<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>3709</id>
    <completedYear/>
    <publishedYear>2004</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2720</pageFirst>
    <pageLast>2725</pageLast>
    <pageNumber/>
    <edition/>
    <issue>7</issue>
    <volume>20</volume>
    <type>article</type>
    <publisherName>American Chemical Society</publisherName>
    <publisherPlace>Washington, DC</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">On the Adsorption Kinetics of Surface-Chemically Pure n-Dodecanoic Acid at the Air/Water Interface</title>
    <abstract language="eng">The dynamic surface tension data for n-dodecanoic acid in 0.005 M hydrochloric acid, for as-received as well as for surface-chemically pure solutions, show the presence of a prolonged induction period, clearly indicating that the adsorption of this nonionic surfactant is not simply diffusion-controlled. A kinetic model for the reversible formation of monolayer islands, long known in the field of electrochemistry, is shown to also apply to the adsorption of n-dodecanoic acid at the air/water interface. The rate constant increases linearly with increasing bulk concentration, while the induction time decreases exponentially. The phenomenon of nucleation at the air/water interface is consistent with the direct experimental observation of the formation of solid-like patches as the interfacial region is drastically compressed.</abstract>
    <parentTitle language="eng">Langmuir</parentTitle>
    <identifier type="old">3862</identifier>
    <identifier type="doi">10.1021/la035732u</identifier>
    <identifier type="issn">0743-7463</identifier>
    <identifier type="issn">1520-5827</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">09.08.2004</enrichment>
    <author>A.J. Prosser</author>
    <author>Utz Retter</author>
    <author>K. Lunkenheimer</author>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
</export-example>
