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    <title language="eng">The Effect of Pore Functionality in Multicomponent Covalent Organic Frameworks on Stable Long‐Term Photocatalytic H&lt;sub&gt;2&lt;/sub&gt; Production</title>
    <abstract language="eng">AbstractIn nature, organic molecules play a vital role in light harvesting and photosynthesis. However, regarding artificial water splitting, the research focus is primarily on inorganic semiconductors. Although organic photocatalysts have high structural variability, they tend to exhibit lower quantum efficiencies for water splitting than their inorganic counterparts. Multicomponent reactions (MCRs) offer an attractive route to introduce different functional units into covalent organic frameworks (COFs) and enable semiconducting properties and high chemical stability, creating promising materials for long‐term photocatalytic applications, such as H2 production. Herein, five highly crystalline donor‐acceptor based, 4‐substituted quinoline‐linked MCR‐COFs are presented that are prepared via the three‐component Povarov reaction. The pore functionality is varied by applying different vinyl derivatives (e.g., styrene, 2‐vinyl pyridine, 4‐vinylpyridine, 4‐vinyl imidazole, 2,3,4,5,6‐pentafluorostyrene), which has a strong influence on the obtained photocatalytic activity. Especially an imidazole‐functionalized COF displays promising photocatalytic performance due to its high surface area, crystallinity, and wettability. These properties enable it to maintain its photocatalytic activity even in a membrane support. Furthermore, such MCR‐COFs display dramatically enhanced (photo)chemical stability even after long‐term solar light irradiation and exhibit a high and steady H2 evolution for at least 15 days.</abstract>
    <parentTitle language="eng">Advanced Energy Materials</parentTitle>
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    <author>Prasenjit Das</author>
    <author>Gouri Chakraborty</author>
    <author>Jin Yang</author>
    <author>Jérôme Roeser</author>
    <author>Hüseyin Küçükkeçeci</author>
    <author>Anh Dung Nguyen</author>
    <author>Michael Schwarze</author>
    <author>Jose Gabriel</author>
    <author>Christopher Penschke</author>
    <author>Shengjun Du</author>
    <author>Vincent Weigelt</author>
    <author>Islam E. Khalil</author>
    <author>Johannes Schmidt</author>
    <author>Peter Saalfrank</author>
    <author>Martin Oschatz</author>
    <author>Jabor Rabeah</author>
    <author>Reinhard Schomäcker</author>
    <author>Franziska Emmerling</author>
    <author>Arne Thomas</author>
    <subject>
      <language>eng</language>
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      <value>Sstability</value>
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    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Covalent organic frameworks</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Pore functionality</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Long-term H2 production</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multicomponent reactions</value>
    </subject>
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    <title language="eng">Heteropolyaromatic Covalent Organic Frameworks via One-Pot Multicomponent Reactions</title>
    <abstract language="eng">Multicomponent reactions (MCRs) offer a platform to create different chemical structures and linkages for highly stable covalent organic frameworks (COFs). As an illustrative example, the multicomponent Povarov reaction generates 2,4-phenylquinoline from aldehydes and amines in the presence of electron-rich alkenes. In this study, we introduce a new domino reaction to generate unprecedented 2,3-phenylquinoline COFs in the presence of epoxystyrene. This work thus presents, for the first time, structural isomeric COFs produced by multicomponent domino and Povarov reactions. Furthermore, 2,3-phenylquinolines can undergo a Scholl reaction to form extended aromatic linkages. With this approach, we synthesize two thermally and chemically stable MCR-COFs and two heteropolyaromatic COFs using both domino and in situ domino and Scholl reactions. The structure and properties of these COFs are compared with the corresponding 2,4-phenylquinoline-linked COF and imine-COF, and their activity toward benzene and cyclohexane sorption and separation is investigated. The position of the pendant phenyl groups within the COF pore plays a crucial role in facilitating the industrially important sorption and separation of benzene over cyclohexane. This study opens a new avenue to construct heteropolyaromatic COFs via MCR reactions.</abstract>
    <parentTitle language="eng">Journal of the American Chemical Society</parentTitle>
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