<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>27488</id>
    <completedYear/>
    <publishedYear>2012</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>16844</pageFirst>
    <pageLast>16867</pageLast>
    <pageNumber/>
    <edition/>
    <issue>52</issue>
    <volume>18</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Synthesis and properties  of fused-ring-expanded porphyrins that were core-modified with group 16 heteroatoms</title>
    <abstract language="eng">The synthesis of a series of novel core-modified and fused-ring-expanded tetraphenylporphyrins is reported. Theoretical calculations and magnetic circular dichroism (MCD) and fluorescence spectroscopic measurements were used to analyze the effect of core modification with Group 16 oxygen, sulfur, selenium, and tellurium atoms on the optical properties and electronic structures of the porphyrins. Marked redshifts of the Q and B bands and accelerated intersystem-crossing rates were observed, thus making these compounds potentially suitable for use in a variety of applications. The scope for further fine-tuning of these optical properties based on additional structural modifications, such as the incorporation of fused benzene rings to form ABAB structures by using a thiophene precursor with a fused bicyclo[2.2.2]octadiene ring and the introduction of various substituents onto the meso-phenyl rings, is also examined.</abstract>
    <parentTitle language="eng">Chemistry - A European journal</parentTitle>
    <identifier type="old">30305</identifier>
    <identifier type="doi">10.1002/chem.201200956</identifier>
    <identifier type="issn">0947-6539</identifier>
    <identifier type="issn">1521-3765</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">20.12.2012</enrichment>
    <author>H.-J. Xu</author>
    <author>J. Mack</author>
    <author>D. Wu</author>
    <author>Z.-L. Xue</author>
    <author>Ana Belén Descalzo López</author>
    <author>Knut Rurack</author>
    <author>N. Kobayashi</author>
    <author>Z. Shen</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Density functional calculations</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MCD spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porphyrinoids</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ring expansion</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>21941</id>
    <completedYear/>
    <publishedYear>2010</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>41</pageFirst>
    <pageLast>106</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>9</volume>
    <type>bookpartcollection</type>
    <publisherName>Springer</publisherName>
    <publisherPlace/>
    <creatingCorporation>National Academy of Sciences of Ukraine</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Optimization of the coupling of target recognition and signal generation</title>
    <abstract language="eng">Fluorescent reporters that literally "light up" upon binding of a target species are particularly interesting from an analytical point of view. This contribution introduces the main signaling concepts in fluorescent probe research, discusses strategies toward their optimization in terms of signal output, and highlights the wealth of alternative protocols that has been realized in the past two decades to create signaling systems with luminescence amplification features.</abstract>
    <parentTitle language="eng">Advanced fluorescence reporters in chemistry and biology II: Molecular constructions, polymers and nanoparticles</parentTitle>
    <identifier type="old">24408</identifier>
    <identifier type="isbn">978-3-642-04699-5</identifier>
    <identifier type="doi">10.1007/978-3-642-04701-5_2</identifier>
    <note>Serientitel: Springer Series on Fluorescence – Series title: Springer Series on Fluorescence</note>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <author>Ana Belén Descalzo López</author>
    <author>Shengchao Zhu</author>
    <author>Tobias Fischer</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>FRET</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Molecular Recognition</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Nanoparticles</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>16448</id>
    <completedYear/>
    <publishedYear>2008</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>193</pageFirst>
    <pageLast>197</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>47</volume>
    <type>article</type>
    <publisherName>Wiley-VCH</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation>Gesellschaft Deutscher Chemiker</creatingCorporation>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">A core-modified Rubyrin with meso-aryl substituents and phenanthrene-fused pyrrole rings: a highly conjugated near-infrared dye and Hg2+ probe</title>
    <parentTitle language="eng">Angewandte Chemie / International Edition</parentTitle>
    <identifier type="old">18435</identifier>
    <identifier type="doi">10.1002/Anie.200702854</identifier>
    <identifier type="issn">1433-7851</identifier>
    <identifier type="issn">1521-3773</identifier>
    <identifier type="issn">0570-0833</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">03.01.2008</enrichment>
    <author>D. Wu</author>
    <author>Ana Belén Descalzo López</author>
    <author>F. Weik</author>
    <author>Franziska Emmerling</author>
    <author>Z. Shen</author>
    <author>X.-Z. You</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mercury</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>NIR dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Porphyrinoids</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sensors</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>12561</id>
    <completedYear/>
    <publishedYear>2006</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>176</pageFirst>
    <pageLast>187</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1-2</issue>
    <volume>1</volume>
    <type>article</type>
    <publisherName>Wiley-VCH Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Mono- and Di(dimethylamino)styryl-Substituted Borondipyrromethene and Borondiindomethene Dyes with Intense Near-Infrared Fluorescence</title>
    <abstract language="eng">Four novel borondipyrromethene (BDP) and -diindomethene (BDI) dyes with one or two (dimethylamino)styryl extensions at the chromophore were synthesized and spectroscopically investigated. An X-ray crystal structure shows that the extended auxochrome is virtually planar. All dyes thus display intense red/near infrared (NIR) absorption and emission. The (dimethylamino)styryl group induces a charge-transfer character that entails bright solvatochromic fluorescence, which is only quenched with increasing solvent polarity according to the energy-gap law. The dye with an additional dimethylanilino group at the meso position of BDP shows a remarkable switching of lipophilicity by protonation. Two dyes with an 8-hydroxyquinoline ligand at the meso position display quenched emission in the presence of Hg2+ or Al3+ owing to electron transfer from the excited BDP to the complexed receptor. The BDI dye presents a pH indicator with bright fluorescence and extremely low fluorescence anisotropy.</abstract>
    <parentTitle language="eng">Chemistry / Asian Journal</parentTitle>
    <identifier type="old">14290</identifier>
    <identifier type="doi">10.1002/asia.200600042</identifier>
    <identifier type="issn">1861-4728</identifier>
    <identifier type="issn">1861-471X</identifier>
    <enrichment key="bibliotheksstandort">Sonderstandort: Publica-Schrank</enrichment>
    <enrichment key="date_peer_review">17.07.2006</enrichment>
    <author>Y.-H. Yu</author>
    <author>Ana Belén Descalzo López</author>
    <author>Z. Sgen</author>
    <author>Holger Röhr</author>
    <author>Q. Liu</author>
    <author>Y.-W. Wang</author>
    <author>Monika Spieles</author>
    <author>Y.-Z. Li</author>
    <author>Knut Rurack</author>
    <author>X.-Z. You</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Borondipyrromethene</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Indicators</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Protonation</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Physisches Exemplar in der Bibliothek der BAM vorhanden ("Hardcopy Access")</collection>
  </doc>
  <doc>
    <id>27783</id>
    <completedYear/>
    <publishedYear>2013</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>25</pageFirst>
    <pageLast>38</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>2</volume>
    <type>article</type>
    <publisherName>Wiley-VCH-Verl.</publisherName>
    <publisherPlace>Weinheim</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Fluorinated Boron-Dipyrromethene (BODIPY) dyes: bright and versatile probes for surface analysis</title>
    <abstract language="eng">A family of bright boron-dipyrromethene-type fluorophores with a high number of fluorine atoms (F-BODIPYs) has been developed and characterized by X-ray crystallography and optical spectroscopy. The introduction of 3,5-bis(trifluoromethyl)phenyl and pentafluorophenyl moieties significantly enhances the photostability of such dyes, yielding for instance photostable near-infrared (NIR) fluorophores that show emission maxima&gt;750 nm, when the BODIPY's π system is extended with two (dimethylamino)styryl and (dimethylamino)naphthastyryl moieties, or green-emitting BODIPYs with fluorescence quantum yields of unity. When equipped with a suitable group that selectively reacts for instance with amines, F-BODIPYs can be used as potent dual labels for the quantification of primary amino groups on surfaces by X-ray photoelectron spectroscopy (XPS) and fluorescence, two powerful yet complementary tools for the analysis of organic surface functional groups. The advantage of reactive F-BODIPYs is that they allow a fast and non-destructive mapping of the labelled supports with conventional fluorescence scanners and a subsequent quantification of selected areas of the same sample by the potentially traceable XPS technique. The performance is exemplarily shown here for the assessment of the amino group density on SiO2 supports, one of the most common reactive silica supports, in particular, for standard microarray applications.</abstract>
    <parentTitle language="eng">ChemistryOpen</parentTitle>
    <identifier type="old">30618</identifier>
    <identifier type="doi">10.1002/open.201200039</identifier>
    <identifier type="issn">2191-1363</identifier>
    <enrichment key="date_peer_review">04.03.2013</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Mandy Hecht</author>
    <author>Tobias Fischer</author>
    <author>Paul Dietrich</author>
    <author>Werner Kraus</author>
    <author>Ana Belén Descalzo López</author>
    <author>Wolfgang Unger</author>
    <author>Knut Rurack</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Amino groups</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dyes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluorescence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Surface analysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray photoelectron spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Amino-Gruppen</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Farbstoffe</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fluoreszenz</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Oberflächenanalytik</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Röntgen-Photoelektronen-Spektroskopie</value>
    </subject>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
</export-example>
