-4803 SN - 0022-2461 VL - 53 IS - 14 SP - 10457 EP - 10468 PB - Springer Science + Business Media CY - Dordrecht AN - OPUS4-46833 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pfennig, Anja A1 - Wolf, Marcus A1 - Gröber, Andre A1 - Böllinghaus, Thomas A1 - Kranzmann, Axel T1 - Corrosion fatigue of 1.4542 exposed to a laboratory saline aquifer water CCS-environment N2 - X5CrNiCuNb16-4 has been proven to be sufficient resistant in corrosive environments, but shows rather unusual corrosion behaviour in CCS environment. Therefore a series of 30 specimens was tested at stress amplitudes between 150 MPa and 500 MPa (sinusoidal dynamic test loads, R=-1; resonant frequency ∼ 30 Hz). Due to the rather heterogeneous fine machined surfaces (Rz=4) the specimens are comparable with prefabricated parts. X5CrNiCuNb16-4 reached the maximum number of cycles (10 x 106) at a stress amplitude of 150 MPa and lies 60% below the stress amplitude measured in air. The scatter range TN = 1:34 is disproportionately large. Although the fracture surface exhibited the typical striations and corroded surface areas no significant differences were found. The hardness was found to be homogeneous in all specimens tested at 335 HV10. Non-metallic inclusions were found within the microstructure, but no correlation could be found between the inclusions and early rupture. Still specimens that showed inclusions at the fracture surface and its cross section endured lower number of cycles. Additionally Aluminium was analysed in specimens with low number of cycles and may be cause for early rupture during corrosion fatigue tests. These findings reveal a very high sensitivity on a homogeneous microstructure upon the corrosion and corrosion fatigue behaviour of X5CrNiCuNb16-4 and needs to be taken into account when regarding this steel as pipe steel during injection of CO2 into saline aquifers. T2 - 13th International Conference on Greenhouse Gas Control Technologies CY - Lausanne, Switzerland DA - 14.11.2016 KW - Steel KW - Corrosion fatigue KW - Electrochemistry KW - Reliability KW - CCS KW - CO2-storage PY - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-418525 SN - 1876-6102 VL - 114 SP - 5219 EP - 5228 AN - OPUS4-41852 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Falkenreck, Thora A1 - Klein, M. A1 - Böllinghaus, Thomas T1 - Dynamic compressive behaviour of weld joints N2 - Materials used in military applications have to withstand multiple threats like ballistics and explosions. Thus, high-strength low alloyed (HSLA) steels are used. The main joining technique for metals is welding. Therefore, analysing the dynamic impact behaviour of high-strength welds is very important to fulfil these demands. Investigation of welds at high strain rates has rarely been conducted in the past. To determine the dynamic impact behaviour of hybrid laser-arc welds, the Split Hopkinson Pressure Bar (SHPB) technique was used. The base material was a quenched and tempered fine-grained armour steel with yield strength of 1100 MPa. First, a full hybrid laser-arc weld was investigated by extracting specimens consisting of weld metal and heat affected base material. The influence of two variables, the cooling time between 800 °C and 500 °C (t8/5) and strength of filler material, on the impact behaviour was studied. The cooling time t8/5 was varied by preheating to influence the microstructure in the HAZ and to analyse the effect on the hardness and dynamic compressive strength. Subsequent analysis to detail the original Investigation was carried out by dilatometer heat treatment of specimens to create homogenous subzones of the weld. These specimens have a homogenous microstructure of HAZ and were tested by SHPB to determine the stress-strain characteristics for the different microstructures of HAZ. The results of the weld specimen showed the effect of preheating and filler material strength on the dynamic compressive behaviour. The analysis of the different microstructures of the HAZ indicated that especially the tempered microstructure caused a reduction in dynamic compressive strength. KW - SHPB KW - Hybrid laser-arc weld KW - Dilatometry PY - 2017 U6 - https://doi.org/10.1016/j.msea.2017.07.032 SN - 0921-5093 SN - 1873-4936 VL - 702 SP - 322 EP - 330 AN - OPUS4-41904 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Rhode, Michael A1 - Schaupp, Thomas A1 - Münster, C. A1 - Mente, Tobias A1 - Kannengießer, Thomas A1 - Böllinghaus, Thomas T1 - Hydrogen determination in welded specimens by carrier gas hot extraction - a review on the main parameters and their effects on hydrogen measurement N2 - Carrier gas hot extraction (CGHE) is a commonly applied technique for determination of hydrogen in weld joints using a thermal conductivity detector (TCD) for hydrogen measurement. The CGHE is based on the accelerated hydrogen effusion due to thermal activation at elevated temperatures. The ISO 3690 standard suggests different specimen geometries as well as necessary minimum extraction time vs. temperature. They have the biggest influence on precise hydrogen determination. The present study summarizes the results and experience of numerous test runs with different specimen temperatures, geometries (ISO 3690 type B and small cylindrical samples), and factors that additionally influence hydrogen determination. They are namely specimen surface (polished/as-welded), limited TCD sensitivity vs. specimen volume, temperature measurement vs. effects of PI-furnace controller, as well as errors due to insufficient data assessment. Summarized, the temperature is the driving force of the CGHE. Two different methods are suggested to increase the heating rate up to the desired extraction temperature without changing the experimental equipment. Suggestions are made to improve the reliability of hydrogen determination depended on the hydrogen signal stability during extraction accompanied by Evaluation of the recorded data. Generally, independent temperature measurement with dummy specimens is useful for further data analysis, especially if this data is used for calculation of trapping kinetics by thermal desorption analysis (TDA). KW - Hydrogen KW - Carrier gas hot extraction KW - Experimental design KW - Thermal conductivity device PY - 2019 U6 - https://doi.org/10.1007/s40194-018-0664-9 SN - 0043-2288 VL - 63 IS - 2 SP - 511 EP - 526 PB - Springer CY - Berlin, Heidelberg AN - OPUS4-47603 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Drexler, A.-K. A1 - Konert, Florian A1 - Nietzke, Jonathan A1 - Hodžić, E. A1 - Pastore, S. A1 - Domitner, J. A1 - Rhode, Michael A1 - Sommitsch, C. A1 - Böllinghaus, Thomas T1 - Effect of Tensile Loading and Temperature on the Hydrogen Solubility of Steels at High Gas Pressure N2 - The hydrogen solubility in ferritic and martensitic steels is affected by hydrostatic stress, pressure, and temperature. In general, compressive stresses decrease but tensile stresses increase the hydrogen solubility. This important aspect must be considered when qualifying materials for high‐pressure hydrogen applications (e.g., for pipelines or tanks) by using autoclave systems. In this work, a pressure equivalent for compensating the effect of compressive stresses on the hydrogen solubility inside of closed autoclaves is proposed to achieve solubilities that are equivalent to those in pipelines and tanks subjected to tensile stresses. Moreover, it is shown that the temperature effect becomes critical at low temperatures (e.g., under cryogenic conditions for storing liquid hydrogen). Trapping of hydrogen in the microstructure can increase the hydrogen solubility with decreasing temperature, having a solubility minimum at about room temperature. To demonstrate this effect, the generalized law of the hydrogen solubility is parameterized for different steels using measured contents of gaseous hydrogen. The constant parameter sets are verified and critically discussed with respect to the high‐pressure hydrogen experiments. KW - Hydrogen KW - Solubility KW - Temperature KW - Tensile loading KW - Analytical calculation PY - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-586701 SN - 1611-3683 SP - 1 EP - 9 PB - Wiley AN - OPUS4-58670 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Konert, Florian A1 - Wieder, Frank A1 - Nietzke, Jonathan A1 - Meinel, Dietmar A1 - Böllinghaus, Thomas A1 - Sobol, Oded T1 - Evaluation of the impact of gaseous hydrogen on pipeline steels utilizing hollow specimen technique and μCT N2 - The high potential of hydrogen as a key factor on the pathway towards a climate neutral economy, leads to rising demand in technical applications, where gaseous hydrogen is used. For several metals, hydrogen-metal interactions could cause a degradation of the material properties. This is especially valid for low carbon and highstrength structural steels, as they are commonly used in natural gas pipelines and analyzed in this work. This work provides an insight to the impact of hydrogen on the mechanical properties of an API 5L X65 pipeline steel tested in 60 bar gaseous hydrogen atmosphere. The analyses were performed using the hollow specimen technique with slow strain rate testing (SSRT). The nature of the crack was visualized thereafter utilizing μCT imaging of the sample pressurized with gaseous hydrogen in comparison to one tested in an inert atmosphere. The combination of the results from non-conventional mechanical testing procedures and nondestructive imaging techniques has shown unambiguously how the exposure to hydrogen under realistic service pressure influences the mechanical properties of the material and the appearance of failure. KW - Energy Engineering and Power Technology KW - Condensed Matter Physics KW - Fuel Technology KW - Renewable Energy, Sustainability and the Environment KW - µCT KW - Hollow Specimen Technique KW - Hydrogen Embrittlement PY - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-595077 SN - 0360-3199 VL - 59 SP - 874 EP - 879 PB - Elsevier B.V. AN - OPUS4-59507 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Cross, Carl T1 - Obituary: Prof. Dr.-Ing. Hans Hoffmeister N2 - On November 3, 2023, our dear colleague, Prof. Dr.-Ing. Hans Hoffmeister, born in 1932 in Kassel, Germany, passed away in Ahrensburg, near Hamburg, Germany. KW - Metals and Alloys KW - Mechanical Engineering KW - Mechanics of Materials PY - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-594160 SP - 1 EP - 2 PB - Springer Science and Business Media LLC AN - OPUS4-59416 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Lüders, V. A1 - Nolze, Gert T1 - Microstructural insights into natural silver wires N2 - Due to the increasing global demand for pure silver, native wire silver aggregates in very high purities are gaining more industrial attention. Up to the present, no substantial metallurgical Investigation of natural wire silver exists in the accessible literature. To convey urgently needed cross-disciplinary fundamental knowledge for geoscientists and metallurgical engineers, twenty natural wire silver specimens from eight different ore deposits have been investigated in detail for the first time by EBSD (Electron Back Scattering Diffraction), supported by light microscopy and micro-probe analyses. The improved understanding of the natural silver wire microstructure provides additional Information regarding the growth of natural silver aggregates in comparison to undesired artificial growth on electronic devices. Clear evidence is provided that natural silver curls and hairs exhibit a polycrystalline face-centered cubic microstructure associated with significant twinning. Although the investigated natural wire silver samples have relatively high purity (Ag > 99.7 wt.-%), they contain a variety of trace elements such as, S, Cu, Mn, Ni, Zn, Co and Bi, As and Sb. Additionally, Vickers micro-hardness measurements are provided for the first time which revealed that natural silver wires and curls are softer than it might be expected from conversion of the general Mohs hardness of 2.7. KW - Natural silver wires PY - 2018 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-451655 UR - http://www.nature.com/articles/s41598-018-27159-w SN - 2045-2322 VL - 8 IS - 1 SP - Article 9053, 1 EP - 9 PB - nature publishing group CY - London, United Kingdom AN - OPUS4-45165 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Röhsler, Andreas A1 - Sobol, Oded A1 - Hänninen, H. A1 - Böllinghaus, Thomas T1 - In-situ ToF-SIMS analyses of deuterium re-distribution in austenitic steel AISI 304L under mechanical load N2 - Hydrocarbons fuel our economy. Furthermore, intermediate goods and consumer products are often hydrocarbon-based. Beside all the progress they made possible, hydrogen-containing substances can have severe detrimental effects on materials exposed to them. Hydrogen-assisted failure of iron alloys has been recognised more than a century ago. The present study aims to providing further insight into the degradation of the austenitic stainless steel AISI 304L (EN 1.4307) exposed to hydrogen. To this end, samples were electrochemically charged with the hydrogen isotope deuterium (2H, D) and analysed by scanning electron microscopy (SEM), electron back-scatter diffraction (EBSD) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). It was found that deuterium caused a phase transformation from the original γ austenite into ε- and α’-martensite. Despite their low solubility for hydrogen, viz. deuterium, the newly formed phases showed high deuterium concentration which was attributed to the increased density of traps. Information about the behaviour of deuterium in the material subjected to external mechanical load was gathered. A four-point-bending device was developed for this purpose. This allowed to analyse in-situ pre-charged samples in the ToF-SIMS during the application of external mechanical load. The results indicate a movement of deuterium towards the regions of highest stress. KW - ToF-SIMS KW - Hydrogen KW - Deuterium KW - AISI 304L KW - EBSD PY - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-505142 VL - 10 IS - 1 SP - 3611 PB - Nature AN - OPUS4-50514 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Röhsler, Andreas A1 - Sobol, Oded A1 - Unger, Wolfgang A1 - Böllinghaus, Thomas T1 - Comprehensive study of deuterium-induced effects in in austenitic stainless steel AISI 304L N2 - The damaging impact of hydrogen on the austenitic stainless steel AISI 304 L was analysed. To this aim, samples were charged electrochemically with the hydrogen isotope deuterium (2H, D) and examined with time-of-flight secondary ion mass spectrometry (ToF-SIMS) and electron backscatter diffraction (EBSD). The fusion of the obtained chemical and structural information revealed local enrichment of deuterium in austenite, transformation into martensite, crack formation and severe roughening of the specimen surface. The results indicated that martensite was not only formed during charging but also during Desorption and ToF-SIMS examinations. Furthermore, cross-sections of deuterium-charged samples revealed that in preferred deformation bands a g/ε/a 0 evolution is taking place. By means of microscopic analyses and carrier gas hot extraction (CGHE), it was found that the use of NaAsO2 as recombination poison decreased the uptake of hydrogen significantly and resulted in severe precipitation on the specimen surfaces. This is in contrast to the popular presumption that NaAsO2 enhances the uptake of hydrogen (and deuterium) during electrochemical charging by hampering its recombination from Atoms to molecules. KW - AISI 304L KW - Hydrogen KW - ToF-SIMS KW - Deuterium KW - Martensite PY - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:b43-477540 SN - 0360-3199 SN - 1879-3487 VL - 44 IS - 23 SP - 12228 EP - 12238 PB - Elsevier Ltd. AN - OPUS4-47754 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Röhsler, Andreas A1 - Sobol, Oded A1 - Nolze, Gert A1 - Unger, Wolfgang A1 - Böllinghaus, Thomas T1 - Use of time-of-flight secondary ion mass spectrometry for the investigation of hydrogen-induced effects in austenitic steel AISI 304L N2 - During the energy transformation from fossil fuels to renewable energy sources, the use of hydrogen as fuel and energy storage can play a key role. This presents new challenges to industry and the scientific community alike. The storage and transport of hydrogen, which is nowadays mainly realized by austenitic stainless steels, remains problematic, which is due to the degradation of mechanical properties and the possibility of phase transformation by hydrogen diffusion and accumulation. The development of materials and technologies requires a fundamental understanding of these degradation processes. Therefore, studying the behavior of hydrogen in austenitic steel contributes to an understanding of the damage processes, which is crucial for both life assessment and safe use of components in industry and transportation. As one of the few tools that is capable of depicting the distribution of hydrogen in steels, time-of-flight secondary ion mass spectrometry was conducted after electrochemical charging. To obtain further information about the structural composition and cracking behavior, electron-backscattered diffraction and scanning electron microscopy were performed. Gathered data of chemical composition and topography were treated employing data fusion, thus creating a comprehensive portrait of hydrogen-induced effects in the austenite grade AISI 304L. Specimens were electrochemically charged with deuterium instead of hydrogen. This arises from the difficulties to distinguish between artificially charged hydrogen and traces existing in the material or the rest gas in the analysis chamber. Similar diffusion and permeation behavior, as well as solubility, allow nonetheless to draw conclusions from the experiments. T2 - 21st International Conference on Secondary Ion Mass Spectrometry CY - Kraków, Poland DA - 10.09.2017 KW - AISI 304L KW - Hydrogen KW - ToF-SIMS KW - Austenitic stainless steel PY - 2018 U6 - https://doi.org/10.1116/1.5013931 SN - 1071-1023 VL - 36 IS - 3 SP - Article 03F103, 1 EP - 6 PB - American Vacuum Society (AVS) AN - OPUS4-44840 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Böllinghaus, Thomas A1 - Holtappels, Kai A1 - Mair, Georg A1 - Grunewald, Thomas T1 - Explosion of iron hydrogen storage containers – Investigations from 120 years ago revisited N2 - The explosion of hydrogen gas storage cylinders on May 25, 1894, represents one of the most spectacular failure cases during the late industrialization period in Germany. With respect to modern applications to hydrogen storage as energy carrier, it has several times been referred to as precedent failure case for the whole industrial sector. The detailed investigation reports by Martens have thus gained interest in the last years, but also, because the publications in 1896 about his expertise already provided in September 1894 document one of the first and most comprehensive investigations which can be regarded as a nucleus for modern failure analysis. After summarizing the newspaper reports in the introduction, the present contribution provides a review of Martens' reports targeted at the development of failure analyses and materials testing procedures as well as potential failure origins. KW - Explosion KW - Hydrogen storage cylinders KW - Failure root cause KW - Hydrogen assisted cracking PY - 2014 U6 - https://doi.org/10.1016/j.engfailanal.2014.03.017 SN - 1350-6307 SN - 1873-1961 VL - 43 IS - Special Issue 'A Tribute to Prof. A. Martens' SP - 47 EP - 62 PB - Elsevier Science Publ. CY - Oxford AN - OPUS4-31592 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -