<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>27265</id>
    <completedYear/>
    <publishedYear>2012</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>12818</pageFirst>
    <pageLast>12823</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>41</volume>
    <type>article</type>
    <publisherName>RSC</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation>Royal Society of Chemistry</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Structure and stability range of a hexanuclear Th(IV)-glycine complex</title>
    <abstract language="eng">A hexanuclear Th(IV)–glycine complex was observed by Th L3-edge EXAFS measurements in an aqueous solution. Within the stability range of this complex the positively charged hexanuclear species [Th6(µ3-O)4(µ3-OH)4(H2O)6(Gly)6(HGly)6]6+ was preserved in a crystal with the composition [Th6(µ3-O)4(µ3-OH)4(H2O)6(Gly)6(HGly)6]·(NO3)3(ClO4)3(H2O)3. This complex appears as a result of a competing reaction between hydrolysis and ligation by glycine. At a pH value below the stability range of the hexanuclear complex, crystals with the composition [Th(H2O)3(HGly)3]·(ClO4)4H2O were obtained from the solution. Three water molecules in the thorium coordination sphere indicate that this complex occurs prior to the onset of Th(IV) hydrolysis.</abstract>
    <parentTitle language="eng">Dalton transactions</parentTitle>
    <identifier type="old">30071</identifier>
    <identifier type="doi">10.1039/c2dt31367g</identifier>
    <identifier type="issn">1477-9226</identifier>
    <identifier type="issn">1477-9234</identifier>
    <identifier type="issn">1364-5447</identifier>
    <enrichment key="date_peer_review">05.12.2012</enrichment>
    <author>C. Hennig</author>
    <author>S. Takao</author>
    <author>K. Takao</author>
    <author>S. Weiss</author>
    <author>Werner Kraus</author>
    <author>Franziska Emmerling</author>
    <author>A.C. Scheinost</author>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>28525</id>
    <completedYear/>
    <publishedYear>2013</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>012116-1</pageFirst>
    <pageLast>012116-5</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>430</volume>
    <type>article</type>
    <publisherName>IOP Publ.</publisherName>
    <publisherPlace>Bristol, UK</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Identification of hexanuclear actinide(IV) carboxylates with thorium, uranium and neptunium by EXAFS spectroscopy</title>
    <abstract language="eng">Hydrated actinide(IV) ions undergo hydrolysis and further polymerization and precipitation with increasing pH. The resulting amorphous and partly crystalline oxydydroxides AnOn(OH)4-2n·xH2O can usually be observed as colloids above the An(IV) solubility limit. The aging process of such colloids results in crystalline AnO2. The presence of carboxylates in the solution prevents the occurrence of such colloids by formation of polynuclear complexes through a competing reaction between hydrolysis and ligation. The majority of recently described carboxylates reveals a hexanuclear core of [An6(µ3-O)4(µ3-OH)4]12+ terminated by 12 carboxylate ligands. We found that the An(IV) carboxylate solution species remain often preserved in crystalline state. The An(IV) carboxylates show An–An distances which are ~ 0.03 Å shorter than the An–An distances in AnO2 like colloids. The difference in the distances could be used to identify such species in solution.</abstract>
    <parentTitle language="eng">Journal of physics / Conference series</parentTitle>
    <identifier type="old">31377</identifier>
    <identifier type="doi">10.1088/1742-6596/430/1/012116</identifier>
    <identifier type="issn">1742-6588</identifier>
    <identifier type="issn">1742-6596</identifier>
    <enrichment key="eventName">XAFS15 - 15th International conference on X-ray absorption fine structure</enrichment>
    <enrichment key="eventPlace">Beijing, China</enrichment>
    <enrichment key="eventStart">22.07.2012</enrichment>
    <enrichment key="eventEnd">28.07.2012</enrichment>
    <enrichment key="zsBemerkung">Die Aufnahme ist grundsätzlich falsch, da es sich trotz des Titels ("Journal of physics / Conference series") nicht um eine Zeitschrift handelt, sondern um eine Tagungsband-Reihe. Da sehr viele Artikel an diesem Eintrag hängen, wäre die Korrektur aber extrem aufwändig.  Die Tagungsband-Reihe findet sich in der Master Journal List bzw. in dem Journal Citation Report selbstverständlich nicht wieder, da es ja keine Zeitschrift ist. Allerdings wird die Tagungsband-Reihe sehr wohl von Thomson-Reuters für Ihre Datenbank ausgewertet, als "Book Series". Daher muss sichergestellt werden, dass die dort erscheinenden Artikel auch für die "1000-Euro-Liste" berücksichtigt werden.  Die einfachste Lösung ist es, den Eintrag als Zeitschrift zu belassen, und das Häkchen bei "In MJL/CPCI von ISI enthalten" zu setzen. Das ist zwar formal nicht ganz korrekt, erzeugt aber das richtige Ergebnis.  Jan Harloff-Puhr 11.7.2014</enrichment>
    <enrichment key="date_peer_review">27.05.2013</enrichment>
    <author>C. Hennig</author>
    <author>S. Takao</author>
    <author>K. Takao</author>
    <author>s. Weiss</author>
    <author>Werner Kraus</author>
    <author>Franziska Emmerling</author>
    <author>M. Meyer</author>
    <author>A.C. Scheinost</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Carboxylates</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>EXAFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Actinide</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
</export-example>
