<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>56883</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>8</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>9</volume>
    <type>article</type>
    <publisherName>Wiley-VCH</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">One-pot covalent functionalization of 2D black phosphorus by anionic ring opening polymerization</title>
    <abstract language="eng">In this work, a one-pot approach for the covalent functionalization of few-layer black phosphorus (BP) by anionic ring opening polymerization of glycidol to obtain multifunctional BP-polyglycerol (BP-PG) with high amphiphilicity for near-infrared-responsive drug delivery and biocompatibility is reported. Straightforward synthesis in combination with exceptional biological and physicochemical properties designates functionalized BP-PG as a promising candidate for a broad range of biomedical applications.</abstract>
    <parentTitle language="eng">Advanced materials interfaces</parentTitle>
    <identifier type="issn">2196-7350</identifier>
    <identifier type="doi">10.1002/admi.202201245</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-568833</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="date_peer_review">24.01.2023</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>O. Bawadkji</author>
    <author>M. Cherri</author>
    <author>A. Schäfer</author>
    <author>S. Herziger</author>
    <author>Philip Nickl</author>
    <author>K. Achazi</author>
    <author>Ievgen Donskyi</author>
    <author>M. Adeli</author>
    <author>R. Haag</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>2D nanomaterial</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Amphiphilicity</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Black phosphorus</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hyperbranched</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polyglycerol</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Water dispersibility</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/56883/10_1002_admi_202201245.pdf</file>
  </doc>
  <doc>
    <id>58229</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>053210-1</pageFirst>
    <pageLast>053210-13</pageLast>
    <pageNumber/>
    <edition/>
    <issue>5</issue>
    <volume>41</volume>
    <type>article</type>
    <publisherName>AIP (American Institute of Physics)</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">VAMAS TWA2 interlaboratory comparison: Surface analysis of TiO2 nanoparticles using ToF-SIMS</title>
    <abstract language="eng">Due to the extremely high specific surface area of nanoparticles and corresponding potential for adsorption, the results of surface analysis can be highly dependent on the history of the particles, particularly regarding sample preparation and storage. The sample preparation method has, therefore, the potential to have a significant influence on the results. This report describes an interlaboratory comparison (ILC) with the aim of assessing which sample preparation methods for ToF-SIMS analysis of nanoparticles provided the most intra- and interlaboratory consistency and the least amount of sample contamination. The BAM reference material BAM-P110 (TiO2 nanoparticles with a mean Feret diameter of 19 nm) was used as a sample representing typical nanoparticles. A total of 11 participants returned ToF-SIMS data,in positive and (optionally) negative polarity, using sample preparation methods of “stick-and-go” as well as optionally “drop-dry” and “spin-coat.” The results showed that the largest sources of variation within the entire data set were caused by adventitious hydrocarbon contamination or insufficient sample coverage, with the spin-coating protocol applied in this ILC showing a tendency toward insufficient sample coverage; the sample preparation method or the participant had a lesser influence on results.</abstract>
    <parentTitle language="eng">Journal of Vacuum Science and Technology A</parentTitle>
    <identifier type="doi">10.1116/6.0002814</identifier>
    <identifier type="issn">0734-2101</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-582290</identifier>
    <enrichment key="date_peer_review">13.09.2023</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Francesca Bennet</author>
    <author>R. Opitz</author>
    <author>N. Ghoreishi</author>
    <author>K. Plate</author>
    <author>J.-P. Barnes</author>
    <author>A. Bellew</author>
    <author>A. Bellu</author>
    <author>G. Ceccone</author>
    <author>E. de Vito</author>
    <author>A. Delcorte</author>
    <author>A. Franquet</author>
    <author>F. Fumageli</author>
    <author>D. Gilliland</author>
    <author>H. Jungnickel</author>
    <author>T.G. Lee</author>
    <author>C. Poleunis</author>
    <author>D. Rading</author>
    <author>H.K. Shon</author>
    <author>V. Spampinato</author>
    <author>J.G. Son</author>
    <author>F. Wang</author>
    <author>Y.-C. A. Wang</author>
    <author>Y. Zhao</author>
    <author>A. Roloff</author>
    <author>J. Tentschert</author>
    <author>Jörg Radnik</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Secondary Ion Mass Spectrometry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>VMAAS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Titania</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Interlaboratory comparison</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Reproducibility</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/58229/jvst_a_2023_tof-sims.pdf</file>
  </doc>
  <doc>
    <id>51395</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>8</pageLast>
    <pageNumber/>
    <edition/>
    <issue>21</issue>
    <volume>12</volume>
    <type>article</type>
    <publisherName>Wiley Online Libary</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Iron and Manganese Containing Multi-Walled Carbon Nanotubes as Electrocatalysts for the Oxygen Evolution Reaction - Unravelling Influences on Activity and Stability</title>
    <abstract language="eng">Hydrogen economy is a central aspect of future energy supply, as hydrogen can be used as energy storage and fuel. In order tomake water electrolysis efficient, the limiting oxygen evolution reaction (OER) needs to be optimized. Therefore, C-based composite materials containing earth-abundant Fe and Mn were synthesized, characterized and tested in the OER. For pyrolysis temperatures above 700°C N-rich multi-walled carbon nanotubes (MWCNT) are obtained. Inside the tubes Fe3C particles are formed, Fe and Mn oxides are incorporated in the carbon matrix and metal spinel nanoparticles cover the outer surface. The best catalyst prepared at 800°C achieves a low overpotential of 389 mV (at 10 mA/cm2) and high stability (22.6 h). From electrochemical measurements and characterization it can be concluded that the high activity is mainly provided by MWCNT, Fe3C and the metal oxides in the conductive carbon matrix. The metal spinel nanoparticles in&#13;
contrast protect the MWCNT from oxidation and thereby contribute to the high stability.</abstract>
    <parentTitle language="eng">Chemistry Europe</parentTitle>
    <identifier type="doi">10.1002/cctc.202000944</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-513955</identifier>
    <enrichment key="date_peer_review">12.10.2020</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Cornelia Broicher</author>
    <author>F. Zeng</author>
    <author>N. Pfänder</author>
    <author>M. Frisch</author>
    <author>T. Bisswanger</author>
    <author>Jörg Radnik</author>
    <author>Jörg M. Stockmann</author>
    <author>S. Palkovits</author>
    <author>A. K. Beine</author>
    <author>R. Palkovits</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Oxygen Evolution Reaction</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Carbon Nanotubes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Stability</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/51395/cctc.202000944.pdf</file>
  </doc>
  <doc>
    <id>50990</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>890</pageFirst>
    <pageLast>894</pageLast>
    <pageNumber/>
    <edition/>
    <issue>12</issue>
    <volume>52</volume>
    <type>article</type>
    <publisherName>John Wiley &amp; Sons Ltd</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">A new test specimen for the determination of the field of view of small-area X-ray photoelectron spectrometers</title>
    <abstract language="eng">Small-area/spot photoelectron spectroscopy (SAXPS) is a powerful tool for the investigation of small surface features like microstructures of electronic devices, sensors or other functional surfaces, and so forth. For evaluating the quality of such microstructures, it is often crucial to know whether a small signal in a spectrum is an unwanted contamination of the field of view (FoV), defined by the instrument settings, or it originated from outside. To address this issue, the d80/20 parameter of a line scan across a chemical edge is often used. However, the typical d80/20 parameter does not give information on contributions from the long tails of the X-ray beam intensity distribution or the electron-optical system as defined by apertures. In the VAMAS TWA2 A22 project “Applying planar, patterned, multi-metallic samples to assess the impact of analysis area in surface-chemical analysis,” new test specimen was developed and tested. The here presented testing material consists of a silicon wafer substrate with an Au-film and embedded Cr circular and square spots with decreasing dimensions from 200 μm down to 5 μm. The spot sizes are traceable to the length unit due to size measurements with a metrological SEM. For the evaluation of the FoV, we determined the Au4f intensities measured with the center of the FoV aligned with the center of the spot and normalized to the Au4f intensity determined on the Au-film. With this test specimen, it was possible to characterize, as an example, the FoV of a Kratos AXIS Ultra DLD XPS instrument.</abstract>
    <parentTitle language="eng">Surface and Interface Analysis</parentTitle>
    <identifier type="doi">10.1002/sia.6831</identifier>
    <identifier type="issn">1096-9918</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-509902</identifier>
    <enrichment key="eventName">ECASIA 2019</enrichment>
    <enrichment key="eventPlace">Dresden, Germany</enrichment>
    <enrichment key="eventStart">15.09.2019</enrichment>
    <enrichment key="eventEnd">20.09.2019</enrichment>
    <enrichment key="date_peer_review">13.07.2020</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Jörg M. Stockmann</author>
    <author>Jörg Radnik</author>
    <author>S. Bütefisch</author>
    <author>I. Busch</author>
    <author>T. Weimann</author>
    <author>C. Passiu</author>
    <author>A. Rossi</author>
    <author>Wolfgang Unger</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Field of view</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Reference material</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Selected area XPS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Small-area XPS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Small-spot XPS</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/50990/sia.6831.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/50990/ECASIA_Supporting Information_Sia.6831.pdf</file>
  </doc>
  <doc>
    <id>53605</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>7278</pageFirst>
    <pageLast>7286</pageLast>
    <pageNumber/>
    <edition/>
    <issue>12</issue>
    <volume>11</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Particle size-controlled synthesis of highperformance MnCo-based materials for alkaline OER at fluctuating potentials</title>
    <abstract language="eng">For the large-scale generation of hydrogen via water electrolysis the design of long term stable and active catalysts for the oxygen evolution reaction (OER) remains a key challenge. Most catalysts suffer from severe structural corrosion that becomes even more pronounced at fluctuating potentials. Herein, MnCo based cubic particles were prepared via a hydrothermal approach, in which the edge length of the micron-sized particles can be controlled by changing the pH value of the precursor solution. The cubes are composed of varying amounts of MnCo2O4, CoCO3 and a mixed (Mn/Co)CO3 phase. Structure–activity relationships were deduced revealing a volcano-type behavior for the intrinsic OER activity and fraction of spinel oxide phase.&#13;
A low overpotential of 0.37 V at 10 mA cm−2 and a stability of more than 25 h was achieved in 1.0 M KOH using a rotating disc electrode (RDE) setup. The best performing catalyst material was successfully tested under dynamic process conditions for 9.5 h and shows a superior catalytic activity as anode for the Overall water splitting in an electrolyser setup in 1.0 M KOH at 333 K compared to a reference NiCo-spinel catalyst.</abstract>
    <parentTitle language="eng">Catalysis Science and Technology</parentTitle>
    <identifier type="doi">10.1039/d1cy00905b</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-536050</identifier>
    <identifier type="issn">2044-4753</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">25.10.2021</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>C. Broichert</author>
    <author>M. Klingenhof</author>
    <author>M. Frisch</author>
    <author>S. Dresp</author>
    <author>N.M. Kubo</author>
    <author>J. Artz</author>
    <author>Jörg Radnik</author>
    <author>S. Palkovits</author>
    <author>A.K. Beine</author>
    <author>P. Strasser</author>
    <author>R. Palkovits</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Water electrolysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Oxygen evolution reaction</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Structure activity relationships</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="621">Angewandte Physik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="themenfelder" number="">Energie</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="themenfelder" number="">Wasserstoff</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/53605/cat-science-techn-broichert.pdf</file>
  </doc>
  <doc>
    <id>54683</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>13</pageLast>
    <pageNumber/>
    <edition/>
    <issue>840758</issue>
    <volume>10</volume>
    <type>article</type>
    <publisherName>Frontiers Media</publisherName>
    <publisherPlace>Lausanne</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Mechanochemical synthesis of fluorine-containing Co-doped zeolitic imidazolate frameworks for producing electrocatalysts</title>
    <abstract language="eng">Catalysts derived from pyrolysis of metal organic frameworks (MOFs) are promising candidates to replace expensive and scarce platinum-based electrocatalysts commonly used in polymer electrolyte membrane fuel cells. MOFs contain ordered connections between metal centers and organic ligands. They can be pyrolyzed into metal- and nitrogen-doped carbons, which show electrocatalytic activity toward the oxygen reduction reaction (ORR). Furthermore, metal-free heteroatom-doped carbons, such as N-F-Cs, are known for being active as well. Thus, a carbon material with Co-N-F doping could possibly be even more promising as ORR electrocatalyst. Herein, we report the mechanochemical synthesis of two polymorphs of a zeolitic imidazole framework, Co-doped zinc 2-trifluoromethyl-1H-imidazolate (Zn0.9Co0.1(CF3-Im)2). Time-resolved in situ X-ray diffraction studies of the mechanochemical formation revealed a direct conversion of starting materials to the products. Both polymorphs of Zn0.9Co0.1(CF3-Im)2 were pyrolyzed, yielding Co-N-F containing carbons, which are active toward electrochemical ORR.</abstract>
    <parentTitle language="eng">Frontiers in chemistry</parentTitle>
    <identifier type="doi">10.3389/fchem.2022.840758</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-546833</identifier>
    <identifier type="issn">2296-2646</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">25.04.022</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Max Rautenberg</author>
    <author>M. Gernhard</author>
    <author>Jörg Radnik</author>
    <author>Julia Witt</author>
    <author>C. Roth</author>
    <author>Franziska Emmerling</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mechanochemistry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Metal-organic-frameworks</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nobel-metal free electrocatalysis</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="621">Angewandte Physik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="institutes" number="">6.3 Strukturanalytik</collection>
    <collection role="themenfelder" number="">Energie</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="institutes" number="">6.0 Abteilungsleitung und andere</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/54683/fchem-10-840758 (1).pdf</file>
  </doc>
  <doc>
    <id>65329</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>14</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Springer Science and Business Media LLC</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Optimization of tablet processing as a reference material for microplastic detection methods</title>
    <abstract language="eng">Reference materials (RMs) are essential and highly demanded tools for the development and validation of methods for microplastic (MP) quantification in complex matrices, to ensure comparable and harmonized approaches aligned with EU commission criteria for monitoring MPs (e.g., Drinking Water Directive and Urban Wastewater Treatment Directive). This study investigates different approaches for optimizing the production of polypropylene (PP) RMs in the form of water-soluble tablets, which were carefully evaluated for their homogeneity and stability according to ISO Guide 30, ISO 33401, and ISO 33405. PP particles (1–100 μm) were produced by cryomilling and embedded in a lactose/PEG matrix, then pressed into tablets (18 µg theoretical PP mass). The production process was optimized by varying (i) the size distribution of the matrix components and (ii) the mixer instrument. The materials obtained were characterized by thermogravimetric analysis to assess the homogeneity distribution of MPs with respect to PP mass in the individual tablets and their stability over a 4-month period. The most promising approach, with a homogenous mass of 19 μg (standard deviation of 4 μg), relative standard deviation of 19%, was further investigated for homogeneity by comparison with thermo-analytical mass determination methods, such as TED-GC/MS (thermal extraction desorption-gas chromatography/mass spectrometry) and Py-GC/MS (pyrolysis-gas chromatography-mass spectrometry), and for number-based characterization using micro-Raman spectroscopy. Material characterization was also examined using laser diffraction, scanning electron microscopy, and ATR-FTIR. Based on the results, the optimized processing protocol yields a PP RM suitable for quality control and method performance studies supporting standardization.</abstract>
    <parentTitle language="eng">Analytical and Bioanalytical Chemistry</parentTitle>
    <identifier type="issn">1618-2642</identifier>
    <identifier type="doi">10.1007/s00216-025-06271-7</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-653290</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://creativecommons.org/licenses/by/4.0</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorFirstName_8,PersonAuthorLastName_8,PersonAuthorFirstName_9,PersonAuthorLastName_9,PersonAuthorFirstName_10,PersonAuthorLastName_10,PersonAuthorFirstName_11,PersonAuthorLastName_11,PersonAuthorFirstName_12,PersonAuthorLastName_12,PersonAuthorFirstName_13,PersonAuthorLastName_13,PersonAuthorFirstName_14,PersonAuthorLastName_14,PersonAuthorFirstName_15,PersonAuthorLastName_15,PublisherName,TitleMain_1,Language,TitleAbstract_1,TitleParent_1,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="date_peer_review">12.01.2026</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Mara Putzu</author>
    <author>Yosri Wiesner</author>
    <author>Christiane Weimann</author>
    <author>Vasile-Dan Hodoroaba</author>
    <author>Soledad Muniategui Lorenzo</author>
    <author>Verónica Fernández-Gonzáles</author>
    <author>Andy M. Booth</author>
    <author>Amaia Igartua</author>
    <author>Nizar Benismail</author>
    <author>Laureen Coïc</author>
    <author>Carine Chivas-Joly</author>
    <author>Ivana Fenoglio</author>
    <author>Andrea Mario Rossi</author>
    <author>Andrea Mario Giovannozzi</author>
    <author>Korinna Altmann</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microplastics</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>TED-GC/MS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Reference materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polypropylene</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="themenfelder" number="">Chemische Charakterisierung und Spurenanalytik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/65329/s00216-025-06271-7.pdf</file>
  </doc>
  <doc>
    <id>54360</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>13</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Wiley VCH</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Size-Tunable Ni–Cu Core–Shell Nanoparticles—Structure, Composition, and Catalytic Activity for the Reverse Water–Gas Shift Reaction</title>
    <abstract language="eng">A facile and efficient methodology is described for the solvothermal synthesis of size-tunable, stable, and uniform NiCu core–shell nanoparticles (NPs) for application in catalysis. The diameter of the NPs is tuned in a range from 6 nm to 30 nm and to adjust the Ni:Cu ratio from 30:1 to 1:1. Furthermore, the influence of different reaction parameters on the final NPs is studied. The NPs are structurally characterized by a method combination of transmission electron microscopy, anomalous small-angle X-ray scattering, X-ray absorption fine structure, and X-ray photoelectron spectroscopy. Using these analytical methods, it is possible to elucidate a core–shell–shell structure of all particles and their chemical composition. In all cases, a depletion from the core to the shell is observed, with the core consisting of NiCu alloy, surrounded by an inner Ni-rich shell and an outer NiO shell. The SiO2-supported NiCu core–shell NPs show pronounced selectivity of &gt;99% for CO in the catalytic reduction of CO2 to CO using hydrogen as reactant (reverse water–gas shift reaction) independent of size and Ni:Cu ratio.</abstract>
    <parentTitle language="eng">Advanced Engineering Materials</parentTitle>
    <identifier type="doi">10.1002/adem.202101308</identifier>
    <identifier type="issn">1438-1656</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-543606</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">17.02.2022</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Maria Heilmann</author>
    <author>Carsten Prinz</author>
    <author>Ralf Bienert</author>
    <author>R. Wendt</author>
    <author>B. Kunkel</author>
    <author>Jörg Radnik</author>
    <author>A. Hoell</author>
    <author>S. Wohlrab</author>
    <author>Ana de Oliveira Guilherme Buzanich</author>
    <author>Franziska Emmerling</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoparticles</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Core-shell</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Catalysis</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.3 Strukturanalytik</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="institutes" number="">6.0 Abteilungsleitung und andere</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/54360/AdvEngMater_2022_Heilmann.pdf</file>
  </doc>
  <doc>
    <id>63365</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>11</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>5</volume>
    <type>article</type>
    <publisherName>Springer Science and Business Media LLC</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Tracking nanoplastics in drinking water: a new frontier with the combination of dielectrophoresis and Raman spectroscopy</title>
    <abstract language="eng">Detection of micro- (MPs) and nanoplastics (NPs) in food and environmental matrices has been gaining relevance due to their potential toxicological effects on human health. While MPs have been detected in a wide range of complex matrices, suitable methods for the characterization and chemical identification of NPs are still lacking, primarily due to significant methodological challenges associated with their nano-specific physiochemical properties, including size distribution (1 nm – 1 µm), dynamic surface chemical changes, and carbon-based composition, which complicate their detection compared to engineered nanomaterials. To overcome the traditional limitations of spectroscopic techniques in terms of spatial resolution and sensitivity at the sub-micrometer level, a novel label-free methodology is presented for specifically identifying the chemical composition of NPs directly in suspension by combining Raman spectroscopy with dielectrophoresis (DEP). Using a custom-built device, small volumes of NPs are injected into a dielectrophoretic cell and locally trapped by DEP forces to fill the Raman confocal volume, facilitating their detection and identification, and providing high signal-to-noise ratio Raman spectra for more reliable analysis. This approach was successfully applied to both Milli-Q water and a commercial brand of drinking water, enabling the rapid identification of various types of NPs with different sizes and polymer compositions at concentrations as low as 20 µg/mL. These included certified reference polystyrene beads ranging from 800 to 60 nm in diameter, as well as polydisperse NPs, more representative of real samples in terms of size distribution and polymer type, such as polyethylene (450 nm), polypropylene (180 nm), and polyethylene terephthalate (100 nm). Moreover, the chemical fingerprint of each NPs was thoroughly investigated and compared with the corresponding bulk polymers, highlighting possible changes in the Raman bands due to surface oxidation or nanometer-scale effect. Therefore, this innovative method can be considered a valuable approach for addressing gaps in the detection and identification of NPs, as well as for monitoring their dynamic phisiochemical changes in real matrices.</abstract>
    <parentTitle language="eng">Microplastics and Nanoplastics</parentTitle>
    <identifier type="issn">2662-4966</identifier>
    <identifier type="doi">10.1186/s43591-025-00131-y</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-633658</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://creativecommons.org/licenses/by/4.0</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="date_peer_review">16.07.2025</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Marta Fadda</author>
    <author>Alessio Sacco</author>
    <author>Korinna Altmann</author>
    <author>Dmitri Ciornii</author>
    <author>Frank Milczewski</author>
    <author>Miguel A. Bañares</author>
    <author>Raquel Portela</author>
    <author>Andrea Mario Giovannozzi</author>
    <author>Andrea Mario Rossi</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoplastics</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Water contaminants</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Raman microspectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dielectrophoresis</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="themenfelder" number="">Chemische Charakterisierung und Spurenanalytik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/63365/s43591-025-00131-y.pdf</file>
  </doc>
  <doc>
    <id>59135</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>10645</pageFirst>
    <pageLast>10657</pageLast>
    <pageNumber/>
    <edition/>
    <issue>24</issue>
    <volume>35</volume>
    <type>article</type>
    <publisherName>American Chemical Society (ACS)</publisherName>
    <publisherPlace>Washington D.C.</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Nonclassical Crystallization Pathway of Transition Metal Phosphate Compounds</title>
    <abstract language="eng">Here, we elucidate nonclassical multistep crystallization pathways of transition metal phosphates from aqueous solutions. We followed precipitation processes of M-struvites, NH4MPO4·6H2O, and M-phosphate octahydrates, M3(PO4)2·8H2O, where M = Ni, Co, or NixCo1–x, by using in situ scattering and spectroscopy-based techniques, supported by elemental mass spectrometry analyses and advanced electron microscopy. Ni and Co phosphates crystallize via intermediate colloidal amorphous nanophases, which change their complex structures while agglomerating, condensing, and densifying throughout the extended reaction times. We reconstructed the three-dimensional morphology of these precursors by employing cryo-electron tomography (cryo-ET). We found that the complex interplay between metastable amorphous colloids and protocrystalline units determines the reaction pathways. Ultimately, the same crystalline structure, such as struvite, is formed. However, the multistep process stages vary in complexity and can last from a few minutes to several hours depending on the selected transition metal(s), their concentration, and the Ni/Co ratio.</abstract>
    <parentTitle language="eng">Chemistry of Materials</parentTitle>
    <identifier type="doi">10.1021/acs.chemmater.3c02346</identifier>
    <identifier type="issn">1520-5002</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2023,12,13]],"date-time":"2023-12-13T00:56:11Z","timestamp":1702428971081},"reference-count":75,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2023,12,12]],"date-time":"2023-12-12T00:00:00Z","timestamp":1702339200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2023,12,12]],"date-time":"2023-12-12T00:00:00Z","timestamp":1702339200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2023,12,12]],"date-time":"2023-12-12T00:00:00Z","timestamp":1702339200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chem. Mater."],"DOI":"10.1021\/acs.chemmater.3c02346","type":"journal-article","created":{"date-parts":[[2023,12,12]],"date-time":"2023-12-12T13:43:41Z","timestamp":1702388621000},"source":"Crossref","is-referenced-by-count":0,"title":["Nonclassical Crystallization Pathway of Transition Metal Phosphate Compounds"],"prefix":"10.1021","author":[{"given":"Stephanos","family":"Karafiludis","sequence":"first","affiliation":[{"name":"Federal Institute for Materials Research and Testing, Richard-Willstatter-Stra\u00dfe 11, Berlin 12489, Germany"},{"name":"Department of Chemistry, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Stra\u00dfe 2, Berlin 12489, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-8375-0365","authenticated-orcid":true,"given":"Zdravko","family":"Kochovski","sequence":"additional","affiliation":[{"name":"Department for Electrochemical Energy Storage, Helmholtz-Zentrum Berlin for Materials and Energy, Hahn-Meitner Platz 1, Berlin 14109, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-6390-052X","authenticated-orcid":true,"given":"Ernesto","family":"Scoppola","sequence":"additional","affiliation":[{"name":"Biomaterials, Hierarchical Structure of Biological and Bio-inspired Materials, Max Planck Institute of Colloids and Interfaces, Potsdam 14476, Germany"}]},{"given":"Anika","family":"Retzmann","sequence":"additional","affiliation":[{"name":"Federal Institute for Materials Research and Testing, Richard-Willstatter-Stra\u00dfe 11, Berlin 12489, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-7901-6114","authenticated-orcid":true,"given":"Vasile-Dan","family":"Hodoroaba","sequence":"additional","affiliation":[{"name":"Federal Institute for Materials Research and Testing, Richard-Willstatter-Stra\u00dfe 11, Berlin 12489, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7995-6571","authenticated-orcid":true,"given":"Johan E.","family":"ten Elshof","sequence":"additional","affiliation":[{"name":"MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, Enschede 7500 AE, The Netherlands"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-8528-0301","authenticated-orcid":true,"given":"Franziska","family":"Emmerling","sequence":"additional","affiliation":[{"name":"Federal Institute for Materials Research and Testing, Richard-Willstatter-Stra\u00dfe 11, Berlin 12489, Germany"},{"name":"Department of Chemistry, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Stra\u00dfe 2, Berlin 12489, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-0881-5808","authenticated-orcid":true,"given":"Tomasz M.","family":"Stawski","sequence":"additional","affiliation":[{"name":"Federal Institute for Materials Research and Testing, Richard-Willstatter-Stra\u00dfe 11, Berlin 12489, Germany"}]}],"member":"316","published-online":{"date-parts":[[2023,12,12]]},"reference":[{"key":"ref1\/cit1","unstructured":"Gislev, M.; Grohol, M.; Mathieux, F.; Ardente, F. Report on Critical Raw Materials in the Circular Economy, European Commission2018."},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.gloenvcha.2008.10.009"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.2138\/rmg.2002.48.10"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.2c00284"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1039\/d2nr05630e"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2019.09.118"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC08770E"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT00839H"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/srep17613"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/es402710y"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c01814"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02658"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c02385"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202100498"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202000360"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.3390\/ma6010217"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2010.11.054"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1016\/j.desal.2006.08.019"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1016\/S0043-1354(00)00236-0"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01494"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1088\/1755-1315\/770\/1\/012034"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/es302296m"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/es500188t"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2020.144269"},{"key":"ref25\/cit25","first-page":"215","volume":"4","author":"Ravikumar R.","year":"2010","journal-title":"Optoelectron. Adv. Mater."},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2008.02.050"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0248(94)90065-5"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.3390\/min9090503"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1039\/C8NR09205B"},{"key":"ref30\/cit30","first-page":"108","volume":"3","author":"Gibbs J. W.","year":"1876","journal-title":"Trans. Conn. Acad. Arts Sci."},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1515\/zpch-1926-11927"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcrysgro.2016.10.028"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1063\/1.1638740"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1063\/1.4916356"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.98.145702"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1016\/j.jnoncrysol.2017.11.047"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1063\/1.474721"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/ar9702278"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1126\/science.1164271"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1039\/c0nr00628a"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-020-75937-2"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.3390\/cryst11070738"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/cg501099d"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/ja510533x"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1309320111"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1179\/1743284713Y.0000000433"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.8b00289"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1007\/s13391-021-00318-4"},{"key":"ref49\/cit49","volume-title":"Chemical Vapor Deposition - Recent Advances and Applications in Optical, Solar Cells and Solid State Devices","author":"Jung J.-S.","year":"2016"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1179\/1743280411Y.0000000015"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms11177"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/acsbiomaterials.1c00196"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.0c00151"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1039\/D3CE00386H"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2406"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1063\/1.4960953"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889895005292"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889895011605"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202001068"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/cm803144d"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2014.05.012"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1039\/c0nr00761g"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms2490"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP05975B"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1021\/ja994286n"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1021\/ar50092a003"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.4236\/aces.2017.72015"},{"key":"ref68\/cit68","unstructured":"Rumble, J.; Lide, D.; Bruno, T. CRC Handbook of Chemistry and Physics; CRC Press: Cleveland, Ohio, 1977; pp 5\u2013189."},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1088\/0022-3727\/24\/2\/001"},{"key":"ref70\/cit70","first-page":"446","volume":"22","author":"Donnay J. D. H.","year":"1937","journal-title":"Am. Mineral."},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.6b00208"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3604"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaa6760"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1039\/C0NR00589D"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201500400"}],"container-title":["Chemistry of Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.chemmater.3c02346","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acs.chemmater.3c02346","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,12,12]],"date-time":"2023-12-12T13:46:43Z","timestamp":1702388803000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.chemmater.3c02346"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,12,12]]},"references-count":75,"alternative-id":["10.1021\/acs.chemmater.3c02346"],"URL":"http:\/\/dx.doi.org\/10.1021\/acs.chemmater.3c02346","relation":{},"ISSN":["0897-4756","1520-5002"],"issn-type":[{"value":"0897-4756","type":"print"},{"value":"1520-5002","type":"electronic"}],"subject":["Materials Chemistry","General Chemical Engineering","General Chemistry"],"published":{"date-parts":[[2023,12,12]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">30.01.2024</enrichment>
    <author>Stephanos Karafiludis</author>
    <author>Z. Kochovski</author>
    <author>E. Scoppola</author>
    <author>Anika Retzmann</author>
    <author>Vasile-Dan Hodoroaba</author>
    <author>J. E. ten Elshof</author>
    <author>Franziska Emmerling</author>
    <author>Tomasz Maciej Stawski</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Non-classical crystallization theory</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Transition metals</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Phosphates</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Amorphous phases</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Intermediate phases</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">1 Analytische Chemie; Referenzmaterialien</collection>
    <collection role="institutes" number="">1.3 Instrumentelle Analytik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.3 Strukturanalytik</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
  </doc>
</export-example>
