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    <id>63742</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>78</pageLast>
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    <edition/>
    <issue/>
    <volume>536</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
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    <title language="eng">Metal-organic framework-based materials: From synthesis and characterization routes to electrochemical sensing applications</title>
    <abstract language="eng">Metal-organic frameworks (MOFs) are formed by coordination bonds between organic ligands and metal ions or clusters. Their key properties, including high surface area, porosity, and adjustable functionalities, enable diverse applications in gas separation, catalysis, energy storage, luminescence, and more recently, the development of electrochemical sensors. In this review, we provide an overview of various electrochemical methods and discuss different MOF-based electrochemical sensors reported in the literature. We focus on the synthesis of MOFs, their characterization, and the preparation of MOF-based working electrodes for electroanalysis. A brief history of MOFs, along with their nomenclature, classifications, and features, is discussed to provide a chronological understanding of MOFs before delving into their electroanalytical uses. Recent advancements in the use of MOFs as electrode materials for electrochemical sensing have been extensively reviewed and documented, highlighting their increasing relevance in various analytical fields. This review investigates the key properties of MOFs that make them suitable candidates for sensing applications and the ability for post-synthesis modifications to improve their selectivity and sensitivity. It also examines the challenges associated with the synthesis and modification of MOFs, including issues related to scalability, eproducibility, and the stability of the materials under operational conditions. Furthermore, the review discusses potential future directions for the use of MOFs in electrochemical sensing, emphasizing their role as electrode materials to enhance the sensitivity and selectivity of modified sensors for sustainable applications.</abstract>
    <parentTitle language="eng">Coordination Chemistry Reviews</parentTitle>
    <identifier type="issn">0010-8545</identifier>
    <identifier type="doi">10.1016/j.ccr.2025.216680</identifier>
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    <enrichment key="date_peer_review">19.08.2025</enrichment>
    <author>Gullit Deffo</author>
    <author>Arnaud Kamdem Tamo</author>
    <author>Cyrille Ghislain Fotsop</author>
    <author>Honorine Hortense Bougna Tchoumi</author>
    <author>Donald Eric Njiajo Talla</author>
    <author>Calice Gildas Wabo</author>
    <author>Marcel Cédric Ngaha Deussi</author>
    <author>Ranil Clément Tonleu Temgoua</author>
    <author>Giscard Doungmo</author>
    <author>Evangeline Njanja</author>
    <author>Ignas Kenfack Tonle</author>
    <author>Panchanan Puzari</author>
    <author>Claudia Birkemeyer</author>
    <author>Emmanuel Ngameni</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Metal-organic frameworks (MOFs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MOF synthesis and characterization</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electrochemical sensors</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electroanalysis</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">1 Analytische Chemie; Referenzmaterialien</collection>
    <collection role="institutes" number="">1.7 Organische Spuren- und Lebensmittelanalytik</collection>
    <collection role="themenfelder" number="">Material</collection>
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    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
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