<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>58210</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>15673</pageFirst>
    <pageLast>15684</pageLast>
    <pageNumber/>
    <edition/>
    <issue>17</issue>
    <volume>6</volume>
    <type>article</type>
    <publisherName>ACS</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Confinement-suppressed phase transition and dynamic self-assembly of ionic superdiscs in ordered nanochannels: Implication for nanoscale applications</title>
    <abstract language="eng">Ionic Liquid Crystals are ionic liquids that exhibit liquid crystalline mesomorphism together with ionic conductivity. As known confined liquid crystal mesophases can show an anomalous dynamics and phase behavior. Investigations considering the factors controlling the macroscopic properties of ILCs in confinement are scare in the literature. This study reports the molecular mobility, and the phase transition behavior of a guanidinium based columnar ILC confined in the nanopores of self-ordered anodic aluminum oxide membranes of various pore diameters (25 – 180 nm) using Broadband Dielectric Spectroscopy (BDS), calorimetry and X-ray scattering. It is aimed to reveal in which way the pore size as well as the pore surface wettability (hydrophobic or hydrophilic) alters the molecular dynamics, and phase transition behavior for this system. These properties are crucial for applications. The DSC investigations reveal: (i) the phase transition temperature for the transition from the plastic crystalline to the crystalline-liquid state has non-monotonic dependence versus the inverse pore diameter and (ii) the transition from the liquid crystalline to the isotropic phase is suppressed for all nanoconfined samples. This transition suppressed in the thermal signal was evidenced by BDS and X-ray scattering. It is discussed as a continuous phase transition taking place in the pores instead of a discontinuous first order transition as observed for the bulk. BDS investigations show different relaxation processes for the bulk and the nanoconfined ILC. Molecular origins for various relaxation processes are discussed and suggested. It is further shown that the self-assembly of this ILC is dynamic in nature which might apply for other ILCs too. The obtained results will have implications for the nanoscale applications of ionic liquid crystals.</abstract>
    <parentTitle language="eng">ACS Applied Nano Materials</parentTitle>
    <identifier type="doi">10.1021/acsanm.3c02473</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">16.10.2023</enrichment>
    <author>Mohamed A. Kolmangadi</author>
    <author>L. Zhuoqing</author>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <author>E. Wuckert</author>
    <author>A. Raab</author>
    <author>S. Laschat</author>
    <author>P. Huber</author>
    <author>Andreas Schönhals</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionic Liquid Crystals</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="institutes" number="">6.6 Digitale Materialchemie</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
  </doc>
  <doc>
    <id>57810</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>19662</pageFirst>
    <pageLast>19673</pageLast>
    <pageNumber/>
    <edition/>
    <issue>29</issue>
    <volume>13</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Highly porous phosphate-based glasses for controlled delivery of antibacterial Cu ions prepared via sol–gel chemistry</title>
    <abstract language="eng">Mesoporous glasses are a promising class of bioresorbable biomaterials characterized by high surface area and extended porosity in the range of 2 to 50 nm. These peculiar properties make them ideal materials for the controlled release of therapeutic ions and molecules. Whilst mesoporous silicate-based glasses (MSG) have been widely investigated, much less work has been done on mesoporous phosphate-based glasses (MPG). In the present study, MPG in the P2O5–CaO–Na2O system, undoped and doped with 1, 3, and 5 mol% of Cu ions were synthesized via a combination of the sol–gel method and supramolecular templating. The non-ionic triblock copolymer Pluronic P123 was used as a templating agent. The porous structure was studied via a combination of Scanning Electron Microscopy (SEM), Small-Angle X-ray Scattering (SAXS), and N2 adsorption–desorption analysis at 77 K. The structure of the phosphate network was investigated via solid state 31P Magic Angle Spinning Nuclear Magnetic Resonance (31P MAS-NMR) and Fourier Transform Infrared (FTIR) spectroscopy. Degradation studies, performed in water via Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES), showed that phosphates, Ca2+, Na+ and Cu ions are released in a controlled manner over a 7 days period. The controlled release of Cu, proportional to the copper loading, imbues antibacterial properties to MPG. A significant statistical reduction of Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) bacterial viability was observed over a 3 days period. E. coli appeared to be more resistant than S. aureus to the antibacterial effect of copper. This study shows that copper doped MPG have great potential as bioresorbable materials for controlled delivery of antibacterial ions.</abstract>
    <parentTitle language="eng">RSC Advances</parentTitle>
    <identifier type="doi">10.1039/D3RA02958A</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-578101</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">10.07.2023</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>F. Foroutan</author>
    <author>B. A. Kyffin</author>
    <author>A. Nikolaou</author>
    <author>J. Merino-Gutierrez</author>
    <author>I. Abrahams</author>
    <author>N. Kanwal</author>
    <author>J. C. Knowles</author>
    <author>A. J. Smith</author>
    <author>Glen Jacob Smales</author>
    <author>D. Carta</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bioresorbable Biomaterials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mesoporous phosphate-based glasses</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Synthesis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Degradation studies</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MOUSE</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Antibacterial properties</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Aantimicrobial</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/57810/d3ra02958a.pdf</file>
  </doc>
  <doc>
    <id>57697</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>4588</pageFirst>
    <pageLast>4598</pageLast>
    <pageNumber/>
    <edition/>
    <issue>24</issue>
    <volume>19</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Comparative study of the co-assembly behaviour of 3-chloro-4-hydroxy-phenylazo dyes with DTAB</title>
    <abstract language="eng">The co-assembly of three one-fold negatively charged 3-chloro-4-hydroxy-phenylazo dyes (Yellow, Blue and Red) with the cationic surfactant dodecyltrimethylammoniumbromide (DTAB) was studied to probe dye–DTAB binding stoichiometry and assembly morphology. For each dye, phase separation was observed above a given dye : DTAB ratio with the ratio depending on the dye. While Yellow and DTAB showed liquid/liquid phase separation above Yellow : DTAB = 1 : 1.67, crystalline dye–DTAB complexes were observed for Blue–DTAB and Red–DTAB above Blue : DTAB = 1 : 2.56 and Red : DTAB = 1 : 2.94 respecively. In homogeneous solution, UV/vis spectroscopic investigations suggest stochiometries of Yellow : DTAB = 1 : 2, Blue : DTAB = 1 : 3 and Red : DTAB = 1 : 4. It was concluded, that Yellow exhibits the highest dye : DTAB binding stoichiometry in both, dye–surfactant complexes in the 2-phase region and in solution, whereas the lowest dye : DTAB binding stoichiometry was observed for Red–DTAB in both cases. The observed stoichiometries are inversely correlated to the impact dye addition has on the morphology of DTAB micelles. Generally, addition of dye to DTAB micelles leads to a reduction in spontaneous curvature of these micelles and to the formation of triaxial ellipsoidal or cylindrical micelles from oblate ellipsoidal DTAB micelles. At a DTAB concentration of 30 mM and a dye concentration of 5 mM, this effect was most pronounced for Red and least pronounced for Yellow, whilst Blue showed an intermediate effect.</abstract>
    <parentTitle language="eng">Soft Matter</parentTitle>
    <identifier type="doi">10.1039/D3SM00501A</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-576978</identifier>
    <identifier type="issn">1744-683X</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">19.06.2023</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>W. Müller</author>
    <author>R. Schweins</author>
    <author>B. Nöcker</author>
    <author>J. Kohlbrecher</author>
    <author>Glen Jacob Smales</author>
    <author>K. Huber</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dye</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>DTAB</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Small-angle X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Data analysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Micelle</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/57697/d3sm00501a.pdf</file>
  </doc>
  <doc>
    <id>50183</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>16</pageFirst>
    <pageLast>23</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Gold and silver dichroic nanocomposite in the quest for 3D printing the Lycurgus cup</title>
    <abstract language="eng">The Lycurgus cup is an ancient glass artefact that shows dichroism as it looks green when a white light is reflected on it and a red colouring appears when a white light is transmitted through it. This peculiar dichroic effect is due to silver and gold nanoparticles present in the glass. In this research we show the synthesis of dichroic silver nanoparticles and their embedding in a 3D printable nanocomposite. The addition of gold nanoparticles to the silver nanoparticle composite, gave a 3D printable nanocomposite with the same dichroism effect of the Lycurgus cup.</abstract>
    <parentTitle language="eng">Beilstein Journal of Nanotechnology</parentTitle>
    <identifier type="doi">10.3762/bjnano.11.2</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-501831</identifier>
    <enrichment key="date_peer_review">20.01.2020</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>L. Kool</author>
    <author>F. Dekker</author>
    <author>A. Bunschoten</author>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <author>A. H. Velders</author>
    <author>V. Saggiomo</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Au</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ag</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanocomposite</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>3D printing</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/50183/007_Saggiomo_Gold_and_silver_dichroic_nanocomposite_in_the_quest_for_3D.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/50183/007_Saggiomo_SI_Gold_and_silver_dichroic_nanocomposite_in_the_quest_for_3D.pdf.pdf</file>
  </doc>
  <doc>
    <id>51553</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>11</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>Royal Society of Chemistry</volume>
    <type>article</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The effect of precursor structure on porous carbons produced by iron-catalyzed graphitization of biomass</title>
    <abstract language="eng">This paper reports a systematic study into the effect of different biomass-derived precursors on the structure and porosity of carbons prepared via catalytic graphitization. Glucose, starch and cellulose are combined with iron nitrate and heated under a nitrogen atmosphere to produce Fe3C nanoparticles, which catalyze the conversion of amorphous carbon to graphitic nanostructures. The choice of organic precursor provides a means of controlling the catalyst particle size, which has a direct effect on the porosity of the material. Cellulose and glucose produce mesoporous carbons, while starch produces a mixture of micro- and mesopores under the same conditions and proceeds via a much slower graphitization step, generating a mixture of graphitic nanostructures and turbostratic carbon. Porous carbons are critical to energy applications such as batteries and electrocatalytic processes. For These applications, a simple and sustainable route to those carbons is essential. Therefore, the ability to control the precise structure of a biomass-derived carbon simply through the choice of precursor will enable the production of a new generation of energy materials.</abstract>
    <parentTitle language="eng">Materials Advances</parentTitle>
    <identifier type="doi">10.1039/d0ma00692k</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-515531</identifier>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>R. D. Hunter</author>
    <author>J. L. Rowlandson</author>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <author>V. P. Ting</author>
    <author>A. Kulak</author>
    <author>Z. Schnepp</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porous carbons</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Graphitization</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Iron nanoparticles</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Catalysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Gas sorption</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/51553/013_Hunter_Effect_of_precursor_structure_on_porous_carbons.pdf</file>
  </doc>
  <doc>
    <id>51825</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>researchdata</type>
    <publisherName>Zenodo</publisherName>
    <publisherPlace>Geneva</publisherPlace>
    <creatingCorporation>Bundesanstalt für Materialforschung und -prüfung (BAM)</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Complete set of raw and processed datasets, as well as associated Jupyter notebooks for analysis, associated with manuscript entitled: "The MOUSE project: a practical approach for obtaining traceable, wide-range X-ray scattering information"</title>
    <abstract language="eng">This dataset is a complete set of raw, processed and analyzed data, complete with Jupiter notebooks, associated with the manuscript mentioned in the title.&#13;
&#13;
In the manuscript, we provide a "systems architecture"-like overview and detailed discussions of the methodological and instrumental components that, together, comprise the "MOUSE" project (Methodology Optimization for Ultrafine Structure Exploration). Through this project, we aim to provide a comprehensive methodology for obtaining the highest quality X-ray scattering information (at small and wide angles) from measurements on materials science samples.</abstract>
    <identifier type="doi">10.5281/zenodo.4312953</identifier>
    <enrichment key="ScientificResourceTypeGeneral">Datensatz</enrichment>
    <enrichment key="ScientificDateCreatedStart">15.08.2018</enrichment>
    <enrichment key="ScientificDateCreatedEnd">26.10.2020</enrichment>
    <enrichment key="ScientificGeolocation">Berlin, Germany</enrichment>
    <enrichment key="ScientificNote">Jupyter notebook with the evaluation of the raw and processed datasets (in NeXus and NXsas formats). The NeXus files are supplied with extensive metadata.</enrichment>
    <enrichment key="RelatedIdentifier">https://nbn-resolving.org/urn:nbn:de:kobv:b43-528669</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Brian Richard Pauw</author>
    <author>Glen Jacob Smales</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Measurement methodology</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Traceability derivation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multi-scale measurements</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Systems architecture</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanomaterials</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="literaturgattung" number="">Graue Literatur</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="unnumberedseries" number="">Forschungsdatensätze der BAM</collection>
  </doc>
  <doc>
    <id>52866</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>50</pageLast>
    <pageNumber/>
    <edition/>
    <issue>6</issue>
    <volume>16</volume>
    <type>article</type>
    <publisherName>IOP</publisherName>
    <publisherPlace>Bristol, UK</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The MOUSE project - A meticulous approach for obtaining traceable, wide-range X-ray scattering information</title>
    <abstract language="eng">Herein, we provide a "systems architecture"-like overview and detailed discussions of the methodological and instrumental components that, together, comprise the "MOUSE" project (Methodology Optimization for UltrafineStructure Exploration). The MOUSE project provides scattering information on a wide variety of samples, with traceable dimensions for both the scattering vector (q) and the absolute scattering cross-section (I). The measurable scattering vector-range of 0.012≤ q (nm-1) ≤ 92, allows information across a hierarchy of structures with dimensions ranging from ca. 0.1 to 400 nm. In addition to details that comprise the MOUSE project, such as the organisation and traceable aspects, several representative examples are provided to demonstrate its flexibility. These include measurements on alumina membranes, the tobacco mosaic virus, and dual-source information that overcomes fluorescence limitations on ZIF-8 and iron-oxide-containing carbon catalyst materials.</abstract>
    <parentTitle language="eng">Journal of instrumentation</parentTitle>
    <identifier type="doi">10.1088/1748-0221/16/06/P06034</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-528669</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="RelatedIdentifier">https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/51825</enrichment>
    <enrichment key="date_peer_review">19.08.2021</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MOUSE</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Instrumentation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Methodology</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Traceability</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Wide-range</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Data curation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>FAIR</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Uncertainties</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanomaterials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanometrology</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/52866/Smales_2021_J._Inst._16_P06034.pdf</file>
  </doc>
  <doc>
    <id>52666</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1634</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue>10</issue>
    <volume>13</volume>
    <type>article</type>
    <publisherName>MDPI</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Calorimetric and Dielectric Investigations of Epoxy-Based Nanocomposites with Halloysite Nanotubes as Nanofillers</title>
    <abstract language="eng">Epoxy nanocomposites are promising materials for industrial applications (i.e., aerospace, marine and automotive industry) due to their extraordinary mechanical and thermal properties. Here, the effect of hollow halloysite nanotubes (HNT) on an epoxy matrix (Ep) was the focus of the study. The structure and molecular mobility of the nanocomposites were investigated using a combination of X-ray scattering, calorimetry (differential (DSC) and fast scanning calorimetry (FSC)) and dielectric spectroscopy. Additionally, the effect of surface modification of HNT (polydopamine (PDA) and Fe(OH)3 nanodots) was considered. For Ep/HNT, the glass transition temperature (Tg) is was de-creased due to a nanoparticle-related decrease of the crosslinking density. For the modified system, Ep/m-HNT, the surface modification resulted in enhanced filler–matrix interactions leading to higher Tg values than the pure epoxy in some cases. For Ep/m-HNT, the amount of interface formed between the nanoparticles and the matrix ranged from 5% to 15%. Through BDS measurements, localized fluctuations were detected as a β- and γ-relaxation, related to rotational fluctuations of phenyl rings and local reorientations of unreacted components. A combination of calorimetry and BDS dielectric spectroscopy revealed a dynamic and structural heterogeneity of the matrix, as confirmed by two glassy dynamics in both systems, related to regions with different crosslinking densities.</abstract>
    <parentTitle language="eng">Polymers</parentTitle>
    <identifier type="doi">10.3390/polym13101634</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-526668</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">03.06.2021</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Hassan Omar</author>
    <author>Glen Jacob Smales</author>
    <author>S. Henning</author>
    <author>Z. Li</author>
    <author>D.-Y. Wang</author>
    <author>Andreas Schönhals</author>
    <author>Paulina Szymoniak</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Rigid amorphous fraction</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Epoxy nanocomposites</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Halloysite nanotubes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Differential scanning calorimetry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Broadband dielectric spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Flash DSC</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="institutes" number="">6.6 Digitale Materialchemie</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/52666/polymers-13-01634.pdf</file>
  </doc>
  <doc>
    <id>58644</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>4</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Royal Society of Chemistry (RSC)</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Substituted Benzophenone Imines for COF Synthesis via Formal Transimination</title>
    <abstract language="eng">Covalent organic frameworks (COFs) are a prominent class of organic materials constructed from versatile building blocks via reversible reactions. The quality of imine-linked COFs can be improved by using amine monomers protected with benzophenone forming benzophenone imines. Here, we present a study on substituted benzophenones in COF synthesis via formal transimination. 12 para-substituted N-aryl benzophenone imines, with a range of electron-rich to electron-poor substituents, were prepared and their hydrolysis kinetics were studied spectroscopically. All substituted benzophenone imines can be employed in COF synthesis and lead to COFs with high crystallinity and high porosity. The substituents act innocent to COF formation as the substituted benzophenones are cleaved off. Imines can be tailored to their synthetic demands and utilized in COF formation. This concept can make access to previously unattainable, synthetically complex COF monomers feasible.</abstract>
    <parentTitle language="eng">Chemical Communications</parentTitle>
    <identifier type="doi">10.1039/D3CC03735E</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-586449</identifier>
    <identifier type="issn">1359-7345</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2023,10,19]],"date-time":"2023-10-19T05:24:36Z","timestamp":1697693076699},"reference-count":0,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2023,10,18]],"date-time":"2023-10-18T00:00:00Z","timestamp":1697587200000},"content-version":"vor","delay-in-days":290,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"&lt;jats:p&gt;Covalent organic frameworks (COFs) are a prominent class of organic materials constructed from versatile building blocks via reversible reactions. The quality of imine-linked COFs can be improved by using amine...&lt;\/jats:p&gt;","DOI":"10.1039\/d3cc03735e","type":"journal-article","created":{"date-parts":[[2023,10,18]],"date-time":"2023-10-18T19:02:06Z","timestamp":1697655726000},"update-policy":"http:\/\/dx.doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Substituted Benzophenone Imines for COF Synthesis via Formal Transimination"],"prefix":"10.1039","author":[{"given":"Josefine","family":"Sprachmann","sequence":"first","affiliation":[]},{"given":"Niklas","family":"Grabicki","sequence":"additional","affiliation":[]},{"given":"Anna","family":"M\u00f6ckel","sequence":"additional","affiliation":[]},{"given":"Jeremy","family":"Maltitz","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9","family":"del Refugio Monroy G\u00f3mez","sequence":"additional","affiliation":[]},{"given":"Glen J.","family":"Smales","sequence":"additional","affiliation":[]},{"given":"Oliver","family":"Dumele","sequence":"additional","affiliation":[]}],"member":"292","published-online":{"date-parts":[[2023]]},"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2023\/CC\/D3CC03735E","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,18]],"date-time":"2023-10-18T19:02:06Z","timestamp":1697655726000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2023\/CC\/D3CC03735E"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023]]},"references-count":0,"URL":"http:\/\/dx.doi.org\/10.1039\/d3cc03735e","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":["Materials Chemistry","Metals and Alloys","Surfaces, Coatings and Films","General Chemistry","Ceramics and Composites","Electronic, Optical and Magnetic Materials","Catalysis"],"published":{"date-parts":[[2023]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">06.11.2023</enrichment>
    <licence>Creative Commons - CC BY-NC - Namensnennung - Nicht kommerziell 4.0 International</licence>
    <author>J. Sprachmann</author>
    <author>N. Grabicki</author>
    <author>Anna Möckel</author>
    <author>J. Maltitz</author>
    <author>J. del Refugio Monroy Gómez</author>
    <author>Glen Jacob Smales</author>
    <author>O. Dumele</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Materials Chemistry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Metals and Alloys</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Surfaces, Coatings and Films</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>General Chemistry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ceramics and Composites</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electronic, Optical and Magnetic Materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Catalysis</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/58644/d3cc03735e.pdf</file>
  </doc>
  <doc>
    <id>58250</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>615</pageFirst>
    <pageLast>631</pageLast>
    <pageNumber/>
    <edition/>
    <issue>11-12</issue>
    <volume>4</volume>
    <type>article</type>
    <publisherName>Wiley-VCH GmbH</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Robocasting of ordered mesoporous silica‐based monoliths: Rheological, textural, and mechanical characterization</title>
    <abstract language="eng">Hierarchically porous, high‐surface‐area silica materials are excellent candidates for multiple applications like catalysis and environmental remediation. Shaping these materials with additive manufacturing (AM) techniques, like robocasting, could enable their use with the benefit of on‐demand, customized shaping and maximizing performance. Herein, ordered mesoporous silica COK‐12 slurries were robocasted into monoliths, containing different ratios of uncalcined COK‐12 and sodium bentonite (0–25 wt.%). The rheology of the mixed slurries is characterized by lower flow indexes (0.69 vs. 0.32) and higher yield stresses (96 vs. 259 Pa) compared to pure COK‐12 ones. Monoliths were printed in woodpile structures and calcined at 600°C. Micro‐CT measurements showed a linear shrinkage of 25% after calcination. Mechanical characterization showed increased uniaxial strength (0.20 ± 0.07 to 1.0 ± 0.3 MPa) with increasing binder/solids ratio from 13 to 25%. The amorphous, mesoporous structure of COK‐12 was retained. The structures exhibited open porosities of 52 ± 4% and showed higher specific mesopore volumes, and increased average mesopore size (6 vs. 8 nm) compared to COK‐12. Small‐angle x‐ray scattering analysis revealed an increased lattice parameter (10.3 vs. 11.0 nm) and reduced wall thickness (3.1 nm vs. 4.1 nm) of the COK‐12 in the monoliths. These properties indicate suitability for their application as porous supports and adsorbents.</abstract>
    <parentTitle language="eng">Nano Select</parentTitle>
    <identifier type="doi">10.1002/nano.202300109</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-582503</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2023,9,11]],"date-time":"2023-09-11T04:45:22Z","timestamp":1694407522630},"reference-count":70,"publisher":"Wiley","license":[{"start":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T00:00:00Z","timestamp":1694304000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006188","name":"Einstein Stiftung Berlin","doi-asserted-by":"publisher"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nano Select"],"abstract":"&lt;jats:title&gt;Abstract&lt;\/jats:title&gt;&lt;jats:p&gt;Hierarchically porous, high\u2010surface\u2010area silica materials are excellent candidates for multiple applications like catalysis and environmental remediation. Shaping these materials with additive manufacturing (AM) techniques, like robocasting, could enable their use with the benefit of on\u2010demand, customized shaping and maximizing performance. Herein, ordered mesoporous silica COK\u201012 slurries were robocasted into monoliths, containing different ratios of uncalcined COK\u201012 and sodium bentonite (0\u201325\u00a0wt.%). The rheology of the mixed slurries is characterized by lower flow indexes (0.69\u00a0vs. 0.32) and higher yield stresses (96\u00a0vs. 259\u00a0Pa) compared to pure COK\u201012 ones. Monoliths were printed in woodpile structures and calcined at 600\u00b0C. Micro\u2010CT measurements showed a linear shrinkage of 25% after calcination. Mechanical characterization showed increased uniaxial strength (0.20\u00a0\u00b1\u00a00.07 to 1.0\u00a0\u00b1\u00a00.3\u00a0MPa) with increasing binder\/solids ratio from 13 to 25%. The amorphous, mesoporous structure of COK\u201012 was retained. The structures exhibited open porosities of 52\u00a0\u00b1\u00a04% and showed higher specific mesopore volumes, and increased average mesopore size (6\u00a0vs. 8\u00a0nm) compared to COK\u201012. Small\u2010angle x\u2010ray scattering analysis revealed an increased lattice parameter (10.3\u00a0vs. 11.0\u00a0nm) and reduced wall thickness (3.1\u00a0nm vs. 4.1\u00a0nm) of the COK\u201012 in the monoliths. These properties indicate suitability for their application as porous supports and adsorbents.&lt;\/jats:p&gt;","DOI":"10.1002\/nano.202300109","type":"journal-article","created":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T18:14:01Z","timestamp":1694369641000},"source":"Crossref","is-referenced-by-count":0,"title":["Robocasting of ordered mesoporous silica\u2010based monoliths: Rheological, textural, and mechanical characterization"],"prefix":"10.1002","author":[{"ORCID":"http:\/\/orcid.org\/0000-0002-1377-3999","authenticated-orcid":false,"given":"Emiliano S.","family":"Dal Molin","sequence":"first","affiliation":[{"name":"Technische Universit\u00e4t Berlin Faculty III Process Sciences Institute of Material Science and Technology Chair of Advanced Ceramic Materials  Berlin Germany"}]},{"given":"Laura M.","family":"Henning","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Berlin Faculty III Process Sciences Institute of Material Science and Technology Chair of Advanced Ceramic Materials  Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-0703-8573","authenticated-orcid":false,"given":"Julian T.","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Berlin Faculty III Process Sciences Institute of Material Science and Technology Chair of Advanced Ceramic Materials  Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-8654-9867","authenticated-orcid":false,"given":"Glen J.","family":"Smales","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und \u2010pr\u00fcfung (BAM) Division 6.5 \u2013 Polymers in Life Sciences and Nanotechnology  Berlin Germany"}]},{"given":"Brian R.","family":"Pauw","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und \u2010pr\u00fcfung (BAM) Division 6.5 \u2013 Polymers in Life Sciences and Nanotechnology  Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-1778-0288","authenticated-orcid":false,"given":"Maged F.","family":"Bekheet","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Berlin Faculty III Process Sciences Institute of Material Science and Technology Chair of Advanced Ceramic Materials  Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7047-666X","authenticated-orcid":false,"given":"Aleksander","family":"Gurlo","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Berlin Faculty III Process Sciences Institute of Material Science and Technology Chair of Advanced Ceramic Materials  Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6233-6595","authenticated-orcid":false,"given":"Ulla","family":"Simon","sequence":"additional","affiliation":[{"name":"Technische Universit\u00e4t Berlin Faculty III Process Sciences Institute of Material Science and Technology Chair of Advanced Ceramic Materials  Berlin Germany"}]}],"member":"44667","published-online":{"date-parts":[[2023,9,10]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2021.08.031"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.clay.2019.105285"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2594-0"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(20020916)14:18&lt;1279::AID-ADMA1279&gt;3.0.CO;2-A"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/la0257135"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200600434"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2016.03.001"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1088\/1758-5090\/aa6c37"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/jbm.b.31811"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201902143"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202005743"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201907212"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300323"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envres.2020.109297"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2013.05.020"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b16732"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2018.01.070"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2020.118628"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/cite.201700151"},{"key":"e_1_2_9_21_1","first-page":"13","author":"Bogdan E.","year":"2020","journal-title":"Materials (Basel, Switzerland)"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-019-0097-z"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY00615B"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00631D"},{"key":"e_1_2_9_25_1","doi-asserted-by":"crossref","unstructured":"J. F.Le Page J.Miquel In: Preparation of Catalysts I\u2014Scientific Bases for the Preparation of Heterogeneous Catalysts Proceedings of the First International Symposium held at the Solvay Research Centre Vol.1 Elsevier1976 p.39.","DOI":"10.1016\/S0167-2991(08)63942-7"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jnnfm.2016.11.001"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.3390\/fluids6040157"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/b517840a"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2018.11.013"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.200751215"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35378D"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1627\/jpi.55.13"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1139\/v2012-094"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1166\/jnn.2005.089"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2009.03.046"},{"key":"e_1_2_9_36_1","author":"Kleitz F.","year":"2003","journal-title":"Chem. Commun. (Camb.)"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2018.10.154"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/b915273c"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja205627t"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2019.01.050"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA05541J"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2018.03.015"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/nano.202200223"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2017.08.002"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NA00368F"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2016.06.025"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jddst.2023.104622"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.3389\/fceng.2022.810443"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SE00518F"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2015.08.008"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2020.106586"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/jps.22535"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/pat.5610"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00060"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1186\/s40694-021-00129-0"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1088\/1748-0221\/16\/06\/P06034"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576717015096"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576717004708"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576715016544"},{"key":"e_1_2_9_60_1","unstructured":"ISO 17162:2014. Fine ceramics (advanced ceramics advanced technical ceramics): Mechanical properties of monolithic ceramics at room temperature \u2014 Determination of compressive strength."},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0927-7757(97)00133-7"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SM01936C"},{"key":"e_1_2_9_63_1","doi-asserted-by":"crossref","unstructured":"L. A.Alc\u00e1zar\u2010Vara J.Guerrero\u2010Hern\u00e1ndez C.Chacon I. R.Cort\u00e9s\u2010Monroy Energy sources part A: recovery utilization and environmental effects.2021 1\u201314.","DOI":"10.1080\/15567036.2021.1977871"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/la00075a004"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11440-019-00903-w"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10934-007-9182-7"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.3934\/environsci.2015.2.154"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1515\/pac-2014-1117"},{"key":"e_1_2_9_69_1","volume-title":"Handbook of applied surface and colloid chemistry","author":"Holmberg K.","year":"2002"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9797(75)90224-6"},{"key":"e_1_2_9_71_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10934-020-00865-5"}],"container-title":["Nano Select"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/nano.202300109","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T18:14:07Z","timestamp":1694369647000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/nano.202300109"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,9,10]]},"references-count":70,"alternative-id":["10.1002\/nano.202300109"],"URL":"http:\/\/dx.doi.org\/10.1002\/nano.202300109","archive":["Portico"],"relation":{},"ISSN":["2688-4011","2688-4011"],"issn-type":[{"value":"2688-4011","type":"print"},{"value":"2688-4011","type":"electronic"}],"subject":["Industrial and Manufacturing Engineering"],"published":{"date-parts":[[2023,9,10]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">25.03.2024</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>E. S. Dal Molin</author>
    <author>L. M. Henning</author>
    <author>J. T. Müller</author>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <author>M. F. Bekheet</author>
    <author>A. Gurlo</author>
    <author>U. Simon</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Industrial and Manufacturing Engineering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Additive manufacturing</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>OMS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porous materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Robocasting</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MOUSE</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="themenfelder" number="">Additive Fertigung</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/58250/Nano Select - 2023 - Dal Molin.pdf</file>
  </doc>
  <doc>
    <id>61480</id>
    <completedYear/>
    <publishedYear>2024</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>10</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Royal Society of Chemistry (RSC)</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The effect of catalyst precursors on the mechanism of iron-catalysed graphitization of cellulose</title>
    <abstract language="eng">Iron-catalysed graphitization of biomass is a simple and sustainable route to carbons with high graphitic content. It uses abundant precursors and moderate processing temperatures and generates carbons with high porosity. Recently, it has been demonstrated that the choice of biomass precursor can have a significant impact on the textural and compositional properties of the resulting carbon. In this paper, we demonstrate that the choice of catalyst is also critical to the carbon structure. Aqueous iron(III) nitrate and iron(III) chloride convert cellulose to carbons with very different textural properties. This is due to the choice of iron catalyst changing the mechanism of cellulose decomposition and also the nature of the active graphitization catalyst.</abstract>
    <parentTitle language="eng">RSC Sustainability</parentTitle>
    <identifier type="doi">10.1039/D4SU00365A</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-614800</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,10,14]],"date-time":"2024-10-14T09:40:10Z","timestamp":1728898810736},"reference-count":40,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2024,10,14]],"date-time":"2024-10-14T00:00:00Z","timestamp":1728864000000},"content-version":"vor","delay-in-days":287,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100000275","name":"Leverhulme Trust","doi-asserted-by":"publisher","award":["RPG-2020-076"],"id":[{"id":"10.13039\/501100000275","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000855","name":"University of Birmingham","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000855","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Sustain."],"abstract":"&lt;jats:p&gt;The choice of catalyst is critical in determining the textural properties during graphitization of biomass.&lt;\/jats:p&gt;","DOI":"10.1039\/d4su00365a","type":"journal-article","created":{"date-parts":[[2024,10,14]],"date-time":"2024-10-14T08:30:42Z","timestamp":1728894642000},"update-policy":"http:\/\/dx.doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["The effect of catalyst precursors on the mechanism of iron-catalysed graphitization of cellulose"],"prefix":"10.1039","author":[{"ORCID":"http:\/\/orcid.org\/0009-0004-9211-954X","authenticated-orcid":false,"given":"Emily C.","family":"Hayward","sequence":"first","affiliation":[{"name":"School of Chemistry, University of Birmingham, B15 2TT, UK"}]},{"given":"Glen J.","family":"Smales","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und -pr\u00fcfung (BAM), Unter den Eichen 87, Berlin 12205, Germany"}]},{"given":"Brian R.","family":"Pauw","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und -pr\u00fcfung (BAM), Unter den Eichen 87, Berlin 12205, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-0282-6020","authenticated-orcid":false,"given":"Masaki","family":"Takeguchi","sequence":"additional","affiliation":[{"name":"Center for Basic Research on Materials, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki, 305-0047, Japan"}]},{"given":"Alexander","family":"Kulak","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK"}]},{"given":"Robert D.","family":"Hunter","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Imperial College London, London SW7 2AZ, UK"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-2171-067X","authenticated-orcid":false,"given":"Zoe","family":"Schnepp","sequence":"additional","affiliation":[{"name":"School of Chemistry, University of Birmingham, B15 2TT, UK"}]}],"member":"292","published-online":{"date-parts":[[2024]]},"reference":[{"key":"D4SU00365A\/cit1\/1","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/j.nanoen.2017.01.021","volume":"33","author":"Zhu","year":"2017","journal-title":"Nano Energy"},{"key":"D4SU00365A\/cit2\/1","doi-asserted-by":"crossref","first-page":"4750","DOI":"10.1002\/celc.202101174","volume":"8","author":"Drews","year":"2021","journal-title":"Chemelectrochem"},{"key":"D4SU00365A\/cit3\/1","doi-asserted-by":"crossref","first-page":"20200336","DOI":"10.1098\/rsta.2020.0336","volume":"379","author":"Hunter","year":"2021","journal-title":"Philos. Trans. R. Soc., A"},{"key":"D4SU00365A\/cit4\/1","first-page":"18","volume":"9","author":"Herou","year":"2018","journal-title":"Green Sustain. Chem."},{"key":"D4SU00365A\/cit5\/1","doi-asserted-by":"crossref","first-page":"695","DOI":"10.1126\/science.1218930","volume":"337","author":"Tuck","year":"2012","journal-title":"Science"},{"key":"D4SU00365A\/cit6\/1","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1039\/C5TA09202G","volume":"4","author":"Coromina","year":"2016","journal-title":"J. Mater. Chem. A"},{"key":"D4SU00365A\/cit7\/1","doi-asserted-by":"crossref","first-page":"551","DOI":"10.1039\/C4GC01673D","volume":"17","author":"Thompson","year":"2015","journal-title":"Green Chem."},{"key":"D4SU00365A\/cit8\/1","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1016\/j.cplett.2010.03.011","volume":"490","author":"Sevilla","year":"2010","journal-title":"Chem. Phys. Lett."},{"key":"D4SU00365A\/cit9\/1","doi-asserted-by":"crossref","first-page":"931","DOI":"10.1016\/j.carbon.2008.02.019","volume":"46","author":"Sevilla","year":"2008","journal-title":"Carbon"},{"key":"D4SU00365A\/cit10\/1","doi-asserted-by":"crossref","first-page":"122380","DOI":"10.1016\/j.matchemphys.2019.122380","volume":"242","author":"Li","year":"2020","journal-title":"Mater. Chem. Phys."},{"key":"D4SU00365A\/cit11\/1","doi-asserted-by":"crossref","first-page":"4489","DOI":"10.1039\/D1TA09654K","volume":"10","author":"Hunter","year":"2022","journal-title":"J. Mater. Chem. A"},{"key":"D4SU00365A\/cit12\/1","first-page":"032001","volume":"5","author":"Abbott","year":"2022","journal-title":"J. Phys.: Mater."},{"key":"D4SU00365A\/cit13\/1","doi-asserted-by":"crossref","first-page":"1126","DOI":"10.1016\/j.rser.2015.12.185","volume":"57","author":"Kan","year":"2016","journal-title":"Renewable Sustainable Energy Rev."},{"key":"D4SU00365A\/cit14\/1","doi-asserted-by":"crossref","first-page":"435","DOI":"10.1016\/j.psep.2022.04.024","volume":"162","author":"Suriapparao","year":"2022","journal-title":"Process Saf. Environ. Prot."},{"key":"D4SU00365A\/cit15\/1","doi-asserted-by":"crossref","first-page":"2797","DOI":"10.1007\/s12649-020-01255-3","volume":"12","author":"Ischia","year":"2021","journal-title":"Waste Biomass Valorization"},{"key":"D4SU00365A\/cit16\/1","doi-asserted-by":"crossref","first-page":"3281","DOI":"10.1039\/D0MA00692K","volume":"1","author":"Hunter","year":"2020","journal-title":"Adv. Mater."},{"key":"D4SU00365A\/cit17\/1","doi-asserted-by":"crossref","first-page":"2070","DOI":"10.1039\/D3MA00039G","volume":"4","author":"Hunter","year":"2023","journal-title":"Adv. Mater."},{"key":"D4SU00365A\/cit18\/1","doi-asserted-by":"crossref","first-page":"3358","DOI":"10.1002\/anie.200460587","volume":"44","author":"Klemm","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"D4SU00365A\/cit19\/1","doi-asserted-by":"crossref","first-page":"10653","DOI":"10.1021\/acs.jpcc.5b00477","volume":"119","author":"Hoekstra","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"D4SU00365A\/cit20\/1","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1016\/j.carbon.2016.05.065","volume":"107","author":"Hoekstra","year":"2016","journal-title":"Carbon"},{"key":"D4SU00365A\/cit21\/1","first-page":"3165","volume":"13","author":"Chen","year":"2018","journal-title":"Bioresources"},{"key":"D4SU00365A\/cit22\/1","doi-asserted-by":"crossref","first-page":"1051","DOI":"10.1515\/pac-2014-1117","volume":"87","author":"Thommes","year":"2015","journal-title":"Pure Appl. Chem."},{"key":"D4SU00365A\/cit23\/1","doi-asserted-by":"crossref","first-page":"5364","DOI":"10.1039\/C3CC47480A","volume":"50","author":"Schnepp","year":"2014","journal-title":"Chem. Commun."},{"key":"D4SU00365A\/cit24\/1","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1038\/nnano.2013.46","volume":"8","author":"Ferrari","year":"2013","journal-title":"Nat. Nanotechnol."},{"key":"D4SU00365A\/cit25\/1","doi-asserted-by":"crossref","first-page":"3412","DOI":"10.1021\/acs.energyfuels.0c00134","volume":"34","author":"Yang","year":"2020","journal-title":"Energy Fuels"},{"key":"D4SU00365A\/cit26\/1","doi-asserted-by":"crossref","first-page":"20097","DOI":"10.1021\/jp906702p","volume":"113","author":"Lin","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"D4SU00365A\/cit27\/1","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.biombioe.2015.04.032","volume":"80","author":"Collard","year":"2015","journal-title":"Biomass Bioenergy"},{"key":"D4SU00365A\/cit28\/1","doi-asserted-by":"crossref","first-page":"123934","DOI":"10.1016\/j.colsurfa.2019.123934","volume":"582","author":"Xu","year":"2019","journal-title":"Colloids Surf., A"},{"key":"D4SU00365A\/cit29\/1","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1016\/j.jaap.2007.09.005","volume":"81","author":"Shimada","year":"2008","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"D4SU00365A\/cit30\/1","doi-asserted-by":"crossref","first-page":"484","DOI":"10.1016\/j.fuproc.2017.08.007","volume":"167","author":"Zhang","year":"2017","journal-title":"Fuel Process. Technol."},{"key":"D4SU00365A\/cit31\/1","first-page":"242","volume":"54","author":"Kawamoto","year":"2008","journal-title":"Sci"},{"key":"D4SU00365A\/cit32\/1","doi-asserted-by":"crossref","first-page":"2664","DOI":"10.1021\/ef101619e","volume":"25","author":"Zhang","year":"2011","journal-title":"Energy Fuels"},{"key":"D4SU00365A\/cit33\/1","doi-asserted-by":"crossref","first-page":"7062","DOI":"10.1021\/acs.inorgchem.0c03692","volume":"60","author":"Chambers","year":"2021","journal-title":"Inorg. Chem."},{"key":"D4SU00365A\/cit34\/1","doi-asserted-by":"crossref","first-page":"1663","DOI":"10.1177\/01445987231164817","volume":"41","author":"Jia","year":"2023","journal-title":"Energy Explor. Exploit."},{"key":"D4SU00365A\/cit35\/1","doi-asserted-by":"crossref","first-page":"107367","DOI":"10.1016\/j.fuproc.2022.107367","volume":"235","author":"Liu","year":"2022","journal-title":"Fuel Process. Technol."},{"key":"D4SU00365A\/cit36\/1","doi-asserted-by":"crossref","first-page":"336","DOI":"10.1007\/BF00549931","volume":"1","author":"Robinson","year":"1966","journal-title":"J. Mater. Sci."},{"key":"D4SU00365A\/cit37\/1","doi-asserted-by":"crossref","first-page":"338","DOI":"10.1016\/j.carbon.2015.12.044","volume":"99","author":"Zhu","year":"2016","journal-title":"Carbon"},{"key":"D4SU00365A\/cit38\/1","doi-asserted-by":"crossref","first-page":"962","DOI":"10.1107\/S1600576715007347","volume":"48","author":"Bressler","year":"2015","journal-title":"J. Appl. Crystallogr."},{"key":"D4SU00365A\/cit39\/1","first-page":"1","volume-title":"Determination of the Specific Surface Area of Solids by Gas Adsorption. BET Method. ISO 9277","author":"ISO","year":"2022","unstructured":"ISO ,  Determination of the Specific Surface Area of Solids by Gas Adsorption. BET Method. ISO 9277 ,  2022 ,  pp. 1\u201321"},{"key":"D4SU00365A\/cit40\/1","first-page":"1","volume-title":"Pore Size Distribution and Porosity of Solid Materials by Mercury Porosimetry and Gas Adsorption \u2013 Part 2: Analysis of Nanopores\nby Gas Adsorption, ISO 15901-2","author":"ISO","year":"2022","unstructured":"ISO .  Pore Size Distribution and Porosity of Solid Materials by Mercury Porosimetry and Gas Adsorption \u2013 Part 2: Analysis of Nanopores\nby Gas Adsorption, ISO 15901-2 ,  2022 ,  pp. 1\u201328"}],"container-title":["RSC Sustainability"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2024\/SU\/D4SU00365A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,10,14]],"date-time":"2024-10-14T08:30:57Z","timestamp":1728894657000},"score":1,"resource":{"primary":{"URL":"https:\/\/xlink.rsc.org\/?DOI=D4SU00365A"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024]]},"references-count":40,"URL":"http:\/\/dx.doi.org\/10.1039\/d4su00365a","relation":{},"ISSN":["2753-8125"],"issn-type":[{"value":"2753-8125","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">30.10.2024</enrichment>
    <licence>Creative Commons - CC BY-NC - Namensnennung - Nicht kommerziell 4.0 International</licence>
    <author>E. C. Hayward</author>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <author>M. Takeguchi</author>
    <author>A. Kulak</author>
    <author>R. D. Hunter</author>
    <author>Z. Schnepp</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Catalyst</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Carbon materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cellulose</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Small-angle scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Green energy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Graphitic carbon</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Green synthesis</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/61480/d4su00365a.pdf</file>
  </doc>
  <doc>
    <id>56890</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>5372</pageFirst>
    <pageLast>5382</pageLast>
    <pageNumber/>
    <edition/>
    <issue>7</issue>
    <volume>25</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Bio-SAXS of single-stranded DNA-binding proteins: Radiation protection by the compatible solute ectoine</title>
    <abstract language="eng">Small-angle X-ray scattering (SAXS) can be used for structural determination of biological macromolecules and polymers in their native states (e.g. liquid phase). This means that the structural changes of (bio-)polymers, such as proteins and DNA, can be monitored in situ to understand their sensitivity to changes in chemical environments. In an attempt to improve the reliability of such experiments, the reduction of radiation damage occurring from exposure to X-rays is required. One such method, is to use scavenger molecules to protect macromolecules against radicals produced during radiation exposure, such as reactive oxygen species (ROS). In this study we investigate the feasibility of applying the compatible solute, osmolyte and radiation protector Ectoine (THP(B)), as a scavenger molecule during SAXS measurements of the single-stranded DNA-binding protein Gene-V Protein (G5P/GVP). In this case, we monitor the radiation induced changes of G5P during bio-SAXS measurments and the resulting microscopic energy-damage relation was determined from microdosimetric calculations by Monte-Carlo based particle scattering simulations with TOPAS/Geant4 and a custom target-model. This resulted in a median-lethal energy deposit of pure G5P at 4 mg mL−1 of E1/2 = 7 ± 5 eV, whereas a threefold increase of energy-deposit was needed under the presence of Ectoine to reach the same level of damage. This indicates that Ectoine increases the possible exposure time before radiation-damage to G5P is observed. Furthermore, the dominant type of damage shifted from aggregation in pure solutions towards a fragmentation for solutions containing Ectoine as a cosolute. These results are interpreted in terms of indirect radiation damage by reactive secondary species, as well as post-irradiation effects, related to preferential-exclusion of the cosolute from the protein surface. Hence, Ectoine is shown to provide a non-disturbing way to improve structure-determination of proteins via bio-SAXS in future studies.</abstract>
    <parentTitle language="eng">Physical chemistry chemical physics (PCCP)</parentTitle>
    <identifier type="doi">10.1039/d2cp05053f</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-568909</identifier>
    <identifier type="issn">1463-9076</identifier>
    <identifier type="issn">1463-9084</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">25.01.2023</enrichment>
    <enrichment key="RelatedIdentifier">https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/56811</enrichment>
    <enrichment key="RelatedIdentifier">https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/57006</enrichment>
    <enrichment key="PaperofMonth">1</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Dorothea C. Hallier</author>
    <author>Glen Jacob Smales</author>
    <author>H. Seitz</author>
    <author>Marc Benjamin Hahn</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BioSAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bio-SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cosolute</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ectoine</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>G5P</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>GVP</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Radiation damage</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Radical Scavenger</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Single-stranded DNA-binding proteins</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>DNA</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>ssDNA</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protein</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Small-angle xray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>McSAS3</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dosimetry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microdosimetry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Geant4</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Geant4-DNA</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Topas</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Topas-MC</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Monte-Carlo simulations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Particle scattering simulations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Topas-nBio</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>OH Radical</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>OH radical scavenger</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>LEE</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionizing radiation damage</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protein unfolding</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ectoin</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="institutes" number="">6.6 Digitale Materialchemie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/56890/Bio-SAXS_single-stranded_DNA-binding_proteins_radiation_protection_ectoine.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/56890/d2cp05053f1.pdf</file>
  </doc>
  <doc>
    <id>57006</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>5889</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue>7</issue>
    <volume>25</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Inside back cover for the article "Bio-SAXS of single-stranded DNA-binding proteins: Radiation protection by the compatible solute ectoine"</title>
    <abstract language="eng">Showcasing research from the Federal Institute for Material Research and Testing Berlin and Fraunhofer Institute for Celltherapy and Immunology Branch Bioanalytics and Bioprocesses Potsdam.&#13;
&#13;
Bio-SAXS of single-stranded DNA-binding proteins: Radiation protection by the compatible solute ectoine.&#13;
&#13;
We aimed to increase the possible undisturbed exposure time during bio-SAXS measurements of single-stranded DNA-binding proteins. Therefore small angle X-ray scattering was performed on Gene-V Protein (G5P/GVP), which is involved in DNA repair processes. To achieve this, irradiations were performed in presence and absence of the hydroxyl-radical scavenger and osmolyte Ectoine, which showed efficient radiation protection and prevented protein aggregation, thus allows for a non-disturbing way to improve structure-determination of biomolecules.</abstract>
    <parentTitle language="eng">Physical chemistry chemical physics (PCCP)</parentTitle>
    <identifier type="doi">10.1039/D3CP90056H</identifier>
    <identifier type="issn">1463-9076</identifier>
    <identifier type="issn">1463-9084</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="RelatedIdentifier">https://nbn-resolving.org/urn:nbn:de:kobv:b43-568909</enrichment>
    <enrichment key="RelatedIdentifier">https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/56811</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Dorothea C. Hallier</author>
    <author>Glen Jacob Smales</author>
    <author>H. Seitz</author>
    <author>Marc Benjamin Hahn</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bio-SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BioSAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cosolute</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>DNA</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dosimetry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ectoin</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ectoine</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>G5P</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>GVP</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Geant4</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Geant4-DNA</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionizing radiation damage</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>LEE</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>McSAS3</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microdosimetry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Monte-Carlo simulations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>OH Radical</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>OH radical scavenger</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protein</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protein unfolding</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Radiation damage</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Radical Scavenger</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SAXS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Single-stranded DNA-binding proteins</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Small-angle xray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Topas-MC</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Topas-nBio</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>TopasMC</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Particle scatterin simulations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>ssDNA</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="institutes" number="">6.6 Digitale Materialchemie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
  </doc>
  <doc>
    <id>57535</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2070</pageFirst>
    <pageLast>2077</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>4</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The effect of nitrogen on the synthesis of porous carbons by iron-catalyzed graphitization</title>
    <abstract language="eng">This paper reports a systematic study into the effect of nitrogen on iron-catalyzed graphitization of biomass. Chitin, chitosan, N-acetylglucosamine, gelatin and glycine were selected to represent nitrogen-rich saccharides and amino-acid/polypeptide biomass precursors. The materials were pyrolyzed with an iron catalyst to produce carbons with a wide range of chemical and structural features such as mesoporosity and nitrogen-doping. Many authors have reported the synthesis of nitrogen-doped carbons by pyrolysis and these have diverse applications. However, this is the first systematic study of how nitrogen affects pyrolysis of biomass and importantly the catalytic graphitization step. Our data demonstrates that nitrogen inhibits graphitization but that some nitrogen survives the catalytic graphitization process to become incorporated into various chemical environments in the carbon product.</abstract>
    <parentTitle language="eng">Materials Advances</parentTitle>
    <identifier type="doi">10.1039/d3ma00039g</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-575351</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">24.05.2023</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>R. D. Hunter</author>
    <author>E. C. Hayward</author>
    <author>Glen Jacob Smales</author>
    <author>Brian Richard Pauw</author>
    <author>A. Kulak</author>
    <author>S. Guan</author>
    <author>Z. Schnepp</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Graphitization</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoparticles</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanocomposite</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porous carbon</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nitrogen</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Scattering</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/57535/d3ma00039g.pdf</file>
  </doc>
  <doc>
    <id>57138</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>researchdata</type>
    <publisherName>Digital Science</publisherName>
    <publisherPlace>Cambridge, MA, USA</publisherPlace>
    <creatingCorporation>Bundesanstalt für Materialforschung und -prüfung (BAM)</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Electric Safety Interlock</title>
    <abstract language="eng">This interlock is designed to prevent electrical shock from high voltage (&gt;60V) equipment.&#13;
&#13;
While the general safety interlock can be generically applied, this particular example employs an external vacuum-activated switch. It is for safeguarding human operations inside a vacuum sample chamber while the chamber doors are open. The circuit is closed (output is active) when a sufficient level of vacuum is reached, i.e. when all accessible openings are necessarily closed.&#13;
&#13;
The initial application is to interrupt power to a 220V, 250W heating cartridge (itself mounted inside a small sample holder with potentially exposed contacts) when the sample chamber is open.&#13;
&#13;
The external circuit can be modified to use different interlock mechanisms as needed. Note that the external interlock circuit is only a single circuit (with two signal lines) and thus is not protected against external shorts.&#13;
&#13;
To accomodate a range of safety interlocks, the 4-pin M12 connector is wired as follows: Pin 1 (Brown): +24V for power supply, max current 0.6A Pin 2 (White): Safety interlock system signal 1 (0 or 24V) Pin 3 (Blue) : Safety interlock system signal 2 (0 or 24V) Pin 4 (Black): 0V for power supply&#13;
&#13;
The safety is interlocked (output active) when both signal pins are set high (24V), with sufficient current to activate the two relays. Pin 1 and 4 can be used to power safety hardware (such as light curtains or proximity detectors) with 24VDC up to a current of 0.6A. A larger power supply can be installed when higher currents are needed, while staying within the current limits imposed by the wiring cross-section.</abstract>
    <identifier type="doi">10.6084/m9.figshare.22265920.v1</identifier>
    <enrichment key="ScientificResourceTypeGeneral">Physikalisches Objekt</enrichment>
    <enrichment key="ScientificDateCreatedStart">01.12.2022</enrichment>
    <enrichment key="ScientificDateCreatedEnd">13.03.2023</enrichment>
    <enrichment key="ScientificGeolocation">Berlin, Germany</enrichment>
    <enrichment key="ScientificNote">Schematic, parts list, description, photos.</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Brian Richard Pauw</author>
    <author>Glen Jacob Smales</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electric Safety Interlock</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MOUSE</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>60-230V</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Chemie und Prozesstechnik</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="literaturgattung" number="">Graue Literatur</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="unnumberedseries" number="">Forschungsdatensätze der BAM</collection>
  </doc>
  <doc>
    <id>63375</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>17750</pageFirst>
    <pageLast>17763</pageLast>
    <pageNumber/>
    <edition/>
    <issue>21</issue>
    <volume>147</volume>
    <type>article</type>
    <publisherName>American Chemical Society (ACS)</publisherName>
    <publisherPlace>Washington, DC</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Homochiral versus racemic 2D covalent organic frameworks</title>
    <abstract language="eng">The synthesis of homochiral two-dimensional covalent organic frameworks (2D COFs) from chiral π-conjugated building blocks is challenging, as chiral units often lead to misaligned stacking interactions. In this work, we introduce helical chirality into 2D COFs using configurationally stable enantiopure and racemic [5]helicenes as linkers in the backbone of 2D [5]HeliCOFs as powders and films. Through condensation with 1,3,5-triformylbenzene (TFB) or 1,3,5-triformylphloroglucinol (TFP), our approach enables the efficient formation of a set of homochiral and racemic 2D [5]HeliCOFs. The resulting carbon-based crystalline and porous frameworks exhibit distinct structural features and different properties between homochiral and racemic counterparts. Propagation of helical chirality into the backbone of the crystalline frameworks leads to the observation of advanced chiroptical properties in the far-red visible spectrum, along with a less compact structure compared with the racemic frameworks. Homogeneous thin films of [5]HeliCOFs disclosed photoluminescent properties arising from the controlled growth of highly ordered π-conjugated lattices. The present study offers insight into general chiral framework formation and extends the Liebisch−Wallach rule to 2D COFs.</abstract>
    <parentTitle language="eng">Journal of the American Chemical Society</parentTitle>
    <identifier type="issn">0002-7863</identifier>
    <identifier type="doi">10.1021/jacs.5c01004</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-633755</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,28]],"date-time":"2025-05-28T08:40:10Z","timestamp":1748421610584,"version":"3.41.0"},"reference-count":119,"publisher":"American Chemical Society (ACS)","issue":"21","license":[{"start":{"date-parts":[[2025,5,15]],"date-time":"2025-05-15T00:00:00Z","timestamp":1747267200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002347","name":"Bundesministerium f?r Bildung und Forschung","doi-asserted-by":"publisher","award":["03XP0457"],"id":[{"id":"10.13039\/501100002347","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001655","name":"Deutscher Akademischer Austauschdienst","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001655","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003141","name":"Consejo Nacional de Humanidades, Ciencias y Tecnolog?as","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003141","id-type":"DOI","asserted-by":"publisher"}]},{"name":"International Max Planck Research School on Multiscale Biosystems"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,5,28]]},"DOI":"10.1021\/jacs.5c01004","type":"journal-article","created":{"date-parts":[[2025,5,15]],"date-time":"2025-05-15T11:58:26Z","timestamp":1747310306000},"page":"17750-17763","source":"Crossref","is-referenced-by-count":0,"title":["Homochiral versus Racemic 2D Covalent Organic Frameworks"],"prefix":"10.1021","volume":"147","author":[{"given":"Jos\u00e9 del Refugio","family":"Monroy","sequence":"first","affiliation":[{"name":"Department of Chemistry &amp; Center for the Science of Materials Berlin, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Strasse 2, Berlin 12489, Germany"},{"name":"Institute of Organic Chemistry, Albert-Ludwigs-Universit\u00e4t Freiburg, Albertstrasse 21, Freiburg 79104, Germany"}]},{"given":"Tejas","family":"Deshpande","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences and Engineering, \u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne, Rue de l\u2019Industrie 17, Sion 1951, Switzerland"}]},{"given":"Jo\u00ebl","family":"Schlecht","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry, Albert-Ludwigs-Universit\u00e4t Freiburg, Albertstrasse 21, Freiburg 79104, Germany"}]},{"given":"Clara","family":"Douglas","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry, Albert-Ludwigs-Universit\u00e4t Freiburg, Albertstrasse 21, Freiburg 79104, Germany"}]},{"given":"Robbie","family":"Stirling","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Center for the Science of Materials Berlin, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Strasse 2, Berlin 12489, Germany"}]},{"given":"Niklas","family":"Grabicki","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Center for the Science of Materials Berlin, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Strasse 2, Berlin 12489, Germany"}]},{"given":"Glen J.","family":"Smales","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und -pr\u00fcfung, Unter den Eichen 87, Berlin 12205, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8375-0365","authenticated-orcid":true,"given":"Zdravko","family":"Kochovski","sequence":"additional","affiliation":[{"name":"Institute of Electrochemical Energy Storage, Helmholtz-Zentrum Berlin f\u00fcr Materialien und Energie, Hahn-Meitner-Platz 1, Berlin 14109, Germany"}]},{"given":"Filippo Giovanni","family":"Fabozzi","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Center for the Science of Materials Berlin, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Strasse 2, Berlin 12489, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6124-0222","authenticated-orcid":true,"given":"Stefan","family":"Hecht","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp; Center for the Science of Materials Berlin, Humboldt-Universit\u00e4t zu Berlin, Brook-Taylor-Strasse 2, Berlin 12489, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6583-5354","authenticated-orcid":true,"given":"Sascha","family":"Feldmann","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences and Engineering, \u00c9cole Polytechnique F\u00e9d\u00e9rale de Lausanne, Rue de l\u2019Industrie 17, Sion 1951, Switzerland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3277-6570","authenticated-orcid":true,"given":"Oliver","family":"Dumele","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry, Albert-Ludwigs-Universit\u00e4t Freiburg, Albertstrasse 21, Freiburg 79104, Germany"},{"name":"Freiburg Materials Research Center, Albert-Ludwigs-Universit\u00e4t Freiburg, Stefan-Meier-Strasse 21, Freiburg 79104, Germany"},{"name":"Freiburg Center for Interactive Materials and Bioinspired Technologies, Albert-Ludwigs-Universit\u00e4t Freiburg, Georges-K\u00f6hler-Allee 105, Freiburg 79110, Germany"}]}],"member":"316","published-online":{"date-parts":[[2025,5,15]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00620A"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00144"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-023-00543-3"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10807"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c09350"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-05877-0"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202412283"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00823"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-024-01838-8"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009215"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC02335G"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-024-01595-w"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal1585"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07516"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07714"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201802564"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC48813F"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12104"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03352"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903534"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13692"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413675"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04008"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07461"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33501-8"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC06045G"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810571"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10007"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00285"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-03689-9"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115044"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316385"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11051"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202406256"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2352"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405769"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c14161"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00285"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216310"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413171"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC06349F"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01097"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306414"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13032"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01969"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm15159f"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07383"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC04103G"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114059"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c13534"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03614"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02153"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11050"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202113979"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c04430"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403878"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae332"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01027H"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.18952860105"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.2533\/chimia.2018.399"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1021\/ja00026a015"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1021\/jo500528k"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00376"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-15976-5"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC00978H"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202403249"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.4c01199"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35154D"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b13512"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01430"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11260"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01088"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1021\/ja0478882"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202304127"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202314337"},{"key":"ref76\/cit76","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00556"},{"key":"ref77\/cit77","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316092"},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411558"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202004488"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1021\/jo981720f"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b01461"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02195"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06913"},{"key":"ref84\/cit84","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC03735E"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909554"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c10501"},{"key":"ref87\/cit87","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04256"},{"key":"ref88\/cit88","doi-asserted-by":"publisher","DOI":"10.1021\/ja00403a076"},{"key":"ref89\/cit89","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307002802"},{"key":"ref90\/cit90","doi-asserted-by":"publisher","DOI":"10.1002\/chir.20473"},{"key":"ref91\/cit91","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112794"},{"key":"ref92\/cit92","doi-asserted-by":"publisher","DOI":"10.1002\/chir.22600"},{"key":"ref93\/cit93","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.2c02647"},{"key":"ref94\/cit94","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.4c00979"},{"key":"ref95\/cit95","doi-asserted-by":"publisher","DOI":"10.1039\/p29820000789"},{"key":"ref96\/cit96","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.3c00964"},{"key":"ref97\/cit97","doi-asserted-by":"publisher","DOI":"10.1515\/pac-2014-1117"},{"key":"ref98\/cit98","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202201502"},{"key":"ref99\/cit99","doi-asserted-by":"publisher","DOI":"10.1021\/ja308278w"},{"key":"ref100\/cit100","doi-asserted-by":"publisher","DOI":"10.1021\/ja409421d"},{"key":"ref101\/cit101","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat7679"},{"key":"ref102\/cit102","doi-asserted-by":"publisher","DOI":"10.1038\/srep14650"},{"key":"ref103\/cit103","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c09238"},{"key":"ref104\/cit104","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c04365"},{"key":"ref105\/cit105","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08452"},{"key":"ref106\/cit106","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03691"},{"key":"ref107\/cit107","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c06518"},{"key":"ref108\/cit108","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12708"},{"key":"ref109\/cit109","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-14056-7"},{"key":"ref110\/cit110","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00365"},{"key":"ref111\/cit111","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44552-w"},{"key":"ref112\/cit112","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767312047587"},{"key":"ref113\/cit113","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c01017"},{"key":"ref114\/cit114","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05404"},{"key":"ref115\/cit115","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC02503E"},{"key":"ref116\/cit116","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06081"},{"key":"ref117\/cit117","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00195"},{"key":"ref118\/cit118","doi-asserted-by":"publisher","DOI":"10.1063\/1.1400157"},{"key":"ref119\/cit119","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302279"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c01004","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c01004","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,28]],"date-time":"2025-05-28T08:14:16Z","timestamp":1748420056000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5c01004"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,15]]},"references-count":119,"journal-issue":{"issue":"21","published-print":{"date-parts":[[2025,5,28]]}},"alternative-id":["10.1021\/jacs.5c01004"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5c01004","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"type":"print","value":"0002-7863"},{"type":"electronic","value":"1520-5126"}],"subject":[],"published":{"date-parts":[[2025,5,15]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://creativecommons.org/licenses/by/4.0/</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorFirstName_8,PersonAuthorLastName_8,PersonAuthorIdentifierOrcid_8,PersonAuthorFirstName_9,PersonAuthorLastName_9,PersonAuthorFirstName_10,PersonAuthorLastName_10,PersonAuthorIdentifierOrcid_10,PersonAuthorFirstName_11,PersonAuthorLastName_11,PersonAuthorIdentifierOrcid_11,PersonAuthorFirstName_12,PersonAuthorLastName_12,PersonAuthorIdentifierOrcid_12,PublisherName,TitleMain_1,Language,TitleParent_1,PageFirst,PageLast,Issue,Volume,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="date_peer_review">13.06.2025</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>José del Refugio Monroy</author>
    <author>Tejas Deshpande</author>
    <author>Joël Schlecht</author>
    <author>Clara Douglas</author>
    <author>Robbie Stirling</author>
    <author>Niklas Grabicki</author>
    <author>Glen Jacob Smales</author>
    <author>Zdravko Kochovski</author>
    <author>Filippo Giovanni Fabozzi</author>
    <author>Stefan Hecht</author>
    <author>Sascha Feldmann</author>
    <author>Oliver Dumele</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Chirality</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Covalent organic frameworks</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Diffraction</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Lattices</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Thin films</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/63375/ja5c01004_article.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/63375/ja5c01004_si_001.pdf</file>
  </doc>
</export-example>
