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    <title language="eng">Interlayer Affected Diamond Electrochemistry</title>
    <abstract language="eng">Diamond electrochemistry is primarily influenced by quantities of sp3‐carbon, surface terminations, and crystalline structure. In this work, a new dimension is introduced by investigating the effect of using substrate‐interlayers for diamond growth. Boron and nitrogen co‐doped nanocrystalline diamond (BNDD) films are grown on Si substrate without and with Ti and Ta as interlayers, named BNDD/Si, BNDD/Ti/Si, and BNDD/Ta/Ti/Si, respectively. After detailed characterization using microscopies, spectroscopies, electrochemical techniques, and density functional theory simulations, the relationship of composition, interfacial structure, charge transport, and electrochemical properties of the interface between diamond and metal is investigated. The BNDD/Ta/Ti/Si electrodes exhibit faster electron transfer processes than the other two diamond electrodes. The interlayer thus determines the intrinsic activity and reaction kinetics. The reduction in their barrier widths can be attributed to the formation of TaC, which facilitates carrier tunneling, and simultaneously increases the concentration of electrically active defects. As a case study, the BNDD/Ta/Ti/Si electrode is further employed to assemble a redox‐electrolyte‐based supercapacitor device with enhanced performance. In summary, the study not only sheds light on the intricate relationship between interlayer composition, charge transfer, and electrochemical performance but also demonstrates the potential of tailored interlayer design to unlock new capabilities in diamond‐based electrochemical devices.</abstract>
    <parentTitle language="eng">Small Methods</parentTitle>
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In this work, a new dimension is introduced\u00a0by investigating the effect of using substrate\u2010interlayers for diamond growth. Boron and nitrogen co\u2010doped nanocrystalline diamond (BNDD) films are grown on Si substrate without and with Ti and Ta as interlayers, named BNDD\/Si, BNDD\/Ti\/Si, and BNDD\/Ta\/Ti\/Si, respectively. After detailed characterization using microscopies, spectroscopies, electrochemical techniques, and density functional theory simulations, the relationship of composition, interfacial structure, charge transport, and electrochemical properties of the interface between diamond and metal is investigated. The BNDD\/Ta\/Ti\/Si electrodes exhibit faster electron transfer processes than the other two diamond electrodes. The interlayer thus determines the intrinsic activity and reaction kinetics. 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    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Xinyue Chen</author>
    <author>Ximan Dong</author>
    <author>Chuyan Zhang</author>
    <author>Meng Zhu</author>
    <author>Essraa Ahmed</author>
    <author>Giridharan Krishnamurthy</author>
    <author>Rozita Rouzbahani</author>
    <author>Paulius Pobedinskas</author>
    <author>Nicolas Gauquelin</author>
    <author>Daen Jannis</author>
    <author>Kawaljit Kaur</author>
    <author>Aly Mohamed Elsayed Hafez</author>
    <author>Felix Thiel</author>
    <author>Rainer Bornemann</author>
    <author>Carsten Engelhard</author>
    <author>Holger Schönherr</author>
    <author>Johan Verbeeck</author>
    <author>Ken Haenen</author>
    <author>Xin Jiang</author>
    <author>Nianjun Yang</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanocrystalline diamond</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Interfaces</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electrochemistry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>TOF-SIMS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SEM</value>
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