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    <title language="eng">Size determination of nanoparticles by ICP-ToF-MS using isotope dilution in microdroplets</title>
    <abstract language="eng">Within this work, the combination of a microdroplet generator and an ICP-ToF-MS for nanoparticle analysis is presented. For the size determination of platinum nanoparticles an on-line isotope dilution analysis approach was developed. The 194Pt/195Pt isotopic ratio was used for the characterization of the particles, while the 182W/183W isotopic ratio was monitored simultaneously for mass bias correction. The on-line ID-MDG-sp-ICP-ToF-MS approach was deployed for the size determination of three platinum nanoparticle samples (50 nm, 63 nm, 70 nm); for validation, complementary size characterization techniques (sp-ICP-ToF-MS and TEM) were used. The robustness of this technique was evidenced, by using sodium chloride concentrations up to 100 mg L−1 as a matrix component. Our new on-line ID MDG-sp-ICP-ToF-MS approach is a promising tool for the fast and reliable determination of nanoparticles' size in severe matrix concentrations, e.g., environmental samples.</abstract>
    <parentTitle language="eng">Journal of Analytical Atomic Spectrometry</parentTitle>
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    <author>Marcus von der Au</author>
    <author>Sebastian Faßbender</author>
    <author>Michail Chronakis</author>
    <author>Jochen Vogl</author>
    <author>Björn Meermann</author>
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      <value>Nanoparticles</value>
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    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Isotope Dilution</value>
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    <title language="eng">Single cell-asymmetrical flow field-flow fractionation/ICP-time of flight-mass spectrometry (sc-AF4/ICP-ToF-MS): an efficient alternative for the cleaning and multielemental analysis of individual cells</title>
    <abstract language="eng">Asymmetrical Flow Field-Flow Fractionation (AF4), as a cleaning technique, was combined on-line with the multielemental analytical capabilities of an Inductively Coupled Plasma-Time of Flight-Mass Spectrometer (ICP-ToF-MS). In that manner, the heavy ionic matrix effect of untreated cells' samples can be significantly reduced. As a proof of concept, commercial baker's yeast cells were analysed.</abstract>
    <parentTitle language="eng">Journal of Analytical Atomic Spectroscopy</parentTitle>
    <identifier type="doi">10.1039/d2ja00264g</identifier>
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    <author>Chronakis Michail Ioannis</author>
    <author>Marcus von der Au</author>
    <author>Björn Meermann</author>
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      <value>AF4</value>
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    <title language="eng">Single cell-asymmetrical flow-field flow Fractionation-ICP-TOF-MS</title>
    <abstract language="eng">AF4 has been coupled to an ICP-ToF-MS and applied to the analysis of single cells. The result in an online cleaning technique that provides the multielemental profile of the sample on a single cell level.</abstract>
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    <author>Michail Ioannis Chronakis</author>
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      <value>AF4</value>
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    <title language="eng">MDG-ICP-ToF-MS: A Versatile Tool for Quantification in  the field of Single Particle ICP-MS Using Isotope Dilution</title>
    <abstract language="eng">In the interest of exploring their potential in the field of single particle analysis, a Microdroplet Generator (MDG) was coupled to an ICP-ToF-MS. Isotopic Dilution Analysis was also incorporated for the size determination of three different Platinum nanoparticles samples (50, 63 and 70 nm). The performance of the technique was validated by comparison to traditional size characterization techniques (sp-ICP-ToF-MS, TEM), while the robustness of the technique was proven by incorporating NaCl in the samples’ matrix, up to 100 mg/L.</abstract>
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    <author>Jochen Vogl</author>
    <author>Björn Meermann</author>
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    <title language="eng">The evolution of data treatment tools in single-particle and single-cell ICP-MS analytics</title>
    <abstract language="eng">Single-particle inductively coupled plasma-mass spectrometry (sp-ICP-MS) is one of the most powerful tools in the thriving field of nanomaterial analysis. Along the same lines, single-cell ICP-MS (sc-ICP-MS) has become an invaluable tool in the study of the variances of cell populations down to a per-cell basis. Their importance and application fields have been listed numerous times, across various reports and reviews. However, not enough attention has been paid to the immense and ongoing development of the tools that are currently available to the analytical community for the acquisition, and more importantly, the treatment of single-particle and single-cell-related data. Due to the ever-increasing demands of modern research, the efficient and dependable treatment of the data has become more important than ever. In addition, the field of single-particle and single-cell analysis suffers due to a large number of approaches for the generated data—with varying levels of specificity and applicability. As a result, finding the appropriate tool or approach, or even comparing results, can be challenging. This article will attempt to bridge these gaps, by covering the evolution and current state of the tools at the disposal of sp-ICP-MS users.&#13;
 Graphical Abstract</abstract>
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