<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>18913</id>
    <completedYear/>
    <publishedYear>2009</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>129</pageFirst>
    <pageLast>137</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>16</volume>
    <type>article</type>
    <publisherName>Chapman &amp; Hall</publisherName>
    <publisherPlace>London</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Solid-state NMR studies of methyl celluloses. Part 1: regioselectively substituted celluloses as standards for establishing an NMR data basis</title>
    <abstract language="eng">Three methyl celluloses with completely uniform substitution pattern, 2-O-methyl cellulose (1), 3-O-methyl cellulose (2) and 6-O-methyl cellulose (3), were prepared according to the cationic ring opening polymerization approaches starting from substituted 1,2,4-orthopivalate derivatives of D-glucose. These samples allowed for the first time to sort out the methyl substitution effects on solid-state NMR chemical shifts and relaxation. Dipolar dephasing experiments allowed the detection and assignment (1H, 13C) of the methyl groups. In 1 and 2, these resonances overlapped with those of C-6, whereas in 3, the methyl signal experienced a low-field shift into the region of C-2,3,5. 13C T1 experiments were used to verify different relaxation behavior of the carbon sites, particularly the short relaxation time of at the carbon substitution site next to the methyl groups. This effect was used to unambiguously identify the 13C chemical shifts of the carbons carrying the methoxyl substituent, although they overlap with all resonances in the C-2,3,5 region. The data obtained for the standard samples with uniform substitution will now be used as the basis for determining methylation patterns and substitution degree in commercial methyl celluloses.</abstract>
    <parentTitle language="eng">Cellulose</parentTitle>
    <identifier type="old">21094</identifier>
    <identifier type="doi">10.1007/s10570-008-9247-z</identifier>
    <identifier type="issn">0969-0239</identifier>
    <identifier type="issn">1572-882X</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">16.02.2009</enrichment>
    <author>Andrea Karrasch</author>
    <author>Christian Jäger</author>
    <author>M. Karakawa</author>
    <author>F. Nakatsubo</author>
    <author>A. Potthast</author>
    <author>T. Rosenau</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Methyl cellulose</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Solid-state NMR</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>CPMAS NMR</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Substituent distribution</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Substitution pattern</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cationic ring opening polymerization</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Methylation</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
</export-example>
