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    <title language="eng">Effect of gypsum on the hydration of fused cement clinker from basic oxygen furnace slag</title>
    <abstract language="eng">Fused cement clinker can be produced from molten basic oxygen furnace slag (BOFS) by way of a reductive thermochemical treatment. During the thermochemical treatment, oxidic iron is reduced to metallic iron and separated. The resulting low-iron slag has a chemical and mineralogical composition similar to ordinary Portland cement (OPC) clinker. In this study, the hydraulic reactivity of the fused clinker from BOFS with and without gypsum was investigated using isothermal calorimetry, differential scanning calorimetry, in situ X-ray diffraction and powder X-ray diffraction. Furthermore, a synthetic fused clinker without foreign ions and fused clinker produced by a mixture of both materials was studied. The hydraulic reaction of the fused clinker from BOFS was considerably slower than that of OPC. However, the reaction can be accelerated by adding gypsum as a sulfate carrier. Furthermore, the results showed an increased reaction rate with decreasing content of foreign ions such as Fe, P or Mn.</abstract>
    <parentTitle language="eng">Advances in Cement Research</parentTitle>
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    <title language="deu">Zementklinker durch Nachbehandlung von Stahlwerksschlacken</title>
    <abstract language="deu">Die Klinkerphasenbildung durch Sinterung in Drehrohröfen bei der Herstellung von Portlandzementklinker (PZK) ist gründlich erforscht und optimiert. Im Hinblick auf mögliche ökonomische und ökologische Vorteile befassen sich aktuelle Forschungsvorhaben darüber hinaus mit der Herstellung von Klinkermineralen aus Stahlwerksschlacken, die eine vergleichbare chemische Zusammensetzung aufweisen.&#13;
Neuste Untersuchungen zeigen, dass nach der reduzierenden Behandlung schmelzflüssiger Linz-Donawitz-(LD)-Schlacken und Abscheidung des gebildeten metallischen Eisens eine mineralische Schlacke entsteht, die unabhängig von ihren Abkühlbedingungen ca. 50–60 Gew.% des wichtigsten Klinkerminerals Alit (C3S) enthält und eine hohe hydraulische Reaktivität aufweist.&#13;
Die Stabilität des Alits auch nach langsamer Abkühlung deutet auf eine Stabilisierung des Minerals durch Nebenelemente aus den LD-Schlacken hin. Ein sinkender Anteil an LD-Schlacke durch Zusatz synthetischer Schlackemischung, die sich hinsichtlich ihrer Hauptkomponenten wie eine ausreduzierte LD-Schlacke zusammensetzt, führt zu einem Rückgang des Alitgehaltes und dem Zerfall der Schlacke beim Erstarren.</abstract>
    <parentTitle language="deu">Schlacken-Symposium 2018: Ressourcenschonung durch Nutzung von Sekundärrohstoffen: Wann wird politische Forderung Realität?</parentTitle>
    <enrichment key="eventName">5. Schlacken-Symposium</enrichment>
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    <author>D. A. Stephan</author>
    <author>Christian Adam</author>
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      <value>LD-Schlacke</value>
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    <subject>
      <language>deu</language>
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      <value>Zement</value>
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    <title language="deu">Strategien für die Nutzung von Schlacken zukünftiger wasserstoffbasierter Stahlproduktionsrouten – Herstellung von Stahlwerksschlacke basierten Ausgangsstoffen für die Zementindustrie</title>
    <abstract language="deu">Die Europäische Kommission präsentierte am 11. Dezember 2019 den European Green Deal, ein Konzept mit dem Ziel, bis zum Jahr 2050 als erster Kontinent Klimaneutralität zu erreichen. Mit Inkrafttreten der Verordnung (EU) 2021/1119 des Europäischen Parlaments und des Europäischen Rates am 29. Juli 2021 zur Schaffung des Rahmens für die Verwirklichung der Klimaneutralität („Europäisches Klimagesetz“), ist dieses, sowie das Ziel der Reduzierung der Nettotreibhausgasemissionen um mindestens 55 % bis 2030 in der Gesetzgebung der Europäischen Union verankert. Die Stahlindustrie in der Europäischen Union mit ca. 57 Mio. t Nettotreibhausgasemissionen im Jahr 2020, die annähernd 2 % der Emissionen der Europäischen Union ausmachen (Inklusive Energie: 127 Mio. t; 4 %), bekennt sich zur erheblichen Reduzierung der CO2-Emissionen bis zum Jahr 2030 und zum Erreichen der Klimaneutralität bis zum Jahr 2050. Als Schlüsselwege zur Verwirklichung dieser Zielstellung hat sie zum einen Smart Carbon Usage (SCU) und zum anderen Carbon Direct Avoidance (CDA) in einer Roadmap formuliert. SCU umfasst CO2-reduzierende Maßnahmen in bestehenden Eisen- und Stahlproduktionsprozessen, Carbon Capture and Storage- (CCS) sowie Carbon Capture and Usage-Technologien (CCU). Wohingegen bei CDA CO2-Emissionen durch erneuerbare elektrische Energie sowie wasserstoffbasierte Reduktion des Eisenerzes gar nicht erst entstehen sollen. Der CDA-Weg, der voraussichtlich beschritten werden muss, um eine klimaneutrale Stahlproduktion zu erreichen [38], geht mit einer kostenintensiven Transformation der Stahlproduktion einher, die bereits von vielen Unternehmen der Stahlindustrie eingeleitet wurde und von der im Wesentlichen die beiden in Europa vorherrschenden Stahlproduktionsrouten Hochofen-Konverter-Route und Elektrolichtbogenofen-Route betroffen sind. Die CO2-Emissionen der Hochofen-Konverter-Route, von denen der überwiegende Anteil auf den Hochofen fällt, liegen laut einer für das Jahr 2015  erstellten Studie bei 1921 kg CO2/t Rohstahl inklusive der CO2-Last der Pellets als Einsatzmaterial sowie der Emissionen der nachgelagerten Stranggießanlagen und Walzwerke. Im Hochofen wird das Eisenerz durch Kohlenstoff (C) bzw. Kohlenstoffmonoxid (CO) – welche größtenteils aus dem Koks, der dem Hochofen zusammen mit dem Möller über die Gicht zugeführten wird, stammen – unter Entstehung von Roheisen und Kohlenstoffdioxid (CO2) reduziert. Das neben dem CO2 im Prozessgas enthaltene CO wird zum Beispiel zur Energiegewinnung in peripheren Prozessen ebenfalls unter Bildung von CO2 verbrannt. Zusätzlich zur Reduktion hat der Koks unter anderem physikalische Aufgaben, wie die Errichtung eines Stützgerüstes und die Gewährleistung der Permeabilität im Hochofenprozess. Somit ist eine vollkommene Substitution des Kokses zur Vermeidung der CO2-Emissionen im Hochofen nicht denkbar. Viele Strategien der Stahlunternehmen zum Erreichen der Klimaziele verfolgen daher den Wechsel von der Rohstahlproduktion aus der Hochofen-Konverter-Route hin zur Rohstahlproduktion im Elektrolichtbogenofen (EAF – Electric Arc Furnace) mit dem Einsatz von direkt reduziertem Eisen (Eisenschwamm, DRI – Direct Reduced Iron) aus vorgelagerten Direktreduktionsanlagen, die mit Wasserstoff (H2) als Reduktionsmittel betrieben werden können. Dabei ist die Elektrostahlerzeugung kein neuer Prozess und nimmt in der europäischen Union bereits jetzt einen Anteil von ca. 44 % der Rohstahlproduktion ein, jedoch überwiegend mit Schrott als Einsatzmaterial. Bei der Elektrostahlerzeugung mit Schrotteinsatz fallen laut der oben genannten Studie von Lüngen für das Jahr 20152 410 kg CO2-Emissionen pro Tonne Rohstahl an, von denen der Großteil auf die CO2-Last der fremd bezogenen elektrischen Energie zurückzuführen ist und daher nicht im Produktionsprozess selbst entsteht. Auch die Direktreduktion wird schon seit 1972 in der weltweit zweiten und bis heute in Westeuropa einzigen Direktreduktionsanlage in Hamburg betrieben. Während hier noch mit einem Reduktionsgas gearbeitet wird, das hauptsächlich aus einem aus Erdgas gewonnenen Wasserstoff-Kohlenstoffmonoxid-Gemisch besteht, liegt eine aktuelle Kernherausforderung in der Bereitstellung des in der Größenordnung der von der Transformation betroffenen Rohstahlproduktionskapazitäten notwendigen, mit erneuerbarer elektrischer Energie hergestellten Wasserstoffs. Wird zusätzlich der Strom für das Einschmelzen im Elektrolichtbogenofen aus erneuerbaren Quellen gewonnen und werden schließlich als Brennstoff verwendete Kohle und als Brennstoff verwendetes Erdgas durch CO2-neutrale Bio-Brennstoffe ersetzt, sind sowohl für den Einsatz von mit Wasserstoff reduziertem und auf Pellets ohne CO2-Last basiertem Eisenschwamm als auch für den Einsatz von Schrott CO2-Emissionen von jeweils nur 60 kg CO2/t Rohstahl erreichbar, was eine Reduktion der Emissionen, ausgehend von der Konverter-Hochofen-Route um 97 % und ausgehend von der Schrott-Elektrolichtbogenofen-Route um 85 % bedeuten würde.&#13;
Der Betrieb von Elektrolichtbogenöfen macht die an den Standorten vorhandenen Konverter sowie die Infrastruktur für Behandlung und Transport des Roheisens überflüssig. Die fortwährende Nutzung dieser bestehenden Anlagenstruktur dient daher unter anderem als Motivation für die Entwicklung einer zweiten Transformationsstrategie, die einen sogenannten Einschmelzer (SAF – Submerged Arc Furnace) als der Direktreduktionsanlage nachgelagerten Prozess vorsieht, in dem wiederum Roheisen erschmolzen wird, das anschließend im Konverter zu Rohstahl veredelt wird.&#13;
Die Transformation der Stahlindustrie beeinflusst einen weiteren CO2-intensiven Industriesektor, nämlich die Zementindustrie die verantwortlich ist für rund 4 % der CO2-Emissionen in der EU. Etwa zwei Drittel dieser Emissionen entfallen als Prozessemissionen auf die Entsäuerung des Rohstoffs Kalkstein (CaCO3), also auf die Abspaltung von CO2 unter Entstehung des für die Herstellung von Zementklinker notwendigen Branntkalks (CaO) als Zwischenstufe bei der Bildung der hydraulischen Phasen Tri- und Dicalciumsilikat. Als eines der fünf Themenfelder (5C-Ansatz: Clinker, Cement, Concrete, Construction, Carbonation), welche die europäische Zementindustrie entlang ihrer Wertschöpfungskette zum Erreichen der gesetzlichen Vorgaben der europäischen Union erarbeitet hat, umfasst das Feld "Cement" zum größten Teil die Reduzierung des Klinker-Zement-Faktors. Im Jahr 2017 betrug er 77 %, das heißt, dass 23 % des Klinkers durch alternative Materialien ersetzt wurden. Bis zum Jahr 2030 wird ein Faktor von 74 % und bis zum Jahr 2050 von 65 % angestrebt. Den größten Anteil an den Klinkersubstituten hat mit 33 % der Hüttensand aus der Stahlindustrie. Bei der Roheisenproduktion im Hochofen entsteht als Nebenprodukt Hochofenschlacke, die unter Zugabe von Schlackebildnern die Gangart des Möllers und mineralische Koksbestandteile abbindet, sowie weitere unerwünschte Begleitelemente wie Schwefel und Alkalien aufnimmt. Allein in Deutschland wurden im Jahr 2021 6,90 Mio. t – das entspricht 90 % der gesamten produzierten Hochofenschlacke – zu glasig erstarrtem Hüttensand granuliert. Dieser Hüttensand besitzt latent hydraulische Eigenschaften und wird daher seit mehr als 140 Jahren als Zementbestandteil eingesetzt, wodurch in Deutschland jährlich rund 4,5 Mio. t CO2-Emissionen eingespart werden. Alle Transformationsstrategien der Stahlindustrie beinhalten die notwendige Außerbetriebnahme der CO2-intensiven Hochöfen. Dies hat unter anderem zur Folge, dass die Hochofenschlacke als Nebenprodukt der Rohstahlerzeugung im Hochofen nicht mehr zur Verfügung stehen wird, wodurch die weitere Reduzierung des Klinker-Zement-Faktors erhebliche Zusatzmengen alternativer Materialien benötigen wird. Derzeit ist noch unklar, ob z.B. calcinierte Tone im benötigten Umfang erzeugt werden können.&#13;
Der Fachbereich Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung der Bundesanstalt für Materialforschung und -prüfung (BAM) und das Institut für Baustoffforschung FEhS forschen zusammen mit Industriepartnern und weiteren Forschungseinrichtungen im Rahmen zweier Projekte in den Kooperationssphären der Stahl- und Zementindustrie, die zur Bewältigung dieser Herausforderungen beitragen. Im Projekt SlagCEM wird die Produktion eines hydraulischen Zementbestandteils durch Reduktion von Konverter- bzw. Linz-Donawitz-Schlacke (LDS) untersucht. Die mit den zusätzlich aufgenommen Lichtbogenofenkapazitäten steigenden Mengen an Elektrolichtbogenofenschlacke (EOS, engl. electric arc furnace slag, EAFS) werden im Projekt DRI-EOS behandelt, welches die Produktion eines latent hydraulischen Hüttensandsubstituts zum Ziel hat.</abstract>
    <parentTitle language="deu">Mineralische Nebenprodukte und Abfälle 10</parentTitle>
    <identifier type="isbn">978-3-944310-72-5</identifier>
    <enrichment key="eventName">Berliner Konferenz Mineralische Nebenprodukte und Abfälle</enrichment>
    <enrichment key="eventPlace">Berlin, Germany</enrichment>
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    <author>Christian Adam</author>
    <author>Joachim Schneider</author>
    <author>Katharina Schraut</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Stahlwerksschlacke</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Zementersatz</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
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    <collection role="themenfelder" number="">Circular Economy</collection>
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  </doc>
  <doc>
    <id>61312</id>
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    <publishedYear>2024</publishedYear>
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    <language>deu</language>
    <pageFirst>78</pageFirst>
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    <pageNumber/>
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    <publisherName>Bundesanstalt für Materialforschung und -prüfung (BAM)</publisherName>
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    <creatingCorporation>Deutscher Ausschuss für Stahlbeton (DAfStb)</creatingCorporation>
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    <title language="deu">Erzeugung von Bindemitteln aus Stahlwerksschlacken</title>
    <abstract language="deu">Die geplante Transformation der Stahlindustrie innerhalb der nächsten 20 Jahre hat aufgrund des mit ihr verbundenen Auslaufens der Hüttensanderzeugung Konsequenzen für die Zementindustrie, deren Abmilderung Gegenstand der Forschungsprojekte SlagCEM und DRI-EOS ist. Ersteres untersucht die Rückgewinnung von Eisen aus LD-Konverter-Schlacke bei gleichzeitiger Herstellung eines mineralischen Produktes mit zementä- ren Eigenschaften. Zweiteres befasst sich mit der Generierung eines Hüttensandersatzes aus Lichtbogen- ofenschlacke mit Rückgewinnung von Schwermetallen sowie deren Umwelteffekt bei Verbleib in der Schlacke.</abstract>
    <parentTitle language="deu">11. Jahrestagung des DAfStb mit 63. Forschungskolloquium der BAM - Beiträge zum 63. Forschungskolloquium Green Intelligent Building am 16. und 17. Oktober 2024</parentTitle>
    <identifier type="isbn">978-3-9818564-7-7</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-613127</identifier>
    <enrichment key="eventName">11. Jahrestagung des DAfStb mit 63. Forschungskolloquium der BAM Green Intelligent Building</enrichment>
    <enrichment key="eventPlace">Berlin, Germany</enrichment>
    <enrichment key="eventStart">16.10.2024</enrichment>
    <enrichment key="eventEnd">17.10.2024</enrichment>
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    <enrichment key="RelatedIdentifier">https://nbn-resolving.org/urn:nbn:de:kobv:b43-613383</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Joachim Schneider</author>
    <author>Burkart Adamczyk</author>
    <author>D. Ebert</author>
    <author>A. Ehrenberg</author>
    <author>Katharina Schraut</author>
    <author>J. Gerlach</author>
    <author>K. Wendt</author>
    <author>D. Algermissen</author>
    <author>Christian Adam</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Bindemittel</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Stahlwerksschlacke</value>
    </subject>
    <collection role="ddc" number="624">Ingenieurbau</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="themenfelder" number="">Infrastruktur</collection>
    <collection role="literaturgattung" number="">Eigenverlag BAM</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Green Intelligent Building</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/61312/2.2_Block_2_02_Schneider.pdf</file>
  </doc>
  <doc>
    <id>51605</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst>1</pageFirst>
    <pageLast>9</pageLast>
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    <publisherName>Montanuniversität Leoben</publisherName>
    <publisherPlace>8700 Leoben, Österreich</publisherPlace>
    <creatingCorporation>Lehrstuhl für Abfallverwertungstechnik und Abfallwirtschaft (AVAW) der Montanuniversität Leoben</creatingCorporation>
    <contributingCorporation/>
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    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Technische Möglichkeiten der Abfallvermeidung in der Stahlproduktion</title>
    <abstract language="deu">Bei der Stahlproduktion fallen verfahrensbedingt große Mengen an Nebenprodukten und Abfällen wie Stahlwerksschlacken, Filterstäube und Gichtgasschlämme an. Hohe Anteile dieser Stoffströme werden aufgrund ihrer Zusammensetzung immer noch deponiert, obwohl sie ein hohes Wertstoffpotential aufweisen. An der Bundesanstalt für Materialforschung und -prüfung (BAM) werden Verfahren untersucht&#13;
und entwickelt, welche eine Verwertung und Kreislaufführung dieser Materialströme ermöglichen. Aus sogenannten Linz-Donawitz-(LD)-Schlacken können durch carbothermische Nachbehandlung Roheisen und ein dem Portlandzementklinker (PZK) ähnliches Bindemittel erzeugt werden. Aus Elektroofenstäuben und Gichtgasschlämmen kann Zink gewonnen und die Anteile an Eisen und Kohlenstoff in den Stahlproduktionsprozess zurückgeführt werden. Durch diese technischen Maßnahmen kann es gelingen die Deponierung von Abfällen der Stahlproduktion zukünftig deutlich zu reduzieren.</abstract>
    <parentTitle language="deu">Recy &amp; DepoTech 2020</parentTitle>
    <enrichment key="eventName">Recy&amp;Depotech 2020</enrichment>
    <enrichment key="eventPlace">Online meeting</enrichment>
    <enrichment key="eventStart">18.11.2020</enrichment>
    <enrichment key="eventEnd">20.11.2020</enrichment>
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    <author>Christian Adam</author>
    <author>Katharina Schraut</author>
    <author>Eric Weingart</author>
    <author>C. Hamann</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Stahlwerksschlacke</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Filterstaub</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Gichtgasschlamm</value>
    </subject>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
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  <doc>
    <id>45199</id>
    <completedYear/>
    <publishedYear>2018</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst>282</pageFirst>
    <pageLast>296</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>5</volume>
    <type>conferenceobject</type>
    <publisherName>Thomé-Kozmiensky Verlag GmbH</publisherName>
    <publisherPlace>Neuruppin</publisherPlace>
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    <belongsToBibliography>0</belongsToBibliography>
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    <title language="deu">Nachbehandlung von Stahlwerksschlacken und deren Verwertung als Klinkermaterial</title>
    <title language="eng">Post-treatment of steelmaking slags and their utilisation as cement clinker</title>
    <abstract language="eng">Steelmaking slags produced using the Linz-Donawitz method (LD slags) are widely used as building and construction materials in road, earth and water works. Because the legal conditions become more and more re-strictive , this application is uncertain in the future. &#13;
LD slags contain high amounts of mineral bound iron (in form of Fe2O3), which must be considered as a waste of resources. Except for the Iron the chemical composition is quite similar to that of Portland cement clinker. However, due to the high content of Fe2O3 the mineralogical composition differs significantly, resulting in a low hydraulic reactivity. A post-treatment of the liquid LD slag in an electric arc furnace under reducing conditions enables the reduction of the iron compounds to metallic iron, which separates from the mineral phase due to its higher density. The remaining solidified mineral fraction mainly contains typical crystalline phases of cement clinker in similar ratios: Alite (Ca3SiO5; &gt; 60%) as main phase, Belite (Ca2SiO4, 10%), Tricalciumaluminate (Ca3Al2O6; 5%) and Brownmillerite (Ca2(Al,Fe)2O5, 1%) as secondary phases. Alite, which usually decomposes to Belite and free lime under slow cooling conditions, is stabilized in the Fe-reduced slag  probably by integration of foreign ions into the lattice and is stable even if the slag is cooled down very slowly. Furthermore, the particularly large Alite crystals do not exhibit the typical decomposition edge of Belite and lime, found in Alite from ordinary ce-ment clinker. Technological tests for building materials show a high hydraulic reactivity and a compressive strength after 28 days comparable or even slightly higher to reference cement.&#13;
Nevertheless, because of the increasing viscosity with decreasing Fe2O3 content, the treatment requires a temperature higher than the slag decanted from the LD converter. Furthermore, during the reduction of the bound Iron huge amounts of carbon monoxide are released, resulting in foaming of the slag. Both aspects make it difficult to manage the process. In addition, for economic reasons the treatment has to be carried out immediately after casting the slag from the LD converter to avoid the solidification, which is a logistical challenge for most steel plants. Otherwise the separation of the mineral bound iron as metallic phase and the utilisation of the mineral fraction as cement clinker will both save resources and lower the global CO2-output. For these reasons further initiatives should be considered in the medium term.</abstract>
    <abstract language="deu">LD-Schlacken weisen eine große chemische Ähnlichkeit zu Protlandzementklinker auf. Sie enthalten jedoch noch bis zu 30% Eisen, das mineralisch in oxidischer Form gebunden vorliegt. Dadurch kann sich bei der Erstarrung die wichtigste Klinkerphase "Alit" nicht ausbilden.&#13;
Durch eine reduzierende Schmelzbehandlung der Schlacke kann des mineralisch gebundene Eisen als Metall separiert werden. Dadurch wird auch die Mineralogie der Schlacke so verändert, dass auch sie nun praktisch einem Portlandzementklinker entspricht.&#13;
Entsprechende Versuche wurden am kleintechnischen Lichtbogenofen der BAM durchgeführt. Es werden Ergebnisse vorgestellt und auf Grenzen und Möglichkeiten eines derartigen Prozesses im Hinblick auf eine industrielle Umsetzung eingegangen.</abstract>
    <parentTitle language="deu">Mineralische Nebenprodukte und Abfälle 5</parentTitle>
    <identifier type="isbn">978-3-944310-41-1</identifier>
    <enrichment key="eventName">Berliner Konferenz Mineralische Nebenprodukte und Abfälle</enrichment>
    <enrichment key="eventPlace">Berlin, Germany</enrichment>
    <enrichment key="eventStart">11.06.2018</enrichment>
    <enrichment key="eventEnd">12.06.2018</enrichment>
    <author>Burkart Adamczyk</author>
    <author>Katharina Schraut</author>
    <author>Christian Adam</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Zementklinker</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Stahlwerksschlacke</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>LD-Schlacke</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Lichtbogenofen</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Alit</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>46409</id>
    <completedYear/>
    <publishedYear>2018</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
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    <type>lecture</type>
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    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Zementklinker durch Nachbehandlung von Stahlwerksschlacken</title>
    <abstract language="deu">Die Klinkerphasenbildung durch Sinterung in Drehrohröfen bei der Herstellung von Portlandzementklinker (PZK) ist gründlich erforscht und optimiert. Im Hinblick auf mög-liche ökonomische und ökologische Vorteile befassen sich aktuelle Forschungsvorha-ben darüber hinaus mit der Herstellung von Klinkermineralen aus Stahlwerksschla-cken, die eine vergleichbare chemische Zusammensetzung aufweisen.&#13;
Neuste Untersuchungen zeigen, dass nach der reduzierenden Behandlung schmelz-flüssiger Linz-Donawitz-(LD)-Schlacken und Abscheidung des gebildeten metallischen Eisens eine mineralische Schlacke entsteht, die unabhängig von ihren Abkühlbedin-gungen ca. 50–60 Gew.% des wichtigsten Klinkerminerals Alit (C3S) enthält und eine hohe hydraulische Reaktivität aufweist.&#13;
Die Stabilität des Alits auch nach langsamer Abkühlung deutet auf eine Stabilisierung des Minerals durch Nebenelemente aus den LD-Schlacken hin. Ein sinkender Anteil an LD-Schlacke durch Zusatz synthetischer Schlackemischung, die sich hinsichtlich ihrer Hauptkomponenten wie eine ausreduzierte LD-Schlacke zusammensetzt, führt zu einem Rückgang des Alitgehaltes und dem Zerfall der Schlacke beim Erstarren.</abstract>
    <enrichment key="eventName">5. Schlacken-Symposium</enrichment>
    <enrichment key="eventPlace">Meitingen, Germany</enrichment>
    <enrichment key="eventStart">25.10.2018</enrichment>
    <enrichment key="eventEnd">26.10.2018</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Zement</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>LD-Schlacke</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Tricalciumsilikat</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>56081</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>lecture</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Reductive treatment of steel making slags to produce a hydraulic binder and crude iron</title>
    <abstract language="eng">Steelmaking slags are a by-product of steel production, that are currently used primarily in road construction, earthwork, and hydraulic engineering. In this use, the iron bound in the steelmaking slags (&lt; 30 wt.%) is lost. &#13;
Recovery of iron from steelmaking slags is possible by thermochemical reductive treatment. The reductive treatment of liquid steelmaking slags causes iron oxides to be reduced to metallic iron, which separates from the mineral phase due to its higher density. The chemical composition of the mineral phase is thus adapted to that of the Portland cement clinker and the mineral alite, the most important component of Portland cement, is formed. This way, crude iron can be recovered, and at the same time a hydraulic binder can be produced. &#13;
This process, however, is uneconomical due to the high temperatures required (~1800 °C). In the current project, the process is to be adapted so that the reduction of liquid steelmaking slag can be carried out at ~1600 °C. The chemical composition is to be modified in such a way that the melting temperature of the slags as well as their viscosity are in a technically suitable range and still a product with good cementitious properties is obtained.</abstract>
    <enrichment key="eventName">LithiumDays</enrichment>
    <enrichment key="eventPlace">Online meeting</enrichment>
    <enrichment key="eventStart">06.12.2021</enrichment>
    <enrichment key="eventEnd">08.12.2021</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BOFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Portland Cement</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hydraulic reactivity</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>58206</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>lecture</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Production of an alite-rich material from reduced basic oxygen furnace slags</title>
    <abstract language="eng">Basic oxygen furnace slag (BOFS) is a by-product of steelmaking of which about 10.4 Mt are produced annually in the EU. BOFS is mostly used in road construction, earthwork and hydraulic engineering. However, in this use, the iron bound in BOFS is lost and the opportunity to produce higher value products from BOFS is forgone.&#13;
In recent decades, many researchers have investigated the production of both Portland cement clinker and crude iron from BOFS via a thermochemical reductive treatment. The reductive treatment of liquid BOFS causes a reduction of iron oxides to metallic iron, which separates from the mineral phase due to its higher density and can be recovered. An advantage of this process is that simultaneously the chemical composition of the reduced BOFS is adapted to that of Portland cement clinker and the hydraulic reactive mineral alite (Ca3SiO5) is formed. &#13;
In this study, German BOFS was reduced in a small-scale electric arc furnace and a low-iron mineral product rich in alite was produced. Despite a chemical and mineralogical composition similar to that of Portland cement clinker, the reduced BOFS produced less heat of hydration, and its reaction was delayed compared to Portland cement. However, adding gypsum accelerated the hydration rate of the reduced BOFS.&#13;
Further research to improve the hydraulic properties of the reduced BOFS is essential. If successful, the production of a hydraulic material and crude iron from BOFS could have economic and ecological benefits for both the cement and steel industry.</abstract>
    <enrichment key="eventName">GeoBerlin 2023</enrichment>
    <enrichment key="eventPlace">Berlin, Germany</enrichment>
    <enrichment key="eventStart">04.09.2023</enrichment>
    <enrichment key="eventEnd">07.09.2023</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BOFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Alite</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hydraulic reactivity</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.1 Baustoffe</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>52123</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>104898</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>126</volume>
    <type>article</type>
    <publisherName>Elsevier Ltd.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Investigation of scandium in bauxite residues of different origin</title>
    <abstract language="eng">This paper focuses on the scandium speciation in bauxite residues of different origin. Insights into mineralchemical similarities and differences of these materials will be presented and links to their natural geological background discussed. The presented research should provide fundamental knowledge for the future development of efficient and viable technologies for Sc-recovery from bauxite residues derived from different bauxites and accumulating at different localities. In total, five bauxite residues were investigated which originated from Greece, Germany, Hungary and Russia (North Ural &amp; North Timan) using a combination of different analytical tools. Those included: laser ablation inductively coupled plasma mass spectrometry, X-ray absorption near Edge structure (XANES) spectroscopy, μ-Raman spectroscopy as well as scanning electron microscopy and electron microprobe analyses. X-ray fluorescence and inductively coupled plasma mass spectrometry were used to determine the overall chemical composition. The investigated samples were found to exhibit a relatively homogenous distribution of Sc between the larger mineral particles and the fine-grained matrix except for Al-phases like diaspore, boehmite and gibbsite. These phases were found to be particularly low in Sc. The only sample where Sc mass fractions in Al-phases exceeded 50 mg/kg was the Russian sample from North Ural. Fe-phases such as goethite, hematite and chamosite (for Russian samples) were more enriched in Sc than the Al-phases.&#13;
In fact, in Greek samples goethite showed a higher capacity to incorporate or adsorb Sc than hematite. Accessory minerals like zircon, rutile/anatase and ilmenite were found to incorporate higher mass fractions of Sc (&gt;150 mg/kg), however, those minerals are only present in small amounts and do not represent major host phases for Sc. In Russian samples from North Ural an additional Ca–Mg rich phase was found to contain significant mass fractions of Sc (&gt;500 mg/kg). μ-XANES spectroscopy was able to show that Sc in bauxite residue occurs adsorbed onto mineral surfaces as well as incorporated into the crystal lattice of certain Fe-phases. According to our observations the bauxite type, i.e. karstic or lateritic, the atmospheric conditions during bauxitization, i.e. oxidizing or reducing, and consequently the dominant Sc-bearing species in the primary Bauxite influence the occurrence of Sc in bauxite residues. In karstic bauxites, underlying carbonate rocks can work as a pH-barrier and stabilize Sc. This prevents the Sc from being mobilized and removed during bauxitization. Hence, karstic bauxites are more prone to show a Sc enrichment than lateritic bauxites. Reducing conditions during bauxitization support the incorporation of Sc into clay minerals such as chamosite, which can dissolve and reprecipitate during Bayer processing causing Sc to be redistributed and primarily adsorb onto mineral surfaces in the bauxite residue. Oxidizing conditions support the incorporation of Sc into the crystal lattice of Fe-oxides and hydroxides, which are not affected in the Bayer process. The genetic history of the bauxite is therefore the major influential factor for the Sc occurrence in bauxite residues.</abstract>
    <parentTitle language="eng">Applied Geochemistry</parentTitle>
    <identifier type="doi">10.1016/j.apgeochem.2021.104898</identifier>
    <identifier type="issn">0883-2927</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">15.04.2021</enrichment>
    <author>Marie Gentzmann</author>
    <author>Katharina Schraut</author>
    <author>Christian Vogel</author>
    <author>H.-E. Gäbler</author>
    <author>T. Huthwelker</author>
    <author>Christian Adam</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sc recovery</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Scandium</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bauxite Residue</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Red Mud</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>XANES</value>
    </subject>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>53475</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>lecture</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Portland cement clinker from reduced basic oxygen furnace slag</title>
    <abstract language="eng">Basic oxygen furnace slag (BOFS) is a by-product of the steelmaking process, of which about 10.4 Mt are produced annually in the European Union. Besides its predominant use in road construction, earthwork, and hydraulic engineering, it is also possible to use BOFS as a source material for Portland cement clinker.&#13;
The main difference in the chemical composition of BOFS from the chemical composition of Portland cement clinker is its high content of iron oxides (7-50 wt.%). In recent decades, many researchers have investigated the production of both Portland cement clinker and crude iron from BOFS via thermochemical reductive treatment. Carbothermal treatment of liquid BOFS causes reduction of iron oxides to metallic iron, which separates from the mineral phase due to its higher density. &#13;
In this study, German BOFS was reduced in a small-scale electric arc furnace using petrol coke as reducing agent. The produced low-iron mineral product was chemically similar to Portland cement clinker and contained the most important Portland cement mineral alite (Ca3SiO5) as main component. Besides alite, the mineral product contained other Portland cement clinker constituents such as belite (β-Ca2SiO4) and tricalcium aluminate (Ca3Al2O6).&#13;
The production of Portland cement clinker and crude iron from BOFS has economic and ecological benefits for both the cement and steel industry. Cement clinker from reduced BOFS may be used as a substitute for cement clinker from conventional cement production, thereby CO2 emissions will be reduced. The steel industry benefits from a high-value application for its by-products that avoids cost expensive landfilling and may even bring economic advantages. However, reductive treatment requires high temperatures and, for economic reasons, has to be carried out immediately after casting of the liquid BOFS, which is a logistical challenge for most steel plants. A cost-benefit analysis is therefore essential.</abstract>
    <enrichment key="eventName">European Congress and Exhibition on Advanced Materials and Processes</enrichment>
    <enrichment key="eventPlace">Online meeting</enrichment>
    <enrichment key="eventStart">13.09.2021</enrichment>
    <enrichment key="eventEnd">17.09.2021</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BOFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Portland Cement</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hydraulic reactivity</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.1 Baustoffe</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>52939</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>6518</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>147</volume>
    <type>article</type>
    <publisherName>Elsevier Ltd.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Synthesis and characterisation of alites from reduced basic oxygen furnace slags</title>
    <abstract language="eng">Basic oxygen furnace slags (BOFS) are by-products of the steelmaking process. Several researchers have studied the production of Portland cement clinker and metallic iron from BOFS via a reductive treatment.&#13;
In this study, we applied a carbothermal reduction of BOFS in a technical-scale electric arc furnace and characterised the clinker-like products. Those clinker-like non-metallic products (NMPs) had a chemical and mineralogical composition comparable to clinker for ordinary Portland cement (OPC) and contained large elongated alite crystals as major component. The pure NMPs reacted more slowly and achieved a lower degree of hydration compared with commercial OPC.&#13;
If the reactivity of the products can be further increased by employing specific adaptations, it can be used as a full clinker substitute for OPC. Nevertheless, it is also an option to use the material without further modifications as a cement component or concrete addition, which contributes to the strength development in both cases.</abstract>
    <parentTitle language="eng">Cement and Concrete Research</parentTitle>
    <identifier type="doi">10.1016/j.cemconres.2021.106518</identifier>
    <identifier type="issn">0008-8846</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">12.08.2021</enrichment>
    <author>Katharina Schraut</author>
    <author>Burkart Adamczyk</author>
    <author>Christian Adam</author>
    <author>D. Stephan</author>
    <author>Birgit Meng</author>
    <author>Sebastian Simon</author>
    <author>Julia von Werder</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BOFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hydration products</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Thermal analysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray diffraction</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.1 Baustoffe</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>53473</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>lecture</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Hydraulic reactivity of alite rich material from post-treated basic oxygen furnace slags</title>
    <abstract language="eng">Basic oxygen furnace slags (BOFS) are a by-product of steel production. In 2016, 10.4 Mt of BOFS were produced in the European Union (EU). The main part of BOFS is used in road construction, earthwork and hydraulic engineering. A smaller part is returned to the metallurgical circle, used as fertilizer or landfilled. However, it is also possible to produce higher value products from BOFS. For example, many researchers have investigated the possibility of producing Portland cement clinker and crude iron from BOFS by a carbothermal post-treatment.&#13;
In this study, German BOFS was reduced in a small-scale electric arc furnace using petrol coke as reducing agent. The carbothermal treatment reduces the iron oxides in the BOFS to metallic iron, which accumulates at the bottom of the furnace by density separation. In addition to metallic iron, the process generates a mineral product rich in the tricalcium silicate solid solution alite. As the main constituent of Portland cement clinker, the hydraulic reactive mineral alite is of high economic importance. &#13;
In previous studies, the hydraulic reactivity of the mineral product was investigated by testing the compressive strength of blends with 70 wt.% ordinary Portland cement (OPC). Recent investigations focused on the hydraulic properties of the pure mineral product from the reduced BOFS. The heat of hydration of the mineral product was measured by isothermal calorimetry and compared with the heat of hydration of a synthetic low-iron slag and OPC. In addition, the formation of hydration products was investigated with differential scanning calorimetry (DSC) and x-ray diffraction analysis (XRD) on freeze-dried samples after defined curing times. The results of the calorimetric measurements indicate that the mineral product produced less heat of hydration and its reaction was delayed compared to the synthetic low-iron slag and OPC. Hydration products such as portlandite and calcium silicate hydrates (C-S-H) formed later and in lower amounts. &#13;
The production of a hydraulic material from BOFS by reductive treatment is of great interest to both the cement and steel industries. The substitution of cement clinker in OPC with a hydraulic material such as reduced BOFS leads to a reduction in greenhouse gas emissions from cement production. The steel industry benefits from an application for its by-products that avoids cost expensive landfilling and may even bring economic advantages. Furthermore, it may be possible to return the recovered crude iron to production.</abstract>
    <enrichment key="eventName">3rd European Mineralogical Conference</enrichment>
    <enrichment key="eventPlace">Cracow, Poland</enrichment>
    <enrichment key="eventStart">30.08.2021</enrichment>
    <enrichment key="eventEnd">02.09.2021</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BOFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Calcium silicate</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hydraulic reactivity</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.1 Baustoffe</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>49591</id>
    <completedYear/>
    <publishedYear>2019</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>poster</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Formation of tricalciumsilicate from post-treated metallurgical slags</title>
    <abstract language="eng">LD-slags differ from Ordinary Portland Cement (OPC) mainly in a higher content of iron oxides and a low content of Tricalciumsilicate (Alite). In the context of an improved resource usage, a procedure to convert LDslags into cement clinker was investigated.</abstract>
    <enrichment key="eventName">15th International Congress on the Chemistry of Cement</enrichment>
    <enrichment key="eventPlace">Prague, Czech Republic</enrichment>
    <enrichment key="eventStart">16.09.2019</enrichment>
    <enrichment key="eventEnd">20.09.2019</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Tricalcium-silicate</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Portland Cement</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Alite</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Steelmaking slag</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Graue Literatur</collection>
  </doc>
  <doc>
    <id>64713</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>187</pageFirst>
    <pageLast>191</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>conferenceobject</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Usage of BOF slag and next generation EAF slag in the cement industry</title>
    <abstract language="eng">When the transformation of its production routes, which the European steel industry aims to complete within the next two decades, is accomplished, increased amounts of EAF slag will be generated. In most cases the BF/BOF production route is intended to be substituted by a DRI/EAF combination. But in some cases only the BF will be substituted by a DRI/SAF (smelter) combination and the BOF process remains. Then BOF slags will remain, too. BAM and FEhS cooperate together with further research and industry partners in two research projects dealing on the one hand with the utilisation of modified BOF slag as a cement clinker substitute ("SlagCEM") and on the other hand with the use of modified and granulated EAF slag as granulated blast furnace slag (GBS) substitute ("DRI-EOS").</abstract>
    <parentTitle language="eng">Proceedings of the 9th International Valorisation Symposium</parentTitle>
    <enrichment key="eventName">9th International Slag Valorisation Symposium</enrichment>
    <enrichment key="eventPlace">Leuven, Belgium</enrichment>
    <enrichment key="eventStart">08.04.2025</enrichment>
    <enrichment key="eventEnd">11.04.2025</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Joachim Schneider</author>
    <author>Burkart Adamczyk</author>
    <author>Dominik Ebert</author>
    <author>Andreas Ehrenberg</author>
    <author>Katharina Schraut</author>
    <author>David Algermissen</author>
    <author>Christian Adam</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Steel slags</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Basic oxygen furnace (BOF)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electric arc furnace (EAF)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cement</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Slag valorisation</value>
    </subject>
    <collection role="ddc" number="624">Ingenieurbau</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="themenfelder" number="">Infrastruktur</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Graue Literatur</collection>
    <collection role="themenfelder" number="">Green Intelligent Building</collection>
  </doc>
  <doc>
    <id>54737</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst>372</pageFirst>
    <pageLast>385</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>conferenceobject</type>
    <publisherName>TK-Verlag</publisherName>
    <publisherPlace>Neuruppin</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Erzeugung klimaschonender Bindemittel als Alternativen zu Zement durch thermochemische Behandlung von mineralischen Nebenprodukten und Abfällen</title>
    <abstract language="deu">Die Zementindustrie erzeugt etwa 6-7% der globalen CO2-Emissionen und steht damit als Industriezweig vor dem Hintergrund einer anvisierten Klimaneutralität vor gewaltigen Herausforderungen. Der Prozess der Klinkerherstellung wurde über die vergangenen Jahrzehnte bereits kontinuierlich optimiert. Seit 1990 ist es der deutschen Zementindustrie gelungen, die spezifischen CO2-Emissionen der Zementproduktion u. a. durch den Einsatz alternativer, nicht fossiler Brennstoffe und durch Absenkung des Klinkergehalts im Zement um 20 % zu senken. Weitere konventionelle Minderungsstrategien versprechen jedoch nur noch wenig zusätzliche Reduktion. Im Falle des Portlandklinkers besteht die Schwierigkeit darin, dass zwei Drittel der CO2-Emissionen rohstoffbedingt durch die Entsäuerung des Kalksteins (CaCO3) anfallen, die durch die beschriebenen Maßnahmen nicht weiter abgesenkt werden können. Vielmehr wird es erforderlich sein, noch zu entwickelnde oder zu optimierende Technologien anzuwenden und ggf. alle relevanten Ebenen wie Produktion, Weiterverarbeitung und Anwendung von Zement und Beton neu zu denken. Neben technologischen Ansätzen zur CO2-Abscheidung mit nachfolgender langfristiger Speicherung (Carbon Capture and Storage – CCS) oder Verwertung (Carbon Capture and Utilisation – CCU) werden auch alternative Rohstoffe für die Zementproduktion und alternative Bindemittel in Betracht zu ziehen sein.</abstract>
    <parentTitle language="deu">Mineralische Nebenprodukte und Abfälle 9</parentTitle>
    <identifier type="isbn">978-3-944310-58-9</identifier>
    <enrichment key="eventName">Berliner Konferenz Mineralische Nebenprodukte und Abfälle</enrichment>
    <enrichment key="eventPlace">Berlin, Germany</enrichment>
    <enrichment key="eventStart">25.04.2022</enrichment>
    <enrichment key="eventEnd">26.04.2022</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Christian Adam</author>
    <author>Katharina Schraut</author>
    <author>Burkart Adamczyk</author>
    <author>Karin Weimann</author>
    <author>Gregor Gluth</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Zement</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Sekundärrohstoff</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Graue Literatur</collection>
  </doc>
  <doc>
    <id>56080</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>lecture</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Formation and hydraulic reactivity of an alite rich material from post treated basic oxygen furnace slag</title>
    <abstract language="eng">Basic oxygen furnace slag (BOFS) is a by-product of steelmaking of which about 10.4 Mt are produced annually in the EU. BOFS is mostly used in road construction, earthwork and hydraulic engineering. However, in this use, the iron bound in BOFS is lost and the opportunity to produce higher value products from BOFS is forgone.&#13;
In recent decades, many researchers have investigated a thermochemical process to reduce iron oxides to metallic iron in molten BOFS. The metallic iron formed separates from the reduced slag due to its higher density and can be recovered. An advantage of this process is that simultaneously the chemical composition of the reduced slag is adapted to that of the Portland cement clinker and the hydraulic reactive mineral alite is formed. &#13;
In this study, BOFS was reduced in a small-scale electric arc furnace using petrol coke as reducing agent, and the hydraulic properties of the reduced, low-iron BOFS were investigated. Despite a chemical and mineralogical composition similar to that of Portland cement clinker, the reduced BOFS produced less heat of hydration, and its reaction was delayed compared to Portland cement. However, the addition of gypsum, as is also done in cement production from Portland cement clinker, has been found to accelerate the hydration rate of reduced BOFS. &#13;
Further research to improve the hydraulic properties of the reduced slag is essential. If successful, the production of a hydraulic binder and crude iron from BOFS could have economic and ecological benefits for both the cement and steel industry.</abstract>
    <enrichment key="eventName">GeoMin Köln 2022</enrichment>
    <enrichment key="eventPlace">Cologne, Germany</enrichment>
    <enrichment key="eventStart">11.09.2022</enrichment>
    <enrichment key="eventEnd">15.09.2022</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BOFS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Portland Cement</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hydraulic reactivity</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.1 Baustoffe</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>52695</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>264003 (12pp)</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue>26</issue>
    <volume>33</volume>
    <type>article</type>
    <publisherName>IOP Publishing</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">In situ synchrotron XRD measurements during solidification of a melt in the CaO–SiO2 system using an aerodynamic levitation system</title>
    <abstract language="eng">Phase formation and evolution was investigated in the CaO–SiO2 system in the range of 70–80 mol% CaO. The samples were container-less processed in an aerodynamic levitation system and crystallization was followed in situ by synchrotron x-ray diffraction at the beamline P21.1 at the German electron synchrotron (DESY). Modification changes of di- and tricalcium silicate were observed and occurred at lower temperatures than under equilibrium conditions. Despite deep sample undercooling, no metastable phase formation was observed within the measurement timescale of 1 s. For the given cooling rates ranging from 300 K s−1 to about 1 K s−1, no decomposition of tricalcium silicate was observed. No differences in phase evolution were observed between reducing and oxidizing conditions imposed by the levitation gas (Ar and Ar + O2). We demonstrate that this setup has great potential to follow crystallization in refractory oxide liquids in situ. For sub-second primary phase formation faster detection and for polymorph detection adjustments in resolution have to be implemented.</abstract>
    <parentTitle language="eng">Journal of Physics: Condensed Matter</parentTitle>
    <identifier type="doi">10.1088/1361-648X/abf7e1</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-526952</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">17.06.2021</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Katharina Schraut</author>
    <author>F. Kargl</author>
    <author>Christian Adam</author>
    <author>O. Ivashko</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Aerodynamic levitation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Calcium silicate</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Phase formation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Oxide melts</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>In situ synchrotron x-ray diffraction</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/52695/In situ synchrotron XRD measurements during solidification.pdf</file>
  </doc>
  <doc>
    <id>49050</id>
    <completedYear/>
    <publishedYear>2019</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>Paper 492, 1</pageFirst>
    <pageLast>10</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>conferenceobject</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Formation and chemical stabilisation of tricalcium-silicate during solidification from the melt of post-treated metallurgical slags</title>
    <abstract language="eng">Tricalcium-silicate (C3S) or Alite is the most important mineral in Portland cement. Since pure tricalcium-silicate is only stable above temperatures of 1250 °C, its decomposition has to be prevented technically by fast cooling after the sintering process. At room temperature, the decomposition velocity is very slow so that metastable tricalcium-silicate is obtained.&#13;
Although the mechanisms of clinker phase formation during burning process of Portland cement in a rotary kiln were solved and improved over the years, in view of possible economic and ecological benefits current projects aim to produce clinker phases from metallurgical slags. Recent studies discovered that the mineral phase which remained after a reducing treatment and separation of formed metallic iron from molten Linz-Donawitz (LD-) slags contained about 60 wt.% Alite despite it was cooled slowly. Because the results could be verified using slags from different origins and varying cooling velocities a chemical stabilisation of the Alite can be assumed. First tests in mortars indicate that workability, hardening and solid state properties are comparable with an ordinary Portland cement. An application of the observed phenomenon in cement production requires enhanced knowledge about formation and stabilisation conditions of Alite during crystallisation from melts in contrast to the sintering reactions in conventional Portland cement production. Therefore, this study focuses on the stabilisation mechanisms of Alite in consolidating melts. Samples from different melting experiments are analysed to determine stabilising factors.</abstract>
    <parentTitle language="eng">Proceedings of the 15th International Congress on the Chemistry of Cement</parentTitle>
    <enrichment key="eventName">15th International Congress on the Chemistry of Cement</enrichment>
    <enrichment key="eventPlace">Prag, Czech Republic</enrichment>
    <enrichment key="eventStart">16.09.2019</enrichment>
    <enrichment key="eventEnd">20.09.2019</enrichment>
    <author>Katharina Schraut</author>
    <author>Burkart Adamczyk</author>
    <author>Sebastian Simon</author>
    <author>Julia von Werder</author>
    <author>Birgit Meng</author>
    <author>D. Stephan</author>
    <author>F. Kargl</author>
    <author>Christian Adam</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Tricalcium-silicate</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Portland Cement</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Alite</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Steelmaking slag</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Graue Literatur</collection>
  </doc>
  <doc>
    <id>58522</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>lecture</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Production of a hydraulic material from post-treated steelmaking slags</title>
    <abstract language="eng">Steelmaking slag is a by-product of steel production of which 4.5 Mt were produced in 2020 in Germany alone. It is mainly used in road construction, earthwork and hydraulic engineering. A smaller part is returned to the metallurgical circle, used as fertilizer or landfilled. &#13;
With this use, iron oxides still contained in steelmaking slag are lost. In addition, the possibility of producing higher-grade products from steelmaking slag is foregone. In recent decades, many researchers have investigated the production of Portland cement clinker and crude iron from basic oxygen furnace slags (BOFS) via a reductive treatment. Carbothermal treatment of liquid BOFS causes a reduction of iron oxides to metallic iron, which separates from the mineral phase due to its higher density. Simultaneously, the chemical composition of the reduced slag is adapted to that of the Portland cement clinker. &#13;
In this study, German BOFS was reduced in a small-scale electric arc furnace using petrol coke as a reducing agent. The resulting low-iron mineral product had a similar chemical composition to Portland cement clinker and was rich in the tricalcium silicate solid solution alite (Ca3SiO5). Based on its chemical and mineralogical composition, similar to that of Portland cement clinker, the reduced BOFS has the potential to react comparably. In our study, the reduced BOFS produced less heat of hydration compared to OPC and its hydraulic reaction was delayed. However, adding gypsum has been shown to accelerate the hydration rate of the reduced BOFS compared to that known from the calcium silicates of Portland cement clinker.&#13;
Further research to improve the hydraulic properties of the reduced slag is essential. If successful, producing a hydraulic binder and crude iron from BOFS could have economic and ecological benefits for both the cement and steel industry.</abstract>
    <enrichment key="eventName">16th International Congress on the Chemistry of Cement  ICCC 2023</enrichment>
    <enrichment key="eventPlace">Bangkok, Thailand</enrichment>
    <enrichment key="eventStart">18.09.2023</enrichment>
    <enrichment key="eventEnd">22.09.2023</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="InvitedTalks">0</enrichment>
    <author>Katharina Schraut</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Steelmaking slag</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Alite hydraulic reactivity</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Clinker substitute</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="institutes" number="">7.1 Baustoffe</collection>
    <collection role="institutes" number="">7.4 Baustofftechnologie</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Circular Economy</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
</export-example>
