TY - CONF A1 - Farahbakhsh, Mahin A1 - Tscheuschner, Frank A1 - Stahl, Michael T1 - Fachinformationssystem Datenbank GEFAHRGUT N2 - Es werden die Anwendungen des Gefahrgutdatenpools der BAM aufgezeigt, der ein zentrales Informationssystem für den Transport gefährlicher Güter darstellt. T2 - Internationale Gefahrguttage Hamburg 2024 CY - Hamburg, Germany DA - 26.02.2024 KW - BAM-Liste KW - Datenbank GEFAHRGUT KW - Gefahrgut-Schnellinfo KW - Gefahrgutdatenpool KW - Gefahrguttransport KW - Informationssystem KW - Kurzinfo KW - Modul für Beförderungspapier KW - Modul für radioaktive Stoffe KW - BAM List KW - Dangerous Goods Database KW - Dangerous Goods Quickinfo KW - Radioactive Materials Module KW - Transport Documents Module PY - 2023 AN - OPUS4-59682 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böttcher, Nils A1 - Dayani, Shahabeddin A1 - Markötter, Henning A1 - Bruno, Giovanni A1 - Schmidt, Anita A1 - Krug von Nidda, Jonas T1 - Visualizing the progression of the thermal runaway in lithium-ion-cells by controlled abuse tests at low temperatures N2 - Due to their increasing energy density, lithium-ion-batteries (LIBs) play a key role in the traffic energy transition. Regarding their safety behavior, the main challenge of LIB-cells remains the thermal runaway (TR) process. In situ/operando investigations of the TR on commercial cells is possible with radiographic and computer tomographic measurements. Nonetheless, high resolution visualization of the TR persists as a challenge due to the high progression speed of the TR-process itself. Generally, performing abuse tests at cryogenic temperatures allows to slow down or even prevent the TR. Nevertheless, not all abuse methods are suitable for TR investigations at low temperatures. Nail penetration is an appropriate option, however, contains numerous unknown parameters and therefore suffers regarding reproducibility. Herein, a self-developed high precision nail-penetration-setup is introduced, approaching the necessary mechanically reproducibility with controlled temperatures down to -190°C. The setup allows the preparation of critically abused, however, at cryogenic temperatures stable LIB-cells. These cells were controlled rethermalized to room temperature during synchrotron x-ray computer tomography (SXCT) with a pixel size up to 0.7 μm. During this measurement, the temperature and voltage of the cell is monitored allowing the visualization of the initial internal cell reactions. This study reveals the relation between internal reactions and cell voltage. Finally, the developed set-up enables in-depth analysis of thermal runaway behavior down to material level for various commercial battery cells in the future. T2 - International Battery Safety Workshop CY - Ulm, Germany DA - 28.09.2023 KW - Thermal Runaway KW - Lithium Ion Batteries KW - Computer Tomography PY - 2023 AN - OPUS4-59270 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krug von Nidda, Jonas A1 - Böttcher, Nils A1 - Yusfi, Nawar A1 - Schmidt, Anita T1 - Hazard-Based Classification of Lithium-Ion Cells and Batteries N2 - Next to performance features, safety aspects of lithium-ion batteries (LIBs) are a crucial research field. The abuse/misuse of a LIB can trigger a chain of exothermic reactions on cell level. Hence, the cell temperature increases dramatically, causing the so-called thermal runaway (TR). Moreover, the TR of one cell can initiate the TR of adjacent cells leading to a TR-propagation. Due to the risk of a TR, special measures need to be applied while handling, storing, and transporting batteries. According to current transport regulations, all different types of lithium-ion and lithium metal cells/batteries (by means of cell format, cathode chemistry, etc.) require the same transport conditions regardless of the intensity of their reaction during abuse tests. To allow more differentiated transport requirements, the United Nations (UN) Subcommittee Transport of Dangerous Goods created an Informal Working Group (IWG) on the topic of a hazard-based classification of LIBs. BAM is one of nine laboratories working on the development of a respective classification scheme including appendant test protocols. Herein, we discuss the latest results of our safety tests on commercial LIB-cells employing the test protocols developed in the UN-IWG. Single cell tests are analysed regarding different hazardous features during the TR, e.g., cell temperature, flame occurrence, and gas amount. Next to the general occurrence of a propagation, the propagation speed is analysed by propagation tests. In total, the presented results are gathered from over 200 tests. Next to the classification of the tested cells, the data set obtained is analysed in respect to the cells’ key features, such as cell energy, state of charge and cathode type. Generally, the presented results can increase the overall understanding of the TR-mechanism supporting the design of advanced safety measures on cell level in the future. T2 - International Battery Safety Workshop CY - Ulm, Germany DA - 28.09.2023 KW - Battery Classification KW - Safe Transport KW - Thermal Runaway KW - Lithium Ion Batteries PY - 2023 AN - OPUS4-59269 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Leonhardt, Robert A1 - Böttcher, Nils A1 - Schmidt, Anita A1 - Krug von Nidda, Jonas T1 - Exploring the safety behavior of lithium-ion cells aged at elevated temperatures N2 - Understanding the safety characteristics of aged Lithiumion (Li-ion) batteries is essential for their effective integration into second-life applications. The SafeLiBatt project is a research initiative focused on evaluating safety-related parameters of these batteries. The presented study elucidates the impact of a cells’ state of health (SOH) on its safety behavior. Four highpower pouch cells (Li-NMC622) were exposed to elevated temperatures to achieve accelerated ageing. Subsequent thermal abuse tests were utilized to assess crucial parameters related to the thermal runaway (TR). When compared to their non-aged (begin of life, BOL) analogs, the aged cells implicated a TR-onset lowered by about 10 – 20 K. T2 - Advanced Battery Power 2023 CY - Aachen, Germany DA - 26.04.2023 KW - li-ion batteries KW - ageing KW - battery ageing PY - 2023 AN - OPUS4-59220 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Böttcher, Nils A1 - Dayani, Shahabeddin A1 - Markötter, Henning A1 - Setzchen, M. A1 - Schmidt, Anita A1 - Krug von Nidda, Jonas T1 - Determination of safe handling and transport conditions of critically damaged lithium battery cells at low temperatures N2 - Lithium batteries are the key technology for the successful implementation of the energy transition. Nevertheless, the consequences of thermal runaway of lithium batteries pose the greatest safety risk. In particular, the transport of damaged lithium batteries poses special challenges in order to minimize the effects of thermal runaway. By developing a precision nail test rig, the positive effects of cooling damaged lithium batteries can be investigated and safe transport temperatures identified. T2 - Advanced Battery konference CY - Aachen, Germany DA - 26.04.2023 KW - Lithium-Ion Battery Safety and Testing PY - 2023 AN - OPUS4-59207 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Farahbakhsh, Mahin A1 - Simon, Katja A1 - Eiben, Mario A1 - Damm, David A1 - Tscheuschner, Frank A1 - Stahl, Michael T1 - Fachinformationssystem Datenbank GEFAHRGUT - Hilfe bei der Kennzeichnung der Umweltgefahr N2 - Möglichkeiten der Datenbank GEFAHRGUT und des Gefahrgutdatenservices die Notwendigkeit der Kennzeichnung der Umweltgefahr zu ermitteln. T2 - 19. Gefahrgut-Technik-Tage Berlin CY - Berlin, Germany DA - 16.11.2023 KW - Datenbank KW - Fachinformationssystem KW - Gefahrgut KW - Kennzeichnung KW - Umweltgefahr KW - Dangerous goods KW - Database KW - Environmentally hazardous substance KW - Labelling KW - Specialised information system PY - 2023 AN - OPUS4-59107 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Farahbakhsh, Mahin A1 - Simon, Katja A1 - Eiben, Mario A1 - Damm, David A1 - Tscheuschner, Frank A1 - Stahl, Michael T1 - Fachinformationssystem Datenbank GEFAHRGUT N2 - Es werden die Anwendungen des Gefahrgutdatenpools der BAM aufgezeigt, der ein zentrales Informationssystem für den Transport gefährlicher Güter darstellt. T2 - 19. Gefahrgut-Technik-Tage Berlin CY - Berlin, Germany DA - 16.11.2023 KW - BAM-Liste KW - Datenbank GEFAHRGUT KW - Gefahrgut-Schnellinfo KW - Gefahrgutdatenpool KW - Gefahrguttransport KW - Informationssystem KW - Kurzinfo KW - Modul für Beförderungspapier KW - Modul für radioaktive Stoffe KW - BAM List KW - Dangerous Goods Database KW - Dangerous Goods Quickinfo KW - Radioactive Materials Module KW - Transport Documents Module PY - 2023 AN - OPUS4-59106 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Katja A1 - Stahl, Michael A1 - Farahbakhsh, Mahin T1 - Fachinformationssystem Datenbank GEFAHRGUT - Hilfe bei der Kennzeichnung der Umweltgefahr N2 - Möglichkeiten der Datenbank GEFAHRGUT und des Gefahrgutdatenservices die Notwendigkeit der Kennzeichnung der Umweltgefahr zu ermitteln. T2 - Stuttgarter Gefahrguttag CY - Stuttgart, Germany DA - 24.10.2023 KW - Datenbank KW - Fachinformationssystem KW - Gefahrgut KW - Kennzeichnung KW - Umweltgefahr KW - Dangerous goods KW - Database KW - Environmentally hazardous substance KW - Labelling KW - Specialised information system PY - 2023 AN - OPUS4-58711 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Katja A1 - Stahl, Michael A1 - Farahbakhsh, Mahin T1 - Fachinformationssystem Datenbank GEFAHRGUT N2 - Es werden die Anwendungen des Gefahrgutdatenpools der BAM aufgezeigt, der ein zentrales Informationssystem für den Transport gefährlicher Güter darstellt. T2 - Stuttgarter Gefahrguttag CY - Stuttgart, Germany DA - 24.10.2023 KW - BAM-Liste KW - Datenbank GEFAHRGUT KW - Gefahrgut-Schnellinfo KW - Gefahrgutdatenpool KW - Gefahrguttransport KW - Informationssystem KW - Kurzinfo KW - Modul für Beförderungspapiere KW - Modul für radioaktive Stoffe KW - BAM List KW - Dangerous Goods Database KW - Dangerous Goods Quickinfo KW - Radioactive Materials Module KW - Transport Documents Module PY - 2023 AN - OPUS4-58710 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Winckelmann, Alexander A1 - Hoffmann, V. A1 - Morcillo, Dalia A1 - Agudo Jacome, Leonardo A1 - Leonhardt, Robert A1 - Richter, Silke A1 - Recknagel, Sebastian A1 - Abad Andrade, Carlos Enrique A1 - You, Zengchao T1 - Chemical characterization of aging processes in high energy-density lithium-ion batteries N2 - Introduction Lithium-ion batteries (LIBs) are one key technology to overcome the climate crisis and energy transition challenges. Demands of electric vehicles on higher capacity and power drives research on innovative cathode and anode materials. These high energy-density LIBs are operated at higher voltages, leading to increased electrolyte decay and the current collectors' degradation. Even though this fundamental corrosion process significantly affects battery performance, insufficient research is being done on the aluminum current collector. Fast and convenient analytical methods are needed for monitoring the aging processes in LIBs. Methods In this work glow-discharge optical emission spectrometry (GD-OES) was used for depth profile analysis of aged cathode material. The measurements were performed in pulsed radio frequency mode. Under soft and controlled plasma conditions, high-resolution local determination (in depth) of the elemental composition is possible. Scanning electron microscopy (SEM) combined with a focused ion beam (FIB) cutting and energy dispersive X-ray spectroscopy (EDX) was used to confirm GD-OES results and obtain additional information on elemental distribution. Results The aging of coin cells manufactured with different cathode materials (LCO, LMO, NMC111, NMC424, NMC532, NMC622, and NMC811) was studied. GD-OES depth profiling of new and aged cathode materials was performed. Quantitative analysis was possible through calibration with synthetic standards and correction by sputter rate. Different amounts of aluminum deposit on the cathode surface were found for different materials. The deposit has its origin in the corrosion of the aluminum current collector. The results are compatible with results from FIB-EDX. However, GD-OES is a faster and less laborious analytical method. Therefore, it will accelerate research on corrosion processes in high energy-density batteries. Innovative aspects - Quantitative depth profiling of cathode material -Monitoring of corrosion processes in high energy-density lithium-ion batteries - Systematic investigation of the influence of different cathode materials T2 - ANAKON 2023 CY - Vienna, Austria DA - 11.04.2023 KW - Lithium Ion Batteries KW - GD-OES KW - Depth-profiling PY - 2023 AN - OPUS4-58586 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -