63795 2025 eng 1 8 284 article Elsevier Ltd. 1 -- -- -- Persistent and mobile trace organic contaminants (TrOCs) in urban stormwater are difficult to remove through sedimentation- or sorption-based treatment and pose a risk to aquatic ecosystems and drinking water supplies. We demonstrate that the chemical oxidant peroxydisulfate (PDS) can be activated by shrimp shell biochar at pH 7 to form reactive species that selectively react with widespread stormwater contaminants. Of 11 TrOCs tested, oxidative transformation was observed for 1,3-diphenylguanidine, 2-hydroxybenzothiazole, 1H-benzotriazole, 5-methyl-benzotriazole, and diuron during water treatment with biochar and PDS. Laboratory batch experiments conducted with street runoff and a synthetic water showed that the water matrix, containing up to 7.5 mg L-1 dissolved organic carbon and 100 mM chloride, had a minor effect on the formation of reactive species and contaminant transformation. Using a set of scavengers and probe compounds, we provide evidence for singlet oxygen (1O2) as the predominant reactive species in the biochar/PDS system, which is in agreement with the selectivity of the process to oxidize electron-rich organic contaminants. The results of our study inform new strategies for stormwater treatment using heterogeneous oxidation processes for the abatement of persistent and mobile organic contaminants. Water Research 0043-1354 10.1016/j.watres.2025.123921 urn:nbn:de:kobv:b43-637952 true ok journal-article https://www.elsevier.com/tdm/userlicense/1.0/ crossref PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorIdentifierOrcid_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorIdentifierOrcid_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorIdentifierOrcid_7,PublisherName,TitleMain_1,Language,TitleParent_1,ArticleNumber,Volume,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence doi-import 28.07.2025 Creative Commons - CC BY - Namensnennung 4.0 International Yiling Zhuang Stefan B. Haderlein Holger V. Lutze Chen Sun Friedrich Fink Andrea Paul Stephanie Spahr eng uncontrolled Stormwater treatment eng uncontrolled Oxidation processes eng uncontrolled Pyrogenic carbon Sanitär- und Kommunaltechnik; Umwelttechnik 6 Materialchemie 6.3 Strukturanalytik Umwelt Umwelt-Material-Interaktionen Verlagsliteratur Datei für die Öffentlichkeit verfügbar ("Open Access") Wissenschaftliche Artikel der BAM Bundesanstalt für Materialforschung und -prüfung (BAM) https://opus4.kobv.de/opus4-bam/files/63795/Persulfate activation by biochar for trace organic contaminant removal from urban stormwater.pdf