<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>27427</id>
    <completedYear/>
    <publishedYear>2012</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>14171</pageFirst>
    <pageLast>14177</pageLast>
    <pageNumber/>
    <edition/>
    <issue>48</issue>
    <volume>116</volume>
    <type>article</type>
    <publisherName>American Chemical Society (ACS)</publisherName>
    <publisherPlace>Washington, DC</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Interaction of levitated ionic liquid droplets with water</title>
    <abstract language="eng">The influence of a humid or dry atmosphere on acoustically levitated ionic liquid droplets was studied by volumetric analysis and vibrational spectroscopy. Imidazolium-based ionic liquids with two types of anions, fluorinated (BF4 and PF6) and alkylsulfate anions, were investigated. The amount of absorbed water was correlated with structural differences of the ionic liquids and analyzed in terms of equilibrium mole fraction as well as absorption rate. The type of anion had the most significant influence on the amount of adsorbed water from the atmosphere. Furthermore, spectral changes in the in situ Raman spectra due to absorbed water were studied for all investigated ionic liquids. For 1-ethyl-3-methylimidazolium ethylsulfate, an exemplary detailed analysis of the intermolecular interactions between cations, anions and water was carried out based on the spectroscopic data. The observed band shifts were explained with a hydrogen bond between the anion and water.</abstract>
    <parentTitle language="eng">The journal of physical chemistry / B</parentTitle>
    <identifier type="old">30242</identifier>
    <identifier type="doi">10.1021/jp309661p</identifier>
    <identifier type="issn">1520-6106</identifier>
    <identifier type="issn">1520-5207</identifier>
    <identifier type="issn">1089-5647</identifier>
    <note>Geburtsname von Buurman, Merwe: Albrecht, M. -  Birth name of Buurman, Merwe: Albrecht, M.</note>
    <enrichment key="date_peer_review">17.12.2012</enrichment>
    <author>Jonas Schenk</author>
    <author>Ulrich Panne</author>
    <author>Merwe Buurman</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionic liquids</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Levitated droplets</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Raman spectroscopy</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
</export-example>
