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    <title language="eng">Carboxylative cyclization of propargyl alcohols with carbon dioxide for the synthesis of α-alkylidene cyclic carbonates in presence of Co(III) schiff base complex catalyst</title>
    <abstract language="eng">A cobalt(III) complex, [Co(L)3](DMF) (1) of Schiff base ligand HL, 2-((E)-(benzylimino)methyl)-4-bromophenol is prepared and single crystal X-ray structural analysis have also been performed. The structures of complex 1 showed hexa-coordinated mononuclear systems that adopt octahedral geometry. The complex has also exhibited the supramolecular networks through non-covalent interactions like H-bonding, C–Hπ stacking. Moreover, the complex 1 is very effective in the catalytic fixation of carbon dioxide in propergyl alcohols to produce α-alkylidene cyclic carbonates. The catalytic production of α-alkylidene cyclic carbonates have been carried out through carboxylative cyclization of propargyl alcohols using CO2 balloon of 1 atm pressure at 80 ◦C. Solvent free condition (green synthesis) made this catalytic protocol eco-friendly towards the environment. Utilizing various substrates of propargyl alcohols moderate to high percentage yield (62–95%) of respective α-alkylidene cyclic carbonates product have been isolated over this catalytic reaction. Besides, the theoretical calculations (DFT) was performed for the prediction of probable mechanism of the catalytic reaction</abstract>
    <parentTitle language="eng">Journal of Molecular Structure</parentTitle>
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    <identifier type="issn">0022-2860</identifier>
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    <author>Juli Nanda Goswami</author>
    <author>Najirul Haque</author>
    <author>Asiful H. Seikh</author>
    <author>Biswajit Bhattacharya</author>
    <author>Franziska Emmerling</author>
    <author>Nimai Bar</author>
    <author>Ahmad A. Ifseisi</author>
    <author>Surajit Biswas</author>
    <author>Malay Dolai</author>
    <subject>
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      <type>uncontrolled</type>
      <value>Catalytic fixation of carbon dioxide</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Carboxylative cyclization of propargyl alcohols</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cobalt (III) Schiff base complex</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray crystal analysis</value>
    </subject>
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    <collection role="institutes" number="">6.3 Strukturanalytik</collection>
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