<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>63195</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>4648</pageFirst>
    <pageLast>4661</pageLast>
    <pageNumber/>
    <edition/>
    <issue>13</issue>
    <volume>12</volume>
    <type>article</type>
    <publisherName>Royal Society of Chemistry (RSC)</publisherName>
    <publisherPlace>Cambridge</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Multifunctional polyoxomolybdate ionic liquid coatings for mitigating microbiologically influenced corrosion</title>
    <abstract language="eng">Corrosion of metals and other materials in marine environments poses significant economic, operational, safety, and environmental challenges across the oil and gas industry, the renewable energy sector, and maritime infrastructure. Microbiologically influenced corrosion (MIC) accounts for a substantial portion of this corrosion, with sulfate-reducing bacteria (SRB) and methanogenic archaea (MA) being key contributors. Conventional methods such as cathodic polarization have proven insufficient in mitigating the colonization of corrosive microbial communities in real marine environments, requiring the development of alternative, broad-spectrum antimicrobial strategies to prevent such biofilm formation. Recently, molybdate has emerged as a potential alternative to traditional biocides and nitrate. Our hypothesis is polyoxometalate-ionic liquids (POM-ILs), which exhibit antimicrobial and anticorrosion properties, could have a broader spectrum of antimicrobial activity than demonstrated until now and could be capable of shielding and protecting sensitive metal surfaces from the extreme acidic environments produced by MIC microorganisms. Here we show how two prototype polyoxomolybdate-based POM-ILs, [(CH3(CH2)6)4N]2[Mo6O19] and [(CH3(CH2)6)4N]4[Mo8O26], demonstrated antimicrobial activity at microgram per millilitre concentrations, prevented biofilm formation on metal surfaces, and provided resistance to corrosive acidic environments. Furthermore, impedance measurements were commensurate with electron microscopy studies showing that POM-IL-coated brass coupons withstood extremely corrosive environments. These proof-of-concept results demonstrate how multi-functional POM-IL coatings represent promising MIC mitigation solutions by providing a hydrophobic acid-resistant and biocidal protective layer that prevents biocolonisation and acidic corrosion by MIC microorganisms.</abstract>
    <parentTitle language="eng">Materials horizons</parentTitle>
    <identifier type="issn">2051-6347</identifier>
    <identifier type="doi">10.1039/d5mh00373c</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-631951</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T13:10:06Z","timestamp":1747660206078,"version":"3.40.5"},"reference-count":50,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2025,5,8]],"date-time":"2025-05-08T00:00:00Z","timestamp":1746662400000},"content-version":"vor","delay-in-days":127,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100010067","name":"Gobierno de Arag\u00f3n","doi-asserted-by":"publisher","award":["E15_23R","T02_23R"],"id":[{"id":"10.13039\/501100010067","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100031478","name":"NextGenerationEU","doi-asserted-by":"publisher","award":["PRTR-C17.I1"],"id":[{"id":"10.13039\/100031478","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000921","name":"European Cooperation in Science and Technology","doi-asserted-by":"publisher","award":["CA20130"],"id":[{"id":"10.13039\/501100000921","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Mater. Horiz."],"abstract":"&lt;jats:p&gt;Corrosion of metals and other materials in marine environments poses significant economic, operational, safety, and environmental challenges across the oil and gas industry, the renewable energy sector, and maritime infrastructure.&lt;\/jats:p&gt;","DOI":"10.1039\/d5mh00373c","type":"journal-article","created":{"date-parts":[[2025,5,8]],"date-time":"2025-05-08T06:01:22Z","timestamp":1746684082000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Multifunctional polyoxomolybdate ionic liquid coatings for mitigating microbiologically influenced corrosion"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-2588-6871","authenticated-orcid":false,"given":"Mariella","family":"Malefioudaki","sequence":"first","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA-CSIC\/UNIZAR), CSIC-Universidad de Zaragoza, C\/Pedro Cerbuna 12, 50009 Zaragoza, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0966-3145","authenticated-orcid":false,"given":"Archismita","family":"Misra","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und -pr\u00fcfung (BAM), Department of Materials and Environment, Unter den Eichen 87, 12205 Berlin, Germany"}]},{"given":"Nadja","family":"Sbeity","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und -pr\u00fcfung (BAM), Department of Materials and Environment, Unter den Eichen 87, 12205 Berlin, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-1244-8793","authenticated-orcid":false,"given":"Juan","family":"Zueco-Vincelle","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA-CSIC\/UNIZAR), CSIC-Universidad de Zaragoza, C\/Pedro Cerbuna 12, 50009 Zaragoza, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7819-8956","authenticated-orcid":false,"given":"Miguel A.","family":"Laguna-Bercero","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA-CSIC\/UNIZAR), CSIC-Universidad de Zaragoza, C\/Pedro Cerbuna 12, 50009 Zaragoza, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9214-6183","authenticated-orcid":false,"given":"Andrea","family":"Koerdt","sequence":"additional","affiliation":[{"name":"Bundesanstalt f\u00fcr Materialforschung und -pr\u00fcfung (BAM), Department of Materials and Environment, Unter den Eichen 87, 12205 Berlin, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0702-8260","authenticated-orcid":false,"given":"Rafael","family":"Mart\u00edn-Rap\u00fan","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA-CSIC\/UNIZAR), CSIC-Universidad de Zaragoza, C\/Pedro Cerbuna 12, 50009 Zaragoza, Spain"},{"name":"CIBER de Bioingenier\u00eda, Biomateriales y Nanomedicina, Instituto de Salud Carlos III, 28029 Madrid, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4848-414X","authenticated-orcid":false,"given":"Scott G.","family":"Mitchell","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia y Materiales de Arag\u00f3n (INMA-CSIC\/UNIZAR), CSIC-Universidad de Zaragoza, C\/Pedro Cerbuna 12, 50009 Zaragoza, Spain"},{"name":"CIBER de Bioingenier\u00eda, Biomateriales y Nanomedicina, Instituto de Salud Carlos III, 28029 Madrid, Spain"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5MH00373C\/cit1\/1","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.psep.2022.12.054","volume":"171","author":"Ma","year":"2023","journal-title":"Saf. Environ. Prot."},{"year":"2018","author":"Cai","key":"D5MH00373C\/cit2\/1","unstructured":"Y. K.Cai ,  Y.Zhao ,  Z. K.Zhang ,  X. B.Ma  and  B.Cheng , Atmospheric and marine corrosion: influential environmental factors and models,  In Proceedings of the International Workshop on Environmental Management, Science and Engineering ,  2018 , pp. 178\u2013186"},{"key":"D5MH00373C\/cit3\/1","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/B978-0-08-101105-8.00001-2","volume":"3","author":"Koch","year":"2017","journal-title":"Trends Oil Gas Corros. Res. Technol."},{"key":"D5MH00373C\/cit4\/1","doi-asserted-by":"crossref","first-page":"5983","DOI":"10.1039\/c2cc32375c","volume":"48","author":"Seter","year":"2012","journal-title":"Chem. Commun."},{"key":"D5MH00373C\/cit5\/1","doi-asserted-by":"crossref","first-page":"1340352","DOI":"10.3389\/fnano.2024.1340352","volume":"6","author":"Kalajahi","year":"2024","journal-title":"Frontal Nanotechnol."},{"key":"D5MH00373C\/cit6\/1","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1007\/s40735-023-00772-7","volume":"9","author":"Rao","year":"2023","journal-title":"J. Bio Tribo Corros."},{"key":"D5MH00373C\/cit7\/1","first-page":"D111S046R001","author":"An","year":"2021","journal-title":"NACE Corrosion"},{"key":"D5MH00373C\/cit8\/1","doi-asserted-by":"crossref","first-page":"3777","DOI":"10.1016\/j.jmrt.2023.10.296","volume":"27","author":"Li","year":"2023","journal-title":"J. Mater. Res. Technol."},{"key":"D5MH00373C\/cit9\/1","doi-asserted-by":"crossref","first-page":"527","DOI":"10.3389\/fmicb.2020.00527","volume":"11","author":"An","year":"2020","journal-title":"Front. Microbiol."},{"key":"D5MH00373C\/cit10\/1","doi-asserted-by":"crossref","first-page":"1357","DOI":"10.1007\/s11665-015-1388-2","volume":"24","author":"G\u00fcng\u00f6r","year":"2015","journal-title":"J. Mater. Eng. Perform."},{"key":"D5MH00373C\/cit11\/1","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1016\/j.corsci.2014.07.001","volume":"87","author":"Chen","year":"2014","journal-title":"Corros. Sci."},{"key":"D5MH00373C\/cit12\/1","doi-asserted-by":"crossref","first-page":"806688","DOI":"10.3389\/fmicb.2022.806688","volume":"13","author":"Amendola","year":"2022","journal-title":"Front. Microbiol."},{"key":"D5MH00373C\/cit13\/1","first-page":"1","volume":"84","author":"Javed","year":"2016","journal-title":"Corros. Prev."},{"key":"D5MH00373C\/cit14\/1","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1016\/j.bioelechem.2013.12.005","volume":"97","author":"Carvalho","year":"2014","journal-title":"Bioelectrochemistry"},{"key":"D5MH00373C\/cit15\/1","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1007\/s40735-022-00661-5","volume":"8","author":"Rkayae","year":"2022","journal-title":"J. Bio Tribo Corros."},{"key":"D5MH00373C\/cit16\/1","doi-asserted-by":"crossref","first-page":"108641","DOI":"10.1016\/j.corsci.2020.108641","volume":"170","author":"Little","year":"2020","journal-title":"Corros. Sci."},{"key":"D5MH00373C\/cit17\/1","doi-asserted-by":"crossref","first-page":"1458","DOI":"10.3390\/met12091458","volume":"12","author":"Khan","year":"2022","journal-title":"Metals"},{"key":"D5MH00373C\/cit18\/1","doi-asserted-by":"crossref","first-page":"fuad041","DOI":"10.1093\/femsre\/fuad041","volume":"47","author":"Knisz","year":"2023","journal-title":"FEMS Microbiol. Rev."},{"year":"2018","author":"Cai","key":"D5MH00373C\/cit19\/1","unstructured":"Y. K.Cai ,  Y.Zhao ,  Z. K.Zhang ,  X. B.Ma  and  B.Cheng , Atmospheric and marine corrosion: influential environmental factors and models,  In Proceedings of the International Workshop on Environmental Management, Science and Engineering ,  2018 , pp. 178\u2013186"},{"key":"D5MH00373C\/cit20\/1","doi-asserted-by":"crossref","first-page":"105158","DOI":"10.1016\/j.ibiod.2020.105158","volume":"157","author":"K\u00f6gler","year":"2021","journal-title":"Int. Biodeterior. Biodegrad."},{"key":"D5MH00373C\/cit21\/1","doi-asserted-by":"crossref","first-page":"2165","DOI":"10.1016\/j.electacta.2010.11.099","volume":"56","author":"Karpakam","year":"2011","journal-title":"Electrochim. Acta"},{"key":"D5MH00373C\/cit22\/1","doi-asserted-by":"crossref","first-page":"215687","DOI":"10.1016\/j.ccr.2024.215687","volume":"506","author":"Liu","year":"2024","journal-title":"Coord. Chem. Rev."},{"key":"D5MH00373C\/cit23\/1","doi-asserted-by":"crossref","first-page":"2207315","DOI":"10.1002\/smll.202207315","volume":"19","author":"Guo","year":"2023","journal-title":"Small"},{"key":"D5MH00373C\/cit24\/1","doi-asserted-by":"crossref","first-page":"7333","DOI":"10.1039\/c2cs90087d","volume":"41","author":"Cronin","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"D5MH00373C\/cit25\/1","doi-asserted-by":"crossref","first-page":"403","DOI":"10.1016\/j.molliq.2017.02.111","volume":"233","author":"Verma","year":"2017","journal-title":"J. Mol. Liq."},{"key":"D5MH00373C\/cit26\/1","doi-asserted-by":"crossref","first-page":"5983","DOI":"10.1039\/c2cc32375c","volume":"48","author":"Seter","year":"2012","journal-title":"Chem. Commun."},{"key":"D5MH00373C\/cit27\/1","doi-asserted-by":"crossref","first-page":"106049","DOI":"10.1016\/j.microc.2021.106049","volume":"165","author":"Ardakani","year":"2021","journal-title":"Microchem. J."},{"key":"D5MH00373C\/cit28\/1","doi-asserted-by":"crossref","first-page":"13596","DOI":"10.1002\/anie.201408171","volume":"53","author":"Herrmann","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5MH00373C\/cit29\/1","doi-asserted-by":"crossref","first-page":"5663","DOI":"10.3390\/molecules25235663","volume":"25","author":"Rajkowska","year":"2020","journal-title":"Molecules"},{"key":"D5MH00373C\/cit30\/1","doi-asserted-by":"crossref","first-page":"14926","DOI":"10.1002\/anie.201809893","volume":"57","author":"Misra","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5MH00373C\/cit31\/1","doi-asserted-by":"crossref","first-page":"74","DOI":"10.1002\/9780470132586.ch15","volume":"27","author":"Klemperer","year":"1990","journal-title":"Inorg. Synth."},{"key":"D5MH00373C\/cit32\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.22401\/ANJS.22.1.01","volume":"22","author":"Al-Majedy","year":"2019","journal-title":"Al-Nahrain J. Sci."},{"key":"D5MH00373C\/cit33\/1","doi-asserted-by":"crossref","first-page":"27","DOI":"10.31436\/iiumej.v9i2.98","volume":"9","author":"Mirghani","year":"2008","journal-title":"IIUM Eng. J."},{"key":"D5MH00373C\/cit34\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/978-1-4939-6960-9_1","volume":"1601","author":"Pr\u00e4bst","year":"2017","journal-title":"Methods Mol. Biol."},{"key":"D5MH00373C\/cit35\/1","doi-asserted-by":"crossref","first-page":"4144","DOI":"10.1021\/acsapm.2c00110","volume":"4","author":"Enderle","year":"2022","journal-title":"ACS Appl. Polym. Mater."},{"key":"D5MH00373C\/cit36\/1","doi-asserted-by":"crossref","first-page":"1153","DOI":"10.1039\/C7CC07549A","volume":"54","author":"Bijelic","year":"2018","journal-title":"Chem. Commun."},{"key":"D5MH00373C\/cit37\/1","doi-asserted-by":"crossref","first-page":"4140","DOI":"10.1149\/1.1838928","volume":"145","author":"L\u00f3pez-Delgado","year":"1998","journal-title":"J. Electrochem. Soc."},{"key":"D5MH00373C\/cit38\/1","doi-asserted-by":"crossref","first-page":"1073","DOI":"10.1016\/0013-4686(95)00440-8","volume":"41","author":"Bonora","year":"1996","journal-title":"Electrochim. Acta"},{"key":"D5MH00373C\/cit39\/1","first-page":"137","author":"Hern\u00e1ndez","year":"2020","journal-title":"Electrochem. Impedance Spectrosc."},{"key":"D5MH00373C\/cit40\/1","doi-asserted-by":"crossref","first-page":"2698","DOI":"10.1002\/celc.201800844","volume":"5","author":"Ram\u00edrez Barat","year":"2018","journal-title":"ChemElectroChem"},{"key":"D5MH00373C\/cit41\/1","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/j.apsusc.2017.02.142","volume":"407","author":"Qiu","year":"2017","journal-title":"Appl. Surf. Sci."},{"key":"D5MH00373C\/cit42\/1","doi-asserted-by":"crossref","first-page":"378","DOI":"10.3390\/ma17020378","volume":"17","author":"Gong","year":"2024","journal-title":"Materials"},{"key":"D5MH00373C\/cit43\/1","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/B978-0-08-101105-8.00008-5","author":"Telegdi","year":"2017","journal-title":"Trends Oil Gas Corros. Res. Technol."},{"key":"D5MH00373C\/cit44\/1","doi-asserted-by":"crossref","first-page":"107920","DOI":"10.1016\/j.bioelechem.2021.107920","volume":"142","author":"Wang","year":"2021","journal-title":"Bioelectrochemistry"},{"key":"D5MH00373C\/cit45\/1","doi-asserted-by":"crossref","first-page":"15458","DOI":"10.1038\/s41598-021-95060-0","volume":"11","author":"Chatterjee","year":"2021","journal-title":"Sci. Rep."},{"key":"D5MH00373C\/cit46\/1","doi-asserted-by":"crossref","first-page":"1673","DOI":"10.1038\/ismej.2014.82","volume":"8","author":"Lohner","year":"2014","journal-title":"ISME J."},{"issue":"11","key":"D5MH00373C\/cit47\/1","doi-asserted-by":"crossref","first-page":"2237","DOI":"10.3390\/microorganisms10112237","volume":"10","author":"Mayer","year":"2022","journal-title":"Microorganisms"},{"key":"D5MH00373C\/cit48\/1","doi-asserted-by":"crossref","first-page":"16620","DOI":"10.1038\/s41598-018-34789-7","volume":"8","author":"Sharma","year":"2018","journal-title":"Sci. Rep."},{"key":"D5MH00373C\/cit49\/1","first-page":"604","volume":"7","author":"Ghazy","year":"2011","journal-title":"J. Am. Sci."},{"key":"D5MH00373C\/cit50\/1","doi-asserted-by":"crossref","first-page":"e13","DOI":"10.1017\/exp.2022.5","volume":"3","author":"Malaret","year":"2022","journal-title":"Exp. Results"}],"container-title":["Materials Horizons"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/MH\/D5MH00373C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T12:29:53Z","timestamp":1747657793000},"score":1,"resource":{"primary":{"URL":"https:\/\/xlink.rsc.org\/?DOI=D5MH00373C"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":50,"URL":"https:\/\/doi.org\/10.1039\/d5mh00373c","relation":{},"ISSN":["2051-6347","2051-6355"],"issn-type":[{"type":"print","value":"2051-6347"},{"type":"electronic","value":"2051-6355"}],"subject":[],"published":{"date-parts":[[2025]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">http://creativecommons.org/licenses/by/3.0/</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorIdentifierOrcid_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorIdentifierOrcid_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorIdentifierOrcid_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorIdentifierOrcid_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorIdentifierOrcid_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorIdentifierOrcid_7,PersonAuthorFirstName_8,PersonAuthorLastName_8,PersonAuthorIdentifierOrcid_8,PublisherName,TitleMain_1,Language,TitleAbstract_1,TitleParent_1,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="date_peer_review">26.05.2025</enrichment>
    <licence>Creative Commons - Namensnennung 3.0</licence>
    <author>Mariella Malefioudaki</author>
    <author>Archismita Misra</author>
    <author>Nadja Sbeity</author>
    <author>Juan Zueco-Vincelle</author>
    <author>Miguel A. Laguna-Bercero</author>
    <author>Andrea Koerdt</author>
    <author>Rafael Martín-Rapún</author>
    <author>Scott G. Mitchell</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polyoxometalates</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionic liquid</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microbiologically influenced corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Heritage preservation</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.1 Biologische Materialschädigung und Referenzorganismen</collection>
    <collection role="institutes" number="">4.5 Kunst- und Kulturgutanalyse</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <collection role="themenfelder" number="">Biokorrosion</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/63195/Multifunctional POM IL to mitigate MIC_Malefioudaki et al_2025.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/63195/d5mh00373c_final_article.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/63195/d5mh00373c_supplementary_information.pdf</file>
  </doc>
  <doc>
    <id>64548</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>poster</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Polyoxometalate Ionic Liquids as Protective Coatings for Industrial Infrastructure and Cultural Heritage against Microbiologically Influenced Corrosion (MIC)</title>
    <abstract language="eng">Corrosion of stone and metal due to acid rain and biodeterioration poses significant challenges for industrial and residential infrastructure, as well as cultural heritage, including statues and historical artefacts. A promising mitigation strategy involves thin, transparent films of polyoxometalate-based ionic liquids (POM-ILs) as chemical shields. Stone samples coated with acid-resistant, biocidal POM-ILs exhibited negligible corrosion when exposed to simulated acid rain, in stark contrast to the severe deterioration of unprotected samples. Additionally, their biocidal properties effectively prevent biofilm formation on coated surfaces. Following studies successfully explored the effectiveness of the coating against lampenflora growing in the Pommery Champagne cellar; and the long-term performance of POM-ILs under outdoor environmental conditions. So, POM-ILs have already demonstrated remarkable anticorrosion and antimicrobial properties against aerobic microorganisms and, being water-insoluble, do not leach into aquatic ecosystem. The current research project repurposes the POM-ILs, extending their application to metals, specifically targeting microbiologically influenced corrosion (MIC) in cultural heritage artefacts made of brass, carbon steel, cast iron, and bronze. This involves optimizing nanocoating adhesion to the metal surface and evaluating its protective efficacy against MIC caused by anaerobic microorganisms such as methanogenic archaea and sulfate reducing bacteria (SRB). This presentation will highlight POM-ILs as sustainable, high-performance nanocoatings for biocorrosion mitigation. It will showcase published success stories, discuss ongoing research and proof-of-concept results, and explore future prospects for these advanced materials in safeguarding metal infrastructure and artefacts across different industrial sectors as well as in the context of cultural heritage conservation.</abstract>
    <enrichment key="eventName">10th International symposium on applied microbiology and molecular biology in oil systems (ISMOS10)</enrichment>
    <enrichment key="eventPlace">Nashville, Tennessee, USA</enrichment>
    <enrichment key="eventStart">11.08.2025</enrichment>
    <enrichment key="eventEnd">14.08.2025</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Archismita Misra</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polyoxometalates</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microbiologically Influenced Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionic Liquid</value>
    </subject>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.1 Biologische Materialschädigung und Referenzorganismen</collection>
    <collection role="institutes" number="">4.5 Kunst- und Kulturgutanalyse</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <collection role="themenfelder" number="">Biokorrosion</collection>
  </doc>
  <doc>
    <id>64549</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>poster</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Polyoxometalate Ionic Liquids as Protective Coatings for Industrial Infrastructure and Cultural Heritage against Microbiologically Influenced Corrosion (MIC)</title>
    <abstract language="eng">Corrosion of stone and metal due to acid rain and biodeterioration poses significant challenges for industrial and residential infrastructure, as well as cultural heritage, including statues and historical artefacts. A promising mitigation strategy involves thin, transparent films of polyoxometalate-based ionic liquids (POM-ILs) as chemical shields. Stone samples coated with acid-resistant, biocidal POM-ILs exhibited negligible corrosion when exposed to simulated acid rain, in stark contrast to the severe deterioration of unprotected samples. Additionally, their biocidal properties effectively prevent biofilm formation on coated surfaces. Following studies successfully explored the effectiveness of the coating against lampenflora growing in the Pommery Champagne cellar; and the long-term performance of POM-ILs under outdoor environmental conditions. So, POM-ILs have already demonstrated remarkable anticorrosion and antimicrobial properties against aerobic microorganisms and, being water-insoluble, do not leach into aquatic ecosystem. The current research project repurposes the POM-ILs, extending their application to metals, specifically targeting microbiologically influenced corrosion (MIC) in cultural heritage artefacts made of brass, carbon steel, cast iron, and bronze. This involves optimizing nanocoating adhesion to the metal surface and evaluating its protective efficacy against MIC caused by anaerobic microorganisms such as methanogenic archaea and sulfate reducing bacteria (SRB). This presentation will highlight POM-ILs as sustainable, high-performance nanocoatings for biocorrosion mitigation. It will showcase published success stories, discuss ongoing research and proof-of-concept results, and explore future prospects for these advanced materials in safeguarding metal infrastructure and artefacts across different industrial sectors as well as in the context of cultural heritage conservation.</abstract>
    <enrichment key="eventName">Euro-MIC COST Action - Closing Workshop  Conference</enrichment>
    <enrichment key="eventPlace">Horsens, Denmark</enrichment>
    <enrichment key="eventStart">17.09.2025</enrichment>
    <enrichment key="eventEnd">19.09.2025</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Archismita Misra</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polyoxometalates</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microbiologically Influenced Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ionic Liquid</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.1 Biologische Materialschädigung und Referenzorganismen</collection>
    <collection role="institutes" number="">4.5 Kunst- und Kulturgutanalyse</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="literaturgattung" number="">Präsentation</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <collection role="themenfelder" number="">Biokorrosion</collection>
  </doc>
</export-example>
