TY - CONF A1 - Resch-Genger, Ute A1 - Weigert, Florian A1 - Frenzel, Florian A1 - Würth, Christian A1 - Hoffmann, Katrin A1 - Martynenko, Irena A1 - Dhamo, Lorena T1 - Photoluminescence Properties of Different Types of Nanocrystals at the Ensemble and Single Emitter Level N2 - Correlating the photoluminescence (PL) properties of nanomaterials like semiconductor nanocrystals (QDs) and upconversion nanocrystals (UCNPs) assessed in ensemble studies and at the single particle level is increasingly relevant for applications of these nanomaterials in the life sciences like bioimaging studies or their use as reporters in microfluidic assays. Here we present a comparison of the spectroscopic properties of ensembles and single emitters for QDs like II/VI QDs and cadmium-free AIS/ZnS QDs as well as different UCNPs. The overall goal of this study was to derive particle architectures well suited for spectroscopic and microscopic applications. T2 - BIOSSPIE CY - San Francisco, CA, USA DA - 02.02.2019 KW - Quantum yield KW - Nanomaterial KW - Photoluminescence KW - Absolute fluorometry KW - Integrating sphere spectroscopy, KW - NIR KW - IR KW - Fluorescence KW - Nanoparticle KW - Semiconductor KW - Quantum dot KW - Single particle spectroscopy KW - Surface chemistry PY - 2019 AN - OPUS4-47358 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gradt, Thomas T1 - Tribological Research in Germany - Overview and Examples from the Federal Institute for Materials Research and Testing (BAM) N2 - The talk gives a historical introduction and introduces some of the biggest and most important research institutes in Germany dealing with tribology at Universities, scientific societies and companies. Some examples for research projects and focus areas are given. As an example for a research institute with a long history in tribological research the activities of BAM in Berlin are presented. T2 - Joint Tribology Symposium of Kyushu University and Yokohama National University KY7 CY - Fukuoka, Japan DA - 01.02.2019 KW - Friction KW - Lubrication KW - Wear PY - 2019 AN - OPUS4-47345 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Daum, Werner A1 - Maierhofer, Christiane A1 - Thiel, Erik A1 - Altenburg, Simon A1 - Pelkner, Matthias A1 - Evans, Alexander T1 - Zerstörungsfreie Prüfung von AM Komponenten - Ein Überblick N2 - Der Vortag erläutert typische Fehlstellen und Inhomogenitäten, die bei der additiven Fertigung entstehen können. Weiterhin wird über den aktuellen Stand der herstellungsbegleitenden zerstörungsfreien Prüfung und der zerstörungsfreien Prüfung fertiger AM-Komponenten berichtet. T2 - 3. ROUND TABLE - Additiv gefertigte Druckgeräte aus metallischen Werkstoffen CY - Frankfurt a.M., Germany DA - 22.01.2019 KW - Additive Fertigung KW - Zerstörungsfreie Prüfung PY - 2019 AN - OPUS4-47344 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gradt, Thomas A1 - Theiler, Géraldine T1 - Influence of cryogenic hydrogen environment on the tribological properties of materials N2 - The presentation gives an overview over the LH2-activities during 20 years of tribological research in cryogenic environments at BAM. T2 - 2019 Hydrogenius & I2CNER Tribology Symposium CY - Fukuoka, Japan DA - 30.01.2019 KW - Friction KW - Wear KW - Hydrogen KW - Cryogenic Engineering KW - Hydrogen Embrittlement PY - 2019 AN - OPUS4-47339 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Herrmann, Ralf T1 - Digitale Methoden und Werkzeuge im BIM Kontext N2 - Die BAM Tagung "Messen im Bauwesen" widmete sich beim 10 Auftakt den digitalen Methoden und Werkzeugen im Bauwesen. T2 - Messen im Bauwesen 2018 CY - Berlin, Germany DA - 13.11.2018 KW - Messen im Bauwesen KW - BIM KW - Tagung PY - 2019 UR - https://onlinelibrary.wiley.com/doi/epdf/10.1002/bate.201970105 DO - https://doi.org/10.1002/bate.201970105 SN - 1437-0999 VL - 96 IS - 1 SP - 78 EP - 78 PB - Ernst & Sohn Verlag für Architektur und technische Wissenschaften GmbH & Co. KG CY - Berlin AN - OPUS4-47337 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Trappe, Volker A1 - Kraus, David A1 - Kübler, Stefan A1 - Eisermann, René T1 - Multiaxial fatigue damage of glass fiber reinforced polymers N2 - Fiber reinforced polymers (FRPs) are a well established material in lightweight applications, e.g. in automotive, aerospace or wind energy. The FRP components are subjected to multiaxial mechanical as well as hygrothermal loads. Common operation temperatures are in the range of 213 K and 373 K (-60 °C and 100 °C) at a relative humidity of 10% to 90%. In spacecraft applications, the environmental conditions are even more extreme. However, the correlation between multiaxial mechanical loading and harsh environment conditions have to-date not been investigated in detail. The project aims to investigate the fatigue behavior of FRPs dependent on multiaxial mechanical loading, temperature, and humidity. Extensive experimental testing is performed on flat plate and cylindrical tube specimens, accompanied by numerical and analytical calculations. T2 - 24. Nationales SAMPE Symposium CY - Dresden, Germany DA - 06.02.2019 KW - Composite KW - Fatigue KW - Thermomechanics KW - Distributed fiber optic sensors PY - 2019 AN - OPUS4-47335 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bornemann-Pfeiffer, Martin A1 - Kern, Simon A1 - Jurtz, N. A1 - Kraume, M. A1 - Maiwald, Michael T1 - Design and validation of an integrated NMR micro mixer N2 - Intensified continuous processes are in focus of current research. Compared to traditional batch processes, intensified continuous production allows the synthesis of new and difficult producible compounds with better product uniformity and reduced consumption of raw materials and energy. Flexible (modular) chemical plants can produce various products using the same equipment with short down-times between campaigns, and quick introduction of new products to the market. Full automation is a prerequisite to realize such benefits of intensified continuous plants. In continuous flow processes, continuous, automated measurements and closed-loop control of the product quality are required. Consequently, the demand for smart sensors, which can monitor key variables like component concentrations in real-time, is increasing. Low-Field NMR spectroscopy presents itself as such an upcoming smart sensor (as addressed, e.g., in the CONSENS project1,2). Systems utilizing such an online NMR analyzer benefits through short development and set-up times when applied to modular production plants starting from a desired chemical reaction. As an example for such a modular process unit, we present the design and validation of an integrated NMR micro mixer based on computational modelling suited for a desired chemical reaction. This method includes a proper design of a continuous reactor, which is optimized through computational fluid dynamics (CFD) for the demands of the NMR sensor as well as for the given reaction conditions. The system was validated with a chemical reaction process. T2 - NMRPM Konferenz 2019 CY - Kaiserslautern, Germany DA - 31.01.2019 KW - NMR KW - Mikromischer KW - Flow Chemie KW - Reaktionsmonitoring PY - 2019 N1 - Geburtsname von Bornemann-Pfeiffer, Martin: Bornemann, M. - Birth name of Bornemann-Pfeiffer, Martin: Bornemann, M. AN - OPUS4-47334 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Philipp, Rosemarie A1 - Lalere, B. A1 - Gantois, F. T1 - EMPIR project ALCOREF - certified forensic alcohol reference materials N2 - The talk presents a short summary of the EMPIR Project ALCOREF "Certified forensic alcohol reference materials". An interlaboratory comparison of analytical methods for the quantification of ethanol in water and a comparison of certified ethanol in water reference materials are proposed. T2 - EURAMET SCOA Meeting CY - Brno, Czech Republic DA - 05.02.2019 KW - Breath alcohol analyser KW - Certified reference material KW - Interlaboratory comparison PY - 2019 AN - OPUS4-47333 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kjaervik, Marit T1 - Quantitative biocide profile measurements by calibrated XPS N2 - This presentation provides an update on recent results from quantitative XPS-measurements of real and artificial biofilms. NAP-XPS, lab-based XPS and synchrotron-based XPS was used to obtain a vertical concentration profile of iodine in agarose-films with information depth ranging from 1 to 18 nm. T2 - Project meeting MetVBadBugs CY - Turin, Italy DA - 05.02.2019 KW - Biofilms KW - NAP-XPS KW - XPS KW - Iodine KW - Agarose PY - 2019 AN - OPUS4-47332 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bruno, Giovanni A1 - Evans, Alexander T1 - Avoid living dangerously: non-destructive characterization of AM parts from powder to end-of-life N2 - The freeform and the revolutionary design possibilities offered by additive manufacturing have skyrocketed the amount of optimization studies in the realm of engineering, and metallic additive manufactured parts are becoming a reality in industry. Not surprisingly, this has not been paralleled by a similar enthusiastic wave in the realm of materials science, and still very little is known about AM materials properties. This has the consequence that, typically, conventional materials properties are still used in design and even in simulations. lt is necessary to dig a lot deeper than at present, in order to understand these new materials classes, and in particular their microstructure and their intemal stresses, largely different from their cast or wrought companions. T2 - ISAM Konferenz 2019 CY - Dresden, Germany DA - 29.01.2019 KW - Computed Tomography KW - Microstructure KW - Metals KW - Additive Manufacturing PY - 2019 AN - OPUS4-47331 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krentel, Daniel A1 - Tschirschwitz, Rico A1 - Kluge, Martin A1 - Askar, Enis A1 - Habib, Abdel Karim A1 - Kohlhoff, Harald A1 - Neumann, Patrick P. A1 - Rudolph, Michael A1 - Schoppa, André A1 - Storm, Sven-Uwe A1 - Szczepaniak, Mariusz T1 - Einsatz von Messtechnik bei Großversuchen N2 - Vortrag über den Einsatz von Messtechnik bei Großversuchen auf dem BAM TTS im Rahmen des Projektes CoFi-ABV T2 - Lehrveranstaltung "Experimentelle Methoden der Aerodynamik" CY - TU Berlin, Institut für Luft- und Raumfahrt, Germany DA - 05.02.2019 KW - Alternative Antriebe KW - Alternative Kraftstoffe KW - Behälterversagen KW - Fahrzeugbrand KW - Messtechnik PY - 2019 AN - OPUS4-47329 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Evans, Alexander A1 - Mishurova, Tatiana A1 - Bruno, Giovanni A1 - Artzt, K. A1 - Haubrich, J. A1 - Requena, G. T1 - Influence of manufacturing parameters on microstructure and subsurface residual stress in SLM Ti-6Al-4V N2 - Using non-optimum combination of manufacturing parameters in selective laser melting (SLM) may lead to reduction of quality of component: defects generation, distortion of geometry and even cracking. Usually, the optimization of parameters is performed by changing volumetric energy density (Ev) and selecting parameters giving low porosity values. However, not only low porosity but also stable microstructure and low residual stresses will help to achieve advanced mechanical behavior of the component. In present work, we investigated cuboid-shaped Ti-6Al-4V samples produced with different manufacturing parameters. The parameters leading to the same Ev were considered as well as parameters which are not included in Ev. Residual stresses in subsurface region were investigated by synchrotron X-ray diffraction, which allows to penetrate around 100 µm from the surface therefore overcome the problem of high roughness of SLM components without additional sample preparation. Only tensile stresses were found along the building direction, that can play critical role especially during cyclic loading. In parallel, using X-ray computed tomography we also observe that porosity is mainly concentrated in the contour region, except in case where the laser speed is small. However, by using some process parameters it was possible to decrease residual stresses and obtain uniform α+β Ti microstructure and relatively low porosity. Additionally, it was found that not included in Ev (e.g., base plate position, focus distance) should be considered as additional manufacturing parameters during SLM process. T2 - ISAM Konferenz 2019 CY - Dresden, Germany DA - 29.01.2019 KW - Computed Tomography KW - Additive Manufacturing KW - Metals KW - Microstructure PY - 2019 AN - OPUS4-47328 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bruno, Giovanni A1 - Thiede, Tobias A1 - Léonard, Fabien A1 - Farahbod, L. T1 - In-Situ Compression CT on Additively Manufactured in 625 Lattice Structures N2 - The porosity and the surface roughness are recently discussed problems for SLM parts. The influence of SLM process parameters on porosity is well studied for different materials. Nevertheless, the build angle (i.e. the angle between part orientation and build plate) needs to be understood as an additional SLM process parameter, as it has been shown, that the microstructure and hence the mechanical performance of various materials depend on the build angle. The inherent build angle of each strut as a part of a lattice structure is the motivation to investigate the influence of the build angle on the porosity and roughness on round-shaped (1 mm diameter) struts by means of CT. Conventional Coordinate Measuring Machine (CMM) has the limitation towards small and round shaped samples. The need for Computed Tomography (CT) regarding investigations of SLM parts will increase because no other non-destructive technique allows the assessment of complex geometries with inner laying surfaces. We used CT to assess the pores and the strut surface. Seven struts out of the nickel alloy Inconel 625 with build angles from 30° to 90° were studied. It was found that the number of pores is smaller, and the size of pores is larger for the 90° strut. In case of 30° strut, the number of pores is increased towards down-skin side, additionally, this strut orientation showed to have the largest number of attached powder particles. The elongated pores exist exclusively near the strut surface. While the roughness at the down-skin surface is highly depending of the biud angle, the roughness at the up-skin surface is the same for all struts. The mechanisms of pore and surface roughness formation is not mainly driven by gravity. T2 - ISAM Konferenz 2019 CY - Dresden, Germany DA - 29.01.2019 KW - Computed Tomography KW - Additive Manufacturing KW - Metals KW - Microstructure PY - 2019 AN - OPUS4-47327 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Burkert, Andreas A1 - Babutzka, Martin T1 - Korrosionsschutz durch Deckschichtbildung und Passivität N2 - Metallene Konstruktionswerkstoffe reagieren infolge ihres thermodynamisch instabilen Zustandes mehr oder weniger stark mit Stoffen aus der Umgebung. Eine große Rolle bei diesen Reaktionen spielt das Feuchtigkeitsangebot an der Metalloberfläche, welches nicht zwingend mit einem sichtbaren Wasserfilm einhergehen muss. An der Atmosphäre bilden sich an sauberen Metalloberflächen bei etwa 80 % relativer Luftfeuchte, bei versalzten Oberflächen auch schon ab etwa 25 % r. F., Feuchtfilme aus. Im Feuchtfilm laufen grundsätzlich die gleichen elektrochemischen Reaktionen ab, wie diese von wässrigen Medien bekannt sind. Dabei geht das Metall zunächst in Ionenform und in nachgelagerten Reaktionen in einen thermodynamisch stabilen Zustand in Form unterschiedlichster Oxid- und Hydroxidverbindungen über. Die so entstehenden Korrosionsprodukte können im Feuchtigkeitsfilm begrenzt löslich oder unlöslich sein und lagern sich auf den Oberflächen der Konstruktionswerkstoffe häufig als feste Korrosionsprodukte ab bzw. wachsen dort auf. Je nachdem wie die Korrosionsprodukte strukturell zum Untergrund passen, können sich dichte, sehr gut haftende Schichten ausbilden oder poröse, dicke Schichten ohne nennenswerte Haftung aufwachsen. Wachsen dichte, porenfreie Schichten mit guter Haftung auf, die im umgebenden Medium unlöslich sind, wird die weitere Auflösung des Metalls stark gehemmt. Man spricht dann von der Ausbildung schützender Deckschichten bzw. von Passivschichten auf welcher der Korrosionsschutz und damit die Dauerhaftigkeit vieler Konstruktionswerkstoffe beruhen. Kaesche bezeichnete die Passivität sehr treffend als „optimalen Grenzfall des Korrosionsschutzes durch Schichten von Korrosionsprodukten“. Aus technischer Sicht hält Kaesche eine Unterscheidung von Deckschichten bzw. Passivschichten für nicht zwingend erforderlich, da beide die Korrosionsgeschwindigkeit in gleichem Maß herabsetzen können. Die Übergänge zwischen den meist dickeren und dadurch sichtbaren Deckschichten und den meist dünnen, nicht sichtbaren Passivschichten sind fließend. T2 - 18. Tagung "Korrosionsschutz in der maritimen Technik" CY - Hamburg, Germany DA - 30.01.2019 KW - Deckschichten KW - Korrosionsschutz KW - Passivität KW - Überzüge PY - 2019 AN - OPUS4-47325 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - de Oliveira Guilherme Buzanich, Ana T1 - Hard X-ray spectroscopy and imaging at the BAMline and MySpot beamlines at BESSY II (Berlin, Germany) N2 - Overview of the X-ray based analytical methods conducted at the BAMline and µSpot Beamline for structure analysis. T2 - Pccr2 + AfLS conference CY - Accra, Ghana DA - 29.01.2019 KW - X-ray spectroscopy KW - Synchrotron KW - Beamline KW - Material characterization PY - 2019 AN - OPUS4-47319 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yusenko, Kirill A1 - de Oliveira Guilherme Buzanich, Ana A1 - Radtke, Martin A1 - Reinholz, Uwe A1 - Riesemeier, Heinrich A1 - Emmerling, Franziska T1 - BAMline 2.0 – further technical developments for a broader multipurpose hard X-ray beamline at BESSY II N2 - We show further development of our beamline in the contexst of further itermational collaboration. T2 - PACC and AfSC CY - Accra, Ghana DA - 28.01.2019 KW - Synchrotron radiation PY - 2019 AN - OPUS4-47317 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - van de Kreeke, Johannes T1 - Databases for proficiency testing schemes and certified reference materials - EPTIS and COMAR N2 - Databases for proficiency testing schemes and certified reference materials - EPTIS and COMAR are introduced against the background of market developments. T2 - IUPAC/CITAC Workshop on Quality of Test Results for Conformity Assessment of a Chemical Composition, Isranalytica 2019 CY - Tel Aviv, Israel DA - 21.01.2019 KW - COMAR KW - Reference materials (RM) KW - EPTIS KW - Proficiency testing (PT) PY - 2019 AN - OPUS4-47314 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Meyer, Klas A1 - Peters, Claudia A1 - Maiwald, Michael T1 - Interlaboratory Comparison of Low-Field NMR Spectrometers – Purities at 200 and 10 mmol/L N2 - Due to its advantages of being a direct comparison method, quantitative NMR spectroscopy (qNMR) becomes more and more popular in industry. While conventional high-field NMR systems are often associated with high investment and operational costs, the upcoming market of permanent-magnet based benchtop NMR systems show a considerable option for a lot of applications. The mobility of these systems allows to bring them more closely to the real production environment, e.g. for at-line quality control. In this work we present an interlaboratory comparison study investigating the qNMR performance of state-of-the-art benchtop NMR spectrometers. Therefore, BAM prepared two samples of a mixture of NMR reference standards tetramethylbenzene (TMB) and tetrachloronitrobenzene (TCNB) at concentration levels of 200 mM and 10 mM. These “ready-to-use” samples were sent to participant laboratories, which performed analysis on their benchtop NMR equipment of different vendors and fields from 43 to 80 MHz. Raw data was reported back and further investigated by using different data analysis methods at BAM. After this very first qNMR comparison study of benchtop NMR spectrometers show promising results, following studies are planned to cover more parts of the qNMR process, e.g. sample preparation and weighing, but also data analysis, as commonly done in similar studies for high-field NMR spectroscopy in industry and metrology. T2 - Quantitative NMR Methods for Reaction and Process Monitoring (NMRPM) CY - Kaiserslautern, Germany DA - 31.01.2019 KW - qNMR KW - Compact NMR spectroscopy KW - Interlaboratory Comparison PY - 2019 AN - OPUS4-47311 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Meyer, Klas A1 - Guhl, Svetlana A1 - Kern, Simon A1 - Wander, Lukas A1 - Gräßer, Patrick A1 - Acker, J. A1 - Maiwald, Michael T1 - Online NMR and Raman Spectroscopy – Combination of PAT tools for Process Monitoring N2 - Improvement in deep process understanding is a mandatory prerequisite for the application of modern concepts like Industrial Internet of Things (IIoT) or “Industrie 4.0”. The direct hyphenation with online methods of process analytical technology (PAT) allows profound insights into the actual reactions within chemical and pharmaceutical production steps and provides necessary information for associated advanced control strategies. While the industrial application of online Raman spectroscopy has already been successfully demonstrated, low-field NMR spectroscopy is not yet adequately developed as a robust online method for use in process industry. The high information content combined with the low calibration effort makes NMR spectroscopy a highly promising method for modern process automation with a high flexibility due to short set-up times and novel calibration concepts. This is a major advantage compared to other analytical methods, especially regarding multi-purpose plant strategies, as well as processes suffering from fluctuating quality of raw materials. The work presented here focusses on the heterogeneous catalyzed hydrogenation of 2-butyne-1,4-diol, as a step of the synthesis of industrially important solvent tetrahydrofuran. This reaction is proceeding via an intermediate product and suffers from competitive reaction paths. In this application, online NMR and Raman spectroscopy were combined with data from classical process sensors, e.g., pressure, temperature, and flow transducers in a highly automated setup for the development of innovative control concepts. T2 - Quantitative NMR Methods for Reaction and Process Monitoring (NMRPM) CY - Kaiserslautern, Germany DA - 31.01.2019 KW - Process Analytical Technology KW - Hydrogenation KW - Compact NMR Spectroscopy KW - Online-NMR spectroscopy PY - 2019 AN - OPUS4-47310 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Meyer, Klas A1 - Kern, Simon A1 - Guhl, Svetlana A1 - Wander, Lukas A1 - Paul, Andrea A1 - Maiwald, Michael T1 - Already Producing or Still Calibrating? – Advances of Model-Based Automation for Online NMR Spectroscopy N2 - The transition from the current automation landscape to next generation automation concepts for the process industry has already begun. Smart functions of sensors simplify their use and enable plug-and-play integration, even though they may appear to be more complex at first sight. Monitoring specific information (i.e., “chemical” such as physico-chemical properties, chemical reactions, etc.) is the key to “chemical” process control. Here we introduce our smart online NMR sensor module provided in an explosion proof housing as example. Due to NMR spectroscopy as an “absolute comparison method”, independent of the matrix, it runs with very short set-up times in combination with “modular” spectral models. These are based on pure component NMR spectra without the need for tedious calibrations runs. We present approaches from statistical, (i.e., Partial Least Squares Regression) to physically motivated models (i.e., Indirect Hard Modelling). Based on concentration measurements of reagents and products by the NMR analyser a continuous production and direct loop process control were successfully realized for several validation runs in a modular industrial pilot plant and compared to conventional analytical methods (HPLC, near infrared spectroscopy). The NMR analyser was developed for an intensified industrial process funded by the EU’s Horizon 2020 research and innovation programme (“Integrated CONtrol and SENsing”, www.consens-spire.eu). T2 - 2nd Reaction Monitoring Symposium CY - Bath, UK DA - 28.01.2019 KW - Process Analytical Technology KW - NMR Spectroscopy KW - Modular Production PY - 2019 AN - OPUS4-47309 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Burkert, Andreas A1 - Babutzka, Martin T1 - Korrosionsschutz durch Deckschichtbildung und Passivität N2 - Metallene Konstruktionswerkstoffe reagieren infolge ihres thermodynamisch instabilen Zustandes mehr oder weniger stark mit Stoffen aus der Umgebung. Eine große Rolle bei diesen Reaktionen spielt das Feuchtigkeitsangebot an der Metalloberfläche, welches nicht zwingend mit einem sichtbaren Wasserfilm einhergehen muss. An der Atmosphäre bilden sich an sauberen Metalloberflächen bei etwa 80 % relativer Luftfeuchte, bei versalzten Oberflächen auch schon ab etwa 25 % r. F., Feuchtfilme aus. Im Feuchtfilm laufen grundsätzlich die gleichen elektrochemischen Reaktionen ab, wie diese von wässrigen Medien bekannt sind. Dabei geht das Metall zunächst in Ionenform und in nachgelagerten Reaktionen in einen thermodynamisch stabilen Zustand in Form unterschiedlichster Oxid- und Hydroxidverbindungen über. Die so entstehenden Korrosionsprodukte können im Feuchtigkeitsfilm begrenzt löslich oder unlöslich sein und lagern sich auf den Oberflächen der Konstruktionswerkstoffe häufig als feste Korrosionsprodukte ab bzw. wachsen dort auf. Je nachdem wie die Korrosionsprodukte strukturell zum Untergrund passen, können sich dichte, sehr gut haftende Schichten ausbilden oder poröse, dicke Schichten ohne nennenswerte Haftung aufwachsen. Wachsen dichte, porenfreie Schichten mit guter Haftung auf, die im umgebenden Medium unlöslich sind, wird die weitere Auflösung des Metalls stark gehemmt. Man spricht dann von der Ausbildung schützender Deckschichten bzw. von Passivschichten auf welcher der Korrosionsschutz und damit die Dauerhaftigkeit vieler Konstruktionswerkstoffe beruhen. Kaesche bezeichnete die Passivität sehr treffend als „optimalen Grenzfall des Korrosionsschutzes durch Schichten von Korrosionsprodukten“. Aus technischer Sicht hält Kaesche eine Unterscheidung von Deckschichten bzw. Passivschichten für nicht zwingend erforderlich, da beide die Korrosionsgeschwindigkeit in gleichem Maß herabsetzen können. Die Übergänge zwischen den meist dickeren und dadurch sichtbaren Deckschichten und den meist dünnen, nicht sichtbaren Passivschichten sind fließend. T2 - 18. Tagung "Korrosionsschutz in der maritimen Technik" CY - Hamburg, Germany DA - 30.01.2019 KW - Korrosionsschutz KW - Überzüge KW - Deckschichten KW - Passivität PY - 2019 SN - 978-3-935406-70-3 VL - 18 SP - 25 EP - 38 AN - OPUS4-47307 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst T1 - Seismic methods to test concrete strcutures N2 - Seismic methods are increasingly used to improve ultrasonic imaging and monitoring of concrete. At BAM, we are research mainly the use of Reverse Time Migration to get better images from ultrasonic echo data of thick, complex concrete structures. Coda wave interferometry is used to detect subtle changes in concrete constructions, e. g. using embedded ultasonic transducers. T2 - Geophysikalisches Seminar der Universität Potsdam CY - Potsdam,. Germany DA - 25.01.2019 KW - Concrete KW - Ultrasound KW - Monitoring KW - Imaging PY - 2019 AN - OPUS4-47302 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Altenburg, Simon A1 - Maierhofer, Christiane A1 - Mohr, Gunther A1 - Hilgenberg, Kai T1 - Process monitoring in LBM using thermography and optical tomography N2 - Additive manufacturing (AM) opens the route to a range of novel applications. However, the complexity of the manufacturing process poses a challenge to produce defect-free parts with a high reliability. Since process dynamics and resulting microstructures of AM parts are strongly influenced by the involved temperature fields and cooling rates, thermography is a valuable tool for process monitoring. Another approach to monitor the energy input into the part during process is the use of optical tomography. Common visual camera systems reach much higher spatial resolution than infrared thermography cameras, whereas infrared thermography provides a much higher temperature dynamic. Therefore, the combined application increases the depth of information. Here, we present first measurement results using a laser beam melting setup that allows simultaneous acquisition of thermography and optical tomography from the same point of view using a beam splitter. A high-resolution CMOS camera operating in the visible spectral range is equipped with a near infrared bandpass filter and images of the build plate are recorded with long-term exposure during the whole layer exposing time. Thus, areas that reach higher maximum temperature or are at elevated temperature for an extended period of time appear brighter in the images. The used thermography camera is sensitive to the mid wavelength infrared range and records thermal videos of each layer exposure at an acquisition rate close to 1 kHz. As a next step, we will use computer tomographic data of the built part as a reference for defect detection. This research was funded by BAM within the focus area Materials. T2 - 3rd International Symposium Additive Manufacturing (ISAM 2019) CY - Dresden, Germany DA - 30.01.2019 KW - Additive manufacturing KW - Laser beam melting KW - Thermography KW - Optical Tomography PY - 2019 AN - OPUS4-47299 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maiwald, Michael A1 - Kern, Simon A1 - Bornemann-Pfeiffer, Martin A1 - Guhl, Svetlana A1 - Wander, Lukas A1 - Meyer, Klas T1 - Accelerating chemical process development and manufacturing by online NMR spectroscopy N2 - Chemical companies must find new paths to successfully survive in a changing environment. The potential of digital technologies belongs to these. Flexible and modular chemical plants can produce various high-quality products using multi-purpose equipment with short down-times between campaigns and reduce time to market for new products. Intensified continuous production plants allow for difficult to produce compounds. Therefore, fully automated “chemical” process control along with real-time quality control are prerequisites to such concepts and thus should be based on “chemical” information. The advances of a fully automated NMR sensor were exploited, using a given pharmaceutical lithiation reaction as an example process within a modular pilot plant. A commercially available benchtop NMR spectrometer was integrated to the full requirements of an automated chemical production environment such as , e.g., explosion safety, field communication, and robust evaluation of sensor data. It was thereof used for direct loop advanced process control and real-time optimization of the process. NMR appeared as preeminent online analytical tool and allowed using a modular data analysis tool, which even served as reliable reference method for further PAT applications. In future, such fully integrated and intelligently interconnecting “smart” systems and processes can speed up the high-quality production of specialty chemicals and pharmaceuticals. T2 - Symposium: Quantitative NMR Methods for Reaction and Process Monitoring (NMRPM) 2019 CY - Kaiserslautern, Germany DA - 31.01.2019 KW - Process Analytical Technology KW - Process Industry KW - Online NMR Spectroscopy KW - Data Analysis KW - Digitization KW - CONSENS PY - 2019 N1 - Geburtsname von Bornemann-Pfeiffer, Martin: Bornemann, M. - Birth name of Bornemann-Pfeiffer, Martin: Bornemann, M. AN - OPUS4-47297 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Chen, Cong A1 - Bousnina, M. A1 - Giovannelli, F. A1 - Delorme, F. T1 - Influence of Bi on the thermoelectric properties of SrTiO3-δ N2 - The thermoelectric properties of Sr1-xBixTiO3-δ (0 ≤ x ≤ 0.07) have been investigated. Dense ceramics of Sr1-xBixTiO3-δ and Sr0.95TiO3-δ have been prepared by solid-state reaction and conventional sintering in air followed by annealing in a reducing atmosphere. XRD and SEM analyses show that the rutile TiO2 in Sr0.95TiO3 formed after sintering becomes Magnéli phase of TinO2n-1 after annealing. Moreover, Bi resolves from Sr1-xBixTiO3 after annealing, resulting in the formation of Sr1-xBixTiO3-δ/Bi/TinO2n-1 composites. With increasing Bi content in Sr1-xBixTiO3-δ, the electrical conductivity increases while the absolute values of the Seebeck coefficient decrease as a result of increasing carrier concentration. The thermal conductivity of SrTiO3-δ is reduced by doping Bi up to x = 0.07. Highest ZT ~ 0.13 is obtained in Sr0.93Bi0.07TiO3-δ at 1000 K. KW - Thermoelectrics KW - SrTiO3 KW - Composite KW - Magnéli phase PY - 2019 UR - https://nbn-resolving.org/urn:nbn:de:kobv:b43-472920 DO - https://doi.org/10.1016/j.jmat.2018.12.004 SN - 2352-8478 VL - 5 IS - 1 SP - 88 EP - 93 PB - Elsevier AN - OPUS4-47292 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schoenhals, Andreas T1 - Structure property relationships of thin polymer films N2 - Polymers at interfaces play a major role in a broad variety of applications ranging from engineering purposes (for instance polymer based nanocomposites) to high tech implications (for instance light emitting diodes). Here, thin films with thicknesses down to few nanometers are prepared on different substrates as model systems for polymer composites. The thin films are investigated by a combination of surface analytical and volume sensitive methods. As surface analytical methods atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and contact angle measurements (CAM) are employed. As volume sensitive broadband dielectric spectroscopy (BDS), specific heat spectroscopy (SHS), and ellipsometry are used. Especially attention is paid to understand the glass transition behavior of thin films because the glass transition is the key phenomenon determines the application of polymers also in thin films. To understand the glass transition behavior of thin films, which is controversially discussed in literature, a three layer model is discussed. Firstly, a mobile surface layer is assumed at polymer air interface of the film due to missing of segment/segment interactions. Secondly, in the middle of the film a bulk-like layer should be expected. Thirdly, for polymers having non-repulsive interactions with the substrate an irreversibly adsorbed layer is expected to be formed. Due the adsorption the molecular mobility of the segments in this layer is slowed down. What is measured for the glass transition of thin films is a complicated average of all of these effects. The different layers are hardly to address separately. Therefore, in the presentation especially model systems are selected and investigated to verify the layer model. T2 - Seminarvortrag Universität Dortmund CY - Dortmund, Germany DA - 29.01.2019 KW - Thin polymer films PY - 2019 AN - OPUS4-47289 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Spranger, Felix A1 - Hilgenberg, Kai T1 - Laser implantation: An innovative technique for surface texturing N2 - The laser implantation technique bases on a localized dispersing of ceramic particles in metallic surface layers for changing their micro geometry as well as their material properties. Using TiB2 and NbC hard particles, tailored microtextures consisting of elevated dome-, ring-, or line-shaped Features can be manufactured. Especially TiB2 implants feature high hardness values up to 1800 HV1 and ceramic particle contents up to 55 %, indicating superior wear resistant properties. KW - Laser implantation KW - Surface texturing KW - AISI D2 KW - TiB2 KW - NbC PY - 2019 UR - https://onlinelibrary.wiley.com/doi/epdf/10.1002/phvs.201900002 DO - https://doi.org/10.1002/phvs.201900002 SN - 2626-1294 VL - 16 IS - 1 SP - 38 EP - 41 PB - WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim CY - Weinheim AN - OPUS4-47290 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Auer, G. A1 - Spanka, M. A1 - Hamann, Christopher A1 - Adam, Christian T1 - Thermal zinc extraction from steel mill dust N2 - Treatment and reusing of hazardous wastes have become significant issues of modern societies. Blast furnace sludge (BFS) and electric arc furnace dust (EAFD) are such typical wastes, because they usually contain high amounts of undesirable elements such as zinc (Zn) and lead (Pb). These elements can cause operational problems in reusing of BFS and EAFD. In this study, the Ferro Duo GmbH and the Federal Institute for Materials Research and Testing have investigated a novel approach for eliminating and/or recovering Zn and Pb from both wastes. Applied was a selective chlorination and volatilization of Zn and Pb as chlorides at temperatures between 500 °C and 1100 °C. Both product obtained, Zn and Pb in the form of ZnCl2 and PbCl2 and the purified solid mineral compound are attractive materials for further use. Hydrochloric acid and iron(II) chloride were used as chlorination agents. Exceptionally high Zn and Pb removal efficiencies of >99.5 % could be achieved with both chlorination agents, whereby iron(II) chloride exhibited better performance. KW - Blast furnace sludge KW - Chlorination KW - Electric arc furnace dust KW - Lead KW - Zinc KW - Thermochemical treatment PY - 2019 SN - 1613-2394 VL - 72 IS - 1 SP - 27 EP - 31 PB - GDMB Verlag GmbH CY - Clausthal-Zellerfeld AN - OPUS4-47288 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Müller, Thoralf A1 - Burkert, Andreas A1 - Lehmann, Jens T1 - Korrosionsschutzmethoden N2 - Der Vortrag thematisiert die Grundlagen des Korrosionsschutzes. Dieser kann planungs-,werkstoff oder mediumsseitig erfolgen oder mit elektrochemischen Methoden umgesetzt werden. Der Vortrag beschreit die Korrosivitäten der Atmosphären und welche Maßnahmen für den Korrosionsschutz daraus abgeleitet werden können. T2 - Fachausbildung Kathodischer Korrosionsschutz - Grundlagenkurs für erdverlegte Anlagen, Stahlbeton und Innenschutz CY - Technische Akademie Esslingen, Germany DA - 22.01.2019 KW - Korrosion KW - Korrosionsschutz KW - Passivität KW - Beschichtung KW - Überzüge KW - Kathodische Korrosionsschutz PY - 2019 AN - OPUS4-47273 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Müller, Thoralf A1 - Burkert, Andreas A1 - Lehmann, Jens T1 - Korrosion metallischer Werkstoffe N2 - Der Vortrag thematisiert die Grundlagen der Korrosion metallischer Werksoffe. Inhalt des Vortrags sind die Grundlagen zur Potentialbildung, die Teilreaktionen der Korrosionsreaktion, elektrochemische Versuche und deren Auswertung sowie die Grundlagen der Bimetallkorrosion T2 - Fachausbildung Kathodischer Korrosionsschutz - Grundlagenkurs für erdverlegte Anlagen, Stahlbeton und Innenschutz CY - Technische Akademie Esslingen, Germany DA - 22.01.2019 KW - Korrosion KW - Bimetallkorrosion KW - Potential KW - Elektrochemie PY - 2019 AN - OPUS4-47272 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Mair, Georg T1 - Minimum safety requirement for CGH2-pressure receptacles: 2nd FDIS ISO 17519 N2 - Der Vortrag fasst alle Bedenken sicherheitstechnischer Art zusammen, die den DIN bewogen haben, ein ISO-Projekt zu extrem großen Gas-/Wasserstofftransporteinheiten abzulehnen. Kernpunkt ist das mit dem Skope des Normprojektes durch Druck- und Volumenerhöhung gegenüber dem heutigen Stand der Technik erheblich angestiegene Konsequenzpotential. Gleichzeitig fehlt ein Ansatz, den von der Konsequenz bis zum kritischen Niveau einer Katastrophe abhängigen Zuverlässigkeitsanforderungen Rechnung zu tragen. N2 - The presentation summarizes all the safety concerns that have led DIN to reject an ISO project about extremely large gas/hydrogen transport units. The core point is the consequence potential, which has increased considerably with the scope of the standardization project in comparison with state of the art systems. At the same time, there is a lack of an approach to take into account the reliability requirements that depend on the consequences, at least up to the level of a catastrophe. T2 - Sitzung des NA 016 DIN-Normenausschuss Druckgasanlagen (NDG) Arbeitskreis Compositeflaschens mit Gästen aus den USA (Convenor) CY - DIN, Berlin, Germany DA - 10.01.2019 KW - Acceptance of a standard KW - Tube trailer KW - Pressure-volume-product KW - Catastrophic consequence KW - Safety goal PY - 2019 AN - OPUS4-47280 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maiwald, Michael T1 - Compact NMR Spectroscopy: A Versatile Tool for Automated Continuous-Flow Production of Chemicals and Pharmaceuticals N2 - Chemical companies must find new paths to successfully survive in a changing environment. The potential of digital technologies belongs to these. Flexible and modular chemical plants can produce various high-quality products using multi-purpose equipment with short down-times between campaigns and reduce time to market for new products. Intensified continuous production plants allow for difficult to produce compounds. Therefore, fully automated “chemical” process control along with real-time quality control are prerequisites to such concepts and thus should be based on “chemical” information. The advances of a fully automated NMR sensor were exploited, using a given pharmaceutical lithiation reaction as an example process within a modular pilot plant. A commercially available benchtop NMR spectrometer was integrated to the full requirements of an automated chemical production environment such as , e.g., explosion safety, field communication, and robust evaluation of sensor data. It was thereof used for direct loop advanced process control and real-time optimization of the process. NMR appeared as preeminent online analytical tool and allowed using a modular data analysis tool, which even served as reliable reference method for further PAT applications. In future, such fully integrated and intelligently interconnecting “smart” systems and processes can speed up the high-quality production of specialty chemicals and pharmaceuticals. T2 - 2nd Reaction Monitoring Symposium, University of Bath CY - Bath, United Kingdom DA - 28.01.2019 KW - Process Analytical Technology KW - Process Industry KW - Online NMR Spectroscopy KW - CONSENS PY - 2019 AN - OPUS4-47271 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wilrich, Cordula T1 - Chemikalienrecht ‒ eine Einführung • Grundzüge & Prinzipien • Wo gibt es Informationen & Hilfestellungen N2 - Der Vortrag gibt einen Überblick über das Chemikalienrecht, stellt die wichtigsten Regelungen sowie ihre Schnittstellen vor und gibt Informationen zu verfügbaren Hilfestellungen. Besprochen werden • das UN-GHS (Globally Harmonized System of Classification and Labelling of Chemicals) • REACH (EU-Verordnung zur Registrierung, Bewertung, Zulassung und Beschränkung chemischer Stoffe) • CLP (EU-Verordnung über die Einstufung, Kennzeichnung und Verpackung von Stoffen und Gemischen) • Gefahrstoffverordnung T2 - Vortrag im Rahmen der Ringvorlesung für den Studiengang "Sicherheit und Gefahrenabwehr" der Hochschule Magdeburg-Stendal in Zusammenarbeit mit der Otto von Guericke Universität Magdeburg und dem Institut für Brand- und Katastrophenschutz Heyrothsberge CY - Magdeburg, Germany DA - 24.01.2019 KW - Chemikalienrecht KW - UN-GHS KW - Gefährliche Stoffe KW - CLP-Verordnung KW - REACH KW - Sicherheitsdatenblatt KW - Gefahrstoffverordnung PY - 2019 AN - OPUS4-47270 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Taparli, Ugur Alp A1 - Griesche, Axel A1 - Kannengießer, Thomas A1 - Jacobsen, L. A1 - Michalik, K. A1 - Mory, D. T1 - In situ TIG-Welding monitoring using Laser-Induced Breakdown Spectroscopy N2 - Chemical composition of the welding seam and HAZ has significant effect on weld quality. Current inspection methods for weld seams measure and investigate post factum and cannot prevent weld defects. Element burn-off may significantly affect solidification leading to embrittlement or cracking. Control of weld chemical compositions insures a controlled solidification and resistance to related weld defects. “Industry 4.0” is the current trend of automation and data exchange in manufacturing technologies. With this trend “intelligent” welding machines will be developed. LIBS can provide significantly important online data for such systems. T2 - Forschungsseminar OvGU Magdeburg CY - Magdeburg, Germany DA - 24.01.2019 KW - In situ measurement KW - LIBS TIG welding KW - Austenitic stainless steels KW - Chemical composition PY - 2019 AN - OPUS4-47266 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Resch-Genger, Ute A1 - Würth, Christian A1 - Kaiser, Martin A1 - Pauli, Jutta A1 - Hoffmann, Katrin T1 - Relative and Absolute Methods for Measuring Photoluminescence Quantum Yields of UV/vis/NIR Emitters N2 - One of the key spectroscopic performance parameters of molecular and particulate emitters is the photoluminescence quantum yield (PL QY) that provides a direct measure for the number of emitted per absorbed photons. This triggered the interest in methods suitable for measuring this property for emitters in various environments in the UV/vis/NIR and above 1000 nm as well as on the ensemble and single emitter level. Moreover, for nonlinear emitters like lanthanide-based upconversion nanocrystals methods including instrumentation for power density-dependent PL QY studies are required. An overview of the research activities in Division Biophotonics of BAM is given and suitable relative and absolute methods for the deter-mination of PL QY of organic dyes and different types of application-relevant nanomaterials in dispersion and in the solid state are presen-ted. This covers also the design and calibration of integrating sphere setups, achievable uncertainties, and candidates for PL QY reference materials. T2 - OSRAM Veranstaltung CY - Regensburg, Germany DA - 09.01.2019 KW - Quantum yield KW - Calibration KW - Reference material KW - Uncertainty KW - Absolute fluorometry KW - Integrating sphere spectroscopy KW - NIR KW - IR KW - Fluorescence KW - Nanoparticle KW - Dye PY - 2019 AN - OPUS4-47263 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Emmerling, Franziska T1 - New insights in mechanochemical processes using real-time in situ investigations N2 - Use of synchrotron radiation for special sample conditions. Recent work of the group at BESSY II. T2 - DESY Usermeeting Satelite Workshop CY - Hamburg, Germany DA - 22.01.2019 KW - XRD KW - In situ KW - Rietveld KW - Synchrotron PY - 2019 AN - OPUS4-47262 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Emmerling, Franziska T1 - May the Force be with you - Mechanochemical syntheses studied in situ N2 - Mechanochemistry is a fast and efficient method applicable for the synthesis of new organic, metal-organic, and inorganic compounds. The direct monitoring of milling reactions is still challenging. The underlying reaction mechanisms remain often unclear. In the last years, have established a tandem in situ approach for investigating mechanochemical reactions using time-resolved in situ XRD coupled with Raman spectroscopy. Here, we present an in situ coupling of synchrotron XRD, Raman spectroscopy, and thermography allowing the observation of mechanochemical reactions in real time. Information on the crystalline, molecular, and temperature state of the materials during grinding could be collected. The chemical composition of the reaction mixture was found to be directly correlated with changes in the temperature profile of the reaction. Furthermore, the presented setup allows the detection of crystalline, amorphous, eutectic as well as liquid intermediates. The resulting deeper kinetic and thermodynamic understanding of milling processes is the key for future optimization of mechanochemical syntheses. T2 - Seminar Universität Montpellier CY - Montpellier, France DA - 24.01.2019 KW - Mechanochemistry KW - In situ PY - 2019 AN - OPUS4-47261 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Pfretzschner, Beate A1 - Griesche, Axel A1 - Kannengießer, Thomas T1 - Neutronen-Radiographie zur Detektion von Wasserstoff in Stahl N2 - Es werden das Verfahren der Neutronenradiographie erläutert und die Ergebnisse von Messungen an wasserstoffbeladenen Zugproben vorgestellt. T2 - BMDK der OvGU Magdeburg CY - Magdeburg, Germany DA - 24.01.2019 KW - Supermartensit KW - Neutronenradiographie KW - Wasserstoff PY - 2019 AN - OPUS4-47259 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Algernon, D. A1 - Arndt, R.W. A1 - Denzel, W. A1 - Ebsen, B. A1 - Feistkorn, S. A1 - Friese, M. A1 - Große, C.U. A1 - Kathage, S. A1 - Keßler, S. A1 - Köpp, Christian A1 - Küttenbaum, Stefan A1 - Lohse, C. A1 - Maack, Stefan A1 - Niederleithinger, Ernst A1 - Schickert, M. A1 - Schröder, G. A1 - Taffe, A. A1 - Timofeev, Juri A1 - Walther, A. A1 - Wilcke, M. A1 - Wolf, J. A1 - Wöstmann, Jens T1 - Test specimen concepts in regard to quality assurance and validation of nondestructive testing in civil engineering N2 - The process of ensuring reliability of NDT applications contains various aspects, such as determining the performance and probability of success, the uncertainty in measurement, the provision of clear and functional procedures and ensuring the correct application accordingly. Test specimens have become powerful elements in supporting many of these aspects. Within the committee for NDT in Civil Engineering (NDT-CE) of the German Society for Nondestructive Testing (DGZfP), the subcommittee on Quality Assurance (UA-QS) therefore addresses the design and the integration of test specimens in the quality assurance process. Depending on the specific purpose, the requirements on test specimens can vary significantly based on the defined simulated scenario. The most prominent purposes of test specimens might be seen in providing references for inspection systems in regard to function control, calibration and validation. Further aspects can be parametric studies, basic investigation of physical principles related to NDT or a simplified and therefore comprehensive demonstration of inspection concepts (e.g. for teaching purposes). The specific purpose of a test specimen dictates the requirements regarding its conception, including the exact design, the material or the fabrication accuracy and the conditioning. In the development of a general guideline by the UA-QS for application-specific procedures and their validation, the use of test specimens is addressed and specific concepts for the design of test specimens are made. This includes the analysis of the measurement process regarding any given application, deriving an adequate calibration approach for it and designing test specimens (calibration specimens) accordingly. Furthermore, it includes the validation of the procedure taking into account all conditions related to the specific application in the field. The validation requires a statistically sufficient number of trials. Thorough evaluation of each trial can only be established if the ground-truth is known. Therefore, test specimens providing a realistic but controlled simulation of the inspection problem are valuable and indispensable elements in the validation process. The requirement of being fully realistic will often not be possible to fulfill due to practical restrictions. Any aspect that cannot be included in the simulation realistically needs to be simulated conservatively. This again, requires a sufficient understanding of the inspection principle and technique to ensure conservativeness. Among other quality-assurance-related aspects, the UA-QS establishes concepts and guidelines regarding sound and efficient approaches for the specific purposes of test specimens. This subcommittee brings together representatives of different Groups along the entire value chain of NDT-CE, including researchers, practitioners, manufacturers and clients. They all work together in establishing a common understanding and level of quality assurance in the industry. T2 - SMT and NDT-CE 2018 CY - New Brunswick, NJ, USA DA - 27.08.2018 KW - Quality assurance KW - Procedure KW - Reliability KW - Validation KW - Reference specimen PY - 2019 UR - https://asnt.org/smt18papers SN - 978-1-57117-456-7 VL - 11/19 SP - 39 EP - 48 PB - The American Society for Nondestructive Testing, Inc. CY - Columbus, OH, USA AN - OPUS4-47240 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Algernon, D. A1 - Arndt, R.W. A1 - Denzel, W. A1 - Ebsen, B. A1 - Feistkorn, S. A1 - Friese, M. A1 - Große, C.U. A1 - Kathage, S. A1 - Keßler, S. A1 - Köpp, Christian A1 - Küttenbaum, Stefan A1 - Lohse, C. A1 - Maack, Stefan A1 - Niederleithinger, Ernst A1 - Schickert, M. A1 - Schröder, G. A1 - Taffe, A. A1 - Timofeev, Juri A1 - Walther, A. A1 - Wilcke, M. A1 - Wolf, J. A1 - Wöstmann, Jens T1 - NDT procedures in relation to quality assurance and validation of nondestructive testing in civil engineering N2 - The field of non-destructive testing of civil structures (NDT-CE) has been continuously growing. Due to the complexity and diversity of civil constructions as well as the heterogeneity of concrete, specific standards or guidelines for the application of modern NDT-CE are still missing. The development of individual solutions is the current approach, which is just as challenging as it is common for NDT-CE. With the increasing development and commercialization of NDT-CE technology, the group of practitioners is growing. To ensure a good level of quality in the industry, it appears necessary to establish adequate means. Naturally, the performance of NDT-CE methods regarding a specific application is strongly dependent on choosing the most suitable inspection technique and applying it correctly, generally referred to as the inspection procedure in the field of NDT. There are well-defined guidelines regarding procedure documentation and handling in many fields of NDT (e.g. nuclear, aerospace or automotive) according to the high importance of procedures in assuring a successful and reliable application. For a long time, this has not always been the case with NDT-CE, which is still considered a unique discipline of NDT. Part of the reason for that might be the young development state of NDTCE, the heterogeneity of building materials like concrete, timber or masonry as a material and the diversity of civil structures. In consequence, NDT-CE procedure development is considered challenging. Among other aspects, addressed in the subcommittee on Quality Assurance (UA-QS) within the committee for NDT-CE of the German Society for Nondestructive Testing (DGZfP), part of its work aims at establishing an adequate basis for NDT-CE procedure development. While some of the highly developed approaches from other industries are taken into consideration, they need to be analyzed regarding their suitability for NDT-CE and adapted accordingly. For a procedure to be as defined as possible, it needs to contain sufficient information, such as the scope and limitations regarding material, geometry and condition of the test object, inspection parameters, calibration, data acquisition, analysis criteria as well as requirements regarding the inspection personnel. For a successful implementation in the field, it is important to define the specific procedure as precisely as possible. Despite the necessity of a great amount of information to be included, the procedure needs to be suitable for efficient field application. The UA-QS is developing a guideline for NDT-CE procedures suitable for application in this field of NDT to ensure correct and reproducible application. To demonstrate and evaluate this concept, specific examples of procedures are also produced. In particular, the UA-QS has developed a procedure for the detection and positioning of tendon ducts using Ground Penetrating Radar (GPR). This procedure is tested regarding the practical applicability in a roundrobin on a defined type of reference test block. T2 - SMT and NDT-CE 2018 CY - New Brunswick, NJ, USA DA - 27.08.2018 KW - Quality assurance KW - Procedure KW - Reliability KW - Validation KW - Reference specimen PY - 2019 UR - https://asnt.org/smt18papers SN - 978-1-57117-456-7 VL - 11/19 SP - 31 EP - 38 PB - The American Society for Nondestructive Testing, Inc. CY - Columbus, OH, USA AN - OPUS4-47239 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Niederleithinger, Ernst A1 - Wiggenhauser, Herbert T1 - The LAUS: First Applications of a New System for Ultrasonic Imaging of Very Concrete Structures N2 - The LAUS (Large Aperture Ultrasonic System) has been developed to image very thick concrete structures, which are not accessible for commercial systems. The device and the corresponding software is the result of joint Research of BAM, an ultrasonic instrument manufacturer and University of Kassel, Germany. It consists of 12 separate Arrays of 32 point-contact shear wave transducers each, which can be deployed in flexible configurations. Each array is combined with battery and transmitter, receiver and wireless communication electronics. Three case histories are presented. First the system was deployed on a 5-m thick heavily reinforced foundation slab. The reflection of the slab’s bottom was imaged clearly. In addition, a multiple reflection was registered, thus giving hope that even thicker elements might be imaged by the instrument. Second, the LAUS was used to investigate a massive bridge girder where a heavy rainstorm during concreting had led to imperfections that were visible after removing the formwork was removed. The LAUS could image tendon ducts in 1.8m depth and the backwall closely behind them. Some limited areas showed blurred reflections and were checked by drill holes; these areas were affected by diffuse damage which could be repaired by injections. Third, a large retaining wall was checked for thickness. Meanwhile, the LAUS has been used in underground waste deposits (nuclear and other) for quality assurance of sealing plugs. A confirmed penetration depth of about 7 m has been reached. T2 - SMT and NDT-CE 2018 CY - New Brunswick, NJ, USA DA - 27.08.2018 KW - LAUS (Large Apertur Ultrasonic System) KW - Ultrasonic echo KW - Deep penetration KW - Concrete PY - 2019 UR - https://asnt.org/smt18papers SN - 978-1-57117-456-7 VL - 11/19 SP - 208 EP - 213 PB - The American Society for Nondestructive Testing, Inc. CY - Columbus, OH, USA AN - OPUS4-47238 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Abraham, O. A1 - Niederleithinger, Ernst A1 - Chapeleau, X. A1 - Klikowicz, P. A1 - Brühwiler, E. A1 - Bassil, A. A1 - Wang, Xin A1 - Chakraborty, J. A1 - Bayane, I. A1 - Leduc, D. A1 - Salamak, M. A1 - Katunin, A. A1 - Sørensen, J.D. T1 - Addressing the need to monitor concrete fatigue with nondestructive testing: Results of infrastar European project N2 - Fatigue is one of the most prevalent issues, which directly influences the service life expectancy of concrete structures. Fatigue has been investigated for years for steel structures. However, recent findings suggest that concrete structures may also be significantly subjected to fatigue phenomena that could lead to premature failure of certain structural elements. To date, fatigue of reinforced concrete has been given little focus. Knowledge on the influence factors and durability/capacity effects on this material should be improved. Current technological means to measure fatigue in civil structures like bridges and wind turbines (both onshore and offshore) are outdated, imprecise and inappropriate. Meanwhile, this topic has got much more attention as time-variant loading on concrete structures plays an increasing role, e.g. in bridges with increasing traffic and heavier trucks, and for wind turbines for renewable energy production, e.g. for offshore wind turbine support structures affected by wind and waves. The European Innovative Training Networks (ITN) Marie Skłodowska-Curie Actions project INFRASTAR (Innovation and Networking for Fatigue and Reliability Analysis of Structures - Training for Assessment of Risk) provides research training for 12 PhD students. The project aims to improve knowledge for optimizing the design of new structures as well as for more realistic verification of structural safety and more accurate prediction of the remaining fatigue lifetime of existing concrete structures. First, the INFRASTAR research framework is detailed. Then it will be exemplified through the presentation of the major results of the four PhD students involved in the work package dealing with auscultation and monitoring. This includes the development and improvement of Fiber Optics (FO) and Coda Wave Interferometry (CWI) for crack sizing and imagery, new sensor technologies and integration, information management, monitoring strategy for fatigue damage investigation and lifetime prediction. T2 - SMT and NDT-CE 2018 CY - New Brunswick, NJ, USA DA - 27.08.2018 KW - Concrete KW - Fatigue KW - Crack KW - Monitoring KW - Non-destructive testing PY - 2019 UR - https://asnt.org/smt18papers SN - 978-1-57117-456-7 VL - 11/19 SP - 2 EP - 13 PB - The American Society for Nondestructive Testing, Inc. CY - Columbus, OH, USA AN - OPUS4-47237 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Otremba, Frank T1 - Hazmat tanks subjected to fire N2 - Transport safety depends in great extent of what happens to the cargo once the carrying vehicle derails or rollovers. The exposure of tanks to direct fire is a condition that potentially involves catastrophic consequences. Studying the behavior of the contained fluid under these drastic circumstances, is critical to develop methods and techniques to mitigate the serious consequences of many mishaps. In this paper, the experimental potentials of a Particle Image Velocimetry data acquisition system are described, for providing experimental data that could be used to calibrate mathematical models. As an example of the situations that need to be modelled, an experiment is described concerning the effect of the boundary conditions and protecting devices, on the rate of variation of pressure and temperature of the fluid in a tank exposed to a direct fire. In this regard, the results emphasize the importance of equipping the vessels with both thermal insulation and safety valves. T2 - ICMEA CY - Da Nang, Vietnam DA - 16.01.2019 KW - Pool fire KW - Pressure vessel PY - 2019 AN - OPUS4-47231 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - RPRT A1 - Denkler, Tilman T1 - Comparison of the operation of accreditation bodies in Europe N2 - This study was designed to examine and compare the operation of accreditation bodies in Europe. A management tool, the Process Maturity Benchmarking Tool (PMBT), was elaborated and validated by applying it to various accreditation bodies. By applying the tool, the values of indicators were determined, thus enabling a comparison of the accreditation bodies despite different operational processes and organizational forms. The management tool PMBT is based on the analysis of selected processes with high relevance for the operation of accreditation bodies. The processes are derived from a process map designed for accreditation bodies in a universally applicable way. The indicators used to characterize the processes come from two sources: The first source relates to data already available from internal databases, reports, financial audits etc. The second source is derived from a self-evaluation of process maturity performed by the accreditation bodies. The criteria for evaluating process maturity were designed by applying the criteria of the EFQM excellence model 2013 of the European Foundation for Quality Management (EFQM) to the processes identified in the process map. The project Comparison of the Operation of Accreditation Bodies in Europe comprised three stages. In the first stage, the processes of accreditation bodies were systematically analyzed. A process map was developed and processes of special relevance for the performance of accreditation bodies were identified and underpinned by indicators as described above. In the second stage, the processes of the German accreditation body DAkkS were assigned to the tool. This stage was used to check and modify the indicators when necessary. In the third stage, the transferability of the model was analyzed by extension to seven other accreditation bodies operating in Europe. The third stage of the project ended with a workshop attended by the eight accreditation bodies, which was used to present and discuss the results of the comparison and to identify best practices. KW - Accreditation KW - Benchmarking PY - 2019 SP - 1 EP - 83 AN - OPUS4-47235 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Pistol, Klaus A1 - Huismann, S. A1 - Diederichs, U. A1 - Pimienta, P. A1 - Jumppanen, U.M. A1 - Mindeguia, J.C. T1 - Stress-strain-relation, compressive strength and modulus of elasticity N2 - This chapter report the most recent experimental results on mechanical behaviour at high temperature of high-performance concretes. After a short introduction, subsection 5.2 describes the main testing methods that were used in the analysed studies. Sub-section 5.3 collects and compares; the temperature-dependency of the compressive strength and modulus of elastici1ty of many experimental studies. The influence of parameters such as the initial compressive strength, the type of aggregate, the presence of additions, the W/C ratio, the moishrre content and the way the mechanical test was performed is analysed. Sub-section 5.4 presents the experimental results obtained under a constant temperature, i.e. creep tests at high temperature. Sub-section 5.5 presents experimental results obtained under increasing temperahrre. These results allow assessing the free thennal strain of concrete (when no mechanical load is applied) and the so-called "transient the1mal strain". Finally, subsection 5.6 collects and analyses the few results conceming the temperature-dependency of the tensile strength of high-perfo1mance concretes. KW - Stress-strain-relation KW - High temperature PY - 2019 SN - 978-3-319-95431-8 SN - 978-3-319-95432-5 SN - 2213-204X SN - 2213-2031 SP - 89 EP - 105 PB - Springer CY - Swizerland AN - OPUS4-47212 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maack, Stefan T1 - Zerstörungsfreie Prüfungen an Konstruktionen aus Beton - Stand der Technik – Stand der Forschung N2 - Übersichtsvortrag zur Anwendung zerstörungsfreier Prüfverfahren für das Bauwesen mit Schwerpunkt auf den Baustoff Beton. T2 - Hausinterne Fortbildungsmaßnahme - Hessen Mobil - Straßen- und Verkehrsmanagement CY - Dillenburg/Hessen, Germany DA - 15.01.2019 KW - Zerstörungsfreie Prüfung KW - Beton KW - Stand der Technik KW - Brücken PY - 2019 AN - OPUS4-47234 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CHAP A1 - Oesch, Tyler A1 - Stelzner, Ludwig A1 - Weise, Frank ED - Herrmann, H. ED - Schnell, J. T1 - Non-destructive evaluation of the contribution of polymer-fibre orientation and distribution characteristics to concrete performance during fire N2 - Although concrete itself is not a combustible material, concrete mixtures with high density, such has high-performance concretes (HPCs), are susceptible to significant damage during fires due to explosive spalling. Past research has shown that the inclusion of polymer fibres in high density concrete can significantly mitigate this fire damage. The exact mechanisms causing this increased spalling resistance are not yet fully under-stood, but it is thought that the fibres facilitate moisture transport during fire exposure, which in turn contributes to relief of internal stresses in the spalling-susceptible region. In this study, X-ray Computed Tomography (CT) was applied to observe the interaction between polymer fibres and cracking during thermal exposure. For this purpose, two concrete samples containing different polymer fibre types were subjected to incremental application of a defined thermal exposure. CT images were acquired before and after each thermal exposure and powerful image processing tools were used to segment the various material components. This enabled a detailed analysis of crack formation and propagation as well as the visualization and quantification of polymer fibre characteristics within the concrete. The results demonstrated that the orientation of both fibres and cracks in polymer-fibre reinforced concrete tend to be anisotropic. The results also indicated that crack geometry characteristics may be correlated with fibre orientation, with cracks tending to run parallel to fibre beds. Clear quantitative relationships were also observed between heating and increasing cracking levels, expressed in terms of both crack surface area and crack volume. KW - X-ray Computed Tomography (CT) KW - Polypropylene Fibres KW - Fire Performance KW - Fibre-Reinforced Concrete (FRC) KW - Fibre Orientation Analysis PY - 2019 SN - 978-3-030-00868-0 DO - https://doi.org/10.1007/978-3-030-00868-0 SP - 51 EP - 73 PB - Springer Nature Switzerland AG AN - OPUS4-47206 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Maiwald, Michael T1 - Compact NMR spectroscopy: A versatile tool for automated continuous-flow production of chemicals and pharmaceuticals N2 - Chemical companies must find new paths to successfully survive in a changing environment. The potential of digital technologies belongs to these. Flexible and modular chemical plants can produce various high-quality products using multi-purpose equipment with short down-times between campaigns and reduce time to market for new products. Intensified continuous production plants allow for difficult to produce compounds. Therefore, fully automated “chemical” process control along with real-time quality control are prerequisites to such concepts and thus should be based on “chemical” information. The advances of a fully automated NMR sensor were exploited, using a given pharmaceutical lithiation reaction as an example process within a modular pilot plant. A commercially available benchtop NMR spectrometer was integrated to the full requirements of an automated chemical production environment such as , e.g., explosion safety, field communication, and robust evaluation of sensor data. It was thereof used for direct loop advanced process control and real-time optimization of the process. NMR appeared as preeminent online analytical tool and allowed using a modular data analysis tool, which even served as reliable reference method for further PAT applications. In future, such fully integrated and intelligently interconnecting “smart” systems and processes can speed up the high-quality production of specialty chemicals and pharmaceuticals. T2 - GDCh-Seminar der Universität Bielefeld CY - Bielefeld, Germany DA - 17.01.2019 KW - Process analytical technology KW - Process industry KW - Online NMR spectroscopy KW - Indirect hard modeling KW - CONSENS KW - Fresenius lecture PY - 2019 AN - OPUS4-47221 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weltschev, Margit T1 - Beständigkeit von Fluorkautschuk in Kraftstoffen und Heizöl mit biogenen Anteilen unter Druckbeanspruchung N2 - Die Bewertung der Werkstoffbeständigkeit ist von großer Bedeutung bei Änderung der Zusammensetzung der Kraftstoffe und des Heizöls, insbesondere die Frage nach der Beständigkeit der Dichtungswerkstoffe bei Zusätzen von Bioethanol und Biodiesel (Rapsölfettsäuremethylester). Vorhergehende Untersuchungen (Messungen der Veränderungen der Masse, der Zugeigenschaften und der Härte) bezogen sich auf die Bewertung der Beständigkeit häufig verwendeter Dichtungswerkstoffe wie FKM, FVMQ, VMQ, EPDM, CR, CSM, IIR, PA, NBR und PUR in Kraftstoffen und Heizöl mit 10 % Biodiesel (nicht gealtert und bis zu 5 Jahre gealtert) unter statischen Bedingungen. Ziel der Untersuchungen war die Bewertung der Beständigkeit von Fluorkautschuk unter verpressten Bedingungen in Analogie zu den Einsatzbedingungen in der Praxis. Die Masse und der Druckverformungsrest von Prüfkörpern aus FKM wurden vor und nach der Auslagerung über einen Zeitraum von 3, 7, 14, 28, 56 und 90 Tagen in E10 (Kraftstoff mit max. 10 % Ethanol), E85 (Kraftstoff mit 85 % Ethanol), Biodiesel (Rapsölfettsäuremethylester), Super (Kraftstoff mit max. 5 % Ethanol), Dieselkraftstoff mit max. 5 % Biodiesel, Super Plus (Kraftstoff ohne Ethanolzusatz) und Heizöl mit 10 % Biodiesel (B10) bei 40 °C gemäß ISO 815-1 bestimmt. Die Druckverformungsrestprüfung zählt neben der Messung der Härte, der Dichte und der Zugeigenschaften zu den wichtigsten Grundprüfverfahren der Elastomerindustrie. Nach Ende der Auslagerung in den Kraftstoffen und der Aufhebung der Verpressung wur-de der Druckverformungsrest der Prüfkörper in regelmäßigen Zeitabständen bis zu einer Rücktrocknung > 90 Tage bestimmt. Zum Vergleich wurden Prüfkörper aus FKM ohne Kraftstoff oder Heizöl unter Verpressung bei 40 °C ausgelagert. Die Masseänderung der Prüfkörper aus FKM betrug nach 90 Tagen Auslagerung in E10 9 %, in Super 8 %, in E85 4% und 0,6 % in Biodiesel. Die Erhöhung der Masse und die damit verbundene Quellung der Prüfkörper in E10 und Super mit 5 – 10% Ethanolzusatz hatte einen Einfluss auf den Druckverformungsrest, der sprunghaften Veränderungen unterlag im Vergleich zu den Werten nach Auslagerung in Biodiesel, Dieselkraftstoff und Heizöl B10 bei 40 °C. Zum Vergleich, unter statischen Bedingungen verringerte sich die Zugfestigkeit der Prüfkörper aus FKM nach Auslagerung in E10 bei 40 °C um 31 % und die Reißdehnung um 18 %. T2 - Gastvortrag im Rahmen des Seminars: Ausgewählte Kapitel der Werkstofftechnik an der Bergischen Universität Wuppertal CY - Wuppertal, Germany DA - 11.01.2019 KW - Dichtungswerkstoffe KW - Beständigkeit in Biokraftstoffen KW - Biodiesel KW - Heizöl mit 10% Biodiesel KW - E10 (Kraftstoff mit bis zu 10% Ethanol) PY - 2019 AN - OPUS4-47222 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Artinov, Antoni A1 - Bakir, Nasim A1 - Bachmann, Marcel A1 - Gumenyuk, Andrey A1 - Na, S.-J. A1 - Rethmeier, Michael T1 - On the search for the origin of the bulge effect in high power laser beam welding N2 - The shape of the weld pool in laser beam welding plays a major role to understand the dynamics of the melt and its solidification behavior. The aim of the present work was its experimental and numerical investigation. To visualize the geometry of the melt pool in the longitudinal section a butt joint configuration of 15 mm thick structural steel and transparent quartz glass was used. The weld pool shape was recorded by means of a high-speed video camera and two thermal imaging MWIR and VIS cameras. The observations show that the dimensions of the weld pool vary depending on the depth. The regions close to the surface form a teardrop shaped weld pool. A bulge-region and its temporal evolution were observed approximately in the middle of the depth of the weld pool. Additionally, a transient numerical simulation was performed until reaching a steady state to obtain the weld pool shape and to understand the formation mechanism of the observed bulging phenomena. A fixed keyhole with an experimentally obtained shape was used to represent the full-penetration laser beam welding process. The model considers the local temperature field, the effects of phase transition, thermo-capillary convection, natural convection and temperature-dependent material properties up to evaporation temperature. It was found that the Marangoni convection and the movement of the laser heat source are the dominant factors for the formation of the bulging-region. Good correlation between the numerically calculated and the experimentally observed weld bead shapes and the time-temperature curves on the upper and bottom surface were found. T2 - International Congress on Applications of Lasers & Electro-Optics (ICALEO®) CY - Orlando, USA DA - 14.10.2018 KW - Bulging effect KW - High power laser beam welding KW - Numerical modelling KW - Solidification cracking PY - 2019 SP - 1 EP - 8 AN - OPUS4-47139 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -