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    <title language="eng">One‐Pot Synthesis of High‐Capacity Sulfur Cathodes via In‐Situ Polymerization of a Porous Imine‐Based Polymer</title>
    <abstract language="eng">AbstractLithium‐ion batteries, essential for electronics and electric vehicles, predominantly use cathodes made from critical materials like cobalt. Sulfur‐based cathodes, offering a high theoretical capacity of 1675 mAh g−1 and environmental advantages due to sulfur's abundance and lower toxicity, present a more sustainable alternative. However, state‐of‐the‐art sulfur‐based electrodes do not reach the theoretical capacities, mainly because conventional electrode production relies on mixing of components into weakly coordinated slurries. Consequently, sulfur‘s mobility leads to battery degradation—an effect known as the “sulfur‐shuttle”. This study introduces a solution by developing a microporous, covalently‐bonded, imine‐based polymer network grown in situ around sulfur particles on the current collector. The polymer network (i) enables selective transport of electrolyte and Li‐ions through pores of defined size, and (ii) acts as a robust host to retain the active component of the electrode (sulfur species). The resulting cathode has superior rate performance from 0.1 C (1360 mAh g−1) to 3 C (807 mAh g−1). Demonstrating a high‐performance, sustainable sulfur cathode produced via a simple one‐pot process, our research underlines the potential of microporous polymers in addressing sulfur diffusion issues, paving the way for sulfur electrodes as viable alternatives to traditional metal‐based cathodes.</abstract>
    <parentTitle language="eng">Angewandte Chemie International Edition</parentTitle>
    <identifier type="doi">10.1002/anie.202400382</identifier>
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Sulfur\u2010based cathodes, offering a high theoretical capacity of 1675\u2005mAh\u2009g&lt;jats:sup&gt;\u22121&lt;\/jats:sup&gt; and environmental advantages due to sulfur's abundance and lower toxicity, present a more sustainable alternative. However, state\u2010of\u2010the\u2010art sulfur\u2010based electrodes do not reach the theoretical capacities, mainly because conventional electrode production relies on mixing of components into weakly coordinated slurries. Consequently, sulfur\u2018s mobility leads to battery degradation\u2014an effect known as the \u201csulfur\u2010shuttle\u201d. This study introduces a solution by developing a microporous, covalently\u2010bonded, imine\u2010based polymer network grown in situ around sulfur particles on the current collector. The polymer network (i) enables selective transport of electrolyte and Li\u2010ions through pores of defined size, and (ii) acts as a robust host to retain the active component of the electrode (sulfur species). The resulting cathode has superior rate performance from 0.1\u2005C (1360\u2005mAh\u2009g&lt;jats:sup&gt;\u22121&lt;\/jats:sup&gt;) to 3\u2005C (807\u2005mAh\u2009g&lt;jats:sup&gt;\u22121&lt;\/jats:sup&gt;). Demonstrating a high\u2010performance, sustainable sulfur cathode produced via a simple one\u2010pot process, our research underlines the potential of microporous polymers in addressing sulfur diffusion issues, paving the way for sulfur electrodes as viable alternatives to traditional metal\u2010based cathodes.&lt;\/jats:p&gt;","DOI":"10.1002\/anie.202400382","type":"journal-article","created":{"date-parts":[[2024,4,15]],"date-time":"2024-04-15T15:40:32Z","timestamp":1713195632000},"update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["One\u2010Pot Synthesis of High\u2010Capacity Sulfur Cathodes via In\u2010Situ Polymerization of a Porous Imine\u2010Based Polymer"],"prefix":"10.1002","author":[{"ORCID":"http:\/\/orcid.org\/0000-0002-6536-3537","authenticated-orcid":false,"given":"Guiping","family":"Li","sequence":"first","affiliation":[{"name":"Department of Chemistry &amp;amp; IRIS Adlershof Humboldt-Universit\u00e4t zu Berlin  Brook-Taylor-Str. 2 12489 Berlin Germany"}]},{"given":"Ye","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry &amp;amp; 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    <author>Guiping Li</author>
    <author>Ye Liu</author>
    <author>Thorsten Schultz</author>
    <author>Moritz Exner</author>
    <author>Ruslan Muydinov</author>
    <author>Hui Wang</author>
    <author>Kerstin Scheurell</author>
    <author>Jieyang Huang</author>
    <author>Paulina Szymoniak</author>
    <author>Nicola Pinna</author>
    <author>Norbert Koch</author>
    <author>Philipp Adelhelm</author>
    <author>Michael J. Bojdys</author>
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      <language>eng</language>
      <type>uncontrolled</type>
      <value>In-situ polymerization</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sulfur cathodes</value>
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