TY - JOUR A1 - Auersch, Lutz T1 - Wave propagation in the elastic half-space due to an interior load and its application to ground vibration problems and buildings on pile foundations JF - Soil dynamics and earthquake engineering N2 - A method is presented which allows to calculate the wave-field in a homogeneous or layered soil in case of a dynamic interior load. The wave propagation along the surface, the distribution of the response over the depth, the horizontal propagation at different depths and the vertical downward propagation are shown and compared with the simpler surface solution of the half-space and the interior solution of the full-space. The complete wave-field (Green's function) is applied to the dynamic behaviour of piles and pile groups by use of a boundary element formulation. The stiffness, damping and – typically for piles – mass of different groups of piles are presented. Different group effects occur for lines, circles, grids, parallels and crosses of piles, which can be regarded as oscillations around average values. Moreover, the piles and pile groups behave almost like a damper for most of the frequencies. A building on a pile group that is excited by ground vibration due to surface or interior loads shows a reduction of the wave-field due to kinematic and inertial soil–building interaction effects. The results presented lead to simplified descriptions of the wave-field due to interior loads and of the soil–pile–building interaction which can be used for the prediction of technically induced vibration. KW - Wave propagation KW - Interior load KW - Dynamic pile and pile group stiffness KW - Kinematic and inertial soil-pile-building KW - Interaction PY - 2010 DO - https://doi.org/10.1016/j.soildyn.2010.04.003 SN - 0261-7277 SN - 0267-7261 VL - 30 IS - 10 SP - 925 EP - 936 PB - Elsevier Science CY - Amsterdam AN - OPUS4-21833 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Lorenzetti, A. A1 - Besco, S. A1 - Hrelja, D. A1 - Roso, M. A1 - Gallo, Emanuela A1 - Schartel, Bernhard A1 - Modesti, M. T1 - Phosphinates and layered silicates in charring polymers: The flame retardancy action in polyurethane foams JF - Polymer degradation and stability N2 - Nanocomposites of a charring polymer (like polyurethane foam) filled with aluminum phosphinate (AlPi) with or without melamine cyanurate (MelCy) have been prepared by microwave processing and their thermal stability and fire behavior have been studied. Results on the interaction between flame retardants and layered silicates were provided as well as detailed investigation of the char strength, which has been carried out using a suitably developed method based on dynamic-mechanic analysis. Generally, the thermo-oxidative stability in presence of layered silicates was higher than the counterparts even if an additive rather than synergic effect took place; however, in some cases the interaction between clays and phosphinate led to a significant decrease of weight residue. In nitrogen the residue amounts were about the same but a higher amount of phosphorus was retained in the solid phase in presence of clays. Cone calorimeter results showed that the use of phosphinates led to a decrease of the PHRR; further addition of clays did not reduce the PHRR owing to the worse quality of char layer as demonstrated by the char strength test. However, it has been shown that the partial substitution of aluminum phosphinate with melamine cyanurate gave improved results: the AlPi–MelCy filled foams showed similar pHRR and THE but lower TSR and higher char strength than AlPi filled foams. It was also confirmed that phosphinate acted by flame inhibition but its action was depressed by the use of nanoclays owing to their interaction. KW - Phosphinate KW - Nanocomposite KW - Polyurethane KW - Interaction KW - Flame retardant PY - 2013 DO - https://doi.org/10.1016/j.polymdegradstab.2013.08.002 SN - 0141-3910 SN - 1873-2321 VL - 98 IS - 11 SP - 2366 EP - 2374 PB - Applied Science Publ. CY - London AN - OPUS4-29281 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER - TY - JOUR A1 - Noskov, Sergey A1 - Scherer, Christian A1 - Maskos, Michael A1 - Thünemann, Andreas T1 - Determination of Hamaker constants of polymeric nanoparticles in organic solvents by asymmetrical flow field-flow fractionation JF - Journal of chromatography A N2 - Interaction forces between all objects are either of repulsive or attractive nature. Concerning attractive interactions, the determination of dispersion forces are of special interest since they appear in all colloidal systems and have a crucial influence on the properties and processes in these systems. One possibility to link theory and experiment is the description of the London–Van der Waals forces in terms of the Hamaker constant, which leads to the challenging problem of calculating the van der Waals interaction energies between colloidal particles. Hence, the determination of a Hamaker constant for a given material is needed when interfacial phenomena such as adhesion are discussed in terms of the total potential energy between particles and substrates. In this work, the asymmetrical flow field-flow fractionation (AF-FFF) in combination with a Newton algorithm based iteration process was used for the determination of Hamaker constants of different nanoparticles in toluene. KW - Hamaker constant KW - Asymmetrical flow field flow fractionation KW - Lifshitz KW - Van der Waals KW - London KW - Thermodynamic KW - Interaction PY - 2013 DO - https://doi.org/10.1016/j.chroma.2012.12.001 SN - 0021-9673 VL - 1274 SP - 151 EP - 158 PB - Elsevier B.V. CY - Amsterdam AN - OPUS4-27625 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -