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    <language>eng</language>
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    <pageLast>2565</pageLast>
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    <issue>7</issue>
    <volume>10</volume>
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    <belongsToBibliography>1</belongsToBibliography>
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    <title language="eng">Tailoring the FeO/SiO2 ratio in electric arc furnace slags to minimize the leaching of Vanadium and Chromium</title>
    <abstract language="eng">Based on recently published research on leaching control mechanisms in electric arc furnace (EAF) slags, it is assumed that a FeO/SiO2 ratio of around one leads to low leached V and Cr concentrations. This ratio influences the mineral phase composition of the slag toward higher amounts of spinel and a lower solubility of calcium silicate phases by suppressing the formation of magnesiowuestite and highly soluble calcium silicate phases. To evaluate this hypothesis, laboratory and scaled up tests in an EAF pilot plant were performed on slag samples characterized by elevated V and Cr leaching and a high FeO/SiO2 ratio. Prior to the melting experiments, the optimum FeO/SiO2 ratio was calculated via FactSageTM. In the melting experiments, the ratio was adjusted by adding quartz sand, which also decreased the basicity (CaO/SiO2) of the slag. As a reference, remelting experiments without quartz sand addition were conducted and additionally, the influence of the cooling rate of the slag was examined. The remelted (without quartz sand) and the remelted modified slags (with quartz sand) were analyzed chemically and mineralogically and the leaching behavior was investigated. The modification of the slags yielded a minimized release of V and Cr, supporting the hypothesis that the FeO/SiO2 ratio influences the mineralogy and the leaching behavior.</abstract>
    <parentTitle language="eng">Applied Sciences</parentTitle>
    <identifier type="doi">10.3390/app10072549</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-507748</identifier>
    <enrichment key="date_peer_review">02.07.2020</enrichment>
    <author>Burkart Adamczyk</author>
    <author>S. Neuhold</author>
    <author>P. Drissen</author>
    <author>D. Algermissen</author>
    <author>P. Presoly</author>
    <author>K. P. Sedlazeck</author>
    <author>J. Schenk</author>
    <author>J. G. Raith</author>
    <author>R. Pomberger</author>
    <author>D. Vollprecht</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electric arc furnace slags</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>FactSage calculations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>EAF slags</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Leaching control mechanisms</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Melting experiments</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
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    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/50774/Tailoring FeO-SiO2 ratio_Applied Sciences 2020.pdf</file>
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  <doc>
    <id>57151</id>
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    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>18</pageLast>
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    <publisherName>MDPI</publisherName>
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    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Tailoring the FeO/SiO2 Ratio in Electric Arc Furnace Slags to Minimize the Leaching of Vanadium and Chromium</title>
    <abstract language="eng">Based on recently published research on leaching control mechanisms in electric arc furnace (EAF) slags, it is assumed that a FeO/SiO2 ratio of around one leads to low leached V and Cr concentrations. This ratio influences the mineral phase composition of the slag toward higher amounts of spinel and a lower solubility of calcium silicate phases by suppressing the formation of magnesiowuestite and highly soluble calcium silicate phases. To evaluate this hypothesis, laboratory and scaled up tests in an EAF pilot plant were performed on slag samples characterized by elevated V and Cr leaching and a high FeO/SiO2 ratio. Prior to the melting experiments, the optimum FeO/SiO2 ratio was calculated via FactSageTM. In the melting experiments, the ratio was adjusted by adding quartz sand, which also decreased the basicity (CaO/SiO2) of the slag. As a reference, remelting experiments without quartz sand addition were conducted and additionally, the influence of the cooling rate of the slag was examined. The remelted (without quartz sand) and the remelted modified slags (with quartz sand) were analyzed chemically and mineralogically and the leaching behavior was investigated. The modification of the slags yielded a minimized release of V and Cr, supporting the hypothesis that the FeO/SiO2 ratio influences the mineralogy and the leaching behavior.</abstract>
    <parentTitle language="eng">Applied Science</parentTitle>
    <identifier type="doi">10.3390/app10072549</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-571517</identifier>
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    <enrichment key="date_peer_review">15.03.2023</enrichment>
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    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>S. Neuhold</author>
    <author>D. Algermissen</author>
    <author>P. Drissen</author>
    <author>Burkart Adamczyk</author>
    <author>P. Presoly</author>
    <author>K. P. Sedlazeck</author>
    <author>J. Schenk</author>
    <author>J. G. Raith</author>
    <author>R. Pomberger</author>
    <author>D. Vollprecht</author>
    <subject>
      <language>eng</language>
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      <value>Electric arc furnace (EAF) slags</value>
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      <language>eng</language>
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    <subject>
      <language>eng</language>
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      <value>Leaching control mechanisms</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Melting experiments</value>
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    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung</collection>
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    <collection role="themenfelder" number="">Circular Economy</collection>
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    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
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