<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>16410</id>
    <completedYear/>
    <publishedYear>2007</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>poster</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Phenanthrene ring-fused boron-dipyrromehenes an new highly emitting red visible/near-infrared dyes</title>
    <parentTitle language="deu">Method and Application of Fluerescence (MAF10)</parentTitle>
    <identifier type="old">18393</identifier>
    <enrichment key="eventName">Method and Application of Fluerescence (MAF10)</enrichment>
    <enrichment key="eventPlace">Salzburg, Austria</enrichment>
    <enrichment key="eventStart">2007-09-09</enrichment>
    <enrichment key="eventEnd">2007-09-12</enrichment>
    <author>Ana Belén Descalzo López</author>
    <collection role="fulltextaccess" number="">Weder Datei noch physisches Exemplar vorhanden ("No Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>5985</id>
    <completedYear/>
    <publishedYear>2005</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>184</pageFirst>
    <pageLast>200</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>127</volume>
    <type>article</type>
    <publisherName>American Chemical Society</publisherName>
    <publisherPlace>Washington, DC</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Rational Design of a Chromo- and Fluorogenic Hybrid Chemosensor Material for the Detection of Long-Chain Carboxylates</title>
    <abstract language="eng">A strategy for the rational design of a new optical sensor material for the selective recognition of long-chain carboxylates in water is presented. The approach relies on the combination of structure-property relationships to single out the optimal molecular sensor unit and the tuning of the sensing characteristics of an inorganic support material. A spacer-substituted 7-urea-phenoxazin-3-one was employed as the signaling moiety and a mesoporous trimethylsilylated UVM-7 (MCM-41 type) material served as the solid support. The sensor material shows the advantageous features of both modules that is absorption and emission in the visible spectral range, a fluorescence red-shift and enhancement upon analyte coordination, and the amplification of noncovalent (binding) and hydrogen-bonding (recognition) interactions in the detection event. Besides these basic results that are related to the design and performance of the sensor material, the paper discusses general aspects of amido-substituted phenoxazinone photophysics and addresses some general features of molecular anion recognition chemistry in aqueous vs nonaqueous media, utilizing steady-state and time-resolved optical as well as NMR spectroscopies. Detailed studies on potentially competing biochemical species and a first access to the schematic model of the response of the sensor material as obtained by a combination of fluorescence lifetime distribution analysis and Langmuir-type fitting of the gross binding constants complement the key issues of the paper.</abstract>
    <parentTitle language="eng">Journal of the American chemical society</parentTitle>
    <identifier type="old">6357</identifier>
    <identifier type="doi">10.1021/ja045683n</identifier>
    <identifier type="issn">0002-7863</identifier>
    <identifier type="issn">1520-5126</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">20.01.2005</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Knut Rurack</author>
    <author>Hardy Weißhoff</author>
    <author>Ramon Martínez-Mánez</author>
    <author>M. Dolores Marcos</author>
    <author>P. Amorós</author>
    <author>Katrin Hoffmann</author>
    <author>J. Soto</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Chemosensor</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Carboxylate</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Rationales Design</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hybridmaterialien</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>27488</id>
    <completedYear/>
    <publishedYear>2012</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>16844</pageFirst>
    <pageLast>16867</pageLast>
    <pageNumber/>
    <edition/>
    <issue>52</issue>
    <volume>18</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Synthesis and properties  of fused-ring-expanded porphyrins that were core-modified with group 16 heteroatoms</title>
    <abstract language="eng">The synthesis of a series of novel core-modified and fused-ring-expanded tetraphenylporphyrins is reported. Theoretical calculations and magnetic circular dichroism (MCD) and fluorescence spectroscopic measurements were used to analyze the effect of core modification with Group 16 oxygen, sulfur, selenium, and tellurium atoms on the optical properties and electronic structures of the porphyrins. Marked redshifts of the Q and B bands and accelerated intersystem-crossing rates were observed, thus making these compounds potentially suitable for use in a variety of applications. The scope for further fine-tuning of these optical properties based on additional structural modifications, such as the incorporation of fused benzene rings to form ABAB structures by using a thiophene precursor with a fused bicyclo[2.2.2]octadiene ring and the introduction of various substituents onto the meso-phenyl rings, is also examined.</abstract>
    <parentTitle language="eng">Chemistry - A European journal</parentTitle>
    <identifier type="old">30305</identifier>
    <identifier type="doi">10.1002/chem.201200956</identifier>
    <identifier type="issn">0947-6539</identifier>
    <identifier type="issn">1521-3765</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">20.12.2012</enrichment>
    <author>H.-J. Xu</author>
    <author>J. Mack</author>
    <author>D. Wu</author>
    <author>Z.-L. Xue</author>
    <author>Ana Belén Descalzo López</author>
    <author>Knut Rurack</author>
    <author>N. Kobayashi</author>
    <author>Z. Shen</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Density functional calculations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MCD spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porphyrinoids</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ring expansion</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>12563</id>
    <completedYear/>
    <publishedYear>2006</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2239</pageFirst>
    <pageLast>2241</pageLast>
    <pageNumber/>
    <edition/>
    <issue>21</issue>
    <volume/>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation>Chemical Society</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Sensory hybrid host materials for the selective chromo-fluorogenic detection of biogenic amines</title>
    <parentTitle language="eng">Chemical communications</parentTitle>
    <identifier type="old">14292</identifier>
    <identifier type="issn">0022-4936</identifier>
    <identifier type="issn">0009-241x</identifier>
    <identifier type="issn">1359-7345</identifier>
    <identifier type="issn">1364-548x</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">17.07.2006</enrichment>
    <author>B. García-Acosta</author>
    <author>M. Comes</author>
    <author>J.L. Bricks</author>
    <author>M.A. Kudinova</author>
    <author>V.V. Kurdyukov</author>
    <author>A.I. Tolmachev</author>
    <author>Ana Belén Descalzo López</author>
    <author>M. Dolores Marcos</author>
    <author>Ramon Martínez-Mánez</author>
    <author>A. Moreno</author>
    <author>F. Sancenón</author>
    <author>J. Soto</author>
    <author>L.A. Villaescusa</author>
    <author>Knut Rurack</author>
    <author>J. M. Barat</author>
    <author>I. Escriche</author>
    <author>P. Amorós</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biogene Amine</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Histamin</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Farbreaktion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Pyralium-Farbstoffe</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hybrid-Materialien</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>27113</id>
    <completedYear/>
    <publishedYear>2012</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>7306</pageFirst>
    <pageLast>7309</pageLast>
    <pageNumber/>
    <edition/>
    <issue>23</issue>
    <volume>18</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Dihydronaphthalene-fused Boron-dipyrromethene (BODIPY) dyes: insight into the electronic and conformational tuning modes of BODIPY fluorophones</title>
    <parentTitle language="eng">Chemistry - A European journal</parentTitle>
    <identifier type="old">29904</identifier>
    <identifier type="doi">10.1002/chem.201201081</identifier>
    <identifier type="issn">0947-6539</identifier>
    <identifier type="issn">1521-3765</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">26.11.2012</enrichment>
    <author>Y.-W. Wang</author>
    <author>Ana Belén Descalzo López</author>
    <author>Z. Shen</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Farbstoffe</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>NMR-Spektroskopie</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Synthese</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>19146</id>
    <completedYear/>
    <publishedYear>2009</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>3173</pageFirst>
    <pageLast>3185</pageLast>
    <pageNumber/>
    <edition/>
    <issue>13</issue>
    <volume>15</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">On the signalling pathways and Cu(II)-mediated anion indication of N-meso-substituted heptamethine cyanine dyes</title>
    <abstract language="eng">Three mid-chain rigidified heptamethine cyanine dyes substituted with dimethylamino or cyclam groups at the meso position of the polymethine chain have been prepared and studied both experimentally and theoretically with respect to their spectroscopic response toward protons and various metal ions. Despite a potentially rich conformational ground-state chemistry, the spectroscopic studies revealed that the behaviour of the dyes is in agreement with Kuhn's classic polymethine dye theory. Coordination of metal ions and protonation of the alkyl amino groups in the cyclam moiety accordingly lead to moderate bathochromic shifts in absorption and reduced Stokes shifts. In contrast, protonation of the dimethylamino-substituted derivatives occurs at the polymethine chain, transforming the heptamethine into a trimethine-type chromophore with concomitant gigantic spectral blueshifts. In the presence of CuII in buffered aqueous solution, the cyclam-substituted dye selectively forms near-infrared absorbing aggregates. The latter allow the determination of citrate under realistic conditions by changes in absorption at wavelengths greater than 800 nm, which results from a disruption of the aggregates when citrate binds to CuII. The copper ions thus act as mediators in a signalling reaction that constitutes a colourimetric displacement assay.</abstract>
    <parentTitle language="eng">Chemistry - A European journal</parentTitle>
    <identifier type="old">21344</identifier>
    <identifier type="doi">10.1002/chem.200802087</identifier>
    <identifier type="issn">0947-6539</identifier>
    <identifier type="issn">1521-3765</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">26.03.2009</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Anions</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Copper</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Crown compounds</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes/pigments</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polymethines</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>12824</id>
    <completedYear/>
    <publishedYear>2006</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>5924</pageFirst>
    <pageLast>5948</pageLast>
    <pageNumber/>
    <edition/>
    <issue>36</issue>
    <volume>45</volume>
    <type>article</type>
    <publisherName>Wiley-VCH</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation>Gesellschaft Deutscher Chemiker</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials</title>
    <abstract language="eng">The combination of nanomaterials as solid supports and supramolecular concepts has led to the development of hybrid materials with improved functionalities. These hetero-supramolecular ideas provide a means of bridging the gap between molecular chemistry, materials sciences, and nanotechnology. In recent years, relevant examples have been reported on functional aspects, such as enhanced recognition and sensing by using molecules on preorganized surfaces, the reversible building of nanometer-sized networks and 3D architectures, as well as biomimetic and gated chemistry in hybrid nanomaterials for the development of advanced functional protocols in three-dimensional frameworks. This approach allows the fine-tuning of the properties of nanomaterials and offers new perspectives for the application of supramolecular concepts.</abstract>
    <parentTitle language="eng">Angewandte Chemie / International Edition</parentTitle>
    <identifier type="old">14563</identifier>
    <identifier type="doi">10.1002/anie.200600734</identifier>
    <identifier type="issn">1433-7851</identifier>
    <identifier type="issn">1521-3773</identifier>
    <identifier type="issn">0570-0833</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="bibliotheksstandort">ZA 12</enrichment>
    <enrichment key="date_peer_review">15.09.2006</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Ramon Martínez-Mánez</author>
    <author>F. Sancenón</author>
    <author>Katrin Hoffmann</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Aggregation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mesoporous materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Molecular recognition</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoparticles</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sensors</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>24208</id>
    <completedYear/>
    <publishedYear>2011</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>8965</pageFirst>
    <pageLast>8983</pageLast>
    <pageNumber/>
    <edition/>
    <issue>32</issue>
    <volume>17</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">meso-Aryl phenanthroporphyrins: Synthesis and spectroscopic properties</title>
    <abstract language="eng">The successful synthesis of tetraphenyltetraphenanthroporphyrin (TPTPhenP; 5a) in 2006 under modified Rothemund–Lindsey conditions yielded a tetraphenyl porphyrinoid with a B band redshifted to an unprecedented 576 nm. Radially symmetric fused-ring expansion of tetraphenylporphyrin with phenanthrene moieties results in very deep saddling due to steric crowding and very marked redshifts of the Q and B (or Soret) porphyrinoid absorption bands. The extent to which the TPTPhenP structure can be further modified is explored, and the optical properties of TPTPhenPs are analyzed based on a perimeter model approach that makes use of time-dependent DFT calculations and magnetic circular dichroism spectroscopy and also based on a detailed analysis of the fluorescence emission. Attempts to introduce substituents at the ortho and meta positions of the meso-phenyl groups and to insert a central metal proved unsuccessful. The synthesis of a series of TPTPhenPs with strong electron-withdrawing (—CN, —NO2) and -donating (—CH3, —N(CH3)2) substituents at the para positions of the meso-phenyl rings is reported. Marked redshifts of the main spectral bands were consistently observed. The most pronounced spectral changes were observed with —N(CH3)2 groups (5i) due to a marked destabilization of the HOMO, which has large MO coefficients on the meso-carbon atoms. Protonation of 5i at both the ligand core and at the —N(CH3)2 groups resulted in unprecedented Q00 band absorption at wavelengths greater than 1200 nm.</abstract>
    <parentTitle language="eng">Chemistry - A European journal</parentTitle>
    <identifier type="old">26839</identifier>
    <identifier type="doi">10.1002/chem.201002596</identifier>
    <identifier type="issn">0947-6539</identifier>
    <identifier type="issn">1521-3765</identifier>
    <enrichment key="date_peer_review">05.09.2011</enrichment>
    <author>H.-J. Xu</author>
    <author>J. Mack</author>
    <author>Ana Belén Descalzo López</author>
    <author>Z. Shen</author>
    <author>N. Kobayashi</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Charge transfer</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Circular dichroism</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes/pigments</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porphyrinoids</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protonation</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>20957</id>
    <completedYear/>
    <publishedYear>2010</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2887</pageFirst>
    <pageLast>2903</pageLast>
    <pageNumber/>
    <edition/>
    <issue>9</issue>
    <volume>16</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Dihydronaphthalene-fused Boron-dipyrromethene (BODIPY) dyes: insight into the electronic and conformational tuning modes of BODIPY fluorophores</title>
    <abstract language="eng">A new series of boron-dipyrromethene (BDP, BODIPY) dyes with dihydronaphthalene units fused to the β-pyrrole positions (1 a-d, 2) has been synthesised and spectroscopically investigated. All the dyes, except pH-responsive 1 d in polar solvents, display intense emission between 550-700 nm. Compounds 1 a and 1 b with a hydrogen atom and a methyl group in the meso position of the BODIPY core show spectroscopic properties that are similar to those of rhodamine 101, thus rendering them potent alternatives to the positively charged rhodamine dyes as stains and labels for less polar environments or for the dyeing of latex beads. Compound 1 d, which carries an electron-donating 4-(dimethylamino)phenyl group in the meso position, shows dual fluorescence in solvents more polar than dibutyl ether and can act as a pH-responsive "light-up" probe for acidic pH. Correlation of the pKa data of 1 d and several other meso-(4-dimethylanilino)-substituted BODIPY derivatives allowed us to draw conclusions on the influence of steric crowding at the meso position on the acidity of the aniline nitrogen atom. Preparation and investigation of 2, which carries a nitrogen instead of a carbon as the meso-bridgehead atom, suggests that the rules of colour tuning of BODIPYs as established so far have to be reassessed; for all the reported couples of meso-C- and meso-N-substituted BODIPYs, the exchange leads to pronounced redshifts of the spectra and reduced fluorescence quantum yields. For 2, when compared with 1 a, the opposite is found: negligible spectral shifts and enhanced fluorescence. Additional X-ray crystallographic analysis of 1 a and quantum chemical modelling of the title and related compounds employing density functional theory granted further insight into the features of such sterically crowded chromophores.</abstract>
    <parentTitle language="eng">Chemistry - A European journal</parentTitle>
    <identifier type="old">23293</identifier>
    <identifier type="doi">10.1002/chem.200902527</identifier>
    <identifier type="issn">0947-6539</identifier>
    <identifier type="issn">1521-3765</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">04.03.2010</enrichment>
    <author>Y.-W. Wang</author>
    <author>Ana Belén Descalzo López</author>
    <author>Z. Shen</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes/pigments</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescent probes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Photophysics</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protonation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Boron</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>17632</id>
    <completedYear/>
    <publishedYear>2008</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>164</pageFirst>
    <pageLast>171</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>1130</volume>
    <type>article</type>
    <publisherName>New York Academy of Sciences</publisherName>
    <publisherPlace>New York, NY</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Red/Near-infrared Boron-Dipyrromethene Dyes as Strongly Emitting Fluorophores</title>
    <parentTitle language="eng">Annals of the New York academy of sciences</parentTitle>
    <identifier type="old">19705</identifier>
    <identifier type="doi">10.1196/annals.1430.016</identifier>
    <identifier type="issn">0077-8923</identifier>
    <identifier type="issn">1749-6632</identifier>
    <identifier type="issn">0094-8500</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">24.06.2008</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>H.-J. Xu</author>
    <author>Z. Shen</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BODIPY dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Near-infrared fluorophores</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescent indicators</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Charge transfer</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ring-fusion</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>20318</id>
    <completedYear/>
    <publishedYear>2009</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>369</pageFirst>
    <pageLast>405</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>9</volume>
    <type>bookpartcollection</type>
    <publisherName>John Wiley &amp; Sons</publisherName>
    <publisherPlace>Hoboken, New Jersey, USA</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Supramolecular hybrid materials - integrating functionality with sensing</title>
    <parentTitle language="eng">Macromolecules containing metal and metal-like elements - Supramolecular and self-assembled metal-containing materials</parentTitle>
    <identifier type="old">22609</identifier>
    <identifier type="isbn">978-0-470-25144-7</identifier>
    <identifier type="issn">1545-438X</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>Ramon Martínez-Mánez</author>
    <author>F. Sancenón</author>
    <author>Ana Belén Descalzo López</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biochemie</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biomakromoleküle</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>DNA</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Gold</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hybridmaterialien</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanopartikel</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Quantenpunkte</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Selbstorganisation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sensorik</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Silica</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Supramolekulare Chemie</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>21941</id>
    <completedYear/>
    <publishedYear>2010</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>41</pageFirst>
    <pageLast>106</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>9</volume>
    <type>bookpartcollection</type>
    <publisherName>Springer</publisherName>
    <publisherPlace/>
    <creatingCorporation>National Academy of Sciences of Ukraine</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Optimization of the coupling of target recognition and signal generation</title>
    <abstract language="eng">Fluorescent reporters that literally "light up" upon binding of a target species are particularly interesting from an analytical point of view. This contribution introduces the main signaling concepts in fluorescent probe research, discusses strategies toward their optimization in terms of signal output, and highlights the wealth of alternative protocols that has been realized in the past two decades to create signaling systems with luminescence amplification features.</abstract>
    <parentTitle language="eng">Advanced fluorescence reporters in chemistry and biology II: Molecular constructions, polymers and nanoparticles</parentTitle>
    <identifier type="old">24408</identifier>
    <identifier type="isbn">978-3-642-04699-5</identifier>
    <identifier type="doi">10.1007/978-3-642-04701-5_2</identifier>
    <note>Serientitel: Springer Series on Fluorescence – Series title: Springer Series on Fluorescence</note>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Shengchao Zhu</author>
    <author>Tobias Fischer</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>FRET</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Molecular Recognition</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoparticles</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>14863</id>
    <completedYear/>
    <publishedYear>2007</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>poster</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Mesoporous Silicia materials with covalently anchored phenoxazinone dyes as fluorescent hybrid materials for vapour sensing</title>
    <parentTitle language="eng">Anakon 2007</parentTitle>
    <identifier type="old">16701</identifier>
    <enrichment key="eventName">Anakon 2007</enrichment>
    <enrichment key="eventPlace">Jena, Germany</enrichment>
    <enrichment key="eventStart">2007-03-27</enrichment>
    <enrichment key="eventEnd">2007-03-30</enrichment>
    <author>Ana Belén Descalzo López</author>
    <collection role="fulltextaccess" number="">Weder Datei noch physisches Exemplar vorhanden ("No Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>17512</id>
    <completedYear/>
    <publishedYear>2007</publishedYear>
    <thesisYearAccepted/>
    <language>spa</language>
    <pageFirst>22</pageFirst>
    <pageLast>27</pageLast>
    <pageNumber/>
    <edition/>
    <issue>4</issue>
    <volume>103</volume>
    <type>article</type>
    <publisherName>Springer</publisherName>
    <publisherPlace/>
    <creatingCorporation>Real Sociedad Espanola de Química</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="spa">Materiales híbridos en química analítica</title>
    <abstract language="spa">El desarrollo de receptores sintéticos complejos basados en conceptos de la química supramolecular no garantiza en ocasiones un reconocimiento molecular selectivo. Una alternativa en ciertos aspectos más simple y prometedora es el empleo de materiales híbridos orgánico-inorgánicos preparados mediante la funcionalización de sólidos inorgánicos porosos con receptores sintéticos adecuados. El anclaje de estos sistemas coordinantes a un soporte sólido da lugar a ciertos efectos sinérgicos que no están presentes ni en el material inicial ni en el receptor por separado y que sugieren que estos nuevos materiales híbridos pueden ser empleados en el desarrollo de nuevos sensores y nuevos protocolos de reconocimiento molecular y/o iónico.

The development of synthetic receptors based in supramolecular chemistry concepts will no allow a selective molecular recognition. A more simple, convenient and innovative approach relies on the use of organic-inorganic hybrid materials. These hybrid materials will be prepared by the grafting of certain synthetic receptors onto porous inorganic solids. The grafting of these coordinating systems onto a solid support leads to synergic effects that are hardly achievable with only the synthetic receptors or the solids alone. The presence of these synergic effects suggests that these organic-inorganic hybrid materials will be used for the development of novel sensory systems and novel molecular and/or ionic recognitionprotocols.</abstract>
    <parentTitle language="spa">Anales de la Real Sociedad Espanola de Química</parentTitle>
    <identifier type="old">19577</identifier>
    <identifier type="issn">1575-3417</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>R. Martínez</author>
    <author>F. Sancenón</author>
    <author>Katrin Hoffmann</author>
    <author>Knut Rurack</author>
    <author>Ana Belén Descalzo López</author>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Soportes inorgánicos</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Receptores sintéticos</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Materiales híbridos</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Efectos sinérgicos</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Química analítica</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Inorganic supports</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Synthetic receptors</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Hybrid materials</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Synergic effects</value>
    </subject>
    <subject>
      <language>spa</language>
      <type>uncontrolled</type>
      <value>Analytical chemistry</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>16448</id>
    <completedYear/>
    <publishedYear>2008</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>193</pageFirst>
    <pageLast>197</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>47</volume>
    <type>article</type>
    <publisherName>Wiley-VCH</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation>Gesellschaft Deutscher Chemiker</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">A core-modified Rubyrin with meso-aryl substituents and phenanthrene-fused pyrrole rings: a highly conjugated near-infrared dye and Hg2+ probe</title>
    <parentTitle language="eng">Angewandte Chemie / International Edition</parentTitle>
    <identifier type="old">18435</identifier>
    <identifier type="doi">10.1002/Anie.200702854</identifier>
    <identifier type="issn">1433-7851</identifier>
    <identifier type="issn">1521-3773</identifier>
    <identifier type="issn">0570-0833</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">03.01.2008</enrichment>
    <author>D. Wu</author>
    <author>Ana Belén Descalzo López</author>
    <author>F. Weik</author>
    <author>Franziska Emmerling</author>
    <author>Z. Shen</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mercury</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>NIR dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porphyrinoids</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sensors</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>16139</id>
    <completedYear/>
    <publishedYear>2007</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>4716</pageFirst>
    <pageLast>4723</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>17</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Mesoporous silica materials with covalently anchored phenoxazinone dyes as fluorescent hybrid materials for vapour sensing</title>
    <parentTitle language="eng">Journal of materials chemistry</parentTitle>
    <identifier type="old">18101</identifier>
    <identifier type="doi">10.1039/b707473e</identifier>
    <identifier type="issn">0959-9428</identifier>
    <identifier type="issn">1364-5501</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">14.11.2007</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>M. Dolores Marcos</author>
    <author>Christian Monte</author>
    <author>Ramon Martínez-Mánez</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Anorganisch-organische Hybridmaterialien</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sensorik</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Flüchtige organische Verbindungen</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>12561</id>
    <completedYear/>
    <publishedYear>2006</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>176</pageFirst>
    <pageLast>187</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1-2</issue>
    <volume>1</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Mono- and Di(dimethylamino)styryl-Substituted Borondipyrromethene and Borondiindomethene Dyes with Intense Near-Infrared Fluorescence</title>
    <abstract language="eng">Four novel borondipyrromethene (BDP) and -diindomethene (BDI) dyes with one or two (dimethylamino)styryl extensions at the chromophore were synthesized and spectroscopically investigated. An X-ray crystal structure shows that the extended auxochrome is virtually planar. All dyes thus display intense red/near infrared (NIR) absorption and emission. The (dimethylamino)styryl group induces a charge-transfer character that entails bright solvatochromic fluorescence, which is only quenched with increasing solvent polarity according to the energy-gap law. The dye with an additional dimethylanilino group at the meso position of BDP shows a remarkable switching of lipophilicity by protonation. Two dyes with an 8-hydroxyquinoline ligand at the meso position display quenched emission in the presence of Hg2+ or Al3+ owing to electron transfer from the excited BDP to the complexed receptor. The BDI dye presents a pH indicator with bright fluorescence and extremely low fluorescence anisotropy.</abstract>
    <parentTitle language="eng">Chemistry / Asian Journal</parentTitle>
    <identifier type="old">14290</identifier>
    <identifier type="doi">10.1002/asia.200600042</identifier>
    <identifier type="issn">1861-4728</identifier>
    <identifier type="issn">1861-471X</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">17.07.2006</enrichment>
    <author>Y.-H. Yu</author>
    <author>Ana Belén Descalzo López</author>
    <author>Z. Sgen</author>
    <author>Holger Röhr</author>
    <author>Q. Liu</author>
    <author>Y.-W. Wang</author>
    <author>Monika Spieles</author>
    <author>Y.-Z. Li</author>
    <author>Knut Rurack</author>
    <author>X.-Z. You</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Borondipyrromethene</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Indicators</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protonation</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>23633</id>
    <completedYear/>
    <publishedYear>2011</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>51</pageFirst>
    <pageLast>91</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>300</volume>
    <type>article</type>
    <publisherName>Springer</publisherName>
    <publisherPlace>Berlin ; Heidelberg [u.a.]</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Luminescence amplification strategies integrated with microparticle and nanoparticle platforms</title>
    <abstract language="eng">The amplification of luminescence signals is often the key to sensitive and powerful detection protocols. Besides optimized fluorescent probes and labels, functionalized nano- and microparticles have received strongly increasing attention in this context during the past decade. This contribution introduces the main signalling concepts for particle-based amplification strategies and stresses, especially the important role that metal and semiconductor nanoparticles play in this field. Besides resonance energy transfer, metal-enhanced emission and the catalytic generation of luminescence, the impact of multi-chromophoric objects such as dye nanocrystals, dendrimers, conjugated polymers or mesoporous hybrid materials is assessed. The representative examples discussed cover a broad range of analytes from metal ions and small organic molecules to oligonucleotides and enzyme activity.</abstract>
    <parentTitle language="eng">Topics in current chemistry</parentTitle>
    <identifier type="old">26217</identifier>
    <identifier type="doi">10.1007/128_2010_99</identifier>
    <identifier type="issn">0340-1022</identifier>
    <identifier type="issn">1436-5049</identifier>
    <enrichment key="date_peer_review">09.05.2011</enrichment>
    <author>Shengchao Zhu</author>
    <author>Tobias Fischer</author>
    <author>Wei Wan</author>
    <author>Ana Belén Descalzo López</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Luminescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multi-chromosphore systems</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoparticles</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Resonance energy transfer</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Signal amplification</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>12821</id>
    <completedYear/>
    <publishedYear>2006</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst>6068</pageFirst>
    <pageLast>6093</pageLast>
    <pageNumber/>
    <edition/>
    <issue>36</issue>
    <volume>118</volume>
    <type>article</type>
    <publisherName>Wiley-VCH</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation>Gesellschaft Deutscher Chemiker</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Die supramolekulare Chemie organisch-anorganischer Hybrid-Nanomaterialien</title>
    <abstract language="deu">Die Entwicklung von Hybridmaterialien mit stark verbesserten Funktionen gelingt durch die Kombination geeigneter Nanomaterialien als Träger mit Motiven aus der supramolekularen Chemie. Diese hetero-supramolekularen Konzepte bieten vielfältige Möglichkeiten, die Lücken zwischen der Molekülchemie, Materialwissenschaften und Nanotechnologie zu schließen. Im Hinblick auf funktionelle Aspekte wurden in jüngster Zeit wichtige Fortschritte erzielt, z. B. verbesserte Erkennungs- und Sensoreigenschaften durch die Anordnung von Molekülen auf vororganisierten Oberflächen, der reversible Aufbau von nanometergroßen Netzwerken und dreidimensionalen Strukturen oder biomimetische und gesteuerte chemische Prozesse in Hybrid-Nanomaterialien, die als Grundlage für hoch spezialisierte Protokolle in dreidimensionalen Gerüststrukturen dienen können. Diese Ansätze ermöglichen eine Feinabstimmung der Eigenschaften von Nanomaterialien und eröffnen neue Perspektiven für die Anwendung supramolekularer Konzepte.</abstract>
    <parentTitle language="deu">Angewandte Chemie</parentTitle>
    <identifier type="old">14560</identifier>
    <identifier type="doi">10.1002/ange.200600734</identifier>
    <identifier type="issn">0044-8249</identifier>
    <identifier type="issn">0932-2140</identifier>
    <identifier type="issn">1521-3757</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Ramon Martínez-Mánez</author>
    <author>F. Sancenón</author>
    <author>Katrin Hoffmann</author>
    <author>Knut Rurack</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Supramolekulare Chemie</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Anorganisch-organische Hybridmaterialien</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Sensorik</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Molekulare Maschinen</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Aggregation</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Mesoporöse Materialien</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Molekulare Erkennung</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Nanopartikel</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Sensoren</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>16080</id>
    <completedYear/>
    <publishedYear>2007</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst>124</pageFirst>
    <pageLast>129</pageLast>
    <pageNumber/>
    <edition/>
    <issue>02</issue>
    <volume>55</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation>Gesellschaft Deutscher Chemiker</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Hybridmaterialien in der analytischen Chemie</title>
    <parentTitle language="deu">Nachrichten aus der Chemie</parentTitle>
    <identifier type="old">18040</identifier>
    <identifier type="issn">1439-9598</identifier>
    <identifier type="issn">1521-3854</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">05.11.2007</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Katrin Hoffmann</author>
    <author>Knut Rurack</author>
    <author>Ramon Martínez-Mánez</author>
    <author>F. Sancenón</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Analytische Chemie</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Hybridmaterialien</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Sensorik</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Absorption</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Mesoporöse Silicate</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Goldnanopartikel</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Quantenpunkte</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>21960</id>
    <completedYear/>
    <publishedYear>2010</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>549</pageFirst>
    <pageLast>580</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>bookpartcollection</type>
    <publisherName>John Wiley &amp; Sons</publisherName>
    <publisherPlace>Hoboken, New Jersey, USA</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Biomimetically inspired signaling</title>
    <parentTitle language="eng">The supramolecular chemistry of organic - inorganic hybrid materials</parentTitle>
    <identifier type="old">24429</identifier>
    <identifier type="isbn">978-0-470-37621-8</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>Knut Rurack</author>
    <author>Ramon Martínez-Mánez</author>
    <author>F. Sancenón</author>
    <author>Ana Belén Descalzo López</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bindungstaschen</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biochemie</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biomimetika</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Chromatophore</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Gold</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Hybridmaterialien</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionenkanäle</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Metalloregulation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanopartikel</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Quantenpunkte</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sensorik</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Silica</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Supramolekulare Chemie</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Verdrängungsassays</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>27783</id>
    <completedYear/>
    <publishedYear>2013</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>25</pageFirst>
    <pageLast>38</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>2</volume>
    <type>article</type>
    <publisherName>Wiley-VCH-Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Fluorinated Boron-Dipyrromethene (BODIPY) dyes: bright and versatile probes for surface analysis</title>
    <abstract language="eng">A family of bright boron-dipyrromethene-type fluorophores with a high number of fluorine atoms (F-BODIPYs) has been developed and characterized by X-ray crystallography and optical spectroscopy. The introduction of 3,5-bis(trifluoromethyl)phenyl and pentafluorophenyl moieties significantly enhances the photostability of such dyes, yielding for instance photostable near-infrared (NIR) fluorophores that show emission maxima&gt;750 nm, when the BODIPY's π system is extended with two (dimethylamino)styryl and (dimethylamino)naphthastyryl moieties, or green-emitting BODIPYs with fluorescence quantum yields of unity. When equipped with a suitable group that selectively reacts for instance with amines, F-BODIPYs can be used as potent dual labels for the quantification of primary amino groups on surfaces by X-ray photoelectron spectroscopy (XPS) and fluorescence, two powerful yet complementary tools for the analysis of organic surface functional groups. The advantage of reactive F-BODIPYs is that they allow a fast and non-destructive mapping of the labelled supports with conventional fluorescence scanners and a subsequent quantification of selected areas of the same sample by the potentially traceable XPS technique. The performance is exemplarily shown here for the assessment of the amino group density on SiO2 supports, one of the most common reactive silica supports, in particular, for standard microarray applications.</abstract>
    <parentTitle language="eng">ChemistryOpen</parentTitle>
    <identifier type="old">30618</identifier>
    <identifier type="doi">10.1002/open.201200039</identifier>
    <identifier type="issn">2191-1363</identifier>
    <enrichment key="date_peer_review">04.03.2013</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Mandy Hecht</author>
    <author>Tobias Fischer</author>
    <author>Paul Dietrich</author>
    <author>Werner Kraus</author>
    <author>Ana Belén Descalzo López</author>
    <author>Wolfgang Unger</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Amino groups</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Surface analysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray photoelectron spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Amino-Gruppen</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Farbstoffe</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Oberflächenanalytik</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Röntgen-Photoelektronen-Spektroskopie</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>20647</id>
    <completedYear/>
    <publishedYear>2009</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>poster</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Highly Emissive Nanoparticles for Applications in FRET Assays</title>
    <parentTitle language="deu">Anakon 2009</parentTitle>
    <identifier type="old">22959</identifier>
    <enrichment key="eventName">Anakon 2009</enrichment>
    <enrichment key="eventPlace">Berlin, Germany</enrichment>
    <enrichment key="eventStart">2009-03-17</enrichment>
    <enrichment key="eventEnd">2009-03-20</enrichment>
    <author>Ana Belén Descalzo López</author>
    <collection role="fulltextaccess" number="">Weder Datei noch physisches Exemplar vorhanden ("No Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
  </doc>
  <doc>
    <id>17511</id>
    <completedYear/>
    <publishedYear>2008</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1581</pageFirst>
    <pageLast>1584</pageLast>
    <pageNumber/>
    <edition/>
    <issue>8</issue>
    <volume>10</volume>
    <type>article</type>
    <publisherName>American Chemical Society</publisherName>
    <publisherPlace>Washington, DC</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Phenanthrene-Fused Boron-Dipyrromethenes as Bright Long-Wavelength Fluorophores</title>
    <abstract language="eng">A new class of boron-dipyrromethene (BDP or BODIPY) dyes was obtained by phenanthrene fusion to the β-pyrrole positions, absorbing in the wavelength range of important laser sources. Despite a 'propeller-like' distorted structure in the crystalline state, the chromophore absorbs (log ε ≥ 5) and fluoresces (Φf ≥  0.8) strongly and can be easily turned into a fluorescence light-up probe. Incorporation into latex beads produces bright and photostable single-dye and Förster Resonance Energy Transfer (FRET) particles for microscopy applications.</abstract>
    <parentTitle language="eng">Organic letters</parentTitle>
    <identifier type="old">19575</identifier>
    <identifier type="doi">10.1021/ol800271e</identifier>
    <identifier type="issn">1523-7060</identifier>
    <identifier type="issn">1523-7052</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">26.05.2008</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>H.-J. Xu</author>
    <author>Z.-L. Xue</author>
    <author>Katrin Hoffmann</author>
    <author>Z. Shen</author>
    <author>Michael G. Weller</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Absorption</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>BODIPY-Farbstoffe</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ladungstransfer</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>NIR-Farbstoffe</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>16447</id>
    <completedYear/>
    <publishedYear>2008</publishedYear>
    <thesisYearAccepted/>
    <language>deu</language>
    <pageFirst>199</pageFirst>
    <pageLast>203</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>120</volume>
    <type>article</type>
    <publisherName>Wiley-VCH</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation>Gesellschaft Deutscher Chemiker</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="deu">Ein kernmodifiziertes Rubyrin mit meso-Aryl-Subsituenten und Phenanthren-anellierten Pyrrolringen als hoch konjugierter NIR-Farbstoff und Hg2+-Sonde</title>
    <parentTitle language="deu">Angewandte Chemie</parentTitle>
    <identifier type="old">18434</identifier>
    <identifier type="doi">10.1002/ange.200702854</identifier>
    <identifier type="issn">0044-8249</identifier>
    <identifier type="issn">0932-2140</identifier>
    <identifier type="issn">1521-3757</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>D. Wu</author>
    <author>Ana Belén Descalzo López</author>
    <author>F. Weik</author>
    <author>Franziska Emmerling</author>
    <author>Z. Shen</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>NIR-Farbstoffe</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Porphyrinoide</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Quecksilber</value>
    </subject>
    <subject>
      <language>deu</language>
      <type>uncontrolled</type>
      <value>Sensoren</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
</export-example>
