<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>5546</id>
    <completedYear/>
    <publishedYear>2004</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>8617</pageFirst>
    <pageLast>8625</pageLast>
    <pageNumber/>
    <edition/>
    <issue>26</issue>
    <volume>43</volume>
    <type>article</type>
    <publisherName>American Chemical Society</publisherName>
    <publisherPlace>Washington, DC</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The Crucial Role of the Diphosphine Heteroatom X in the Stereochemistry and Stabilization of the Substitution-Inert [M(N)(PXP)]2+ Metal Fragments (M = Tc, Re; PXP = Diphosphine Ligand)</title>
    <abstract language="eng">The nature of the heteroatom X incorporated in the five-membered PXP-diphosphine bridging chain was found to play a primary unit role both in the overall stability and in the stereochemical arrangement of nitrido-containing [M(N)(PXP)]2+ metal fragments (M = Tc, Re). Thus, by mixing PXP ligands with labile [Re(N)Cl4]- and Tc(N)Cl2(PPh3)2 nitrido precursors in CH2Cl2/MeOH mixtures, a series of neutral M(N)Cl2(PXP) complexes (M = Tc, 1-5; M = Re, 8, 9) was collected. In the resulting distorted octahedrons, PXP adopted facial or meridional coordination, and combination with halide co-ligands produced three different stereochemical arrangements, that is, fac,cis, mer,cis, and mer,trans, depending primarily on the nature of the diphosphine heteroatom X. When X = NH, mer,cis-Tc(N)Cl2(PNP1), 1, was the only isomer formed. Alternatively, when a tertiary amine nitrogen (X = NR; R = CH3, CH2CH2OCH3) was introduced in the bridging chain, fac,cis-M(N)Cl2(PN(R)P) complexes (M = Tc, 2, 3; M = Re, 8f) were obtained. Isomerization into the mer,cis-Re(N)Cl2(PN(R)P), 8m, species was observed only in the case of rhenium when the tertiary amine group carried the less encumbering methyl substituent. fac,cis-Tc(N)Cl2(PSP), 4f, was isolated in the solid state when X = S, but a mixture of fac,cis-Tc(N)Cl2(PSP) and mer,trans-Tc(N)Cl2(PSP), 4m, isomers was found in equilibrium in the solution state. A similar equilibrium between fac,cis-M(N)Cl2(POP) (M = Tc, 5f; M = Re, 9f) and mer,trans-M(N)Cl2(POP) (M = Tc, 5m; M = Re, 9m) species was detected in POP-containing complexes. The molecular structure of all of these complexes was assessed by means of conventional physicochemical techniques including multinuclear NMR spectroscopy and X-ray diffraction analysis of representative mer,cis-Tc(N)Cl2(PN(H)P), 1, fac,cis-Tc(N)Cl2(PSP), 4f, and mer,cis-Re(N)Cl2(PN(Me)P), 8m, compounds.</abstract>
    <parentTitle language="eng">Inorganic Chemistry</parentTitle>
    <identifier type="old">5886</identifier>
    <identifier type="doi">10.1021/ic049139r</identifier>
    <identifier type="issn">0020-1669</identifier>
    <identifier type="issn">1520-510X</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">06.01.2005</enrichment>
    <author>F. Tisato</author>
    <author>F. Refosco</author>
    <author>M. Porchia</author>
    <author>C. Bolzati</author>
    <author>G. Bandoli</author>
    <author>A. Dolmella</author>
    <author>A. Duatti</author>
    <author>A. Boschi</author>
    <author>C. M. Jung</author>
    <author>H.-J. Pietzsch</author>
    <author>Werner Kraus</author>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>45149</id>
    <completedYear/>
    <publishedYear>2018</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>317</pageFirst>
    <pageLast>326</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1-2</issue>
    <volume>69</volume>
    <type>article</type>
    <publisherName>IOS Press</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Albumin solder covalently bound to a polymer membrane: New approach to improve binding strength in laser tissue soldering in-vitro</title>
    <abstract language="eng">Laser tissue soldering (LTS) based on indocyanine green (ICG)-mediated heat- denaturation of proteins might be a promising alternative technique for micro-suturing, but up to now the Problem of too weak shear strength of the solder welds in comparison to sutures is not solved. Earlier reports gave promising results showing that solder supported by carrier materials can enhance the cohesive strength of the liquid solder. In these studies, the solder was applied to the carriers by dip coating. Higher reliability of the connection between the solder and the carrier material is expected when the solder is bound covalently to the carrier material. In the present study a poly(ether imide) (PEI) membrane served as carrier material and ICG- supplemented albumin as solder substrate. The latter was covalently coupled to the carrier membrane under physiological conditions to prevent structural protein changes. As laser source a diode continuous-wave laser emitting at 808 nm with intensities between 250mW and 1500mW was utilized. The Albumin functionalized carrier membrane was placed onto the tunica media of explanted pig thoracic aortae forming an overlapping area of approximately 0.5×0.5 cm2. All tests were performed in a dry state to prevent laser light absorption by water. Infrared spectroscopy, spectro-photometrical determination of the secondary and Primary amine groups after acid orange II staining, contact angle measurements, and atomic force microscopy proved the successful functionalization of the PEI membrane with albumin. A laser power of 450mW LTS could generate a membrane-blood vessel connection which was characterized by a shear strength of 0.08±0.002MPa, corresponding to 15% of the tensile strength of the native blood vessel. Theoretically, an overlapping zone of 4.1mmaround the entire circumference of the blood vessel could have provided shear strength of the PEI membrane-blood vessel compound identical to the tensile strength of the native blood vessel. These in-vitro results confirmed the beneficial effects of solder reinforcement by carrier membranes, and suggest LTS with covalently bound solders on PEI substrates for further studies in animal models.</abstract>
    <parentTitle language="eng">Clinical Hemorheology and Microcirculation</parentTitle>
    <identifier type="doi">10.3233/CH-189108</identifier>
    <identifier type="issn">1386-0291</identifier>
    <identifier type="issn">1875-8622</identifier>
    <enrichment key="date_peer_review">12.06.2018</enrichment>
    <author>B. Hiebl</author>
    <author>Lena Ascher</author>
    <author>K. Luetzow</author>
    <author>K. Kratz</author>
    <author>C. Gruber</author>
    <author>C. Mrowietz</author>
    <author>M. E. Nehring</author>
    <author>A. Lendlein</author>
    <author>R.- P. Franke</author>
    <author>F. Jung</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Tissue soldering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Albumin</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polymer membrane</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Laser</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>19659</id>
    <completedYear/>
    <publishedYear>2009</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2036</pageFirst>
    <pageLast>2038</pageLast>
    <pageNumber/>
    <edition/>
    <issue>9-10</issue>
    <volume>28</volume>
    <type>article</type>
    <publisherName>Elsevier</publisherName>
    <publisherPlace>Amsterdam [u.a.] ; Jena</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Spin transition in heptanuclear star-shaped iron(III)-antimony(V) NCS- and CN-bridged compounds</title>
    <abstract language="eng">The precursor [FeIII(L)Cl] (LH2 = N,N'-bis(2'-hydroxy-benzyliden)-1,6-diamino-3-azahexane) has been prepared and Mössbauer spectroscopy assigned a high-spin (S = 5/2) state at room temperature. The precursor is combined with the bridging units [SbV(X)6]- (X = CN-, NCS-) to yield star-shaped heptanuclear clusters [(LFeIII-X)6SbV]Cl5. The star-shaped compounds are in general high-spin systems at room temperature. On cooling to 20 K some of the iron(III) centers switch to the low-spin state as indicated by Mössbauer spectroscopy, i.e. multiple electronic transitions. While the cyano-bridged complex performs a multiple spin transition the thiocyanate-compound shows no significant population at both temperatures.</abstract>
    <parentTitle language="eng">Polyhedron</parentTitle>
    <identifier type="old">21902</identifier>
    <identifier type="doi">10.1016/j.poly.2008.12.027</identifier>
    <identifier type="issn">0277-5387</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">20.07.2009</enrichment>
    <author>F. Renz</author>
    <author>C. Zaba</author>
    <author>L. Roßberg</author>
    <author>S. Jung</author>
    <author>M. Klein</author>
    <author>G. Klingelhöfer</author>
    <author>A. Wünsche</author>
    <author>S. Reinhardt</author>
    <author>Michael Menzel</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Heptanuclear</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>High-spin molecule</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SbV</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multistability</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multiple spin transition</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>22905</id>
    <completedYear/>
    <publishedYear>2010</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1501</pageFirst>
    <pageLast>1511</pageLast>
    <pageNumber/>
    <edition/>
    <issue>4</issue>
    <volume>396</volume>
    <type>article</type>
    <publisherName>Springer</publisherName>
    <publisherPlace>Berlin</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Evaluation of the state-of-the-art measurement capabilities for selected PBDEs and decaBB in plastic by the international intercomparison CCQM-P114</title>
    <abstract language="eng">An international intercomparison involving eight national metrology institutes (NMIs) was conducted to establish their current measurement capabilities for determining five selected congeners from the brominated flame retardant classes polybrominated diphenyl ethers and polybrominated biphenyls. A candidate reference material consisting of polypropylene fortified with technical mixtures of penta-, octa- and decabromo diphenyl ether and decabromo biphenyl, which was thoroughly assessed for material homogeneity and stability, was used as study material. The analytical procedures applied by the participants differed with regard to sample pre-treatment, extraction, clean-up, employed calibrants and type of calibration procedure as well as regarding analytical methods used for separation, identification and quantification of the flame retardant congeners (gas chromatography coupled to an electron capture detector (GC-ECD), gas chromatography-mass spectrometry in the electron ionisation mode (GC-EI-MS), gas chromatography-mass spectrometry in the electron capture negative ionisation mode (GC-ECNI-MS), and liquid chromatography-inductive coupled plasma-mass spectrometry (LC-ICP-MS)). The laboratory means agreed well with relative standard deviations of the mean of means of 1.9%, 4.8%, 5.5% and 5.4% for brominated diphenyl ether (BDE) 47, 183 and 209 and for the brominated biphenyl (BB) congener 209, respectively. For BDE 206, a relative standard deviation of 28.5% was obtained. For all five congeners, within-laboratory relative standard deviations of six measurements obtained under intermediate precision conditions were between 1% and 10%, and reported expanded measurements uncertainties typically ranged from 4% to 10% (8% to 14% for BDE 206). Furthermore, the results are in good agreement with those obtained in the characterization exercise for determining certified values for the flame retardant congeners in the same material. The results demonstrate the state-of-the-art measurement capabilities of NMIs for quantifying representative BDE congeners and BB 209 in a polymer. The outcome of this intercomparison (pilot study) in conjunction with possible improvements for employing exclusively calibrants with thoroughly assessed purity suggests that a key comparison aiming at underpinning calibration and measurement capability (CMC) claims of NMIs can be conducted.</abstract>
    <parentTitle language="eng">Analytical and bioanalytical chemistry</parentTitle>
    <identifier type="old">25465</identifier>
    <identifier type="doi">10.1007/s00216-009-3314-7</identifier>
    <identifier type="issn">1618-2642</identifier>
    <identifier type="issn">1618-2650</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">10.01.2011</enrichment>
    <author>R. Zeleny</author>
    <author>S. Voorspoels</author>
    <author>M. Ricci</author>
    <author>Roland Becker</author>
    <author>Christian Jung</author>
    <author>Wolfram Bremser</author>
    <author>M. Sittidech</author>
    <author>N. Panyawathanakit</author>
    <author>W. F. Wong</author>
    <author>S.M. Choi</author>
    <author>K.C. Lo</author>
    <author>W. Y. Yeung</author>
    <author>D.H. Kim</author>
    <author>J. Han</author>
    <author>J. Ryu</author>
    <author>S. Mingwu</author>
    <author>W. Chao</author>
    <author>M.M. Schantz</author>
    <author>K.A. Lippa</author>
    <author>S. Matsuyama</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Flame retardants</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polymer</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polybrominated diphenyl ethers (PBDEs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polybrominated biphenyls (PBBs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>International intercomparison</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>22561</id>
    <completedYear/>
    <publishedYear>2010</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>6</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1 / 012027</issue>
    <volume>217</volume>
    <type>article</type>
    <publisherName>IOP Publ.</publisherName>
    <publisherPlace>Bristol, UK</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Molecular switching in iron complexes bridged via tincyanides observed by Mössbauer and ESR spectroscopy</title>
    <abstract language="eng">The precursor [FeIII(L)Cl] (LH2 = N,N'-bis(2'-hydroxy-3'-X-benzyliden)-1,6-diamino-3-N-hexane) is a high-spin (S = 5/2) complex (with X = -CH3, -O-CH3). This precursor is combined with the bridging unit [SnIV(CN)4] to yield star-shaped pentanuclear clusters, [(L-X-FeIII)4Sn(CN)4]Cl4 57Fe-Mössbauer, 119mSn-Mössbauer, and ESR spectroscopy are used to study our samples. For X = -CH3 the 57Fe-Mössbauer data show a multiple spin transition between iron(III) in the high-spin and low-spin state. Changing the functional group from X = -CH3 to X = -O-CH3 turns the switchability off.</abstract>
    <parentTitle language="eng">Journal of physics / Conference series</parentTitle>
    <identifier type="old">25100</identifier>
    <identifier type="doi">10.1088/1742-6596/217/1/012027</identifier>
    <identifier type="issn">1742-6588</identifier>
    <identifier type="issn">1742-6596</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="zsBemerkung">Die Aufnahme ist grundsätzlich falsch, da es sich trotz des Titels ("Journal of physics / Conference series") nicht um eine Zeitschrift handelt, sondern um eine Tagungsband-Reihe. Da sehr viele Artikel an diesem Eintrag hängen, wäre die Korrektur aber extrem aufwändig.  Die Tagungsband-Reihe findet sich in der Master Journal List bzw. in dem Journal Citation Report selbstverständlich nicht wieder, da es ja keine Zeitschrift ist. Allerdings wird die Tagungsband-Reihe sehr wohl von Thomson-Reuters für Ihre Datenbank ausgewertet, als "Book Series". Daher muss sichergestellt werden, dass die dort erscheinenden Artikel auch für die "1000-Euro-Liste" berücksichtigt werden.  Die einfachste Lösung ist es, den Eintrag als Zeitschrift zu belassen, und das Häkchen bei "In MJL/CPCI von ISI enthalten" zu setzen. Das ist zwar formal nicht ganz korrekt, erzeugt aber das richtige Ergebnis.  Jan Harloff-Puhr 11.7.2014</enrichment>
    <enrichment key="date_peer_review">30.11.2010</enrichment>
    <author>S. Jung</author>
    <author>F. Renz</author>
    <author>M. Klein</author>
    <author>Michael Menzel</author>
    <author>R. Boca</author>
    <author>R. Stößer</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Switching iron complexes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Spin-transition</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mössbauer spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>ESR-spectroscopy</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>40013</id>
    <completedYear/>
    <publishedYear>2016</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>08013, 1</pageFirst>
    <pageLast>71</pageLast>
    <pageNumber/>
    <edition/>
    <issue>Techn Suppl</issue>
    <volume>53</volume>
    <type>article</type>
    <publisherName>IOP publishing</publisherName>
    <publisherPlace/>
    <creatingCorporation>BIPM</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">CCQM K101 Final report international comparison CCQM-K101：Oxygen in nitrogen-a track B comparison and that the matrix contains argon</title>
    <abstract language="eng">This key comparison aims to assess the capabilities of the participants to determine the amount-of-substance fraction oxygen in nitrogen. The GAWG has classified this as a track B comparison, due to the unexpected 50 μmol/mol argon mole fraction content of the transfer standards, which effects the achievable performance of some measurement techniques such a GC-TCD. The separation of oxygen and argon is challenging, and not all systems in use are equally well designed for it. As this analytical challenge due to a substantial fraction of argon in the transfer standards became a reality, the Gas Analysis Working Group (GAWG) decided to qualify this key comparison as a regular key comparison and not as a core comparison, which may be used to support calibration and measurement capabilities (CMCs) for oxygen in nitrogen, or for oxygen in nitrogen mixtures containing argon only (see also the section on support to CMCs).</abstract>
    <parentTitle language="eng">Metrologia</parentTitle>
    <identifier type="url">http://iopscience.iop.org/article/10.1088/0026-1394/53/1A/08013</identifier>
    <identifier type="issn">1681-7575</identifier>
    <identifier type="issn">0026-1394</identifier>
    <enrichment key="date_peer_review">28.04.2017</enrichment>
    <author>Z. Zhou</author>
    <author>Q. Han</author>
    <author>D. Wang</author>
    <author>T. Macé</author>
    <author>Heinrich Kipphardt</author>
    <author>Michael Maiwald</author>
    <author>Dirk Tuma</author>
    <author>S. Uehara</author>
    <author>D. Akima</author>
    <author>T. Shimosaka</author>
    <author>J. Jung</author>
    <author>S.-H. Oh</author>
    <author>A. van der Veen</author>
    <author>J.I.T. van Wijk</author>
    <author>P. R. Ziel</author>
    <author>L. Konopelko</author>
    <author>M. Valkova</author>
    <author>D.M. Mogale</author>
    <author>A. Botha</author>
    <author>P. Brewer</author>
    <author>A. Murugan</author>
    <author>M.D. Minnaro</author>
    <author>M. Miller</author>
    <author>F. Guenther</author>
    <author>M.E. Kelly</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>CCQM-K101</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Gas analysis</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>19660</id>
    <completedYear/>
    <publishedYear>2009</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1818</pageFirst>
    <pageLast>1821</pageLast>
    <pageNumber/>
    <edition/>
    <issue>9-10</issue>
    <volume>28</volume>
    <type>article</type>
    <publisherName>Elsevier</publisherName>
    <publisherPlace>Amsterdam [u.a.] ; Jena</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Molecular switching complexes with iron and tin as central atom</title>
    <abstract language="eng">The precursor [FeIII(L)Cl] (LH&lt;sub2 = N,N'-bis(2'-hydroxy-benzyliden)-1,6-diamino-3-N-hexane is a high-spin (S = 5/2) complex. This precursor is combined with the bridging units [SnIV(X)4] (X = CN-, NCS-) to yield star-shaped pentanuclear clusters, [(LFeIII-X)4Sn]Cl4. For X = CN- the 57Fe-Mössbauer data show a multiple spin transition between iron(III) in the high-spin and low-spin state, while the 119mSn-Mössbauer data indicate a valence tautomerism between Sn(IV) and Sn(II). Changing the bridging unit from X = CN- to X = NCS- turns the switchability off.</abstract>
    <parentTitle language="eng">Polyhedron</parentTitle>
    <identifier type="old">21903</identifier>
    <identifier type="doi">10.1016/j.poly.2008.12.028</identifier>
    <identifier type="issn">0277-5387</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">20.07.2009</enrichment>
    <author>F. Renz</author>
    <author>S. Jung</author>
    <author>M. Klein</author>
    <author>Michael Menzel</author>
    <author>Andreas Thünemann</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Pentanuclear</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>High-spin molecule</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SnIV(CN)4</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multistability</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Valence tautomerism</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multiple spin transition</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>119mSn- and 57Fe-Mössbauer spectroscopy</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>30819</id>
    <completedYear/>
    <publishedYear>2014</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>3626</pageFirst>
    <pageLast>3635</pageLast>
    <pageNumber/>
    <edition/>
    <issue>23</issue>
    <volume>2</volume>
    <type>article</type>
    <publisherName>Royal Soc. of Chemistry</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Multivalent grafting of hyperbranched oligo- and polyglycerols shielding rough membranes to mediate hemocompatibility</title>
    <abstract language="eng">Hemocompatible materials are needed for internal and extracorporeal biomedical applications, which should be realizable by reducing protein and thrombocyte adhesion to such materials. Polyethers have been demonstrated to be highly efficient in this respect on smooth surfaces. Here, we investigate the grafting of oligo- and polyglycerols to rough poly(ether imide) membranes as a polymer relevant to biomedical applications and show the reduction of protein and thrombocyte adhesion as well as thrombocyte activation. It could be demonstrated that, by performing surface grafting with oligo- and polyglycerols of relatively high polydispersity (&gt;1.5) and several reactive groups for surface anchoring, full surface shielding can be reached, which leads to reduced protein adsorption of albumin and fibrinogen. In addition, adherent thrombocytes were not activated. This could be clearly shown by immunostaining adherent proteins and analyzing the thrombocyte covered area. The presented work provides an important strategy for the development of application relevant hemocompatible 3D structured materials.</abstract>
    <parentTitle language="eng">Journal of materials chemistry B</parentTitle>
    <identifier type="old">33799</identifier>
    <identifier type="doi">10.1039/c4tb00184b</identifier>
    <identifier type="issn">2050-750X</identifier>
    <identifier type="issn">2050-7518</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-308196</identifier>
    <enrichment key="date_peer_review">12.06.2014</enrichment>
    <licence>Creative Commons - Namensnennung - Nicht kommerziell 3.0</licence>
    <author>A.T. Neffe</author>
    <author>M. Von Ruesten-Lange</author>
    <author>S. Braune</author>
    <author>K. Lützow</author>
    <author>T. Roch</author>
    <author>K. Richau</author>
    <author>A. Krüger</author>
    <author>T. Becherer</author>
    <author>Andreas Thünemann</author>
    <author>F. Jung</author>
    <author>R. Haag</author>
    <author>A. Lendlein</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanotechnology</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>thrombocyte adhesion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>biomedical applications</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/30819/Multivalent Grafting of Hyperbranched Oligo- and Polyglycerols Shielding Rough Membranes to Mediate Hemocompatibility_Neffe.pdf</file>
  </doc>
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