TY - CONF A1 - Hertwig, Andreas A1 - Ermilova, Elena A1 - Hülagü, Deniz T1 - Determining Material Properties with Spectroscopic Ellipsometry N2 - In this lecture, an introduction will be given on Spectroscopic Ellipsometry, what quantities can be obtained with it, and how we use it in ELENA and other projects to determine functional parameters of thin layers at the nanoscale. T2 - Summer school ELENAM : metrology at the nanoscale CY - Fréjus, France DA - 02.06.2024 KW - Thin Layers KW - Ellipsometry KW - Nanotechnology KW - Electrical Paramters PY - 2024 AN - OPUS4-60247 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - Fire Behaviour and Flame Retardancy of Polymeric Materials N2 - Lecture-like introduction in the topic. Fundamental aspects are discussed: Burning of polymers, fire risks, pyrolysis, combustion in the flame, physical chemistry of ignition, flame spread and steady state burning, flame retardancy mechanisms and groups of flame retardants, fire hazards (smoke, toxic products) and environmental concerns, fire testing. T2 - International Combustion Institute Summer School on Near-Wall Reactive Flows CY - Darmstadt, Germany DA - 10.06.2024 KW - Flame retardants KW - Fire behaviour PY - 2024 AN - OPUS4-60246 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Blaeß, Carsten A1 - Müller, Ralf T1 - Undesired Foaming of Silicate Glass Powders N2 - The manufacture of sintered glasses and glass-ceramics, glass matrix composites, and glass-bounded ceramics or pastes is often affected by un-expected gas bubble formation also named foaming. Against this background, in this presentation the main aspects and possible reasons of foaming are shown for completely different glass powders: a barium silicate glass powders used as SOFC sealants, and bioactive glass powders using different powder milling procedures. Sintering and foaming were measured by means of heating microscopy backed up by XRD, differential thermal analysis (DTA), vacuum hot extraction (VHE), optical and electron microscopy, and infrared spectroscopy, and time-of-flight secondary ion mass spectrometry (ToF-SIMS). Different densification was reached followed by significant foaming starting partly immediately, partly at higher temperature. Foaming increased significantly as milling progressed. For moderately milled glass powders, subsequent storage in air could also promote foaming. Although the milling atmosphere significantly affects the foaming of uniaxially pressed powder compacts sintered in air. VHE studies show that foaming is driven by carbon gases and carbonates were detected by Infrared spectroscopy to provide the major foaming source. Carbonates could be detected even after heating to 750 °C, which hints on a thermally very stable species or mechanical trapping or encapsulating of CO2. Otherwise, dark gray compact colors for milling in isopropanol indicate the presence of residual carbon as well. Its significant contribution to foaming, however, could not be proved and might be limited by the diffusivity of oxygen needed for carbon oxidation to carbon gas. T2 - Seminário de Laboratório de Materiais Vítreos (LaMaV) de Departamento de Engenharia de Materiais (DEMa), Universidade Federal São Carlos UFSCar) CY - Saint Charles, Brazil DA - 06.06.2024 KW - Bioactive KW - Foaming KW - Glass KW - Crystallization KW - Viscose sintering PY - 2024 AN - OPUS4-60245 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reinsch, Stefan A1 - Müller, Ralf T1 - Oriented Surface Crystallization in Glasses N2 - Up to now, oriented surface crystallization phenomena are discussed controversially, and related studies are restricted to few glasses. For silicate glasses we found a good correlation between the calculated surface energy of crystal faces and oriented surface nucleation. Surface energies were estimated assuming that crystal surfaces resemble minimum energy crack paths along the given crystal plane. This concept was successfully applied at the Institute of Physics of Rennes in calculating fracture surface energies of glasses. Several oriented nucleation phenomena can be herby explained assuming that high energy crystal surfaces tend to be wetted by the melt. This would minimize the total interfacial energy of the nucleus. Furthermore, we will discuss the evolution of the microstructure and its effect on the preferred crystal orientation. T2 - ACerS GOMD 2024- Glass & Optical Materials Division Meeting CY - Las Vegas, NV, USA DA - 19.05.2024 KW - Surface nucleation KW - Oriented surface crystallization KW - Surface energy PY - 2024 AN - OPUS4-60238 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Griesche, Axel A1 - Mente, Tobias A1 - Falahat, Ala'A . M. Al A1 - Tengattini, Alessandro A1 - Dal Pont, Stefano A1 - Kardjilov, Nikolay T1 - Crystallographic phase transformations and corresponding temperature distributions during gtaw of supermartensitic stainless steel visualized by nbei N2 - We investigated the phase transformations during butt-welding of supermartensitic steel plates with help of Neutron-Bragg-Edge Imaging (NBEI). Gas tungsten arc welding (GTAW) was used with a motorized torch allowing for automated weldments. The austenitization in the heat affected zone (HAZ) could be clearly visualized at λ = 0.39 nm, a wavelength smaller than the Bragg edge wavelengths of both austenite and martensite. The re-transformation into the martensitic phase during cooling was clearly detected. However, we observed an unexpected additional change in transmission at λ = 0.44 nm, a wavelength larger than the wavelength of the Bragg edges of both the martensitic and austenitic phases. We attribute this change to the Deybe-Waller-Factor that describes the temperature dependence of coherent scattering at a crystal lattice. The observed two-dimensional attenuation map corresponds well with a temperature distribution modelling by software macros in ANSYS [3]. Here, the absolute temperature values could be achieved by calibrating the modelled attenuation with help of a thermocouple placed at the steel plate. This allows in return for a direct two-dimensional temperature reading based on the Debye-Waller-relation between neutron attenuation and sample temperature. T2 - WCNR-12 CY - Idaho Falls, Id, USA DA - 02.06.2024 KW - Neutron KW - Radiography KW - Welding PY - 2024 AN - OPUS4-60242 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hertwig, Andreas A1 - Radnik, Jörg A1 - Ermilova, Elena A1 - Hodoroaba, Vasile-Dan T1 - Accuracy on all scales: Hybrid metrology for micro- and nanomanufacturing N2 - In this presentation, we discuss hybrid metrology and correlative imaging. These techniques are used to improve the design and quality monitoring of nanomaterials used in energy technology and for referencing the properties of nanoparticles. T2 - EMN for Advanced Manufacturing workshop CY - Berlin, Germany DA - 22.05.2024 KW - Nanotechnology KW - Nanoanalytics KW - Correlative Spectroscopy KW - Correlative Imaging PY - 2024 AN - OPUS4-60240 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reinsch, Stefan A1 - Müller, Ralf T1 - Orientierte Oberflächenkristallisation in Gläsern N2 - Bislang wird das Phänomen der orientierten Oberflächenkristallisation kontrovers diskutiert und entsprechende Studien beschränken sich auf nur wenige Gläser. Für Silikatgläser haben wir eine gute Korrelation zwischen der berechneten Oberflächenenergie von Kristallflächen und der orientierten Oberflächenkeimbildung gefunden. Die Oberflächenenergien wurden unter der Annahme abgeschätzt, dass die Kristalloberflächen bei der Keimbildung den Kristallebenen mit minimaler Energie entsprechen, denen ein Riss beim Bruch folgt. Dieses Konzept wurde am Institut für Physik in Rennes erfolgreich bei der Berechnung der Bruchflächenenergien von Gläsern angewandt. Mehrere orientierte Keimbildungsphänomene lassen sich dadurch erklären, dass man annimmt, dass Kristalloberflächen mit hoher Energie dazu neigen, von der Schmelze benetzt zu werden. Dies minimiert die gesamte Grenzflächenenergie des Keims. Darüber hinaus werden wir die Entwicklung der Mikrostruktur beim weiteren Kristallwachstum und ihre Auswirkungen auf die bevorzugte Kristallorientierung diskutieren. T2 - 21. Treffen des DGG-DKG Arbeitskreises „Glasig-kristalline Multifunktionswerkstoffe“ CY - Mainz, Germany DA - 22.02.2024 KW - Oberflächenkeimbildung KW - Kristallorientierung KW - Grenzflächenenergie PY - 2024 AN - OPUS4-60237 LA - mul AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Feldkamp, Martin A1 - Gleim, Tobias A1 - Quercetti, Thomas A1 - Wille, Frank T1 - Combustion Chamber Design for Encapsulated Wood-Component Testing N2 - eavy-weight packages for the safe transport of radioactive material are equippedwith impact limiters often built ofwood-filled steel sheet structures to fulfil the requirements of the International Atomic Energy Agency (IAEA) regulations. The requirements definemechanical tests followed by a thermal test, including criteria ensuring the package design’s ability to withstand severe accidents and provide a high level of technical safety. Impact limiters are a package component mainly designed for the packages to withstand severe mechanical accident scenarios. In drop tests the impact limiters absorb the kinetic energy during impact of the package. The package must then - with its pre-damaged impact limiters - endure a thermal test defined precisely in the IAEA regulations as a 30-min fully engulfing 800 °C-fire. After the fire, a wood-filled impact limiter may continue to release thermal energy from an ongoing combustion process, defining relevant package temperatures. The energy flow from a possible burning impact limiter to the package is important for the safety evaluation of transport packages. To investigate the combustion behaviour of densely packed layers of spruce wood, encapsulated in pre-damaged cylindrical metal enclosures, a test set-up has been realised. The set-up consists of a combustion chamber to perform these tests under defined boundary conditions. The temperature development of the test specimens will be observed fromoutside with a thermographic imager, with HD-Cameras, and the mass loss will be measured during the entire test. Airflow conditions in the combustion chamber are analysed using Computational Fluid Dynamics (CFD) calculations in OpenFOAM. The planned combustion test setup is described. T2 - Wood & Fire Safety 2024 CY - Štrbské Pleso, Slovakia DA - 12.05.2024 KW - IAEA KW - Combustion Chamber KW - Smouldering KW - Wood PY - 2024 AN - OPUS4-60227 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Oberbeckmann, Sonja A1 - Gorbushina, Anna T1 - On the intersection of microbiome and material research: what can be achieved? N2 - Any surface in the environment acts as hotspot for microbial attachment and activity. These biofilms represent the interface between humans and the environment. While in the past biofilms were often seen as disturbance, we now start to understand the enormous potential of beneficial biofilms. They can be used in a broad range of applications and are sources for new microorganisms and traits. After all, biofilms represent a great example for a collaborative lifestyle. T2 - Bioeconomy Changemakers Festival, Hereon CY - Teltow, Germany DA - 14.03.2024 KW - Biofilm KW - Microbiome KW - Sustainability KW - Biosphere KW - Microplastics PY - 2024 AN - OPUS4-60202 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reichel, Levin A1 - Schroepfer, Dirk A1 - Kannengiesser, Thomas A1 - Kromm, Arne A1 - Becker, Amadeus T1 - Residual stress formation during repeated gouging and repair welding cycles of high-strength steels N2 - The construction of foundation and erection structures for wind power plants requires the use of modern, sustainable and resource-efficient high-strength fine-grained structural steels. Weld defects due to the welding process are unacceptable. To overcome this issue, local thermal gouging followed by re-welding is a common and cost-effective method. The high shrinkage restraint of the gouge by the surrounding structure can cause crack initiation when design and re-weld induced residual stresses are superimposed. This risk is intensified by the progressive degradation of the microstructure and mechanical properties of high-strength steels during the weld repair process. This investigation focuses on high-strength steels S500MLO for offshore applications and S960QL for mobile crane applications. The reduction and development of residual stresses caused by local thermal gouging and re-welding was investigated. Digital Image Correlated (DIC) stress-strain analysis was performed during preheating, welding and cooling. The results of the global DIC analysis and local longitudinal and transverse residual stresses of the weld determined by X-ray diffraction were found to be in good agreement. Furthermore, different stress levels were identified during gouging and welding. Repeated repair cycles led to an increase of longitudinal and transverse residual stresses in the weld metal as well as a hardness increase in the heat affected zone. T2 - European Conference on Residual Stresses - ECRS11 CY - Prague, Czech Republic DA - 03.06.2024 KW - Repair welding KW - Gouging KW - Residual stress KW - Repair cycles KW - High-strength steels PY - 2024 AN - OPUS4-60215 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bulling, Jannis A1 - Jurgelucks, B. A1 - Prager, Jens A1 - Walther, A. T1 - Modellierung und Validierung eines inversen Verfahrens zur Schadensrekonstruktion mittels Lamb-Wellen im Ultraschallbereich N2 - Das Ausbreitungsverhalten geführter Ultraschallwellen ermöglicht die großflächige Prüfung von Platten und schalenförmigen Bauteilen wie Rohren und Laminaten auf Fehlstellen von wenigen Prüfpunkten aus. Während die beschränkte Divergenz der geführten Wellen die Ultraschallprüfung begünstigt, erschwert das dispersive und multimodale Verhalten der Lamb-Wellen die Auswertung der Ultraschallsignale. Die dispersive und multimodale Wellenausbreitung verkompliziert die Bestimmung der Fehlerposition bei der Auswertung der Geschwindigkeiten einzelner Wellenpakete. Zudem ist es herausfordernd, einen einfachen Zusammenhang zwischen den Reflexionen der Fehlstelle und deren Größe und Form herzustellen. Eine Möglichkeit zur genauen Bestimmung der Fehlerposition und -geometrie bietet der direkte Vergleich der Messsignale mit den Signalen aus einem Simulationsmodell. Die Nachbildung des Schadens im Simulationsmodell stellt ein inverses Problem dar, das iterativ gelöst werden kann, indem ein Vorwärtsmodell immer weiter optimiert wird. Klassische Ansätze wie die Finite Elemente Methode (FEM) sind für die Simulation von Ultraschallwellen aufgrund der kleinen Wellenlängen im Vergleich zur Bauteilgröße meist ineffizient. Aus diesem Grund basiert das vorgestellte Vorwärtsmodell auf der semi-analytischen Scaled Boundary Finite Element Method (SBFEM), die große Teile der Wellenausbreitung analytisch berechnet. In diesem Beitrag wird die Validierung des zweidimensionalen Modells an Platten mit einer rechteckigen Nut als Ersatzfehler präsentiert und es werden erste Schritte zur Validierung von 3D-Modellen vorgestellt. T2 - DAGA 2024 CY - Hannover, Germany DA - 18.03.2024 KW - Geführter Ultraschall KW - Inverse Verfahren KW - SBFEM PY - 2024 AN - OPUS4-60214 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Denkler, Tilman T1 - WP8 - METABUILDING LABS OITB catalogue of testing infrastructures and services, its structuring and exploitation, training and quality management N2 - Developments of Workpackage 8 in the last year are presented. Focuss on the development of quality assurance procedures for the O3BETs. Upcoming activites for the tasks 8.2, 8.3, 8.4, 8.5 and 8.6 are described. T2 - 5th General Meeting Metabuilding Labs Project CY - Online meeting DA - 06.06.2024 KW - Open Innovation Test Bed KW - Quality assurance KW - Quality management PY - 2024 AN - OPUS4-60208 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ladu, Luana T1 - Making the transition to a sustainable and circular bioeconomy N2 - This presentation provides an introduction and intermediate results of the Horizon-Europe STAR4BBS project.It focuses on how to maximize the potential of Sustainability Certification Schemes (SCS) and labels to support a successful transition to a sustainable bio-based economy by assessing their effectiveness, robustness, and credibility. T2 - Sustainability Transition Assessment Rules for Bio-Based Systems (STAR4BBS) CY - Rome, Italy DA - 17.05.2024 KW - Sustainability Certificaiton Schemes KW - Quality Infrastructure KW - Governance indicators KW - Robust certification schemes PY - 2024 AN - OPUS4-60211 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - You, Zengchao A1 - Winckelmann, Alexander A1 - Vogl, Jochen A1 - Recknagel, Sebastian A1 - Abad, Carlos T1 - Determination of calcium, iron, and selenium in human serum by isotope dilution analysis using MICAP-MS N2 - Trace elemental analysis in human serum is integral in both clinical and research settings. Analyzing the level of some specific elements like Se and Zn helps indicate the nutritional and health status. Furthermore, elucidating the roles of trace elements in various physiological and pathological conditions can shed light on disease mechanisms and potential treatments. Inductively coupled plasma mass spectrometry (ICP-MS) stands out as a preeminent method for trace elemental analysis, given its exceptional sensitivity and minimal sample requirements. However, ICP-MS has challenges, such as argon-related interferences that hinder the accurate quantification of elements like Ca, Fe, and Se. The naturally most abundant isotopes of Ca (40Ca), Fe (56Fe), and Se (80Se) are subject to isobaric interference from 40Ar+, 40Ar16O+, and 40Ar2+, thereby complicating their direct measurement and preventing isotope dilution analysis. In response to these challenges, nitrogen microwave inductively coupled atmospheric pressure mass spectrometry (MICAP-MS) emerges as a viable alternative to ICP-MS, eliminating argon consumption and associated interferences. This study employed MICAP-MS to quantify Ca, Fe, and Se in 11 certified reference human serums using matrix-matched calibration and isotope dilution with the isotopes 40Ca, 56Fe, and 80Se. The results obtained with both methods were validated against certified values, and the suitability of MICAP-MS for isotope dilution was evaluated. Additionally, the performance of MICAP-MS in the Na matrix was investigated and discussed alongside the impact of organic species. T2 - Winter Conference on Plasma Spectrochemistry 2024 CY - Tucson, AZ, USA DA - 15.01.2024 KW - MICAP-MS KW - Isotope-dilution KW - Human serum PY - 2024 AN - OPUS4-60210 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kemmler, Samuel A1 - Cuéllar, Pablo A1 - Köstler, Harald T1 - A Fluid Solid Coupled Micromechanical Simulation of Piping Erosion During the Installation of a Suction Bucket for the Foundation of an Offshore Wind Turbine N2 - We present our approach and methodology for simulating piping erosion, which occurs during the installation process of suction bucket foundations for offshore wind turbines. We show several simulations and analyze the hydrodynamic and contact forces acting on the granular fabric and the differential pressure of the fluid phase. We demonstrate weak scaling performance on the LUMI supercomputer with a parallel efficiency of up to 90% for 4096 Graphics Compute Dies. T2 - 9th European Congress on Computational Methods in Applied Sciences and Engineering (ECCOMAS) CY - Lisbon, Potugal DA - 03.06.2024 KW - Offshore wind turbine KW - Suction bucket KW - Coupled fluid-particle simulation KW - High-performance computing PY - 2024 AN - OPUS4-60207 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Oberbeckmann, Sonja T1 - The Microplastic Microbiome N2 - Microplastics represent man-made and newly emerging surfaces in our ecosystems, where they interact with microorganisms. The ecosystem in focus of this presentation will be the aquatic environment. It will be portrayed, which microorganisms use microplastics as a habitat, how environmental factors shape this colonization, and why the biodegradation of plastics in the ocean is an overall unlikely process. We will also discuss whether potentially pathogenic microorganisms use microplastics as a raft. Finally, possible adaptation mechanisms of plastic-colonizing microorganisms will be presented, such as the production of photoreactive molecules. The microplastic microbiome has a large potential to harbor so far unknown species with curious traits, representing an exciting research topic for the future. T2 - Geomicrobiological and Geochemical Colloquium, GFZ CY - Potsdam, Germany DA - 20.02.2024 KW - Microplastics KW - Microbiome KW - Biofilm PY - 2024 AN - OPUS4-60203 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hahn, Sarah-K. A1 - Saupe, Alexander A1 - Tschirschwitz, Rico A1 - Bernardy, Christopher A1 - Janßen, Marvin A1 - Amano, Kofi Owusu Ansah A1 - Krause, Ulrich T1 - Sicherheit elektrochemischer Energiespeicher – Ergebnisse aus dem Projekt SEE-2L N2 - Die Transformation der Energienutzung von konventionellen zu erneuerbaren Quellen führt dazu, dass zukünftig mehr Energie effizient zwischengespeichert werden muss. Eine Möglichkeit der elektrochemischen Zwischenspeicherung bieten Lithium-Ionen-Batterien. Hierfür können ausgemusterte Automobilantriebsbatterien verwendet werden. Erfüllen sie die hohen Anforderungen des mobilen Bereichs nicht mehr, haben sie oftmals noch eine ausreichende Kapazität und Leistungsfähigkeit für die stationäre Zwischenspeicherung. Neben der Verwendung der Batterien im größeren Maßstab, z.B. bei Energieversorgern, werden durch den vermehrten Einsatz von Photovoltaik-Anlagen in Ein- und Mehrfamilienhäusern verstärkt Zwischenspeicher für Privathaushalte nachgefragt. Dies birgt auch für Einsatzkräfte neue Herausforderungen in der Gefahrenabwehr. Im vom Bundesministerium für Bildung und Forschung (BMBF) geförderten Verbundprojekt „SEE-2L – Sicherheit elektrochemischer Energiespeicher in Second Life Anwendungen“ wurden Versuche mit Second Life Modulen durchgeführt. Verbundpartner im Projekt waren neben der vfdb die Otto-von-Guericke-Universität Magdeburg und die Bundesanstalt für Materialforschung und -prüfung. Zudem war das Institut der Feuerwehr Nordrhein-Westfalen eingebunden. Die durchgeführten Versuche bilden eine Grundlage für die Einordnung der Batteriespeicher, z.B. aus Sicht des baulichen Brandschutzes, zur Methodik der Brandbekämpfung oder zur Risikobewertung hinsichtlich der Prozess- und Anlagensicherheit. Im Beitrag werden die Versuchsergebnisse vorgestellt und Ansätze für deren Anwendung gezeigt. Um die gewonnenen Erkenntnisse zu vermitteln, wurde im Projekt zudem ein Schulungskonzept für Einsätze mit Lithium-Ionen-Technologien erarbeitet, das im Beitrag präsentiert wird. Es besteht aus theoretischen und praktischen Anteilen, sodass bei den Feuerwehren praxisnah aus- bzw. fortgebildet werden kann. T2 - vfdb-Jahresfachtagung CY - Magdeburg, Ger DA - 06.05.2024 KW - Auswirkungsbetrachtungen KW - Elektrische Energiespeicher KW - Lithium-Ionen-Batterie KW - Stationäre Energiespeicher KW - Thermisches Durchgehen PY - 2024 AN - OPUS4-60192 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Winckelmann, Alexander T1 - Advanced spectroscopic methods for fluorine microanalysis in lithium-ion batteries N2 - To address the challenges of the climate crisis, multiple solutions for sustainable energy sources and storage systems are needed. One such solution is lithium-ion batteries (LIBs). Currently, 5 to 30 % of LIBs are discarded immediately after manufacturing. The homogeneous distribution of all materials used in the coating of cathodes and anodes is critical for the quality of LIBs. Furthermore, during formation i.e., the first steps of the charge/discharge cycling, the solid-electrolyte interphase forms on the anode particles, which has a huge impact on the performance. The same happens to some extent on the cathode, forming the cathode-electrolyte interphase. Fluorinated polymers and electrolytes are used in the manufacturing of LIBs. The electrolyte in particular is prone to degradation during formation and aging of the batteries. The interface of the cathode material with the aluminum current collector is also a critical point where degraded fluorine components cause pitting corrosion and at the same time promote passivation of the metal foil. Monitoring the spatial distribution of fluorine on these surfaces and interfaces is essential for sustainable LIB production. T2 - SALSA Kick-Off Meeting CY - Berlin, Germany DA - 11.04.2024 KW - Lithium Ion Batteries KW - solid microanalysis KW - depth-profiling KW - fluorine PY - 2024 AN - OPUS4-60199 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bernardy, Christopher A1 - Habib, Abdel Karim A1 - Kluge, Martin A1 - Schalau, Bernd A1 - Kant, Hanjo A1 - Schulze, Marcel A1 - Orchini, Alessandro T1 - Thermal Radiation Investigations of Real-Scale Hydrogen Jet Flames at High Pressure N2 - In order to reduce global warming, the use of hydrogen as a renewable energy source is becoming more important. To enable this transition, unprecedently large amounts of hydrogen need to be safely transported and stored. Since hydrogen is usually stored and transported under pressure, one scenario to be considered is the release of hydrogen from a leakage with subsequent ignition. The resulting jet flame must be characterized with respect to the thermal radiation emitted into the environment to define safety distances. Various models that characterize the resulting flame shape and radiation already exist in the literature, but these are mainly based on empirical data from hydrocarbon jet flames. To verify the applicability of these models to hydrogen, real-scale tests are carried out at the BAM Test Site for Technical Safety (BAM-TTS) with the aim to assess the flame geometry and the emitted thermal radiation. Parameters such as leakage diameter (currently up to 30 mm), pressure (currently up to max. 250 bar) and mass flow (up to max. 0.5 kg/s) are varied. In particular, the focus will be laid on the measurement and modelling of the thermal radiation. The challenge here is the characterization of the flame geometry in an open environment and its impact on the thermal radiation. Existing heat radiation data from literature are mostly based on unsteady outflow conditions. The experimental setup used here allows for the generation of a steady-state outflow for several minutes and thus a direct comparability with existing (steady-state) models. Furthermore, stationary outflow tests with hydrocarbons (methane) were also carried out, which are intended to serve as reference tests for checking flame models based on hydrocarbon data. Following from the experimental investigations, modelling parameters such as the Surface Emissive Power (SEP) and the radiant heat fraction for hydrogen and methane will be compared to literature data. T2 - Center for Hydrogen Safety Americas Conference, American Institute of Chemical Engineers CY - Las Vegas, NV, USA DA - 21.05.2024 KW - Thermal radiation KW - Hydrogen KW - Release KW - Jet flame PY - 2024 AN - OPUS4-60195 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Winckelmann, Alexander T1 - Taking Chances – Cheese, Chocolate and Laser Spectroscopy N2 - Science Café Adlershof is having its next edition in 2024 on February 20th '24! We will have one speaker next week: Alexander Winckelmann is a PhD student at Bundesanstalt für Materialforschung und -Prüfung and will give a talk about his stay abroad in Switzerland - there will be free chocolates! There will be enough time to ask questions or simply chat with the guests and participants. T2 - Science Café Adlershof CY - Berlin, Germany DA - 20.02.2024 KW - Laser-induced XUV Spectroscopy KW - Multivariate Data Analysis KW - Science Communication PY - 2024 AN - OPUS4-60197 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tschirschwitz, Rico T1 - Sicherheit stationärer elektrischer Energiespeicher – Ergebnisse aus dem Projekt SEE-2L N2 - Einleitend wird im Vortrag das Aktivitätsfeld Elektrische Energiespeicher und -umwandlung vorgestellt sowie eine kurze Einführung in die Terminologie der elektrischen Energiespeicher gegeben. Im Folgenden wird das BMBF-Vorhaben SEE-2L vorgestellt. Hier wird der Schwerpunkt auf die Entwicklung und den Aufbau eines Großversuchsstand für das thermische Durchgehen von Lithium-Batterien auf Modul- und Batterieebene gelegt. Darüber hinaus werden die Ergebnisse einer ersten Versuchsserie vorgestellt. Zum Abschluss wird ein kurzer Ausblick zu weiteren anstehenden Versuchen gegeben. T2 - Behörden-Erfahrungsaustausch Anlagensicherheit 2024 CY - Berlin, Deutschland DA - 03.06.2024 KW - Auswirkungsbetrachtungen KW - Elektrische Energiespeicher KW - Lithium-Ionen-Batterie KW - Stationäre Energiespeicher KW - Thermisches Durchgehen PY - 2024 AN - OPUS4-60190 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hahn, Sarah-K. A1 - Tschirschwitz, Rico T1 - Second Life Verwendungen - Untersuchungen und erste Erfahrungen mit einem Ausbildungsdemonstrator N2 - Der Vortrag gibt zunächst einen Themeneinstieg in den Bereich der Second-Life-Batterien sowie rechtliche und technische Grundlagen zu Lebenszyklus und Alterung. Im Weiteren werden experimentelle Ergebnisse aus Versuchen zum thermischen Durchgehen mit Batteriemodulen aus dem BMBF-Vorhaben SEE-2L vorgestellt. Darüber hinaus wird ein eigens entwickelter Ausbildungsdemonstrators vorgestellt, welcher einen wesentlichen Baustein des Ergebnistransfers aus dem Vorhaben darstellt. T2 - Brände von Lithium-Ionen Batterien in Elektrofahrzeugen kontrollieren, eindämmen und vorbeugen CY - Essen, Germany DA - 25.04.2024 KW - Auswirkungsbetrachtungen KW - Elektrische Energiespeicher KW - Lithium-Ionen-Batterie KW - Stationäre Energiespeicher KW - Thermisches Durchgehen PY - 2024 AN - OPUS4-60187 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schilling, Markus T1 - Interoperabilität und Wiederverwendung von Materialdaten: Der Weg zu Daten- und Wissensrepräsentationen in der PMD N2 - Die Integration und Wiederverwendung von Wissen und Daten aus der Herstellung, Bearbeitung und Charakterisierung von Materialien wird im Zuge der digitalen Transformation in der Materialwissenschaft und Werkstofftechnologie in verschiedenen Projekten behandelt. Dabei liegt der Fokus auf der Interoperabilität von Daten und Anwendungen, die nach den FAIR-Prinzipien erstellt und veröffentlicht werden. Zur Umsetzung eines komplexen Datenmanagements und der Digitalisierung im Bereich der Materialwissenschaften gewinnen Ontologien zunehmend an Bedeutung. Sie ermöglichen sowohl menschenlesbare als auch maschinenverständliche und -interpretierbare Wissensrepräsentationen durch semantische Konzeptualisierungen. Im Rahmen des Projektes Plattform MaterialDigital (PMD, materialdigital.de), welches in dieser Präsentation vorgestellt wird, werden Ontologien verschiedener Ebenen entwickelt (verbindende mid-level sowie Domänen-Ontologien). Die PMD-Kernontologie (PMD Core Ontology - PMDco) ist eine Ontologie der mittleren Ebene, die Verbindungen zwischen spezifischeren MSE-Anwendungsontologien und domänenneutralen Konzepten herstellt, die in bereits etablierten Ontologien höherer Ebenen (top-level Ontology) verwendet werden. Sie stellt somit einen umfassenden Satz von durch Konsensbildung in der Gemeinschaft (geteiltes Vokabular) entstanden Bausteinen grundlegender Konzepte aus der Materialwissenschaft und Werkstofftechnik (MSE) dar. In dieser Präsentation wird die PMDco adressiert. Weiterhin wird eine auf die PMDco bezogene normenkonforme ontologische Repräsentation zur Speicherung und Weiterverarbeitung von Zugversuchsdaten – die Tensile Test Ontology (TTO) – präsentiert, die in enger Zusammenarbeit mit dem zugehörigen DIN-Standardisierungsgremium NA 062-01-42 AA erstellt wurde. Dies umfasst den Weg von der Entwicklung einer Ontologie nach Norm, der Konvertierung von Daten aus Standardtests in das interoperable RDF-Format bis hin zur Verbindung von Ontologie und Daten. Auf Grundlage der dabei entwickelten Struktur und Vorgehensweise können weitere Materialcharakterisierungsmethoden semantisch beschrieben werden, woraus sich in diesem Zusammenhang Kooperationsmöglichkeiten ergeben. T2 - 20. Sitzung des NA 062-01-43 AA CY - Online meeting DA - 28.05.2024 KW - Semantische Daten KW - Plattform Material Digital KW - Ontologie KW - Normung KW - Wissensrepräsentation PY - 2024 AN - OPUS4-60178 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hodoroaba, Vasile-Dan A1 - Sachse, René A1 - Kotil, L. A1 - Matjacic, L. A1 - McMahon, G. A1 - Bernicke, M. A1 - Bernsmeier, D. A1 - Kraehnert, R. A1 - Hertwig, Andreas T1 - Morphological and chemical analysis of mesoporous mixed IrOx-TiOy thin films as electrode materials N2 - Porous films play an important role particularly in energy applications like photovoltaics, electrolysis or batteries. Thin film properties such as thickness, chemical composition, crystallinity of the framework, and porosity define the activity of the porous films. The accurate morpho-chemical characterisation of mesoporous thin films is a challenging analytical task which requires the consideration of new analytical approaches based on the combination of data of different methods able to address the structure and chemical composition at the nanoscale. In this contribution we characterise thin mesoporous iridium-titanium mixed oxide film properties by Electron Probe Microanalysis (EPMA) with Energy-Dispersive X-ray Spectroscopy (EDS) at an SEM applied in a dedicated “thin film analysis” approach (1). Thus, the film mass deposition, film thickness and the film density can be determined. Further, by dividing the measured film density to an assumed (theoretical) metal oxide framework (skeletal) density, the thin film porosity can be extracted, too. In order to assess the homogeneity of the thin film properties like the chemical composition, Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and Auger Electron Spectrometry are applied in the depth profiling mode, so that possible in-depth gradients are detected. Lateral inhomogeneities in the chemical composition and structure of the thin mesoporous films are also identified by applying the same methods in the line-scan or mapping mode, which can be further combined with in-depth sputtering for 3D information. The role of the spatial resolution of the analytical methods considered, which can go down well below 100 nm, will be highlighted. T2 - 2024 Spring Meeting of the European Materials Research Society (E-MRS) CY - Strasbourg, France DA - 27.05.2024 KW - Mesoporous KW - Thin films KW - Iridium oxide KW - Titanium oxide KW - Thin film analysis KW - Porosity KW - SIMS KW - Auger electron spectroscopy PY - 2024 AN - OPUS4-60185 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hodoroaba, Vasile-Dan A1 - Salzmann, Christoph A1 - Heilmann, Maria T1 - Ongoing VAMAS interlaboratory comparisons on nanoparticles size and shape as pre standardisation projects for harmonized measurements N2 - Traceable morphological and chemical characterization of nanomaterials with respect to the various possible sizes, size distributions, shapes, and concentrations of real-world nanoparticles (NPs) is a challenging task. Particularly for the nonspherical, non-monodisperse nanoparticles – as typically for most of the commercial particles, including their strong tendency to agglomerate, there is a lack of standard operation procedures providing accurate nanoparticle characterisation. In the framework of the pre-standardisation framework of VAMAS (Versailles Project on Advanced Materials and Standards, www.vamas.org) two interlaboratory comparison (ILC) studies are being carried out under the Technical Working Area (TWA) 34 “Nanoparticle Populations”:i) Project #15 addresses the analysis of the size and shape distribution of TiO2 bipyramidal NPs by traceable imaging methods such as TEM, SEM, STEM-in-SEM, AFM as well as with SAXS as an ensemble method. This ILC is thought as the next level development of the case studies exemplified in the published ISO standards ISO 21363 and ISO 19749. It was agreed to complete the first ILC with the NPs already prepared according to the same procedure on a TEM grid, and, at a later stage, to carry out second ILCs with the same NPs distributed to the participants as liquid suspensions together with protocols for the uniform NP deposition on suited substrates - as developed and optimized within the European project nPSize. Once having good deposition protocols available, the door for automated image analysis gets opened. Corresponding image analysis protocols and reporting templates have been distributed to the ILC participants, too. ii) Project #16: two spherical SiO2 NP samples with bi-modal size distributions in two nominal relative number concentrations were prepared and distributed also as liquid suspensions accompanied by sample preparation, measurement, and image analysis protocols and reporting templates. Here, the NP concentration is the primary parameter to be measured. For the imaging methods it is targeted to measure the relative nanoparticle concentrations (relative populations of the two modes). The results of all the participating laboratories, in both ILCs, compiled in comparative representations will be shown and discussed for the first time. The reduction of the measurement uncertainties associated to the size, shape and number-concentration results induced by the significant improvement of the sample preparation on substrates (as single particles with a high-density coverage), combined with welldefined image analysis procedures will be highlighted. T2 - 2024 Spring Meeting of the European Materials Research Society (E-MRS) CY - Strasbourg, France DA - 27.05.2024 KW - VAMAS KW - Interlaboratory comparison KW - Electron microscopy KW - Particle size distribution KW - Article concentration PY - 2024 AN - OPUS4-60184 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien A1 - Hirsch, Philipp A1 - Ahmadi, Samim A1 - Pech-May, Nelson W. A1 - Hauffen, Jan Christian A1 - Thiel, Erik A1 - Ziegler, Mathias T1 - New options for finding defects on and below the surface using structured laser thermography N2 - In infrared thermography, the interaction of the heat flow with the internal geometry or inhomogeneities in a sample and their effect on the transient temperature distribution is used, e.g., to detect defects non-destructively. An equivalent way of describing this is the propagation of thermal waves inside the sample. Although thermography is suitable for a wide range of inhomogeneities and materials, the fundamental limitation is the diffuse nature of thermal waves and the need to measure their effect radiometrically at the sample surface only. The crucial difference between diffuse thermal waves and propagating waves, as they occur, e.g., in ultrasound, is the rapid degradation of spatial resolution with increasing defect depth. This degradation usually limits the applicability of thermography for finding small defects on and below the surface. A promising approach to improve the spatial resolution and thus the detection sensitivity and reconstruction quality of the thermographic technique lies in the shaping of these diffuse thermal wave fields using structured laser thermography. Some examples are: • Narrow crack-like defects below the surface can be detected with high sensitivity by superimposing several interfering thermal wave fields, • Defects very close to each other can be separated by multiple measurements with varying heating structures, • Defects at different depths can be distinguished by an optimized temporal shaping of the thermal excitation function, • Narrow cracks on the surface can be found by robotic scanning with focused laser spots. We present the latest results of this technology obtained with high-power laser systems and modern numerical methods. T2 - 20th World Conference on Non-Destructive Testing (WCNDT) CY - Incheon, Korea DA - 27.05.2024 KW - Thermography KW - Laser KW - NDT KW - Super-Resolution KW - DLP KW - DMD PY - 2024 AN - OPUS4-60172 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Littner, Linus A1 - Gaal, Mate T1 - Standardisierung von luftgekoppelten Ultraschallmessungen: Leitfaden und Prüfkörper N2 - Die zunehmende Bedeutung der luftgekoppelten Ultraschallprüfung (ACUT) in der zerstörungsfreien Prüfung (ZfP) unterstreicht die Notwendigkeit von standardisierten Abläufen und Methoden. Bei der ACUT bestehen grundlegende Unterschiede zur manuell durchgeführten Ultraschallprüfung mit Kontakttechnik oder zur automatisierten Tauchtechnik. Die Unterschiede bei der Bestimmung von Prüfkopfparametern für ACUT wurde von Herstellern, Forschungseinrichtungen und Anwendern bereits als wichtig erkannt, was sie veranlasst hat, im Rahmen des Unterausschusses Luftgekoppelte Ultraschallprüfung der DGZfP die Richtlinie US08 zur standardisierten Charakterisierung von luftgekoppelten Ultraschallwandlern zu erarbeiten. Darüber hinaus bestehen auch bei der Durchführung einer Messung grundlegende Unterschiede, die aktuell in einem Leitfaden zusammengetragen und definiert werden. In diesem Beitrag wird ein Überblick über die geplanten Inhalte dieses Leitfadens gegeben. Insbesondere wird die Auswahl von Prüfparametern in Form von Frequenzen, Abständen und Positionierung sowie die Auswertung behandelt. Darüber hinaus werden die Ergebnisse eines Ringversuchs vorgestellt, welcher an einem eigens hierfür entwickelten und mit Defekten versehenem Prüfkörper, der sog. ACUT-Prüfplatte, durchgeführt wurde. In diesem Ringversuch werden unterschiedliche Messanordnungen, die mittels luftgekoppeltem Ultraschall möglich sind, anhand des erreichbaren Signal-Rausch-Verhältnisses sowie der messbaren Defektgröße quantifiziert. Zudem findet eine Abgrenzung zu weiteren gängigen Verfahren der ZfP statt. Anhand der hier vorgestellten Ergebnisse ist es möglich, die Anwendbarkeit des luftgekoppelten Ultraschalls unter Berücksichtigung unterschiedlicher Messanordnungen besser einzuschätzen. T2 - DGZfP-Jahrestagung CY - Osnabrück, Germany DA - 06.05.2024 KW - Ultraschall KW - Luftgekoppelter Ultraschall KW - Standardisierung KW - Charakterisierung PY - 2024 AN - OPUS4-60170 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gaal, Mate A1 - Wernicke, Pascal A1 - Hufschläger, Daniel T1 - Pulskompression für luftgekoppelte Ultraschallprüfung mit Ferroelektret- und thermoakustischen Wandlern N2 - Die größten Vorteile der luftgekoppelten Ultraschallprüfung sind: die berührungslose Prüfung und der Verzicht auf ein flüssiges Koppelmittel. Allerdings weisen die meisten luftgekoppelten Prüfszenarien ein sehr geringes Signal-zu-Rausch-Verhältnis (SNR) auf und die Pegel, die von luftgekoppelten Ultraschallwandlern realisiert werden, sind um mehrere Größenordnungen kleiner. Da diese Herausforderung auch in anderen Disziplinen wie bspw. der Radartechnik existiert und dort ebenfalls eine entscheidende Rolle spielt, wurde die dort eingesetzte Pulskompression auf die physikalischen Gegebenheiten der luftgekoppelten Ultraschallprüfung angepasst und angewandt. Dieser Beitrag präsentiert die Ergebnisse von zwei Versuchsaufbauten: 1) ein thermoakustischer Sender und ein optisches Mikrofon und 2) ein Paar Ferroelektret-Wandler als Sender und Empfänger. Aufgrund der physikalischen Randbedingungen wurden unipolare Kodierungen verwendet. Die Verwendung von unipolaren Kodes zur Modulation der Anregungssignale stellt dabei eine neue Methode dar, die so die Pulskompression für Ferroelektret- und thermoakustische Wandler ermöglichen soll. Die Anwendung der Pulskompression auf die Kombination aus thermoakustischem Sender und optischem Mikrofon konnte das Signal-zu-Rausch-Verhältnis um bis zu 15 dB und für die Ferroelektret-Wandler um bis zu 23 dB erhöhen. T2 - DAGA CY - Hannover, Germany DA - 19.03.2024 KW - Pulskompression KW - Luftgekoppelter Ultraschall KW - Ferroelektrete KW - Thermoakustik PY - 2024 AN - OPUS4-60168 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wittwer, Philipp A1 - Schneider, Rudolf T1 - Results of ILC Data Treatment N2 - Results of the interlaboratory comparison study for data treatment were presented. They show, that nearly all participants found all the problems in the data. However, only a few corrected the problems, therefore making it one possible point to focus on in the knowledge sharing program. T2 - AGM POLMO Meeting 2024 CY - Paris, France DA - 21.05.2024 KW - JNP POLMO KW - ILC KW - Ringversuch PY - 2024 AN - OPUS4-60166 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Walter, Astrid T1 - Neues aus der EU-Konformitätsbewertung und Normung von Explosivstoffen N2 - Aktuelle Produktentwicklungen, die im Rahmen des EU-Konformitätsbewertungsverfahren relevant sind, werden thematisiert und aus der Normungsarbeit von Explosivstoffen in den jeweiligen Gremien berichtet. T2 - Erfahrungsaustausch Sprengwesen CY - Munich, Germany DA - 22.05.2024 KW - Normung KW - Explosivstoffe KW - EU-Konformitätsbewertung PY - 2024 AN - OPUS4-60161 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Yagdjian, H. A1 - Lecompagnon, Julien A1 - Hirsch, Philipp A1 - Ziegler, Mathias A1 - Gurka, M. T1 - Application of the Thermal Shock Response Spectrum (TSRS) methodology to various forms of heat sources by impulse thermography N2 - In this paper, we investigate the influence of different heat source pulse shapes by Infrared impulse thermography (IRT) on the results of the thermal shock response spectrum (TSRS) methodology. TSRS is a new alternative approach for evaluating impulse thermography (IRT) data based on an analogy to Shock Response Spectrum (SRS) analysis (ISO 18431) for mechanical systems. It allows processing the entire recorded signal without truncating the saturated thermogram, as in pulse-phase thermography (PPT) or thermal signal reconstruction (TSR). For this purpose, we use a widespread halogen lamp as heat source as well as laser spot. The laser source enables not only to generate a precise shape of the pulse, but also to heat a specific area of the sample uniformly. This makes it possible to suppress influences of lateral fluxes due to uneven distribution of the excitation source on the surface of the specimen and leads to improved results. In order to quantitatively compare the results and to investigate the possible influence of the source shape on the TSRS, the Tanimoto criterion and the signal-to-noise ratio (SNR) were applied to the region of interest (ROI) of the carbon fiber reinforced polymer (CFRP) laminate with artificial defects as defect detectability criterion. T2 - Jahrestaung der Deutschen Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) 2024 CY - Osnabrück, Germany DA - 06.05.2024 KW - Thermal shock response KW - Laser KW - ZfP KW - Post-processing KW - Thermografie PY - 2024 AN - OPUS4-60158 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Altmann, Korinna T1 - Mikroplastik Detektion mit Thermoanalytischen Methoden: Analytik, Referenzmaterial, Ringversuche N2 - Ich dem Vortrag geht es um die Vorstellung von thermoanalytischen Methoden für die Mikroplastik-Detektion. Verschiedene Kopplungsmöglichkeiten werden gezeigt und die Funktionsweise der TED-GC/MS wird erklärt. Im zweiten Teil werden Referenzmaterialien für die Mikroplastik-Analytik diskutiert. PET -Tabletten des PlasticTrace Projektes werden vorgestellt. Am Ende wird der VAMAS Ringversuch zur Mikroplastik-Detektion gezeigt. T2 - Plastik, Mikroplastik, Nanopartikel, PFAS und Verunreinigungen (Agilent Workshop) CY - Hamburg, Germany DA - 28.05.2024 KW - Mikroplastik KW - TED-GC/MS KW - Polymer 3R KW - Ringversuche KW - Referenzmaterial PY - 2024 AN - OPUS4-60155 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Altenburg, Simon A1 - Breese, Philipp P. A1 - Oster, Simon A1 - Becker, Tina A1 - Scheuschner, Nils T1 - SAMMIE – Forschungssystem für die additive Fertigung von Metallen (PBF-LB/M) zur Entwicklung von In-situ-Überwachungs- und -prüfmethoden N2 - Die additive Fertigung von Metallen hat inzwischen einen Reifegrad erreicht, der einen Einsatz in vielen Industriezweigen ermöglicht oder in greifbare Nähe rückt. Die Vorteile liegen vor allem in der Möglichkeit der Fertigung komplexer Bauteile, die sich konventionell nicht oder nur sehr aufwändig produzieren lassen, sowie in der Fertigung von hochindividualisierten Bauteilen in kleinen Stückzahlen. Allerdings ist der additive Fertigungsprozess hoch komplex und fehleranfällig. Um eine insbesondere für sicherheitsrelevante Bauteile notwendige Qualitätskontrolle zu gewährleisten, ist aktuell aufwändige nachgelagerte ZfP der einzelnen Bauteile notwendig. Alternativen könnten die In-situ-Prozessüberwachung und -prüfung bieten, die aktuell aber noch keinen ausreichenden Entwicklungsstand erreicht haben. Industrielle Fertigungsanlagen bieten keine oder nur geringe Flexibilität und Zugänglichkeit, um umfangreiche Untersuchungen auf diesem Gebiet zu ermöglichen. Daher haben wir an der BAM ein System für den Prozess des selektiven Laserschmelzens (PBF-LB/M) entwickelt, genannt SAMMIE. Es bietet eine komplett offene Systemarchitektur mit voller Kontrolle über den Prozess und flexiblem Zugang zur Baukammer, z.B. optisch sowohl direkt als auch koaxial zum Fertigungslaser. In diesem Beitrag stellen wir das System vor und zeigen erste experimentelle Ergebnisse der In-situ-Überwachung und -prüfung: Thermografische Schmelzbadüberwachung, optische Tomografie und In-situ-Laserthermografie. SAMMIE ermöglicht uns grundlegende Untersuchungen, die helfen werden, die In-situ-Prozessüberwachung und -prüfung weiterzuentwickeln, neue Erkenntnisse über die additive Fertigung zu gewinnen und die Sicherheit und Zuverlässigkeit des Prozesses zu verbessern. T2 - DGZfP-Jahrestagung 2024 CY - Osnabrück, Germany DA - 06.05.2024 KW - PBF-LB/M KW - In situ monitoring KW - Anlage KW - Additive Fertigung KW - Prozessüberwachung KW - Additive Manufacturing PY - 2024 AN - OPUS4-60149 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Jauregui Rozo, Maria A1 - Sunder, Sruthi A1 - Schartel, Bernhard A1 - Ruckdäschel, Holger T1 - Weaving through fire and force: Fire behavior, fire stability and modes of action between epoxy resin and glass-fiber composites N2 - Several investigation groups have studied the flame-retardancy modes of action and properties of epoxy resins in the past; nevertheless, the selection of suitable flame retardants for epoxy resins remains challenging, and the transfer to fiber composites is difficult. The addition of flame retardants and glass fibers (GFs) to a polymeric system in a fire scenario changes the polymer's pyrolytic path and burning characteristics, reduces the heat released in the combustion, and suppresses the modes of action in the condensed and gas phase. In this study, the thermal analysis, flammability, fire behavior, residue analysis, fire stability, and quantification of modes of action of three different systems with three halogen-free flame retardants (melamine polyphosphate (MPP), ammonium polyphosphate (APP), and silane ammonium polyphosphate (SiAPP)) and three different types of GFs (unidirectional (UD), bidirectional (BD), and woven roving (WR)) will be compared with pure epoxy resin as a reference. T2 - Fire & Polymers CY - New Orleans, LA, USA DA - 12.05.2024 KW - Glass-fiber-composites KW - Epoxy Resins KW - Flame Retardancy KW - Fire Stability KW - Bench-scale Fire Resistance Test PY - 2024 AN - OPUS4-60150 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lu, Xin A1 - Hicke, Konstantin A1 - Krebber, Katerina T1 - Distributed fiber optic sensing for monitoring of underground facilities N2 - Distributed fiber optic sensing (DFOS) technique is a promising and robust non-destructive testing tool that can seamlessly acquire environmental conditions over large scales. Therefore, it has found extensive applications in structural health monitoring. Its appeal for monitoring underground facilities lies in the intrinsic properties of the optical fiber, such as immunity to magnetic interference, small size, chemical inertia, etc. This paper provides a concise overview of DFOS applications in underground facility monitoring. Following a brief introduction to the working principle of the DFOS technique, various examples are provided to demonstrate how distributed fiber sensors contribute to monitoring underground facilities. The paper presents unpublished field test results with an emphasis in the energy sector, including monitoring gas storage facilities, geothermal reservoir exploration, and ground movement detection. Furthermore, the paper identifies several directions for enhancing the DFOS system. T2 - SPIE Photonics Europe CY - Strasbourg, France DA - 07.04.2024 KW - Underground gas storage KW - Distributed fiber sensing KW - Geothermal borehole KW - Ground movement KW - Leakage detection KW - Structure health monitoring PY - 2024 AN - OPUS4-60146 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Tschirschwitz, Rico A1 - Bernardy, Christopher A1 - Hahn, Sarah-K. A1 - Krause, Ulrich T1 - Sicherheit elektrochemischer Energiespeicher - Ergebnisse aus dem Projekt SEE-2L N2 - Im Rahmen des BMBF-Vorhabens SEE-2L wurde auf dem Testgelände Technische Sicherheit (BAM TTS) ein Großversuchsstand für das thermische Durchgehen von Lithium-Batterien auf Modul- und Batterieebene entwickelt und aufgebaut. Im Zuge des Projektes konnte eine erste Versuchsserie zu den Auswirkungen des thermischen Durchgehens von Batteriemodulen durchgeführt werden. Im Vortrag werden die wesentlichen Ergebnisse der Versuche vorgestellt. T2 - Magdeburg-Köthener Brandschutz- und Sicherheitstagung CY - Magdeburg, Germany DA - 14.03.2024 KW - Auswirkungsbetrachtungen KW - Elektrische Energiespeicher KW - Lithium-Ionen-Batterie KW - Stationäre Energiespeicher KW - Thermisches Durchgehen PY - 2024 AN - OPUS4-60143 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Friedrich, Alexander A1 - Zhang, Tianyun A1 - Heckel, Thomas A1 - Casperson, Ralf T1 - Simulation von Ultraschall- und Wirbelstromprüfdaten für die Schienenprüfung N2 - Im Rahmen des Forschungsprojekts "Artificial Intelligence for Rail Inspection" (AIFRI) wird ein KI-Algorithmus entwickelt, um die Fehlererkennung und Bewertung bei der Auswertung von Schienenprüfungen mittels Ultraschall- und Wirbelstromprüfverfahren zu verbessern. Die Bandbreite möglicher Defekte und die Menge an Einflussgrößen auf die Schienenprüfung ist sehr groß, aber die Prüfdaten aus dem Feld bilden diese Bandbreite nicht balanciert ab und sind unzureichend gelabelt. Durch Simulationen werden große Mengen detailliert gelabelter Daten für relevante Schienenschädigungen und Artefakte bereitgestellt. Aus diesen Daten werden wiederum virtuellen Prüffahrten erstellt, die für das Training und die Validierung der KI genutzt werden können. In unserem Vortrag stellen wir den Erstellungsprozess der Datensätze vor. Jeder Schritt von der Geometriedarstellung bis zur Datenverarbeitung wird erfasst. Der Fokus wird auf Simulationsergebnisse und deren Verarbeitung gelegt. Die Signalverarbeitung spielt in den Datensätzen eine große Rolle, dabei werden die Datensätze an die realen Daten angepasst. Für Wirbelstrom und Ultraschall werden diese Prozesse im Hinblick auf die Fehlertypen Head Checks und Bohrungsanrisse veranschaulicht. Ferner diskutieren wir die Simulation von Schweißnähten, die von beiden Prüfsystem detektiert werden können; und somit besondere Abstimmung bedürfen aber auch Synergieeffekte zwischen den Prüfsystem ermöglichen. Für die Ablage der Datensätze verweisen wir auf das ebenfalls eingereichte Poster „Verwendung von DICONDE bei der Eisenbahn-Schienenprüfung“. Das Projekt AIFRI wird im Rahmen der Innovationsinitiative mFUND unter dem Förderkennzeichen 19FS2014 durch das Bundesministerium für Digitales und Verkehr gefördert. T2 - DGZfP-Jahrestagung 2024 CY - Osnabrück, Germany DA - 06.05.2024 KW - Wirbelstrom KW - Ultraschall KW - Simulation KW - Machine Learning PY - 2024 AN - OPUS4-60138 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dudziak, Mateusz A1 - Bhatia, Riya A1 - Dey, Rohit A1 - Ullrich, Matthias S. A1 - Schartel, Bernhard T1 - Phosphor-enriched wastewater products as sustainable flame retardant in PLA N2 - Revolutionizing our polymer industry for adaption to a sustainable carbon circular economy has become one of today’s most demanding challenges. Exploiting renewable resources to replace fossil-fuel—based plastics with biopolymers such as poly(lactic acid) (PLA) is inevitable while using waste streams as a raw material resource at least is promising. When it comes to using PLA as technical polymer, its high flammability must be addressed by flame retardants compatible with the thermoplastic processing of PLA and its compostability. This study proposes microalgae enriched with phosphorus from wastewater (P-Algae) as an elegant way towards a kind of sustainable organophosphorus flame retardant. The concept is demonstrated by investigating the processing, pyrolysis, flammability, and fire behavior of PLA/P-Algae, while varying the P-Algae content and comparing P-Algae with four alternative bio-fillers (phosphorylated lignin, biochar, thermally treated sewage sludge, and metal phytate) with different P-contents as meaningful benchmarks. T2 - EcoFRam2024 CY - Valencia, Spain DA - 22.05.2024 KW - PLA KW - Flame retardancy KW - Phosphorylated algae KW - Wastewater flame retardants KW - Zink phytate KW - Phosphorylated lignin KW - Thermally treated sludge PY - 2024 AN - OPUS4-60142 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kemmler, Samuel T1 - Simulating Piping Erosion in Suction Buckets N2 - This presentation gives an overview of the recent achievements in simulating piping erosion during the installation process of suction bucket foundations for offshore wind turbines. The physical correctness of the code is validated, and the simulation code's performance on the LUMI supercomputer is presented. The simulation results are compared to experimental data. T2 - Forschungsbesuch CY - Aix-en-Provence, France DA - 14.05.2024 KW - Offshore wind turbine KW - Suction bucket KW - Coupled fluid-particle simulation KW - High-performance computing PY - 2024 AN - OPUS4-60136 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hübner, Martin A1 - Dittmann, Florian A1 - Kromm, Arne A1 - Varfolomeev, Igor A1 - Kannengießer, Thomas T1 - Einfluss der Nahtgeometrie auf den Eigenspannungsabbau unter Verwendung von Low Transformation Temperature (LTT) – Schweißzusätzen N2 - Low Transformation Temperature (LTT)-Schweißzusätze stellen einen innovativen Ansatz zur Erhöhung der Ermüdungsfestigkeit geschweißter Konstruktionen dar. LTT-Schweißzusätze zeichnen sich durch eine martensitische Phasenumwandlung nahe der Raumtemperatur aus, welche Druckeigenspannungen in der Schweißnaht und der Wärmeeinflusszone (WEZ) generieren. Dieser Vortrag fokussiert sich auf die gezielte Einbringung zusätzlicher LTT-Lagen an ermüdungskritischen Stellen von konventionell geschweißten Verbindungen. Dies ermöglicht eine ökonomische Anwendung, ohne dass die Schweißnahtintegrität zu stark beeinflusst wird. Die Auswirkungen zusätzlicher LTT-Lagen wurden anhand geschweißter Längssteifen aus hochfestem Stahl hinsichtlich der chemischen Zusammensetzung und der Eigenspannungen untersucht. Unter Variation der Schweißgeschwindigkeit und Abstand zur konventionellen Naht konnten 3 unterschiedliche Nahtausführungen des Chrom-Nickellegierten LTT-Zusatzes bewertet werden. Die chemische Zusammensetzung wurde mittels OES-Analysen untersucht. Dabei stellte heraus, dass die Aufmischung in allen Varianten sehr ähnlich war trotz teils unterschiedlicher LTT-Volumina. Härtebestimmungen ergaben in allen 3 Varianten eine ähnliche Härte. Daraus lässt sich annehmen, dass die Martensitstarttemperatur bei allen Nahtvarianten ähnlich ist. Röntgenografische Eigenspannungsmessungen belegen, dass die Eigenspannungen am versa-genskritischen Nahtübergang bei Einsatz von LTT-Schweißzusätzen deutlich abgesenkt werden. Während die konventionelle Schweißnaht Zugeigenspannungen von ca. 350 MPa aufweist, können an den LTT-Nähten teilweise Druckeigenspannungen von bis zu -150 MPa nachgewiesen werden. Je höher der Abstand zur konventionellen Naht und je größer das eingebrachte LTT-Volumen ist, umso stärker sind die Eigenspannungsreduzierungen am Nahtübergang. Da in allen 3 Varianten eine ähnliche Martensitstarttemperatur angenommen werden kann, ist somit die Geometrische Komponente der LTT-Zusatzlage ein entscheidender Faktor für die Eigenspannungsreduzierung. T2 - AWT FA 13 CY - Wolfsburg, Germany DA - 19.03.2024 KW - Chemische Zusammensetzung, KW - LTT KW - Nahtgeometrie KW - Eigenspannungen PY - 2024 AN - OPUS4-60135 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Müller, Karsten A1 - Mair, Georg A1 - Dufner, Eric A1 - Kriegsmann, Andreas T1 - Experimentelle Untersuchungen von Composite-Druckgasbehältern: Prüfverfahren, Anwendungsbeispiele und Entwicklungen N2 - Dem AVK-Arbeitskreis Wasserstoff-Drucktanks werden ausgehend von Zielen und Aufgaben der BAM sowie der Fachkompetenz auf dem Gebiet der Sicherheit von Composite-Druckbehältern über die prüftechnische Ausstattung, die angewendeten und weiterentwickelten Prüf- und Untersuchungsmethoden sowie zu Beispielen von Forschungsvorhaben wie DELFIN, COLIBRI und SH2APED berichtet. T2 - Arbeitskreissitzung CY - Frankfurt a.M., Germany DA - 24.04.2024 KW - Composite-Druckbehälter KW - Berstversuch KW - Hydraulischer Lastwechselversuch KW - Feuersicherheit KW - Impakt PY - 2024 AN - OPUS4-60117 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Klein, Ulrich A1 - Erning, Johan Wilhelm A1 - Yerlikaya, K. T1 - Korrosion an Rohren aus ferritischem Stahl 1.4521 N2 - An Trinkwasserrohren aus ferritischem Stahl (1.4521) sind bei einigen größeren Bauvorhaben massive Korrosionsschäden aufgetreten. Die Leckagen treten ausschließlich durch Spaltkorrosion in Pressverbindungen auf, wo konstruktionsbedingt ein mit Wasser gefüllter Spalt zwischen der Rohr-Außenseite und dem Pressfitting gebildet wird. Im Vortrag werden die gewonnenen Erkenntnisse aus verschiedenen Schadensfällen der jüngeren Vergangenheit vorgestellt. T2 - GfKORR e.V. Arbeitskreis Schadensanalyse CY - Berlin, Germany DA - 09.03.2024 KW - Spaltkorrosion KW - Chromstahl KW - Trinkwasser PY - 2024 AN - OPUS4-60098 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Patrick P. A1 - Kohlhoff, Harald A1 - Lohrke, Heiko T1 - Robotic Scanning Absorption Spectroscopy for Methane Leak Detection: The Virtual Gas Camera N2 - This paper explores combining a gimbal-mounted tunable diode laser absorption spectroscopy (TDLAS) sensor and a video camera to create a virtual gas camera for methane leak detection. This provides a low-to-zero-cost extension of typical TDLAS gas tomography systems. A prototype setup mounted on a ground robot is evaluated. Results acquired using a simulated methane leak show the feasibility of the virtual gas camera, accurately detecting methane leaks by overlaying concentrations onto a visual image. While the acquisition time is significantly longer than for traditional gas cameras, potential enhancements are discussed. The study concludes that the virtual gas camera is feasible and useful, despite its longer acquisition time. It serves as a valuable software-only addition to typical TDLAS gas tomography systems, offering quickly-available on-site data augmentation for visual leak assessment at low-to-zero cost. T2 - 20th International Symposium on Olfaction and Electronic Nose CY - Grapevine, Texas, USA DA - 12.05.2024 KW - Mobile Robotic Olfaction KW - TDLAS KW - Gas Tomography KW - Gas Camera KW - Plume PY - 2024 AN - OPUS4-60110 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Winkler, Nicolas P. A1 - Neumann, Patrick P. A1 - Schaffernicht, Erik A1 - Lilienthal, Achim J. T1 - Gas Distribution Mapping With Radius-Based, Bi-directional Graph Neural Networks (RABI-GNN) N2 - Gas Distribution Mapping (GDM) is essential in monitoring hazardous environments, where uneven sampling and spatial sparsity of data present significant challenges. Traditional methods for GDM often fall short in accuracy and expressiveness. Modern learning-based approaches employing Convolutional Neural Networks (CNNs) require regular-sized input data, limiting their adaptability to irregular and sparse datasets typically encountered in GDM. This study addresses these shortcomings by showcasing Graph Neural Networks (GNNs) for learningbased GDM on irregular and spatially sparse sensor data. Our Radius-Based, Bi-Directionally connected GNN (RABI-GNN) was trained on a synthetic gas distribution dataset on which it outperforms our previous CNN-based model while overcoming its constraints. We demonstrate the flexibility of RABI-GNN by applying it to real-world data obtained in an industrial steel factory, highlighting promising opportunities for more accurate GDM models. T2 - International Symposium on Olfaction and Electronic Nose (ISOEN) CY - Grapevine, TX, USA DA - 12.05.2024 KW - Gas distribution mapping KW - Spatial interpolation KW - Graph neural networks KW - Mobile robot olfaction PY - 2024 AN - OPUS4-60106 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Gleim, Tobias A1 - Wille, Frank A1 - Feldkamp, Martin A1 - Quercetti, Thomas A1 - Musloff, André A1 - Werner, Jan T1 - Enhancement of Fire Test Stand Performance at Test Site of BAM: Installation and Evaluation of an Augmented System with a Fire Reference Package N2 - Packages for the transport of radioactive material are designed to en-dure severe accidents. Packages for the transportation of radioactive material must demonstrate that the package can withstand certain prescribed tests from the IAEA Regulations [1]. In addition to mechanical tests, a thermal test in form of a fire test must be carried out. As packages to be tested at BAM are signifi-cantly larger than previous package designs, BAM has expanded an existing fire test stand. A modular concept is chosen, which means that the arrangement of the burner nozzles can be adapted to the test specimen. The dimensions of the burner rings, the type, the orientation and the number of burner nozzles can be varied depending on the test specimen. In addition, various pumps can be used to set the corresponding mass flow. With the help of a calorimeter test, the fire test stand can be qualified for a specific size of packages regarding the boundary conditions of the IAEA Regulations [1]. Due to the typically wood filled impact limiters in German package designs, a fire test is necessary, as experiments have shown that possible openings that occurred during a mechanical test contributed to the igni-tion of the wood filled impact limiters within the prescribed 30 minutes of the IAEA Regulations [1]. From a series of experiments, two experiments are pre-sented to show the possibilities to obtain different temperatures and temperature rates in the test specimen. In addition to sensor data, the heat flux into the package is calculated to verify that the IAEA boundary conditions are satisfied. In addition to the temperature data, other data such as wind speed and wind direction are also recorded to explain subsequent effects in the measurement data in a comprehen-sible manner. T2 - Wood & Fire Safety 2024 CY - Štrbské Pleso, Slovakia DA - 13.05.2024 KW - Fire Test Stand KW - Accident Scenario KW - Fire Qualification KW - IAEA Regu-lations PY - 2024 UR - https://link.springer.com/book/9783031591761 AN - OPUS4-60104 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hodoroaba, Vasile-Dan T1 - Ongoing VAMAS ILC s on Nanoparticles and Graphene Oxide N2 - This contributions shows the first results of the ongoing interlaboratory comparisons under VAMAS/TWA 34 Nanoparticle populations related on the determination of pasrticle size distribution and relative concentration of nanoparticles and an example of an ILC running under VAMAS/TWA 41 Graphene and Related 2D Materials on the determination of the lateral diemsnions of graphene oxide flakes by Scanning Electron Microscopy. The link to related standardisation projects at ISO/TC Nanotechnologies are explained. T2 - Webinar Building the Foundation: Interlaboratory Comparisons and Reference Products for Advanced Materials CY - Berlin, Germany DA - 16.05.2024 KW - Nanoparticles KW - VAMAS KW - Interlaboratory comparison KW - Standardisation KW - Electron microscopy KW - AFM KW - SAXS PY - 2024 AN - OPUS4-60097 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Hodoroaba, Vasile-Dan T1 - About Interlaboratory Comparisons (ILCs) and VAMAS N2 - Advanced materials, such as nanomaterials, 2D materials, or thin films, play a crucial role in driving economic development and addressing major challenges in the coming years. These challenges include mitigating the impact of climate change, advancing lightweight engineering, enhancing catalysis, and improving medical applications. To comprehend the performance of these materials and ensure their acceptance across various sectors as safe and sustainable for both humans and the environment, the availability of reference procedures, materials, and data is essential. One versatile tool for establishing such references and evaluating the proficiency of individual laboratories and their competencies is through (international) interlaboratory comparisons (ILC). Notably, initiatives like the Versailles Project on Advanced Materials and Standards (VAMAS) provide a platform for conducting ILCs. This webinar will showcase various examples of interlaboratory comparisons, illustrating their impact on the development of reference products. T2 - Webinar Building the Foundation: Interlaboratory Comparisons and Reference Products for Advanced Materials CY - Berlin, Germany DA - 16.05.2024 KW - Interlaboratory comparison KW - Reference products KW - VAMAS KW - Standardisation PY - 2024 AN - OPUS4-60096 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dudek, Gabriele A1 - Denkler, Tilman T1 - Digital Product Passport (DPP) and possible consequences for classification N2 - The presentation provides an overview of the current European initiatives to introduce the Digital Product Passport (DPP). Starting from the political background, reference is made to the implementation in various European directives. According to current considerations, explosives and pyrotechnics are not excluded from this. The introduction of the DPP system requires the development of a solid basis of relevant standards, which are now being developed. The aim of BAM's efforts will be to digitally align the classification processes with a view to these developments. T2 - International Group of experts on the explosion risks of Unstable Substances (IGUS)- Joint Meeting CIE/IGUS-EPP CY - Manchester, GB DA - 28.04.2024 KW - Feuerwerk KW - Pyrotechnik KW - Lagergruppenzuordnung KW - Transportklassifizierung PY - 2024 AN - OPUS4-60093 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Neumann, Martin A1 - Feldkamp, Martin A1 - Linnemann, Konrad A1 - Wille, Frank T1 - Transport of HLW canisters on sea vessels N2 - Germany had been transporting spent fuel to the reprocessing plant in Sellafield and La Hague for decades until around 2005. Resulting from the obligation to take back the vitrified high-level waste from reprocessing six CASTOR® HAW28M filled with 168 canisters with radioactive waste in vitrified form were transported from Sellafield to the interim storage facility Biblis in 2020. Rail wagons were used for the transport to the port in Barrow-in-Furness, where they were loaded into a dedicated seagoing vessel, certified as INF Class 3 according to the INF Code. This was the first time that vitrified high level waste with considerable heat load was transported under a German design approval certificate. BAM was involved in the authority assessment of the conditions for the sea transport. For the first transport BAM required among others, assessment of temperature distribution during transport, logging of temperatures of cargo bays and graphical imaging of temperatures of the bay with the cask in order to ensure compliance with temperature specifications, e.g. maximal neutron absorber and gasket temperatures. Special interest was taken in the identification of possible events exceeding the specified temperatures considering the different philosophies of IMDG code and its supplement INF code regarding temperature control of hatches. Results show compliance with assumed conditions. T2 - RAMTrans 2024 CY - London, GB DA - 14.05.2024 KW - Transport KW - Spent nuclear fuel KW - Ship KW - Sea KW - High level waste PY - 2024 AN - OPUS4-60091 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Falkenhagen, Jana T1 - A Tribute to Harald –Lignin as biobased polymer-Trends and analytical issues N2 - The presentation includes aspects of material design and characterization with a focus on lignin. Examples are the structural elucidation of lignosulfonates by means of two-dimensional chromatography, the mechanochemical degradation and functionalization of Kraft-Lignin with accompanying analytics. Future projects involving the incorporation of lignin into polymers will be presented. T2 - Farewell Symposium for Prof. Harald Pasch; Polymer Analysis: Advancements in Characterization and Quantification CY - Teltow, Germany DA - 18.03.2024 KW - Lignin KW - Biobased polymers PY - 2024 AN - OPUS4-60003 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Altmann, Korinna A1 - Ciornii, Dmitri A1 - Hodoroaba, Vasile-Dan T1 - Validation of microplastics detection methods and proficiency testing: Suitable microplastic reference materials for interlaboratory comparison N2 - The talk summarizes challenges in microplastic analysis. It shows the preparation of microplastic reference materials as well as the testing on homogeneity and stability. The reference material is used in an international laboratory comparison to compare different detection methods used for microplastic analysis. The methods used were µ-IR (FTIR+LDIR) for number-based methods and TED-GC/MS and Py-GC/MS for mass-based methods. The ILC was done under the umbrella of VAMAS TWA 45. Results of the participants are presented. T2 - BAM Akademie CY - Online meeting DA - 16.05.2024 KW - Microplastics KW - Reference materials KW - ILC KW - Microplastics detection KW - TED-GC/MS KW - Polymer 3R PY - 2024 AN - OPUS4-60085 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schartel, Bernhard T1 - More than the sum of its parts – synergistic FR-combinations N2 - Efficient flame retardancy is often achieved only when applying synergistic multicomponent systems. Flame retardants are combined or used together with adjuvants or synergists to enhance their efficiency, reduce the amount required, or reduce the costs; fibers and fillers contribute to fire properties crucially. Although the main flame-retardant modes of action are known, the detailed scientific understanding usually falls short, when it comes to complex synergistic multicomponent systems, the important tiny optimizations, or quantifying in terms of specific fire properties. This paper tries to illuminate the concept of synergistic flame retardants. The need for the multicomponent approach and the main phenomena are described. Thought-provoking impulses are delivered on how the understanding of multicomponent systems promotes the evidence-based development of future flame retardant polymeric materials. Multicomponent systems are discussed in their capacity as general powerful strategy for achieving and optimizing flame retardant polymeric materials. This paper is based mainly on the overall conclusions and concrete results of several projects performed in the group of the author. Thanks to my (former) students and co-operation partners in these projects. Thanks for financing to DFG (Scha 730/8-1 Scha 730/8-2, Br 3376/1-1, Scha 730/19-1), AiF IGF (438 ZN, 17833N/2, 19078 N/2), and BMBF (03X0111C, 01DN16040). T2 - Fire & Polymers CY - New Orleans, LA, US DA - 12.05.2024 KW - Flame retardants KW - Synergy KW - Composites KW - Adjuvants PY - 2024 AN - OPUS4-60082 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Mühler, T. A1 - Günster, Jens T1 - LSD-print: a 10-years journey of an additive manufacturing technology from porcelain to technical ceramics N2 - Motivated by the aim of developing an additive manufacturing (AM) technology easily integrated in the process chains of the ceramic industry, the LSD-print technology was conceived as a slurry-based variation of binder jetting (BJ). BJ and other powder bed technologies (such as powder bed fusion) are amongst the most successful AM techniques, especially for metals and polymers, thanks to their high productivity and scalability. The possibility to use commercially available feedstocks (in the form of powders or granules) makes BJ also attractive for ceramic materials. The application of these techniques to most advanced ceramics has however been difficult so far, because of the limitations in depositing homogeneous layers with fine, typically poorly flowable powders. In this context, the "layerwise slurry deposition" (LSD) was proposed at TU Clausthal (Germany) as a slurry-based deposition of ceramic layers by means of a doctor blade. Combined with layer-by-layer laser sintering of the material, the LSD process was originally demonstrated for the rapid prototyping of silicate ceramics. Due to the difficulties in controlling the microstructure and the defect formation in laser-sintered technical ceramics, the LSD process was later combined with inkjet printing in the LSD-print technology, which has been further developed at BAM (Germany) in the past decade. The LSD-print technology combines the high speed of inkjet printing, typical of BJ, with the possibility of producing a variety of high-quality ceramics with properties comparable to those achieved by traditional processing. Due to the mechanical stability of the powder bed, the process can also be carried out with continuous layer deposition on a rotating platform, which further increases its productivity. This presentation will delve into 10 years of research on the LSD-print of a wide variety of technical ceramics including alumina, silicon carbides and dental ceramics. The discussion highlights how a seemingly small process and feedstock modification (from powders to slurries) has great influence on the challenges and potential of this process, which are being addressed on its path to industrialization. T2 - young Ceramists Additive Manufacturing Forum (yCAM) 2024 CY - Tampere, Finland DA - 06.05.2024 KW - Additive Manufacturing KW - Ceramic KW - Layerwise slurry deposition KW - Slurry KW - LSD-print PY - 2024 AN - OPUS4-60056 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Mühler, T. A1 - Günster, Jens T1 - Continuous layer deposition for the Additive Manufacturing of ceramics by Layerwise Slurry Deposition (LSD-print) N2 - Powder bed technologies are amongst the most successful Additive Manufacturing (AM) techniques. The application of these techniques to most ceramics has been difficult so far, because of the challenges related to the deposition of homogeneous powder layers when using fine powders. In this context, the "layerwise slurry deposition" (LSD) has been developed as a layer deposition method enabling the use of powder bed AM technologies also for advanced ceramic materials. The layerwise slurry deposition consists of the layer-by-layer deposition of a ceramic slurry by means of a doctor blade, in which the slurry is deposited and dried to achieve a highly packed powder. Not only very fine, submicron powders can be processed with low organics, but also the dense powder bed provides excellent support to the parts built. The LSD technology can be combined with binder jetting to develop the so-called “LSD-print” process. LSD-print combines the high-speed printing of binder jetting with the possibility of producing a variety of high-quality ceramics with properties comparable to traditional processing. The latest development of this technology shows that it is possible to print ceramic parts in a continuous process by depositing a layer onto a rotating platform, growing a powder bed following a spiral motion. The unique mechanical stability of the layers in LSD-print allows to grow a powder bed several centimeters thick without any lateral support. The continuous layer deposition allows to achieve a productivity more than 10X higher compared to the linear deposition, approaching a build volume of 1 liter/hour. T2 - 3rd Global Conference and Exhibition on Smart Additive Manufacturing, Design & Evaluation Smart MADE CY - Osaka, Japan DA - 10.04.2024 KW - Additive Manufacturing KW - Ceramic KW - Layerwise slurry deposition KW - LSD-print KW - Slurry KW - Binder jetting PY - 2024 AN - OPUS4-60055 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Ciornii, Dmitri A1 - Hodoroaba, Vasile-Dan A1 - Altmann, Korinna T1 - Validation of microplastics detection methods and proficiency testing: Suitable microplastic reference materials for interlaboratory comparison N2 - Since microplastics (MPs) can be found everywhere and are becoming a problem of high concern, it is necessary to understand their physico-chemical properties. To obtain reliable analytical data a set of validated methods for sampling, sample preparation, detection, and data evaluation are needed. To meet these needs an interlaboratory comparison (ILC) with 84 participants worldwide has been organized under the international pre-standardisation platform VAMAS (www.vamas.org/twa45/) as Project 2 “Development of standardized methodologies for characterisation of microplastics with microscopy and spectroscopy methods” within the Technical Working Area TWA 45 “Micro and Nano Plastics in the Environment”. In this ILC thermo-analytical methods (Py-GC/MS and TED-GC/MS) and vibrational methods (µ-Raman and µ-FTIR) have been tested and compared by providing a set of microplastic representative test materials and measurement protocols developed at BAM. The defined measurands were: particle number concentration, particle size distribution (PSD), and polymer identity and mass content. To increase the statistical quality, 6 samples were shipped together with blank samples. Hence, the ILC provides information on precision and accuracy of the results obtained with different methods as well as strengths and limitations of the proposed protocols. T2 - SETAC 34th Meeting CY - Seville, Spain DA - 05.05.2024 KW - ILC KW - Microplastic KW - Method validation KW - Stakeholder KW - Reference materials KW - Polyethylene KW - Polyethylene Terephtalate PY - 2024 AN - OPUS4-60039 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Mühler, T. A1 - Schubert, Hendrik A1 - Günster, Jens T1 - Water-based additive manufacturing of ceramics by Laser-Induced Slip Casting (LIS) N2 - The Laser-Induced Slip Casting is an additive manufacturing technology specifically developed for ceramic materials using water-based ceramic slurries. The process takes place layer-by-layer in a similar fashion as top-down vat photopolymerization, selectively consolidating each layer by means of a laser energy source positioned on the top. Contrary to vat photopolymerization, in which the consolidation is achieved by selectively cross-linking a ceramic-filled resin, LIS uses water-based slurries with a low amount of organic additives (typically < 5 wt%) as feedstocks. In LIS, a green body is formed by local evaporation of water which causes the suspension to collapse forming a cast, following a mechanism similar to slip casting. Only a small content of organic additives is needed to effectively disperse the ceramic particles and to increase the green strength. The technology is very versatile and can be applied to all ceramic systems that can be dispersed in water. One of the main advantages is that even dark materials such as silicon carbide can be processed without issues related to light scattering and absorption. The presentation will discuss strengths and limitations of LIS compared to other AM technologies and will highlight the latest results for alumina and for silicon carbide ceramics. T2 - 48th International Conference and Expo on Advanced Ceramics and Composites (ICACC2024) CY - Daytona, FL, USA DA - 28.01.2024 KW - Additive Manufacturing KW - Ceramic KW - Water-based KW - Slurry KW - Laser PY - 2024 AN - OPUS4-60054 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Seeber, Henrik A1 - Grobert, Steffen A1 - Krentel, Daniel A1 - Kluge, Martin A1 - Hauer, Thorsten T1 - Investigation of intracorporeal shock wave propagation using a simplified torso model and a shock wave generator N2 - Blast injuries are among the most common injuries in military operations. Also, in civilian environments, more explosive threats are expected in the future due to emerging conflicts and threats. While the effect of fragments, which is classified as secondary blast injury, could be minimized by police and military personnel’s modern ballistic body protection systems, the effects of shock wave propagation in the body as part of the primary explosion trauma still remain a serious threat needing further research. The detonation-physical processes of highly dynamic pressure changes within the human body, the reflection-related amplification of shock waves at organ-dermis interfaces, and the consequences of injury mechanisms have become more prominent in international research. Various approaches have been used to investigate these aspects. Animal experiments on free field test sites or shock tube setups combined with a subsequent biological evaluation and numerical simulations provided promising results and allowed the discussion of different biomechanical aspects. However, due to poor reproducibility and a lack of short-term dynamic material properties, most research approaches have significant limitations. Laboratory test setups do not represent real-scale high explosive detonation parameters with regards to pressure characteristics, impulse duration and blockage problems. Measured values are interpreted with partly outdated, selective and not validated limit values for overpressures from field tests with animals. This is due to the lack of a validated and comprehensive data set covering a variation of the crucial parameter. Injury mechanisms and their effects have not yet been sufficiently elucidated for the torso and extremities. In order to contribute to the research efforts on the primary explosion effects, the German Federal Armed Forces established an interdisciplinary military medical research project in cooperation of the Bundeswehr Hospital Berlin and the German Federal Institute for Materials Research and Testing (BAM). The aim of the planned investigation is the development of a multidisciplinary method to investigate shock wave behavior in various generic tissue simulants under the most reproducible conditions possible with realistic loads in an experimental test series with short set-up times. T2 - 7th International Forum on Blast Injury Countermeasures CY - Tokio, Japan DA - 17.05.2023 KW - Shock wave generator KW - Blast injury KW - Primäre Explosionswirkung KW - Experimental setup PY - 2023 AN - OPUS4-60045 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Zocca, Andrea A1 - Wilbig, Janka A1 - Günster, Jens T1 - An overview of ceramic AM with focus on bioceramics and powder bed technologies N2 - The presentation will start with an overview of ceramic additive manufacturing (AM) technologies and will discuss the potential of AM in the field of bioceramics. The presentation will then focus on two possible use cases of binder jetting technologies. In the first example, standard powder-based binder jetting is used to manufacture a porous implant design for large scale bone defects. The related challenges in the process chain will be discussed, from powder synthesis to sintering and characterization of the printed part. In the second example, the LSD-print slurry-based binder jetting technology is presented as a possibility to adapt powder-bed AM to produce dense ceramic parts. The use case will focus on an application in the field of dental ceramics, specifically for the manufacturing of patient individualized single tooth restorations (veneers, crowns) with a high throughput process chain. T2 - BioCAM - Additive Manufacturing Applied to Bioceramics CY - Mons, Belgium DA - 06.12.2023 KW - Additive Manufacturing KW - Bioceramic KW - Binder Jetting PY - 2023 AN - OPUS4-60053 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Reichel, Levin A1 - Schroepfer, Dirk A1 - Kannengiesser, Thomas A1 - Kromm, Arne T1 - Effiziente Reparaturkonzepte mittels geregelter MSG Hochleistungsprozesse bei der Fertigung hochfester Dickblechverbindungen für Offshore Windenergieanlagen P1629 N2 - Der Bau von Gründungs- und Turmstrukturen für Windkraftanlagen erfordert den Einsatz moderner, nachhaltiger und ressourcenschonender hochfester Feinkornbaustähle. Durch den Schweißprozess verursachte Schweißnahtfehler sind nicht akzeptabel. Um diese zu beheben, ist das lokale thermische Fugenhobeln mit anschließendem Reparaturschweißen ein gängiges und wirtschaftliches Verfahren. Die hohe Schrumpfbehinderung um die ausgefugte Nut durch das umgebende Gefüge kann zu Rissbildung führen, wenn sich konstruktiv bedingte Spannungen und Eigenspannungen aus der Reparaturschweißung überlagern. Diese Gefahr wird durch die Verschlechterung der Mikrostruktur und der mechanischen Eigenschaften hochfester Stähle während des Schweißreparaturprozesses noch verstärkt. T2 - Bachelor-, Master-, Doktoranden-Kolloquium CY - Magdeburg, Germany DA - 16.05.2024 KW - Reparaturschweißen KW - Thermisches Ausfugen KW - Offshore KW - Sprühlichtbogen PY - 2024 AN - OPUS4-60050 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wilrich, Cordula T1 - Lagerung von Gefahrstoffen gemäß TRGS 510 N2 - Der Vortrag stellt die wesentlichen Inhalte sowie die wichtigsten Änderungen der TRGS 510 "Lagerung von Gefahrstoffen in ortsbeweglichen Behältern" vor. Die TRGS 510 zeichnet sich durch ein gestuftes Maßnahmenkonzept in Abhängigkeit von der Art und Menge der gelagerten Gefahrstoffe aus. Folgende Maßnahmenstufen werden durch die TRGS 510 beschrieben: 1. Kleinmengen -> Allgemeine Maßnahmen 2. Überschreitung der Kleinmengen -> Lagerung im Lager 3. Überschreitung bestimmter Mengen für spezielle Gefahrstoffe -> Spezielle Maßnahmen 4. Verschiedene Gefahrstoffe und Lagerung im Lager erforderlich -> ggf. Getrenntlagerung und Separatlagerung T2 - Schulungsveranstaltung der Länder für den Vollzug / die Gewerbeaufsicht CY - Online meeting DA - 16.05.2024 KW - Gefahrstoffe KW - Gefahrstoffverordnung KW - Lagerung KW - TRGS KW - Technische Regeln für Gefahrstoffe PY - 2024 AN - OPUS4-60049 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Seeber, Henrik A1 - Grobert, Steffen A1 - Krentel, Daniel T1 - Investigation of intracorporeal shock wave propagation using a simplified torso model and a shock wave generator –a progress report N2 - Following directly from the information presented at IFBIC 2023 on the research project 'Investigation of intracorporeal shock wave propagation using a simplified torso model and a shock wave generator', the latest results are presented below [1]. In order to contribute to the research efforts on the primary explosion effects, the aim of the investigation is the development of a multidisciplinary method to investigate shock wave behavior in various generic tissue simulants under the most reproducible conditions possible with realistic loads in an experimental series with short set-up times. To achieve this, an autoclave with a volume of 0.065 m3 is used to generate reproducible pressure waves (Fig. 1). The autoclave will be referred to as Shockwave Generator (SWG). The pressure wave is produced by the detonation of a stoichiometric mixture of acetylene and oxygen under atmospheric conditions. The SWG-outlet is sealed by a rupture disc, which can be adjusted in thickness to vary the initial pressure. Additionally, modifying the composition of the acetylene-oxygen mixture can result in different load cases. The SWG requires approximately 30 minutes of set-up time between trials. The SWG was adjusted to match the characteristics of a real and typical explosive through free-field measurements. The experiments demonstrated that the pressure wave propagates in a hemispherical shape and has sufficient reproducibility. To represent soft tissue, a basic model made of homogeneous ballistic gelatin is used in a geometrically simplified torso model (STM) (Fig. 2). The STM was enlarged to outer dimensions of 400 x 250 x 240 mm. Viscoelastic behavior of the ballistic gelatin can be assumed due to the collagen structure [2]. The density of the ballistic gelatin, and therefore the sound velocity, can be adjusted by changing the mixing ratio. Simplified simulants, such as hollow and solid material (bone simulant), were embedded in the STM. Additionally, the STM has been tested as a carrier material for biological substances, such as indicator species. The next step is to test the STM as a carrier material for larger organic tissue structures such as lungs or kidneys. The organic tissue samples will undergo histological examination to analyze their structural changes afterwards. The STM is equipped with embedded piezoelectric pressure sensors, an accelerometer and a temperature sensor. Visual documentation is captured using a high-speed camera. This measurement setup allows for the tracking of the coupled pressure wave and its behavior within the model and at the media transitions. Pressure values can be recorded after certain media changes, such as from soft tissue to a solid material (Figure 3). The following is a review of the optimizations made to the entire experimental setup. The reproducibility of the SWG was increased. This was achieved by extending the evacuation process to the entire feed system of the SWG. Nitrogen residues in the SWG system can thus be avoided. As a result, the double peaks that occur at the first maximum can be avoided, as combustion runs more evenly without the nitrogen residues. In addition, partially varying peak overpressures can be avoided, as the acytelene-oxygen mixture is not too lean due to the elimination of the nitrogen residues. The workflow has been streamlined, resulting in an average set-up time of 25 minutes for the SWG. In the case of the STM, the manufacturing process in particular was optimized by examining and defining the manufacturing process based on scientific publications, which increases the reproducibility of the STM base bodies. As already mentioned in the previous paragraph, the STM was equipped with various additives in order to investigate the transition behavior of the pressure wave. The following trail serves as an example: A comparison is made between the STM in the basic structure (Fig. 2 l.s.) and with an embedded solid material (bone plate) (Fig. 3 l.s.). An external overpressure of 100 kPa is generated by the SWG at a distance of 1 m, where the STM is placed. For the basic STM structure, the sensor distance is consistently 100 mm. The internal overpressure is visible in Fig. 2 r.s.. A typical ideal pressure curve can be seen. The characteristic points are easily distinguishable from the reflection peaks. In the STM with an embedded solid material, the sensor distance remains consistently at 66.6 mm T2 - 8th International Forum on Blast Injury Countermeasures CY - Washington D.C., USA DA - 01.05.2024 KW - Shock wave generator KW - Blast injury KW - Primäre Explosionswirkung KW - Experimental setup PY - 2024 AN - OPUS4-60044 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Altmann, Korinna A1 - Milczewski, Frank A1 - Ciornii, Dmitri A1 - Hodoroaba, Dan T1 - Preliminary results of an interlaboratory comparison on microplastics organised by plasticsfate N2 - Microplastics are everywhere in the environment, but analytics is challenging. Since harmonisation is missing as well es suitable reference materials, BAM did under th umbrella of VAMAS funded by the EU Horizon 2020 project PlasticsFate a ILC for microplastic detection methods. Methods adressed were IR, Raman, Py-GC/MS and TED-GC/MS. The talk gives a first presentation and evaluation on the results. T2 - CUSP annual meeting and conference CY - Utrecht, Netherlands DA - 12.09.2023 KW - Microplastics KW - TED-GC/MS KW - Polymer 3R KW - Reference material KW - ILC on detection methods PY - 2023 AN - OPUS4-60036 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Giovannozzi, A A1 - Altmann, Korinna A1 - Wiesner, Yosri T1 - Metrological traceability of measurement data from nano- to small microplastics for a greener environment and food safety N2 - This talk descibes the EMPIR project PlasticTrace. Reference materials for microplastics will be developed. The production process and characterisation is explained by SEM, Raman, IR, Py-GC/MS and TED-GC/MS. Homogeneity control was successful. Stability check show no changes over 6 month. T2 - SETAC Europe 2024 CY - Sevilla, Spain DA - 05.05.2024 KW - Microplastics KW - Reference materials KW - Polymer 3R KW - TED-GC/MS PY - 2024 AN - OPUS4-60033 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Dalgic, Mete-Sungur T1 - Lösemittelfreie Probenpräparation zur Untersuchung von Polymerblends mittels MALDI-TOF MS N2 - Die Probenpräparation ist ein wichtiger Schritt für die Qualität der Massenspektren in MALDI-TOF MS. Es werden Polymerproben, die lösungsmittelbasiert und lösungsmittelfrei präpariert worden sind, verglichen. Dabei werden die Intensitätsverhältnisse von ternären Mischungen von PEG-, PS- und PMMA-Polymeren beachtet. T2 - 28. Kolloquium - Massenspektrometrische Techniken zur Untersuchung synthetischer Polymere CY - Berlin, Germany DA - 14.05.2024 KW - Polymere KW - Massenspektrometrie KW - Probenpräparation PY - 2024 AN - OPUS4-60032 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Weidner, Steffen A1 - Kricheldorf, H. T1 - MALDI TOF MS zur Aufklärung von Kristallisationsprozessen in Polyestern N2 - MALDI TOF Massenspektrometrie wurde verwendet, um Kristallisationsprozesse in Polyestern (Polylactide, Polyglycolide) zu untersuchen. Dabei konnte gezeigt werden, dass Zyklen und Linearen simultan, aber in unterschiedlichen Kristalliten, kristallisieren. Die dabei ablaufenden Umesterungen (Transesterifizierungen) konnten mit der MALDI TOF Massenspektrometrie nachgewiesen werden. Damit wurde ein völlig neues Anwendungsgebiet dieser MS Methode demonstriert. T2 - 28. Kolloquium Massenspektrometrie von Polymeren CY - Berlin, Germany DA - 14.05.2024 KW - MALDI TOF MS KW - Bioabbaubare Polymere KW - Crystallinity PY - 2024 AN - OPUS4-60029 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Heinekamp, Christian A1 - Guiherme Buzanich, Ana A1 - Ahrens, Mike A1 - Emmerling, Franziska A1 - Braun, Thomas T1 - An Amorphous Lewis-acidic Zirconium Chlorofluoride as HF Shuttle: C-F Bond Activation and Formation N2 - In recent years, fluorine chemistry has gained increasing political attention. Owing to a growing shortage of fluorspar, a raw material used for producing fluorinated base chemicals, fluorospar has been named among the 30 critical raw materials in the EU.2 As such, it becomes increasingly important to recycle existing fluorinated compounds and make them available as sources of fluorine for reactions. Significant progress has been made in the field of C-F bond activation using heterogeneous catalysts such as aluminum chlorofluoride (ACF).3–5 However, the transfer of fluorine atoms from one molecule to another using heterogeneous catalysts has not yet been reported. In this study, we successfully synthesized amorphous zirconium chlorofluoride (ZCF), and we were able to establish a catalytic behavior of ZCF in C-F bond activation reactions. We present a heterogeneous catalyst that performs dehydrofluorination of a fluoroalkane and consecutive hydrofluorination of an alkyne at room temperature. T2 - 2nd South African Fluorine Symposium CY - Sun City, South Africa DA - 09.02.2024 KW - ZCF KW - Heterogeneous catalysis KW - C-F bond activation KW - HF-shuttle PY - 2024 AN - OPUS4-59618 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Heinekamp, Christian A1 - Guiherme Buzanich, Ana A1 - Ahrens, Mike A1 - Emmerling, Franziska A1 - Braun, Thomas T1 - Exploring amorphous lewis-acidic zirconium chloro fluoride as a heterogeneous HF shuttle N2 - Owing to a growing shortage of fluorspar, a raw material used for producing fluorinated base chemicals, fluorspar has been named among the 30 critical raw materials in the EU. 1 However, the sustainable transfer of fluorine atoms from one molecule to another using heterogeneous catalysts has not yet been reported. Herein, we present the heterogeneous catalyst zirconium chloro fluoride (ZCF) that performs dehydrofluorination of a fluoroalkane and consecutive hydrofluorination of an alkyne at room temperature. T2 - Make and Measure 2023 CY - Berlin, Germany DA - 13.09.2023 KW - ZCF KW - Heterogeneous catalysis KW - C-F bond activation KW - HF-shuttle PY - 2023 AN - OPUS4-59616 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Wiesner, Yosri A1 - Giovannozzi, A.M. A1 - Fadda, M. A1 - Sacco, A. A1 - Putzu, M. A1 - Norberta, S. A1 - Lorenzo, M. A1 - Miclea, P.-T. A1 - Benismail, N. A1 - Maltseva, A. A1 - van Bavel, B. A1 - Altmann, Korinna T1 - Reference material candidates for Microplastic analysis N2 - Microplastic reference material is required for validation and harmonization purposes. This includes the analysis of the pure polymer particles and the validation of the respective measurement methods. In addition, there is the harmonization of different laboratories. On the other hand, sample preparation methods must be validated and harmonized with regard to their recovery and subsequent analysis in the respective matrices. For this purpose, we produce reference material candidates in the form of tablets with different mass fractions and particle numbers of polyethelene terephthalate. In the presentation first measurement results by µ-Raman, µ-FTIR, pyrolysis-GC-MS and TED-GC/MS will be presented. T2 - SETAC Europe 34th Annual Meeting CY - Seville, Spain DA - 05.05.2024 KW - Reference material KW - Microplastics KW - PlasticTrace PY - 2024 AN - OPUS4-60019 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien T1 - Nondestructive defect characterization using full-frame spatially structured super resolution laser thermography N2 - Die laserbasierte aktive thermografische Prüfung als berührungslose Methode der zerstörungsfreien Werkstoffprüfung (NDT) basiert auf der aktiven Erwärmung des Testobjekts (OuT) und Messung des resultierenden Temperaturanstiegs mit einer Infrarotkamera. Dadurch bedingt können systematische Abweichungen vom vorhergesagten Erwärmungsverhalten Aufschluss über dessen innere Struktur geben. Jedoch ist das Auflösungsvermögen für innenliegende Defekte durch die diffusive Natur der Wärmeleitung in Festkörpern begrenzt. Thermografische Super-Resolution (SR)-Methoden zielen darauf ab, diese Limitation durch die Kombination mehrerer Messungen mit jeweils unterschiedlicher strukturierter Erwärmung und mathematischer Optimierungsmethoden zu überwinden. Zur Rekonstruktion innerer Defekte mithilfe thermografischer SR-Rekonstruktionsmethodik wird für die Gesamtheit mehrerer Messungen ein schlecht gestelltes und stark regularisiertes inverses mathematisches Problem gelöst, was in einer dünnbesetzten Karte der internen Defektstruktur des OuTs resultiert. Der vorliegende Vortrag gibt einen Überblick über die geleisteten Arbeiten in diesem Gebiet im Rahmen der hier mit dem Wissenschaftspreis der DGZfP 2024 prämierten Arbeit. T2 - Jahrestagung der Deutschen Gesellschaft für Zerstörungsfreie Prüfung (DGZfP) 2024 CY - Osnabrück, Germany DA - 06.05.2024 KW - Thermografie KW - Laser KW - ZfP KW - Super-Resolution KW - DLP KW - DMD PY - 2024 AN - OPUS4-60007 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Falkenhagen, Jana T1 - Biobased and biodegradable Polymers: Analytical Challenges N2 - The variability and heterogeneity in their structural composition is significant for nearly all synthetic and natural polymers. Beside molar mass also functionality type distribution, copolymer composition distribution and architectural features are responsible for changing the material properties. A wide range of analytical techniques are available to get insight into these parameters. However, in most cases it is essential to combine different sophisticated techniques to get closer to actual structures and to avoid statistical averages. Different liquid chromatographic separation modes and their coupling in a two-dimensional way (SEC, LCCC, HILIC, 2D-LC) in combination with suitable detection techniques (e.g. UV, RI, LS, IR, MALDI/ESI-MS) as well as techniques like BET, DCS, SEM/TEM were applied to make structural features visible. A few aspects are discussed for structural different polylactides from various synthesis routes and their behavior in LC-MS. T2 - 34th International Symposium on Polymer Analysis and Characterization (ISPAC) CY - Stellenbosch, South Africa DA - 24.04.2023 KW - Biobased polymers KW - Biodegradable polymers KW - Analytical techniques PY - 2023 AN - OPUS4-60002 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Konert, Florian T1 - Deep Dive: Visualizing hydrogen assisted cracks in hollow specimens utilizing µCT N2 - The Deep-Dive provides a short introduction and summary of the performed tests on API X65 Pipelinesteels. The aim of the tests is the visualization of hydrogen assisted crack popagation in hollow specimens. T2 - DAAD Green Hydrogen Workshop CY - Online meeting DA - 07.05.2024 KW - Hydrogen KW - Hollow specimen technique KW - µCT KW - Hydrogen embrittlement KW - Pipeline steel PY - 2024 AN - OPUS4-60001 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Krentel, Daniel A1 - Patzelt, Katrin T1 - Bedarfserhebung für BOS am Beispiel des Projekts InnoBOSK N2 - Im Rahmen des Vortrags wurden die Ergebnisse und die Methodik zur Erhebung von Forschungsbedarfen und Fähigkeitslücken bei den Behörden und Organisationen mit Sicherheitsaufgaben, welche im Rahmen des Projektes InnoBOSK durchgeführt wurden, vorgestellt. Den Schwerpunkt bildete dabei die Umsetzung der Workshops gemeinsam mit den Einsatzkräften und die Umsetzung der problemorientierten Erhebungsmethodik. T2 - Vorstellung im Rahmen eines SiFo-Workshops der Polizei Berlin CY - Berlin, Germany DA - 29.04.2024 KW - Bedarfserhebung KW - SiFo KW - Sicherheitsforschung KW - BOS PY - 2024 AN - OPUS4-59983 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Munsch, Sarah Mandy A1 - Telong, Melissa A1 - Grobla, Lili A1 - Schumacher, Katrin A1 - Völker, Christoph A1 - Yared, Kaleb A1 - Kruschwitz, Sabine T1 - Study on the predictability of carbonation resistance of cementitous materials based on nmr features and the use of slamd N2 - This study explores the acceleration of material design in the concrete industry, focusing on improving carbonation resistance, a key factor in the durability of concrete structures. Traditional tests for carbonation resistance are lengthy, but with the construction industry aiming for sustainable production, finding a balance between carbonation resistance and CO2 footprint is crucial. Our research employs two innovative methods: 1. Applying the Sequential Learning App for Materials Discovery (SLAMD), an AI materials design framework, to an extensive dataset of real-world concrete compositions to selectively test materials that meet market demands: maximum durability, optimal eco-durability, and the best cost-durability trade-off. 2. Investigating 1H Nuclear Magnetic Resonance (NMR) relaxometry as a quick alternative for characterizing carbonation behavior, as it saves time compared to traditional tests and assesses the complete material's pore space. Specific NMR features are then integrated into the material design model, with the model's performance compared against traditional approaches. The results of our study are compelling, demonstrating that materials can be precisely tailored to meet specific requirements with minimal data points. This marks a significant stride in the concrete industry, indicating that NMR-based, low-fidelity surrogate characterizations, combined with a focused, data-driven design approach, can substantially accelerate the development of durable, sustainable concrete mixtures. T2 - Rilem Spring Convention & Conference CY - Milan, Italy DA - 10.04.2024 KW - Nuclear magnetic resonance KW - Carbonation resistance KW - Cement and concrete KW - SLAMD app KW - Predictability PY - 2024 AN - OPUS4-60000 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Unger, Jörg F. T1 - Coupling of structural and material design N2 - The presentations discusses a use case for the optimization of concrete structures where structural and material design are integrated in a computational workflow. The workflow is based on both physics-based and data-based models and experimental data is used to calibrate/train these models with a specific focus on the integration of ucertainties. T2 - 2nd Technical Meeting of TG.SAG.2 CY - Hannover, Germany DA - 16.04.2024 KW - Coupling of structural and material design KW - Cement Hydration Model PY - 2024 AN - OPUS4-59999 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - George, Janine T1 - New Opportunities for Data-Driven Chemistry and Materials Science Through Automation N2 - In recent years, many protocols in computational materials science have been automated and made available within software packages (primarily Python-based). This ranges from the automation of simple heuristics (oxidation states, coordination environments) to the automation of protocols, including multiple DFT and post-processing tools such as (an)harmonic phonon computations or bonding analysis. Such developments also shorten the time frames of projects after such developments have been made available and open new possibilities. For example, we can now easily make data-driven tests of well-known rules and heuristics or develop quantum chemistry-based materials descriptors for machine learning approaches. These tests and descriptors can have applications related to magnetic ground state predictions of materials relevant for spintronic applications or for predicting thermal properties relevant for thermal management in electronics. Combining high-throughput ab initio computations with fitting, fine-tuning machine learning models and predictions of such models within complex workflows is also possible and promises further acceleration in the field. In this talk, I will show our latest efforts to link automation with data-driven chemistry and materials science. T2 - MRS Spring CY - Seattle, Washington, USA DA - 21.04.2024 KW - Automation KW - Workflows KW - Chemical Bonding KW - Thermal Properties KW - Materials Design PY - 2024 AN - OPUS4-59982 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Simon, Franz-Georg A1 - Scholz, Philipp A1 - Gleis, Markus T1 - Aschen und Schlacken aus der Abfallverbrennung im Lichte der Ersatzbaustoffverordnung N2 - Im Rahmen eines vom Umweltbundesamt geförderten Forschungsprojekts wurde untersucht, ob die Abtrennung der Feinfraktion (0-2 mm) eine Verbesserung der umweltrelevanten Eigenschaften bewirkt und somit HMVA-1 erreicht werden kann. In Deutschland wird die Rostasche durch Nassentschlackungssysteme aus dem Feuerraum ausgetragen. Durch den Kontakt mit Wasser setzen direkt hydraulische Reaktionen ein, die eine vollständige Abtrennung der Feinfraktion unmöglich machen. Das wurde bereits in den 1990er Jahren erkannt und führte zur Entwicklung des ABB InRec Verfahrens mit Trockenentaschung als ersten Verfahrensschritt. Auch damals war das Ziel eine möglichst inerte Rostasche für die Verwertung zu erzeugen. In den letzten Jahren wurden in der Schweiz Trockenentaschungssystem installiert, hier vor allem um die Rückgewinnung von elementaren Metallen auch in der Feinfraktion zu verbessern. Welche Potenziale sich dabei erschließen lassen, wurde in einem anderen UBA-Projekt untersucht. Im Rahmen unserer Arbeiten wurde versuchsweise trockene Rostasche an einer Anlage in Süddeutschland genommen und im Labor untersucht. Im Vortrag werden die Ergebnisse zum Auslaugverhalten und zur Gefahreneigenschaft HP14 (Ökotoxizität) vorgestellt. T2 - Jahrestreffen 2024 der DECHEMA-Fachgruppen Abfallbehandlung und Wertstoffrückgewinnung (AuW) und Gasreinigung (GAS) CY - Dresden, Germany DA - 25.03.2024 KW - Rostasche KW - Ersatzbaustoffe PY - 2024 AN - OPUS4-59985 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Beygi Nasrabadi, Hossein A1 - Skrotzki, Birgit T1 - Digital representation of materials testing data for semantic web analytics: Tensile stress relaxation testing use case N2 - This study aims to represent an approach for transferring the materials testing datasets to the digital schema that meets the prerequisites of the semantic web. As a use case, the tensile stress relaxation testing method was evaluated and the testing datasets for several copper alloys were prepared. The tensile stress relaxation testing ontology (TSRTO) was modeled following the test standard requirements and by utilizing the appropriate upper-level ontologies. Eventually, mapping the testing datasets into the knowledge graph and converting the data-mapped graphs to the machine-readable Resource Description Framework (RDF) schema led to the preparation of the digital version of testing data which can be efficiently queried on the web. T2 - ICMDA 2024: 7th International Conference on Materials Design and Applications CY - Tokyo, Japan  DA - 09.04.2024 KW - Digitalization KW - Tensile stress relaxation KW - Ontology KW - Mechanical testing KW - Semantic web PY - 2024 AN - OPUS4-59979 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Rhode, Michael A1 - Richter, Tim A1 - Erxleben, Kjell A1 - Schröpfer, Dirk A1 - Witt, Julia A1 - Özcan-Sandikcioglu, Özlem A1 - Kannengießer, Thomas T1 - Processing and application properties of multiple principal element alloys (MPEA) N2 - The presentation gives an overview of BAM's activities on processing influences and application properties of MPEAs in the form of joined and machined high and medium entropy alloys (CoCrFeMnNi and CoCrNi). In the case of welding, the focus is on defect-free welded joints with sufficient mechanical properties. In the case of machining, the focus is on the possible influence on the surface quality of the materials through adequate milling parameters. In addition, the hydrogen absorption and diffusion properties as well as the electrochemical corrosion behavior are fundamentally examined. T2 - FAU-Department Werkstoffwissenschaften, Seminar: Aktuelle Probleme der Werkstoffwissenschaften CY - Erlangen, Germany DA - 25.04.2024 KW - Welding KW - Application properties KW - Machining KW - High-entropy alloy KW - Hydrogen PY - 2024 AN - OPUS4-59975 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien T1 - Automatisierte aktive thermografische Prüfung N2 - Aktive thermografische Prüfung ist ein vielseitiges Instrument in der Familie der zerstörungsfreien Prüfverfahren. Der Einzug moderner Lasertechnologie hat hier bedeutende neue Anwendungsfelder eröffnet. In Kombination mit Industrierobotik können nun beispielsweise beliebig komplex geformte Bauteile großflächig vollautomatisiert auf Oberflächenrisse überprüft werden. Der hier vorliegende Vortrag gibt einen Überblick über die Grundlagen der Laserthermografie, zeigt unsere Anstrengungen am Fachbereich im Bereich der automatisierten thermografischen Detektion von Oberflächenrissen und gibt ein Ausblick über neue moderne Thermografieverfahren aus der Forschung. T2 - VATH Frühjahrssymposium CY - Lingen, Germany DA - 26.04.2024 KW - Thermografie KW - Laser KW - ZfP PY - 2024 AN - OPUS4-59965 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Skrotzki, Birgit A1 - Gesell, Stephan A1 - Rehmer, Birgit A1 - Fedelich, Bernard T1 - Fatigue Crack Growth of Heat Resistant Austenitic Cast Iron under Isothermal and Anisothermal Conditions N2 - The heat-resistant cast iron EN-GJSA-XNiSiCr35-5-2 (Ni-Resist D-5S) was investigated for its fatigue crack growth behavior at room and high temperatures. Force-controlled tests were carried out at constant temperatures (20 °C, 500 °C, 700 °C) without and with hold time and different load ratios. The crack growth behavior was also characterized under TMF loading (Tmin = 400 °C, Tmax = 700 °C) by applying IP and OP conditions and different load ratios. Three different techniques were combined to monitor crack growth: potential drop, thermography, and compliance method. The effect of the different loading conditions on the fatigue crack growth behavior will be presented and discussed. T2 - TMF Workshop 2024 CY - Berlin, Germany DA - 25.04.2024 KW - Fatigue crack growth KW - Thermomechanical fatigue KW - Austenitic cast iron KW - Ni-Resist PY - 2024 AN - OPUS4-59964 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Grimmer, Christoph A1 - Strzelczyk, Rebecca A1 - Richter, Matthias A1 - Musyanovych, Anna A1 - Horn, Wolfgang T1 - Development, application and measurement uncertainty of emission reference materials N2 - Volatile organic compounds (VOCs) emitted by furniture and building materials can cause health issues. For an improvement of indoor air quality low emitting materials should be used. Quality assurance and –control (QA/QC) measures require an emission reference material (ERM) with a predictable emission rate of VOCs. The idea is to use porous materials as ERM, which store the VOCs inside their pores and emit them constantly. T2 - Webinar Metrology for Indoor Air Quality Reference materials for QA/QC of the emission test chamber procedure CY - Online meeting DA - 11.04.2024 KW - Emission reference materials KW - Indoor air quality KW - Materials emissions test KW - VOC PY - 2024 AN - OPUS4-59963 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Nikoonasab, Ali A1 - Licht, M. A1 - Weiler, L. A1 - Achenbach, R. A1 - Raupach, M. A1 - Gluth, Gregor T1 - Pore Solution composition of GGBFS-containing cement pastes N2 - Ground Granulated Blast-Furnace Slag (GGBFS), a by-product of the iron-making process, has gained significant attention as a supplementary cementitious material and has become increasingly popular in recent years due to its remarkable properties. GGBFS can significantly reduce the environmental impact of cement production when it comes to building concrete structures. GGBFS can either be blended with ordinary Portland cement (OPC) (up to a 90% replacement), or it can be used in the production of alkali-activated materials (AAMs). However, a comprehensive understanding of the pore solution composition is necessary for understanding various aspects of cementitious materials and their durability, including corrosion behavior, passivation of steel, and resistance to deteriorative processes. In the present work, the pore solutions of seven different GGBFS-containing cements (alkali-activated slag, alkali-activated slag/fly ash blends, a hybrid alkaline cement, CEM III/C, and CEM III/B) were extracted and analysed by inductively coupled plasma-optical emission spectroscopy, ion chromatography, pH, redox potential, and conductivity measurements. For comparison, a Portland cement pore solution was analysed similarly. The Concentrations of reduced sulfur were noteworthy in all GGBFS-containing cements, particularly in alkali-activated cements, where concentrations were notably higher compared to standard cements. The redox potentials of the pore solutions were primarily dictated by the concentrations of reduced sulfur, although other factors may contribute. Additionally, sulfur species in the pore solutions had an impact on pH, electrical conductivity, and other properties pertinent to the corrosion of reinforcements. T2 - RILEM Spring Convention 2024 & Conference on Advanced Construction Materials and Processes for a Carbon Neutral Society CY - Milan, Italy DA - 10.04.2024 KW - GGBFS KW - AAM KW - Sulfide KW - Pore solution composition KW - Redox potential PY - 2024 AN - OPUS4-59960 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Grimmer, Christoph A1 - Richter, Matthias A1 - Musyanovych, Anna A1 - Strzelczyk, Rebecca A1 - Horn, Wolfgang T1 - Preparation of novel emission reference materials: μ-capsules & impregnated porous materials N2 - Volatile organic compounds (VOCs) emitted by furniture and building materials can cause health issues. For an improvement of indoor air quality low emitting materials should be used. Quality assurance and –control (QA/QC) measures require an emission reference material (ERM) with a predictable emission rate of VOCs. The idea is to use porous materials as ERM, which store the VOCs inside their pores and emit them constantly. T2 - WORKSHOP: METROLOGY FOR INDOOR AIR QUALITY CY - Mol, Belgium DA - 18.10.2023 KW - Emission reference materials KW - Indoor air quality KW - Materials emissions test KW - VOC PY - 2023 AN - OPUS4-59961 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Engelking, Lorenz A1 - Schröpfer, Dirk A1 - Kannengießer, Thomas A1 - Eissel, A. A1 - Treutler, K. A1 - Wesling, V. T1 - Herstellung beanspruchungsgerechter Oberflächen durch Kombination innovativer additiver und abtragender Fertigungsschritte an hochbelasteten Komponenten N2 - Die additive Fertigung mittels Schweißverfahren bietet große ökonomische Vorteile für eine ressourceneffiziente Bauteilherstellung. Offene Fragen bezüglich Homogenität, Anisotropie der Schweißgefüge und den damit verbundenen Bauteileigenschaften stehen einer wirtschaftlichen Verarbeitung oftmals im Wege. Finale Bauteilgeometrie und Oberflächengüte erfordern meist komplementäre subtraktive Fertigungsschritte. Werkstoffe für hochbelastbare Komponenten sind oftmals schwer spanbar. In einem Vorhaben der BAM und des ISAF wurde untersucht, wie die Modifikation der AM-Schweißzusätze und das ultraschallunterstützte Fräsen (US) die Zerspanungssituation verbessern. Der vorliegende Artikel stellt wesentliche Zusammenhänge zwischen Legierung, Gefüge und Zerspanung zweier schwer spanbarer Hochleistungslegierungen (FeNi und CoCr) dar. Großes Potenzial zeigte neben dem US die Modifikation mit Zr und Hf bei Zulegierung in das Schweißgut mittels Beschichtung von Massivdrähten bzw. Herstellung von Fülldrähten. T2 - Innovationstag 2024 CY - Düsseldorf, Germany DA - 10.04.2024 KW - Legierungsmodifikation KW - Ultraschallunterstütztes Fräsen KW - Additive Fertigung KW - Oberflächenintegrität PY - 2024 AN - OPUS4-59958 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Burkert, Andreas A1 - Lehmann, Jens T1 - Innovation und Sicherheit durch Einsatz von Duplexstählen in Straßentunneln N2 - Es werden die Ergebnisse eines mehrjährigen Forschungsvorhabens der BAM in Zusammenarbeit mit Straßenbauverwaltungen der Länder und Industriebeteiligten zur betriebstechnischen Ausrüstung von Straßentunneln präsentiert. Schwerpunkte waren die Bestimmung der Korrosivität der Atmosphäre von 3 ausgewählten Straßentunneln, die Analyse korrosionsrelevanter Ablagerungen und von Klimadaten. Die Auswirkungen dieser Einflussgrößen auf die Dauerhaftigkeit von Konstruktionen aus nichtrostenden Stählen wurde ermittelt und in Abhängigkeit verschiedener Einflussparameter dargestellt. Die Ergebnisse der systematischen Untersuchungen an Prüfköpern decken sich mit Beobachtungen an realen Bauteilen. Spaltbehaftete Konstruktionen aus Werkstoffen der CRC III führen demnach in Zeiträumen zwischen 10 und 15 Jahren zu Korrosionserscheinungen, welche die technische Sicherheit beeinträchtigen können und die erwartete Dauerhaftigkeit nicht erfüllen. Die Folge sind zusätzliche Sperrungen und ein vorzeitig notwendiger Unterhaltsaufwand, die erhebliche Kosten verursachen. Im Ergebnis ist eine Überarbeitung des aktuellen Regelwerkes erforderlich, um die angestrebte Dauerhaftigkeit von 30 Jahren zu gewährleisten. T2 - Sitzung ISER Marketingausschuss CY - Dusseldorf, Germany DA - 24.04.2024 KW - Korrosion KW - Straßentunnel KW - Dauerhaftigkeit KW - Nichtrostender Stahl PY - 2024 AN - OPUS4-59955 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Abad Andrade, Carlos Enrique T1 - Optical spectrometry for isotope analysis N2 - Isotope analysis plays a critical role in various disciplines, including environmental science, archaeology, and forensic investigations. Traditional methods such as mass spectrometry provide precise isotopic data but often require complex, costly setups and extensive sample preparation. As an alternative, optical spectrometry has emerged as a versatile and less invasive technique. This presentation explores the advancements and applications of optical spectrometry methods in isotope analysis, emphasizing their benefits and challenges. T2 - University of Calgary PHYS 561 - Stable And Radioactive Isotope - Winter 2024 CY - Online meeting DA - 07.03.2024 KW - Isotopes KW - HR-CS-MAS KW - Chemometrics KW - Laser Ablation Molecular Absorption spectrometry KW - LAMIS PY - 2024 AN - OPUS4-59948 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Abad Andrade, Carlos Enrique A1 - Winckelmann, Alexander A1 - Morcillo, Dalia A1 - Jegieka, Dennis A1 - Vogl, Jochen A1 - Florek, S. A1 - Recknagel, Sebastian T1 - Isotope analysis through the integration of chemometrics into optical spectroscopy N2 - Lithium (Li), Boron (B), Nitrogen (N), Magnesium (Mg), and Calcium (Ca) are pivotal elements across various spheres such as the hydrosphere, biosphere, and lithosphere, significantly impacting (bio-) geochemical and physiological processes. These elements exhibit stable isotopes with substantial roles in geological, environmental, and biological studies. The traditional method for measuring isotope amount ratios has been through mass spectrometry, which, despite its accuracy, comes with high operational costs, the need for skilled operators, and time-consuming sample preparation processes. Combining optical spectroscopy with chemometrics introduces an innovative, cost-effective approach by the hand of high-resolution continuum source atomic and molecular absorption spectrometry (HR-CS-AAS and HR-CS-MAS) for the analysis of isotope ratios in Li, B, N, Mg, and Ca. By analyzing the atomic or molecular absorption spectrum of the in-situ generated cloud of atoms of diatomic molecules (e.g., Li, BH, NO, MgF, CaF) during the electronic transition from the fundamental state, this method allows for the rapid determination of isotope ratios directly from sample solutions without the need for complex sample preparation. For each element, the respective atomic or molecule's absorption spectrum was deconvoluted into its isotopic components using partial least squares regression or machine learning algorithms. Robust calibration models were developed, calibrated with enriched isotope, and validated against certified reference materials. Spectral data underwent preprocessing to optimize the modeling to determine the optimal number of latent variables. The findings showcase that this optical spectrometric method yields results that agree with those obtained via inductively coupled plasma mass spectrometry (ICP-MS), offering a promising, cost-effective, and rapid alternative for isotope analysis with precisions as low as ± 0.2‰. This approach is a significant advancement in analytical chemistry, providing a new way to study isotope variations in biological, environmental, and geological samples. T2 - Analytica Conference CY - Munich, Germany DA - 09.04.2024 KW - Isotopes KW - HR-CS-MAS KW - Chemometrics KW - Lithium KW - Boron KW - Magnesium KW - Nitrogen PY - 2024 AN - OPUS4-59946 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Abad Andrade, Carlos Enrique A1 - Winckelmann, Alexander A1 - Hoffmann, Volker A1 - You, Zengchao A1 - Richter, Silke A1 - Recknagel, Sebastian T1 - What does GD-OES reveal about the aging and manufacturing processes of lithium-ion batteries? N2 - Glow-Discharge Optical Emission Spectroscopy (GD-OES), a powerful analytical technique, sheds light on the two critical aspects of lithium-ion batteries (LIBs): manufacturing and aging 1, 2. We optimized cell production in manufacturing by adjusting parameters, including cathode doping, electrolyte concentration, and pressing force. GD-OES provided in-depth elemental composition and homogeneity analysis, which is crucial for identifying optimal manufacturing conditions. These findings were validated by electrochemical impedance spectroscopy, confirming the quality of the manufactured batteries. Shifting the focus to aging, we use GD-OES for fluorine depth profiling, a key element in understanding polymer and electrolyte degradation. However, fluorine presents analytical challenges. We addressed this by substituting argon with a neon:argon mixture, which significantly enhanced fluorine detection sensitivity. This advancement not only improves accuracy but also holds the potential to guide sustainable and cost-efficient manufacturing strategies. Through its versatility, GD-OES has proven to be a powerful tool for not only optimizing LIB manufacturing processes but also gaining deeper insights into their aging mechanisms. This research extends beyond academic interest, offering tangible benefits for the industry by translating into improved battery quality, extended lifespan, and overall performance. T2 - The 6th International Glow Discharge Spectroscopy Symposium CY - Liverpool, United Kingdom DA - 21.04.2024 KW - GD-OES KW - Depth profiles KW - Lithium KW - Battery KW - Fluorine KW - Aging KW - Manufacturing KW - Glow-discharge PY - 2024 AN - OPUS4-59945 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Kromm, Arne T1 - Spannungen beim Schweißen von Bauteilen N2 - Der Vortrag gibt einen Überblick über das Phänomen der Schweißeigenspannungen. Es wird auf die Bedeutung und Entstehungsursachen eingegangen. Mit besonderem Fokus auf die Eigenspannungen beim Schweißen von Komponenten werden Messmöglichkeiten und Anwendungsbeispiele vorgestellt. T2 - Jahresmitgliederversammlung DVS Bezirksverbandes Berlin CY - Berlin, Germany DA - 24.04.2024 KW - Eigenspannungen PY - 2024 AN - OPUS4-59944 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Lecompagnon, Julien T1 - Lasers: A versatile Heat Source for Modern Active Thermographic Testing N2 - The properties of laser radiation result in a wide range of applications, making laser technologies indispensable in areas such as industry, science and medicine. The possible areas of application for thermography in this context are just as diverse. Thermography is used in laser applications when permanent monitoring and control of thermal development is necessary. Among others, this is the case in additive manufacturing, laser-based measuring devices and non-destructive testing. Furthermore, thermography is ideally suited as a testing method when it comes to ensuring the quality of the laser itself. In this talk it is outlined, how lasers can be used as a heat source in active thermographic testing. Furthermore, two special variants (spatial & temporal structured heating) are described, for which lasers are highly suitable. T2 - Webinar: Laser Technologies Benefiting from Infrared Thermography CY - Online meeting DA - 24.04.2024 KW - Thermography KW - Laser KW - NDT PY - 2024 UR - https://www.infratec.eu/press/press-releases/details/2024-03-04-laser-technologies-benefiting-from-infrared-thermography/ AN - OPUS4-59934 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Soruco Aloisio, Ricardo A1 - Klaus, Christian A1 - Klaus, Christian T1 - Auf dem Weg zu einer digitalen Qualitätsinfrastruktur - Use Case Wasserstofftankstelle N2 - Im Rahmen der von der BAM und anderen Partnern ins Leben gerufenen Initiative „Digitale Qualitätsinfrastruktur“ liegt der Fokus u.a. auf der Entwicklung von neuen Zertifizierungsworkflows. Dabei ist eine besondere Bedeutung dem Zusammenführen von Operational Technology (OT) und Informationstechnik (IT) beizumessen. Zur Datenintegration aus der Sensor-Feldebene einer Versuchs-wasserstofftankstelle wurde eine solche Infrastruktur zunächst in einer Laborumgebung aufgebaut. T2 - Hannover Messe 2024 - Speakers Corners CY - Hannover, Germany DA - 23.04.2024 KW - IT KW - OT KW - Infrastruktur KW - Datenintregration KW - VPN KW - Verwaltungsschale KW - Open Source KW - Software PY - 2024 AN - OPUS4-59930 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Strangfeld, Christoph A1 - Nayeri, Daria T1 - Rissdetektion Spannbetonschwellen - Meilensteinpräsentation AP C.1 N2 - Vorhaben 8082: Spannbetonschwellen sollen mit Hilfe von akustischen Verfahren untersucht und der Zustand abgeleitet werden. Die Ergebnisse von Los C- Arbeitspaket 1 werden dem Deutschen Zentrum für Schienenforschung und Siemens Mobility vorgestellt. T2 - DZSF - Rissdetektion Spannbetonschwellen - Meilensteinpräsentation Arbeitspakete B.1 und C.1 CY - Dresden, Germany DA - 23.04.2024 KW - Spannbetonschwellen KW - Zerstörungsfreie Prüfung KW - Akustische Verfahren KW - Zustandsermittlung PY - 2024 AN - OPUS4-59927 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Eberwein, Robert A1 - Hajhariri, Aliasghar A1 - Camplese, Davide A1 - Scarponi, Giordano Emrys A1 - Cozzani, Valerio A1 - Otremba, Frank T1 - Cryogenic Storage Tanks In Fire Incidents N2 - The ongoing geo-political conflicts and the increasing need for the implementation of measures to improve the energetic system sustainability are increasing the importance of tanks for storing cryogenic fluids in the energy industry. The most common example of cryogenic tank applications is the transport of natural gas and hydrogen in their liquid form (LNG and LH2 respectively) for which, considering the same transport volume cryogenic storage ensures significantly higher transport capacities with respect storage based solely on overpressure. A common feature of all cryogenic transported fluids is that their condition must be maintained minimizing heat leaks from the environment as much as possible. This is achieved by the implementation of thermal super Insulations (TSI) systems based on e. g. rock wool, perlites, microspheres, multilayer insulations (MLI), and vacuum which have proven to be effective in applications. However, due to the relatively short period of use in some applications, the small number of documented incidents, and the still few investigations carried out in the field, the exploitation of such systems in the cryogenic fluids transport sector still suffers from insufficient knowledge about the course and consequences of incidents. Accidents involving collisions, fires, and their combination are quite common in the transportation sector and may generate extraordinary loads on the tank and its insulation system, eventually leading to tank failure. The present study focuses on the behavior of TSI systems in tanks when it is exposed to an external heat source representative of a hydrocarbon fire scenario. This may cause an increase of the heat flux into a tank by several orders of magnitude with respect to normal design conditions, thus inducing severe and in the TSI, causing the rapid release of flammable gas and even resulting in a Boiling Liquide Expanding Vapour Explosion (BLEVE). To study such scenarios a test rig was developed at BAM that allows testing of TSI at industrial conditions and enables subsequent analysis of TSI samples. This test rig considers the typical double-walled design of tanks for cryogenic fluids with vacuum and an additional insulating material in the interspace. Adjustable electrical heating elements simulate the fire on one side of the double wall. This process allows the implementation of repeatable heat loads of up to 100 kW/m². The other side of the double wall is represented by a fluid-supported heat exchanger, which allows the simulation of cold or cryogenic conditions in the test rig, and to determine the heat flux transmitted through the double wall. Thus, the test rig allows thermal loading and performance analysis of TSI samples at the same time. In the presentation, the results of diverse tested TSI systems will be presented and discussed. As a result of this study, the list of advantages and disadvantages for the choice of tested TSI expands. Within the test, all samples degraded as a consequence of a hydrocarbon fire-orientated thermal load. Strong differences in the behavior of the tested TSI systems over temperature, location, and time were observed. Additionally, the tested MLI insulations were significantly more resistant to their base materials. These results are relevant for the design, the definition of national and international regulations, the Risk assessment, and the development of safety concepts for cryogenic tanks. T2 - Cryogenic Storage Tanks CY - Munich, Germany DA - 18.04.2024 KW - LH2 KW - LNG KW - Fire KW - Insulation PY - 2024 AN - OPUS4-59921 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Plarre, Rudy T1 - Sylfuryldiflourid im Holzschutz N2 - Die Anwendung von Sulfuryldiflourid ist auf den bekämpfenden Holzschutz gegen Insekten beschränkt. Die Anwendung in Deutschland regelt die DIN 68800 Teil 4 und das europäische Biozidgesetz. Zur Erhaltung von Kulturgut ist dieses Begasungsmittel einzigartig. T2 - Seminar E.: Symposium zukünftige Verwendung von Sulfuryldifluorid CY - Hannover, Germany DA - 17.04.2024 KW - Holzschutz KW - Begasung KW - Regelwerk PY - 2024 AN - OPUS4-59917 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Durlo Tambara, Luis Urbano A1 - Dehn, F. A1 - Gluth, Gregor T1 - Effect of alkali-activated concrete composition on carbonation rate under accelerated and natural conditions N2 - While alkali-activated binders offer certain advantages over traditional Portland cement binders, particu¬larly in terms of resistance against chemical attacks and potentially environmental footprint, their degra¬dation mechanisms remain incompletely understood at present, specifically carbonation. Thus, this study investigates the impact of natural and accelerated carbonation (1% and 4% CO2) on three different compositions of alkali-activated concretes: 100% calcined clay (C100) binder, 100% ground blast furnace slag (S100) binder, and a 40% calcined clay and 60% blast furnace slag blend (C40S60). C100 concretes exhibit faster carbonation kinetics, with five times greater natural carbonation depths than S100. This difference diminishes under accelerated carbonation, showing a 1.5 times difference for 1% CO2 and complete carbonation for 4% CO2 at 90 days. The results thus confirm that accelerated carbonation testing of low-Ca alkali-activated concretes yields results that are not representative of natural carbonation. The C40S60 sample demonstrates a carbonation profile similar to a CEM I concrete, i.e., a high carbonation resistance. Microstructure analysis indicates the formation of three polymorphs of calcium carbonate for S100 (calcite, vaterite, and aragonite), with a higher CO2 concentration favouring aragonite over vaterite. C100 exhibits no calcium carbonates; instead, sodium carbonates form, including trona for 4% CO2 and natrite for both accelerated tests. C40S60 shows calcium and sodium carbonates, although to a lesser extent, containing predominantly calcite and minor signals of natrite. Suitable compositions, like C40S60, prove as effective during natural or accelerated carbonation tests as conventional Portland cement concrete. T2 - RILEM Spring Convention 2024 CY - Milan, Italy DA - 10.04.2024 KW - Alkali-activated concrete KW - Carbonation KW - Calcined clay KW - Slag KW - Durability PY - 2024 AN - OPUS4-59915 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - He, Yuxiang A1 - Robens-Radermacher, Annika A1 - Noda, S. A1 - Wolf, Christoph A1 - Unger, Jörg F. A1 - Mai, I. T1 - Automated workflows for concrete additive manufacturing for design, optimization and fabrication of parametrized elements N2 - 3D concrete printing is an innovative new construction technology offering the potential to enable an efficient production of individual structures with less consumption of resources. The technology will mainly shape the future construction philosophy, automate the build process and help reaching the climate goals in civil engineering. From the design of a structure to the printed component, many individual steps based on different software are required which must be repeated for each new or changed structure. First, the geometry of the structure is created in a CAD program. Second, the print path is defined in a slicer software creating the machine code for the printer (G-Code). Finally, the structure can be printed. Furthermore, a numerical model of the printed structure is necessary for process optimization and control. In that way the number of test prints can be reduced, costs can be saved, and the component behavior can be predicted. For those purposes, an automated workflow allowing to run all steps or individual steps without interacting with each individual software program is required. Furthermore, changes in parameters or the exchange of parts (using a different design or different printer) must be possible in a simple manner. In the presented work, such an automated workflow based on the example of a parametrized wall element for extrusion-based concrete printing is developed. The investigated wall structure is parametrized using the global geometry parameters: height, width, thickness, radius, kind of infill structure (honey-comb, zig-zag) and number of repeated infills. All above mentioned steps are implemented via python interfaces using pydoit as workflow tool. General interfaces with prescribed input and output files are defined allowing adaptations for different software and tools. The described workflow is tested by performing a test series investigating the influence of the in-fill structure on the mechanical properties of the test walls. T2 - RILEM spring convention & conference on advanced construction materials and processes for a carbon neutral society 2024 CY - Milan, Italy DA - 07.04.2024 KW - 3D concrete printing KW - Design KW - G-Code KW - Simulation KW - Automatization PY - 2024 UR - https://www.rilem.net/agenda/rilem-spring-convention-conference-on-advanced-construction-materials-and-processes-for-a-carbon-neutral-society-1530 AN - OPUS4-59909 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bernardy, Christopher A1 - Habib, Abdel Karim A1 - Kluge, Martin A1 - Schalau, Bernd A1 - Kant, Hanjo A1 - Schulze, Marcel A1 - Orchini, Alessandro T1 - Sicherheitstechnische Untersuchungen von Wasserstoff Freistrahlflammen bei Hochdruck im Realmaßstab N2 - Wasserstoff als Energieträger gewinnt zunehmend an Bedeutung. Die Untersuchung von Störfallauswirkungen mit Wasserstoff rückt somit stärker in den Fokus. Da Wasserstoff meist unter Druck gelagert und transportiert wird, ist ein zu betrachtendes Szenario die Freisetzung aus einer Leckage mit anschließender Zündung. Die daraus resultierende Freistrahlflamme (Jet Flame) muss hinsichtlich der in die Umgebung emittierten Wärmestrahlung charakterisiert werden. In der Literatur existieren bereits verschiedene Modelle, welche jedoch vermehrt auf Daten aus Kohlenwasserstoffflammen mit geringem Impuls basieren. Zur Überprüfung dieser Modelle wird im Zuge des BAM internen H2 Jet Flame Projektes die sicherheitstechnische Untersuchung von impulsbehafteten Wasserstoff Freistrahlflammen vorgenommen. Hierfür finden Versuche im Realmaßstab auf dem Testgelände Technische Sicherheit der BAM (BAM-TTS) statt. Gegenstand der Untersuchungen ist die Beurteilung der Auswirkungen von realistischen Freisetzungsszenarien hinsichtlich der Flammengeometrie und der freigesetzten Wärmestrahlung. Dabei werden Parameter wie Freisetzungswinkel, Leckagedurchmesser (z.Zt. 1 mm bis 30 mm), Druck (z.Zt. bis max. 250 bar) und Massenstrom (bis max. 0,5 kg/s) variiert. Zusätzlich können auch Einflüsse wie Art der Zündung, Zündort sowie Zündung mit zeitlichem Verzug untersucht werden. Gewonnene Erkenntnisse werden mit den Ergebnissen bereits vorhandener Modelle verglichen und diese im Bedarfsfall weiterentwickelt. Insbesondere wird der Fokus auf die Modellierung der freigesetzten Wärmestrahlung von Wasserstoffflammen gelegt. Herausforderung dabei stellt die IR-Vermessung und Modellierung von Sichtmodellen der Flammen dar. Die Visualisierung der Flammengeometrie wird mit Hilfe mehrerer Infrarot Kamerasystemen (aus mindestens zwei Blickwinkeln) vorgenommen. Bisherige Messungen, die in der Literatur zu finden sind, basieren meist auf instationären Auströmbedingungen. Der hier verwendete Versuchsaufbau ermöglicht ein stationäres Ausströmen für mehrere Minuten und somit eine direkte Vergleichbarkeit mit den existierenden (stationären) Modellen. Weiterhin ist der Versuchsstand umrüstbar für Vergleichsmessungen mit Kohlenwasserstoffen (Methan etc.) sowie Mischungen aus Wasserstoff und Kohlenwasserstoffen. T2 - Magdeburg-Köthener Brandschutz- und Sicherheitstagung 2024 CY - Magdeburg, Germany DA - 14.03.2024 KW - Wassersoff KW - Freistrahlflamme KW - Wärmestrahlung PY - 2024 AN - OPUS4-59911 LA - deu AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Bernardy, Christopher A1 - Habib, Abdel Karim A1 - Kluge, Martin A1 - Schalau, Bernd A1 - Kant, Hanjo A1 - Schulze, Marcel A1 - Orchini, Alessandro T1 - Real scale safety investigations of hydrogen jet flames at high pressure N2 - In order to reduce the human footprint of CO2 emissions and limit global warming effects hydrogen combustion is becoming increasingly important. To enable fuel cells and gas turbines to operates this carbon free fuel, unprecedently large amounts of hydrogen need to be produced and safely transported and stored. The investigation of the effects of accidents involving hydrogen is therefore becoming of outmost importance. Since hydrogen is usually stored and transported under pressure, one scenario to be considered is the release of hydrogen from a leakage with subsequent ignition. The resulting jet flame must be characterized with respect to the thermal radiation emitted into the environment to define safety regulations. Various models that characterize the resulting flame shape and radiation already exist in the literature, but these are mainly based on empirical data from hydrocarbon jet flames.[1-4] To verify these models, a H2 Jet Flame project conducted at BAM, is investigating the safety of momentum driven hydrogen jet flames. For this purpose, large-scale tests are carried out at the Test Site Technical Safety (BAM-TTS). The object of the investigations is to assess the effects of real scale release scenarios regarding flame geometry and the thermal radiation emitted. Parameters such as release angle, leakage diameter (currently 1 mm to 10 mm), pressure (currently up to max. 250 bar) and mass flow (up to max. 0.5 kg/s) are varied. In addition, influences such as the type of ignition, ignition location as well as delayed ignition can also be investigated. The gained knowledge will be compared with existing jet flame models, to validate these and identify a possible need for further development. In particular, the focus will be laid on the thermal radiation of hydrogen flames. The challenge here is the visualization and characterization of the flame geometry in an open environment. Visualization is performed using infrared (IR) camera systems from at least two viewing angles. Measurements of the heat radiation of jet flames, which can be found in the literature, are mostly based on unsteady outflow conditions.The experimental setup used here allows for the generation of a steady-state outflow for several minutes and thus a direct comparability with existing (steady-state) models. Furthermore, the tests can be carried out for comparative measurements with hydrocarbons (methane, etc.) as well as mixtures of hydrogen and hydrocarbons. T2 - European PhD Hydrogen Conference 2024 (EPHyC2024) CY - Gent, Belgium DA - 20.03.2024 KW - Hydrogen KW - Release KW - Jet flame KW - Thermal radiation PY - 2024 AN - OPUS4-59908 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Robens-Radermacher, Annika A1 - Kujath, Cezary A1 - Bos, F. A1 - Mechtcherine, V. A1 - Unger, Jörg F. T1 - Advantages and challenges of data stores for interlaboratory studies – an example from mechanical test data of printed concrete structures N2 - Interlaboratory studies are common tools for collecting comparable data to implement standards for new materials or testing technologies. In the case of construction materials, these studies form the basis for recommendations and design codes. Depending on the study, the amount of data collected can be enormous, making manual handling and evaluation difficult. On the other hand, the importance of the FAIR (findable, accessible, interoperable, and reusable) principles for scientific data management, published by Wilkinson et al. in 2016, is constantly growing and changing the view on data usage. The benefits of using data management tools such as data stores/repositories or electronic laboratory notebooks are many. Data is stored in a structured and accessible way (at least within a group) and data loss due to staff turnover is reduced. Tools usually support data publishing and analysis interfaces. In this way, data can be reused years later to generate new knowledge with future insights. On the other hand, there are many challenges in setting up a data repository, such as selecting suitable software tools, defining the data structure, enabling data access, and understanding by others and ensuring maintenance, among others. This talk discusses the advantages and challenges of setting up and applying a data repository using the interlaboratory study on the mechanical properties of printed concrete structures carried out in RILEM TC 304-ADC as example. First, the definition of a suitable data structure including all information is discussed. The tool-dependent upload process is then described. Here, the data management system openBIS (open source software developed by ETH Zurich) is used. Since in most cases an open compute platform allowing access from different organisations is not possible or available due to data protection and maintenance issues, tool-independent export options are discussed and compared. Finally, the different query and analysis possibilities are demonstrated. T2 - RILEM spring convention & conference on advanced construction materials and processes for a carbon neutral society 2024 CY - Milan, Italy DA - 07.04.2024 KW - Data stores KW - Data structuring KW - Data evaluation KW - Automatization KW - Interlaboratory PY - 2024 UR - https://www.rilem.net/agenda/rilem-spring-convention-conference-on-advanced-construction-materials-and-processes-for-a-carbon-neutral-society-1530 AN - OPUS4-59906 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - CONF A1 - Schröder, Jakob A1 - Heldmann, Alexander A1 - Hofmann, Michael A1 - Evans, Alexander A1 - Petry, Winfried A1 - Bruno, Giovanni T1 - Diffraction and Single-Crystal Elastic Constants of Laser Powder Bed Fused Inconel 718 N2 - In this presentation, the results of the determination of the diffraction and single-crystal elastic constants of laser powder bed fused Inconel 718 are presented. The analysis is based on high-energy synchrotron diffraction experiments performed at the Deutsches Elektronen-Synchrotron. It is shown that the characteristic microstructure of laser powder bed fused Inconel 718 impacts the elastic anisotropy and therefore the diffraction and single-crystal elastic constants. Finally, the consequences on the diffraction-based residual stress determination of laser powder bed fused Inconel 718 are discussed. T2 - AWT-Fachausschuss 13 "Eigenspannungen" CY - Wolfsburg, Germany DA - 19.03.2024 KW - Additive Manufacturing KW - Laser Powder Bed fusion KW - Diffraction KW - In-Situ Testing KW - Diffraction Elastic Constants PY - 2024 AN - OPUS4-59900 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -