<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>62586</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>854</pageFirst>
    <pageLast>862</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>8</volume>
    <type>article</type>
    <publisherName>American Chemical Society (ACS)</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Upconverting Nanoparticles and Cu(I) Complex-Based Platform for Oxygen Sensing, Thermometry, and Emission Color Tuning</title>
    <abstract language="eng">Multifunctional nanoplatforms combine different material properties to meet a wide range of applications, allowing highly customizable systems. In this rapidly advancing research field, we introduce a multifunctional nanomaterial based on the synergy between Tm3+-doped upconverting nanoparticles (UCNPs) and a Cu(I) complex (CuCom). This material is designed for oxygen sensing, optical thermometry, and emission color tuning. In various concentrations, the CuCom complex was electrostatically integrated into a mesoporous silica shell surrounding the core UCNPs (UCNP@mSiO2). The optimized system, UCNP@mSiO2@CuCom-10, was evaluated for different applications. Due to the spectral overlap between the CuCom absorption and the nanoparticles emission, excitation at 980 nm allows most of the UV-blue emission output from the UCNPs to be transferred to the CuCom via luminescent resonance energy transfer (LRET), producing red emission from the molecule. The remaining Tm3+ emission enables optical thermometry, while CuCom’s sensitivity to molecular oxygen supports its application in gas sensing. In upconversion mode, the nanoplatform achieved a Stern−Volmer constant for O2 sensing of 1.64 and demonstrated thermometric relative sensitivities of 0.9% and 1% K−1 at room temperature, with a linear response from 193 to 373 K. Additionally, the emission color of UCNP@mSiO2@CuCom-10 can be tuned from blue to white and yellow, by varying the excitation and temperature, adding further functionality to the system. This multifunctional platform suggests promising applications in biology, medicine, and environmental monitoring.</abstract>
    <parentTitle language="eng">ACS Applied Nano Materials</parentTitle>
    <identifier type="doi">10.1021/acsanm.4c06351</identifier>
    <identifier type="isbn">2574-0970</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-625869</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,11]],"date-time":"2025-01-11T13:10:08Z","timestamp":1736601008464,"version":"3.32.0"},"reference-count":37,"publisher":"American Chemical Society (ACS)","issue":"1","license":[{"start":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T00:00:00Z","timestamp":1734048000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100005285","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de Goi\u00e1s","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100005285","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006162","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Ci\u00eancia e Tecnologia do Estado de Pernambuco","doi-asserted-by":"publisher","award":["APQ-0096-3.03\/19","DCR-0010-3.03\/21"],"id":[{"id":"10.13039\/501100006162","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"publisher","award":["2013\/07793-6","2019\/12588-9","2021\/01170-3"],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002322","name":"Coordena\u00e7\u00e3o de Aperfei\u00e7oamento de Pessoal de N\u00edvel Superior","doi-asserted-by":"publisher","award":["88887.666855\/2022-0"],"id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ACS Appl. Nano Mater."],"published-print":{"date-parts":[[2025,1,10]]},"DOI":"10.1021\/acsanm.4c06351","type":"journal-article","created":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T06:41:26Z","timestamp":1734072086000},"page":"854-862","source":"Crossref","is-referenced-by-count":0,"title":["Upconverting Nanoparticles and Cu(I) Complex-Based Platform for Oxygen Sensing, Thermometry, and Emission Color Tuning"],"prefix":"10.1021","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1278-5274","authenticated-orcid":true,"given":"Marylyn Setsuko","family":"Arai","sequence":"first","affiliation":[{"name":"S\u00e3o Carlos Institute of Physics, University of S\u00e3o Paulo, 13566-590 S\u00e3o Carlos, Brazil"}]},{"given":"Leandro Piaggi","family":"Ravaro","sequence":"additional","affiliation":[{"name":"S\u00e3o Carlos Institute of Physics, University of S\u00e3o Paulo, 13566-590 S\u00e3o Carlos, Brazil"},{"name":"Graduate Program on Physics Engineering, Federal Rural University of Pernambuco, 54518-430 Cabo de Santo Agostinho, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1382-866X","authenticated-orcid":true,"given":"Gabriel","family":"Brambilla","sequence":"additional","affiliation":[{"name":"S\u00e3o Carlos Institute of Physics, University of S\u00e3o Paulo, 13566-590 S\u00e3o Carlos, Brazil"}]},{"given":"Lauro June Queiroz","family":"Maia","sequence":"additional","affiliation":[{"name":"Physics Institute, Federal University of Goi\u00e1s, 74690-900 Goi\u00e2nia, Brazil"}]},{"given":"Mohammad","family":"Reza Dousti","sequence":"additional","affiliation":[{"name":"Graduate Program on Physics Engineering, Federal Rural University of Pernambuco, 54518-430 Cabo de Santo Agostinho, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8352-2573","authenticated-orcid":true,"given":"Andrea Simone Stucchi","family":"de Camargo","sequence":"additional","affiliation":[{"name":"Federal Institute for Materials Research and Testing (BAM), 12489 Berlin, Germany"},{"name":"Otto-Schott Institute of Materials Research, Friedrich-Schiller University (FSU), 07743 Jena, Germany"}]}],"member":"316","published-online":{"date-parts":[[2024,12,13]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2008.10.013"},{"key":"ref2\/cit2","doi-asserted-by":"crossref","DOI":"10.1201\/9781482268591","volume-title":"Nanomaterials","author":"Edelstein A. S.","year":"1998"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1039\/b502142c"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005159"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.7b07120"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1039\/D1NA00327E"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1021\/acsabm.8b00224"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c06117"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2021.162494"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1016\/j.jlumin.2023.120306"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/cm4018375"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2020.103923"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.sna.2021.112722"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/cm0010708"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/ja103112m"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2021.130566"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja036736o"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT00532F"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT03121H"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2018.07.020"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1023\/A:1026370729205"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00039K"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1016\/0925-4005(95)01685-6"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c14579"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402060"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2019.00218"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00136h"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT03167D"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/ja00485a016"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC04326C"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2015.02.014"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/ja302807s"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1039\/b910305h"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1039\/C6TC04630D"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1038\/nprot.2016.035"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1039\/C3TB21442G"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/cm4010807"}],"container-title":["ACS Applied Nano Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsanm.4c06351","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsanm.4c06351","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T09:23:53Z","timestamp":1736501033000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acsanm.4c06351"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,13]]},"references-count":37,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2025,1,10]]}},"alternative-id":["10.1021\/acsanm.4c06351"],"URL":"https:\/\/doi.org\/10.1021\/acsanm.4c06351","relation":{},"ISSN":["2574-0970","2574-0970"],"issn-type":[{"type":"print","value":"2574-0970"},{"type":"electronic","value":"2574-0970"}],"subject":[],"published":{"date-parts":[[2024,12,13]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">20.02.2025</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Marylyn Setsuko Arai</author>
    <author>Leandro Piaggi Ravaro</author>
    <author>Gabriel Brambilla</author>
    <author>Lauro June Queiroz Maia</author>
    <author>Mohammad Reza Dousti</author>
    <author>Andrea Simone Stucchi de Camargo</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>M</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>O2 sensing</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Upconversion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Luminescence resonance energy transfer (LRET)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Optical thermometry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mesoporous silica shell</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">5 Werkstofftechnik</collection>
    <collection role="institutes" number="">5.6 Glas</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/62586/Arai-et-al-2025-UCNP and CuComplex.pdf</file>
  </doc>
</export-example>
