<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>57982</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>48</pageLast>
    <pageNumber/>
    <edition/>
    <issue>4</issue>
    <volume>13</volume>
    <type>article</type>
    <publisherName>MDPI</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Biocompatible Macroion/Growth Factor Assemblies for Medical Applications</title>
    <abstract language="eng">Growth factors are a class of proteins that play a role in the proliferation (the increase in the number of cells resulting from cell division) and differentiation (when a cell undergoes changes in gene expression becoming a more specific type of cell) of cells. They can have both positive (accelerating the normal healing process) and negative effects (causing cancer) on disease progression and have potential applications in gene therapy and wound healing. However, their short half-life, low stability, and susceptibility to degradation by enzymes at body temperature make them easily degradable in vivo. To improve their effectiveness and stability, growth factors require carriers for delivery that protect them from heat, pH changes, and proteolysis. These carriers should also be able to deliver the growth factors to their intended destination. This review focuses on the current scientific literature concerning the physicochemical properties (such as biocompatibility, high affinity for binding growth factors, improved bioactivity and stability of the growth factors, protection from heat, pH changes or appropriate electric charge for growth factor attachment via electrostatic interactions) of macroions, growth factors, and macroion-growth factor assemblies, as well as their potential uses in medicine (e.g., diabetic wound healing, tissue regeneration, and cancer therapy).&#13;
Specific attention is given to three types of growth factors: vascular endothelial growth factors, human fibroblast growth factors, and neurotrophins, as well as selected biocompatible synthetic macroions (obtained through standard polymerization techniques) and polysaccharides (natural macroions composed of repeating monomeric units of monosaccharides). Understanding the mechanisms by which growth factors bind to potential carriers could lead to more effective delivery methods for these proteins, which are of significant interest in the diagnosis and treatment of neurodegenerative and civilization diseases, as well as in the healing of chronic wounds.</abstract>
    <parentTitle language="eng">Biomolecules</parentTitle>
    <identifier type="doi">10.3390/biom13040609</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-579820</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">26.07.2023</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>A. Michna</author>
    <author>A. Pomorksa</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polyelectrolytes</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polysaccharides</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Vascular endothelial growth factor</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Human fibroblast growth factors</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Neurotrophins</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Macroion/growth factor assemblies</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/57982/Biomolecules_2023.pdf</file>
  </doc>
  <doc>
    <id>63689</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>13</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>9</volume>
    <type>article</type>
    <publisherName>Springer Science and Business Media LLC</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Long-term corrosion studies of CrCoNi and CrMnFeCoNi in sulfuric acid</title>
    <abstract language="eng">This study investigates the long-term corrosion behavior of CrCoNi and CrMnFeCoNi MPEAs over 28 d in 1 M H2SO4. Corrosion progression and passive film evolution were analyzed using open circuit potential measurements, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. Unlike short-term polarization tests, where CrCoNi exhibited intergranular corrosion, long-term immersion resulted in a stable, Cr-rich passive oxide layer. In contrast, CrMnFeCoNi formed a porous mixed oxide layer, increasing its susceptibility to degradation and revealing a distinct corrosion mechanism. X-ray photoelectron spectroscopy tracking at weekly intervals showed that prolonged immersion led to the transformation of sulfide/sulfite species into a sulfate-containing surface film. This effect was only detectable in long-term corrosion studies. These findings provide new insights into the time-dependent degradation mechanisms of MPEAs and demonstrate that corrosion mechanisms differ significantly from short-term polarization tests. This highlights the need for long-term studies to properly assess material stability in practical applications.</abstract>
    <parentTitle language="eng">npj Materials Degradation</parentTitle>
    <identifier type="issn">2397-2106</identifier>
    <identifier type="doi">10.1038/s41529-025-00637-z</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-636895</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,13]],"date-time":"2025-07-13T10:40:04Z","timestamp":1752403204733,"version":"3.41.2"},"reference-count":70,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2025,7,13]],"date-time":"2025-07-13T00:00:00Z","timestamp":1752364800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"},{"start":{"date-parts":[[2025,7,13]],"date-time":"2025-07-13T00:00:00Z","timestamp":1752364800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["npj Mater Degrad"],"abstract":"&lt;jats:title&gt;Abstract&lt;\/jats:title&gt;\n          &lt;jats:p&gt;This study investigates the long-term corrosion behavior of CrCoNi and CrMnFeCoNi MPEAs over 28\u2009d in 1\u2009M H&lt;jats:sub&gt;2&lt;\/jats:sub&gt;SO&lt;jats:sub&gt;4&lt;\/jats:sub&gt;. Corrosion progression and passive film evolution were analyzed using open circuit potential measurements, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. Unlike short-term polarization tests, where CrCoNi exhibited intergranular corrosion, long-term immersion resulted in a stable, Cr-rich passive oxide layer. In contrast, CrMnFeCoNi formed a porous mixed oxide layer, increasing its susceptibility to degradation and revealing a distinct corrosion mechanism. X-ray photoelectron spectroscopy tracking at weekly intervals showed that prolonged immersion led to the transformation of sulfide\/sulfite species into a sulfate-containing surface film. This effect was only detectable in long-term corrosion studies. These findings provide new insights into the time-dependent degradation mechanisms of MPEAs and demonstrate that corrosion mechanisms differ significantly from short-term polarization tests. This highlights the need for long-term studies to properly assess material stability in practical applications.&lt;\/jats:p&gt;","DOI":"10.1038\/s41529-025-00637-z","type":"journal-article","created":{"date-parts":[[2025,7,13]],"date-time":"2025-07-13T10:14:23Z","timestamp":1752401663000},"update-policy":"https:\/\/doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Long-term corrosion studies of CrCoNi and CrMnFeCoNi in sulfuric acid"],"prefix":"10.1038","volume":"9","author":[{"given":"Annica","family":"Wetzel","sequence":"first","affiliation":[]},{"given":"Ann-Kathrin","family":"Hans","sequence":"additional","affiliation":[]},{"given":"Marcus","family":"von der Au","sequence":"additional","affiliation":[]},{"given":"Izabella","family":"Brand","sequence":"additional","affiliation":[]},{"given":"Gunther","family":"Wittstock","sequence":"additional","affiliation":[]},{"given":"Ozlem","family":"Ozcan","sequence":"additional","affiliation":[]},{"given":"Julia","family":"Witt","sequence":"additional","affiliation":[]}],"member":"297","published-online":{"date-parts":[[2025,7,13]]},"reference":[{"key":"637_CR1","doi-asserted-by":"crossref","first-page":"846","DOI":"10.1038\/s41578-024-00720-y","volume":"9","author":"LL Han","year":"2024","unstructured":"Han, L. L. et al. Multifunctional high-entropy materials. Nat. Rev. Mater. 9, 846\u2013865 (2024).","journal-title":"Nat. Rev. Mater."},{"key":"637_CR2","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1002\/adem.200300567","volume":"6","author":"JW Yeh","year":"2004","unstructured":"Yeh, J. W. et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299\u2013303 (2004).","journal-title":"Adv. Eng. Mater."},{"key":"637_CR3","doi-asserted-by":"crossref","first-page":"1759","DOI":"10.1007\/s11837-013-0761-6","volume":"65","author":"JW Yeh","year":"2013","unstructured":"Yeh, J. W. Alloy design strategies and future trends in high-entropy alloys. JOM 65, 1759\u20131771 (2013).","journal-title":"JOM"},{"key":"637_CR4","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1016\/j.matchemphys.2007.02.042","volume":"104","author":"T Kosec","year":"2007","unstructured":"Kosec, T. &amp; Milosev, I. Comparison of a ternary Cu-18Ni-20Zn alloy and binary Cu-based alloys in alkaline solutions. Mater. Chem. Phys. 104, 44\u201349 (2007).","journal-title":"Mater. Chem. Phys."},{"key":"637_CR5","doi-asserted-by":"publisher","unstructured":"Gao, L. B. et al. Microstructure, mechanical and corrosion behaviors of CoCrFeNiAl0.3 high entropy alloy (HEA) films. Coatings 7 https:\/\/doi.org\/10.3390\/coatings7100156 (2017).","DOI":"10.3390\/coatings7100156"},{"key":"637_CR6","volume":"9","author":"S Huang","year":"2018","unstructured":"Huang, S. et al. Twinning in metastable high-entropy alloys. Nat. Commun. 9, 2381 (2018).","journal-title":"Nat. Commun."},{"key":"637_CR7","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1038\/nature17981","volume":"534","author":"Z Li","year":"2016","unstructured":"Li, Z., Pradeep, K. G., Deng, Y., Raabe, D. &amp; Tasan, C. C. Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off. Nature 534, 227\u2013230 (2016).","journal-title":"Nature"},{"key":"637_CR8","doi-asserted-by":"crossref","first-page":"933","DOI":"10.1126\/science.aas8815","volume":"362","author":"T Yang","year":"2018","unstructured":"Yang, T. et al. Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys. Science 362, 933\u2013937 (2018).","journal-title":"Science"},{"key":"637_CR9","volume":"6","author":"Z Zhang","year":"2015","unstructured":"Zhang, Z. et al. Nanoscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi. Nat. Commun. 6, 10143 (2015).","journal-title":"Nat. Commun."},{"key":"637_CR10","doi-asserted-by":"publisher","unstructured":"Zhao, R.-F. et al. Corrosion behavior of CoxCrCuFeMnNi high-entropy alloys prepared by hot pressing sintered in 3.5% NaCl solution. Results Phys. 15 https:\/\/doi.org\/10.1016\/j.rinp.2019.102667 (2019).","DOI":"10.1016\/j.rinp.2019.102667"},{"key":"637_CR11","doi-asserted-by":"crossref","first-page":"14729","DOI":"10.1007\/s10853-018-2652-2","volume":"53","author":"BL Zhang","year":"2018","unstructured":"Zhang, B. L., Zhang, Y. &amp; Guo, S. M. A thermodynamic study of corrosion behaviors for CoCrFeNi-based high-entropy alloys. J. Mater. Sci. 53, 14729\u201314738 (2018).","journal-title":"J. Mater. Sci."},{"key":"637_CR12","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1016\/j.corsci.2018.10.025","volume":"146","author":"L Wei","year":"2019","unstructured":"Wei, L., Liu, Y., Li, Q. &amp; Cheng, Y. F. Effect of roughness on general corrosion and pitting of (FeCoCrNi)0.89(WC)0.11 high-entropy alloy composite in 3.5 wt.% NaCl solution. Corros. Sci. 146, 44\u201357 (2019).","journal-title":"Corros. Sci."},{"key":"637_CR13","doi-asserted-by":"publisher","unstructured":"Wang, J. et al. Tribocorrosion behavior of high-entropy alloys FeCrNiCoM (M = Al, Mo) in artificial seawater. Corros. Sci. 218 https:\/\/doi.org\/10.1016\/j.corsci.2023.111165 (2023).","DOI":"10.1016\/j.corsci.2023.111165"},{"key":"637_CR14","doi-asserted-by":"publisher","unstructured":"Sun, Y., Lan, A., Wang, Z., Zhang, M. &amp; Qiao, J. Effect of sulfuric acid concentration on corrosion behavior of Al0.1CoCrFeNi high-entropy alloy. J. Phys. Chem. Solids 161 https:\/\/doi.org\/10.1016\/j.jpcs.2021.110397 (2022).","DOI":"10.1016\/j.jpcs.2021.110397"},{"key":"637_CR15","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1016\/j.corsci.2018.01.030","volume":"133","author":"Y Shi","year":"2018","unstructured":"Shi, Y. et al. Homogenization of Al CoCrFeNi high-entropy alloys with improved corrosion resistance. Corros. Sci. 133, 120\u2013131 (2018).","journal-title":"Corros. Sci."},{"key":"637_CR16","doi-asserted-by":"publisher","unstructured":"Muangtong, P., Rodchanarowan, A., Chaysuwan, D., Chanlek, N. &amp; Goodall, R. The corrosion behaviour of CoCrFeNi-x (x=Cu, Al, Sn) high entropy alloy systems in chloride solution. Corros. Sci. 172 https:\/\/doi.org\/10.1016\/j.corsci.2020.108740 (2020).","DOI":"10.1016\/j.corsci.2020.108740"},{"key":"637_CR17","doi-asserted-by":"crossref","first-page":"1675","DOI":"10.1007\/s11696-021-01975-3","volume":"76","author":"GA Gaber","year":"2022","unstructured":"Gaber, G. A., Abolkassem, S. A., Elkady, O. A., Tash, M. &amp; Mohamed, L. Z. ANOVA and DOE of comparative studies of Cu\/Mn effect on corrosion features of CoCrFeNi high entropy alloy immersed in different acidic media. Chem. Pap. 76, 1675\u20131690 (2022).","journal-title":"Chem. Pap."},{"key":"637_CR18","doi-asserted-by":"crossref","first-page":"1420","DOI":"10.1016\/j.apsusc.2016.11.176","volume":"396","author":"QF Ye","year":"2017","unstructured":"Ye, Q. F. et al. Microstructure and corrosion properties of CrMnFeCoNi high entropy alloy coating. Appl. Surf. Sci. 396, 1420\u20131426 (2017).","journal-title":"Appl. Surf. Sci."},{"key":"637_CR19","doi-asserted-by":"crossref","first-page":"1375","DOI":"10.1007\/s11666-022-01364-6","volume":"31","author":"BW Xing","year":"2022","unstructured":"Xing, B. W. et al. Influence of microstructure evolution on the electrochemical corrosion behavior of (CoCrFeNi)TiAl high entropy alloy coatings. J. Therm. Spray. Technol. 31, 1375\u20131385 (2022).","journal-title":"J. Therm. Spray. Technol."},{"key":"637_CR20","doi-asserted-by":"publisher","unstructured":"Popescu, A. M. J. et al. Influence of heat treatment on the corrosion behavior of electrodeposited CoCrFeMnNi high-entropy alloy thin films. Coatings 12 https:\/\/doi.org\/10.3390\/coatings12081108 (2022).","DOI":"10.3390\/coatings12081108"},{"key":"637_CR21","doi-asserted-by":"crossref","first-page":"1235","DOI":"10.1179\/1743284715Y.0000000026","volume":"31","author":"Y Qiu","year":"2015","unstructured":"Qiu, Y., Gibson, M. A., Fraser, H. L. &amp; Birbilis, N. Corrosion characteristics of high entropy alloys. Mater. Sci. Technol. 31, 1235\u20131243 (2015).","journal-title":"Mater. Sci. Technol."},{"key":"637_CR22","volume":"1","author":"Y Qiu","year":"2017","unstructured":"Qiu, Y., Thomas, S., Gibson, M. A., Fraser, H. L. &amp; Birbilis, N. Corrosion of high entropy alloys. npj Mater. Degrad. 1, 15 (2017).","journal-title":"npj Mater. Degrad."},{"key":"637_CR23","doi-asserted-by":"crossref","first-page":"081509","DOI":"10.1149\/1945-7111\/ab8ddf","volume":"167","author":"JT Moon","year":"2020","unstructured":"Moon, J. T., Schindelholz, E. J., Melia, M. A., Kustas, A. B. &amp; Chidambaram, D. Corrosion of additively manufactured CoCrFeMnNi high entropy alloy in molten NaNO3-KNO3. J. Electrochem. Soc. 167, 081509 (2020).","journal-title":"J. Electrochem. Soc."},{"key":"637_CR24","doi-asserted-by":"crossref","first-page":"741","DOI":"10.1149\/07711.0741ecst","volume":"77","author":"A Rodriguez","year":"2017","unstructured":"Rodriguez, A., Tylczak, J. H. &amp; Ziomek-Moroz, M. Corrosion behavior of CoCrFeMnNi high-entropy alloys (HEAs) under acidic aqueous conditions. ECS Trans. 77, 741\u2013752 (2017).","journal-title":"ECS Trans."},{"key":"637_CR25","doi-asserted-by":"crossref","DOI":"10.1016\/j.matchemphys.2022.127123","volume":"295","author":"RI Bogdanov","year":"2023","unstructured":"Bogdanov, R. I. et al. Corrosion and electrochemical behavior of Co\u0421rFeNiMo high-entropy alloy in acidic oxidizing and neutral chloride solutions. Mater. Chem. Phys. 295, 127123 (2023).","journal-title":"Mater. Chem. Phys."},{"key":"637_CR26","volume":"183","author":"P Wu","year":"2021","unstructured":"Wu, P., Gan, K., Yan, D., Fu, Z. &amp; Li, Z. A non-equiatomic FeNiCoCr high-entropy alloy with excellent anti-corrosion performance and strength-ductility synergy. Corros. Sci. 183, 109341 (2021).","journal-title":"Corros. Sci."},{"key":"637_CR27","volume":"819","author":"J Yang","year":"2020","unstructured":"Yang, J. et al. Effects of Mn on the electrochemical corrosion and passivation behavior of CoFeNiMnCr high-entropy alloy system in H2SO4 solution. J. Alloy. Compd. 819, 152943 (2020).","journal-title":"J. Alloy. Compd."},{"key":"637_CR28","volume":"190","author":"K-M Hsu","year":"2021","unstructured":"Hsu, K.-M., Chen, S.-H. &amp; Lin, C.-S. Microstructure and corrosion behavior of FeCrNiCoMnx (x = 1.0, 0.6, 0.3, 0) high entropy alloys in 0.5 M H2SO4. Corros. Sci. 190, 109694 (2021).","journal-title":"Corros. Sci."},{"key":"637_CR29","doi-asserted-by":"crossref","first-page":"C3241","DOI":"10.1149\/2.0261911jes","volume":"166","author":"KL Cwalina","year":"2019","unstructured":"Cwalina, K. L. et al. In operando analysis of passive film growth on Ni-Cr and Ni-Cr-Mo alloys in chloride solutions. J. Electrochem. Soc. 166, C3241\u2013C3253 (2019).","journal-title":"J. Electrochem. Soc."},{"key":"637_CR30","doi-asserted-by":"crossref","first-page":"1443","DOI":"10.1016\/S0010-938X(01)00147-0","volume":"44","author":"D Hamm","year":"2002","unstructured":"Hamm, D., Ogle, K., Olsson, C. O. A., Weber, S. &amp; Landolt, D. Passivation of Fe-Cr alloys studied with ICP-AES and EQCM. Corros. Sci. 44, 1443\u20131456 (2002).","journal-title":"Corros. Sci."},{"key":"637_CR31","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.electacta.2019.03.104","volume":"306","author":"TS Li","year":"2019","unstructured":"Li, T. S. et al. Localized corrosion behavior of a single-phase non-equimolar high entropy alloy. Electrochim. Acta 306, 71\u201384 (2019).","journal-title":"Electrochim. Acta"},{"key":"637_CR32","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1016\/j.actamat.2018.10.026","volume":"164","author":"KF Quiambao","year":"2019","unstructured":"Quiambao, K. F. et al. Passivation of a corrosion resistant high entropy alloy in non-oxidizing sulfate solutions. Acta Mater. 164, 362\u2013376 (2019).","journal-title":"Acta Mater."},{"key":"637_CR33","doi-asserted-by":"crossref","first-page":"2679","DOI":"10.1016\/j.corsci.2004.09.026","volume":"47","author":"YY Chen","year":"2005","unstructured":"Chen, Y. Y., Hong, U. T., Shih, H. C., Yeh, J. W. &amp; Duval, T. Electrochemical kinetics of the high entropy alloys in aqueous environments\u2014a comparison with type 304 stainless steel. Corros. Sci. 47, 2679\u20132699 (2005).","journal-title":"Corros. Sci."},{"key":"637_CR34","volume":"200","author":"XY Wang","year":"2022","unstructured":"Wang, X. Y. et al. Enhanced passivity of Cr-Fe-Co-Ni-Mo multi-component single-phase face-centred cubic alloys: design, production and corrosion behaviour. Corros. Sci. 200, 110233 (2022).","journal-title":"Corros. Sci."},{"key":"637_CR35","doi-asserted-by":"crossref","DOI":"10.1016\/j.corsci.2024.111855","volume":"229","author":"J Czerski","year":"2024","unstructured":"Czerski, J. et al. Corrosion and passivation of AlCrFe2Ni2Mox high-entropy alloys in sulphuric acid. Corros. Sci. 229, 111855 (2024).","journal-title":"Corros. Sci."},{"key":"637_CR36","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2022.154171","volume":"601","author":"A Wetzel","year":"2022","unstructured":"Wetzel, A. et al. The comparison of the corrosion behavior of the CrCoNi medium entropy alloy and CrMnFeCoNi high entropy alloy. Appl. Surf. Sci. 601, 154171 (2022).","journal-title":"Appl. Surf. Sci."},{"key":"637_CR37","first-page":"7020043","volume":"7","author":"YZ Shi","year":"2017","unstructured":"Shi, Y. Z., Yang, B. &amp; Liaw, P. K. Corrosion-resistant high-entropy alloys: a review. Metals 7, 7020043 (2017).","journal-title":"Metals"},{"key":"637_CR38","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1016\/j.scriptamat.2020.06.065","volume":"188","author":"JR Scully","year":"2020","unstructured":"Scully, J. R. et al. Controlling the corrosion resistance of multi-principal element alloys. Scr. Mater. 188, 96\u2013101 (2020).","journal-title":"Scr. Mater."},{"key":"637_CR39","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/j.corsci.2018.02.031","volume":"134","author":"H Luo","year":"2018","unstructured":"Luo, H., Li, Z. M., Mingers, A. M. &amp; Raabe, D. Corrosion behavior of an equiatomic CoCrFeMnNi high-entropy alloy compared with 304 stainless steel in sulfuric acid solution. Corros. Sci. 134, 131\u2013139 (2018).","journal-title":"Corros. Sci."},{"key":"637_CR40","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/j.intermet.2017.06.002","volume":"89","author":"J Jayaraj","year":"2017","unstructured":"Jayaraj, J., Thinaharan, C., Ningshen, S., Mallika, C. &amp; Kamachi Mudali, U. Corrosion behavior and surface film characterization of TaNbHfZrTi high entropy alloy in aggressive nitric acid medium. Intermetallics 89, 123\u2013132 (2017).","journal-title":"Intermetallics"},{"key":"637_CR41","volume":"167","author":"LT Wang","year":"2020","unstructured":"Wang, L. T. et al. Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMS. Corros. Sci. 167, 108507 (2020).","journal-title":"Corros. Sci."},{"key":"637_CR42","volume":"170","author":"Y Qiu","year":"2019","unstructured":"Qiu, Y. et al. Microstructural evolution, electrochemical and corrosion properties of Al CoCrFeNiTi high entropy alloys. Mater. Des. 170, 107698 (2019).","journal-title":"Mater. Des."},{"key":"637_CR43","volume":"7","author":"XY Wang","year":"2023","unstructured":"Wang, X. Y. et al. Origin of enhanced passivity of Cr-Fe-Co-Ni-Mo multi-principal element alloy surfaces. npj Mater. Degrad. 7, 13 (2023).","journal-title":"npj Mater. Degrad."},{"key":"637_CR44","doi-asserted-by":"crossref","first-page":"16367","DOI":"10.1021\/acs.jpcc.3c02830","volume":"127","author":"CK Li","year":"2023","unstructured":"Li, C. K., Peng, Z. Q. &amp; Huang, J. Impedance response of electrochemical interfaces: part IV-lowfrequency inductive loop for a single-electron reaction. J. Phys. Chem. C. 127, 16367\u201316373 (2023).","journal-title":"J. Phys. Chem. C."},{"key":"637_CR45","doi-asserted-by":"crossref","first-page":"462","DOI":"10.1016\/j.corsci.2019.06.024","volume":"157","author":"CC Yen","year":"2019","unstructured":"Yen, C. C. et al. Corrosion mechanism of annealed equiatomic AlCoCrFeNi tri-phase high-entropy alloy in 0.5 M H2SO4 aerated aqueous solution. Corros. Sci. 157, 462\u2013471 (2019).","journal-title":"Corros. Sci."},{"key":"637_CR46","doi-asserted-by":"crossref","first-page":"2717","DOI":"10.1016\/j.apsusc.2010.10.051","volume":"257","author":"MC Biesinger","year":"2011","unstructured":"Biesinger, M. C. et al. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl. Surf. Sci. 257, 2717\u20132730 (2011).","journal-title":"Appl. Surf. Sci."},{"key":"637_CR47","unstructured":"Moulder, J. F., Stickle, W. F., Sobol, P. E. &amp; Bomben, K. D. Handbook of X-ray photoelectron spectroscopy. 1 edn, (Perkin-Elmer-Corporation, 1992)."},{"key":"637_CR48","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1016\/j.elspec.2010.12.001","volume":"184","author":"BP Payne","year":"2011","unstructured":"Payne, B. P., Biesinger, M. C. &amp; McIntyre, N. S. X-ray photoelectron spectroscopy studies of reactions on chromium metal and chromium oxide surfaces. J. Electron. Spectrosc. Relat. Phenom. 184, 29\u201337 (2011).","journal-title":"J. Electron. Spectrosc. Relat. Phenom."},{"key":"637_CR49","doi-asserted-by":"crossref","first-page":"7575","DOI":"10.1039\/C4RA15097J","volume":"5","author":"Y Lei","year":"2015","unstructured":"Lei, Y., Wang, Y. Y., Yang, W., Yuan, H. Y. &amp; Xiao, D. Self-assembled hollow urchin-like NiCo2O4 microspheres for aqueous asymmetric supercapacitors. Rsc Adv. 5, 7575\u20137583 (2015).","journal-title":"Rsc Adv."},{"key":"637_CR50","doi-asserted-by":"crossref","first-page":"67839","DOI":"10.1039\/C6RA14099H","volume":"6","author":"MJ Pang","year":"2016","unstructured":"Pang, M. J. et al. Mesoporous NiCo2O4 nanospheres with a high specific surface area as electrode materials for high-performance supercapacitors. Rsc Adv. 6, 67839\u201367848 (2016).","journal-title":"Rsc Adv."},{"key":"637_CR51","doi-asserted-by":"crossref","first-page":"1771","DOI":"10.1016\/j.susc.2006.01.041","volume":"600","author":"AP Grosvenor","year":"2006","unstructured":"Grosvenor, A. P., Biesinger, M. C., Smart, R. S. &amp; McIntyre, N. S. New interpretations of XPS spectra of nickel metal and oxides. Surf. Sci. 600, 1771\u20131779 (2006).","journal-title":"Surf. Sci."},{"key":"637_CR52","doi-asserted-by":"crossref","first-page":"1939","DOI":"10.1016\/j.corsci.2004.01.007","volume":"46","author":"P Keller","year":"2004","unstructured":"Keller, P. &amp; Strehblow, H. H. XPS investigations of electrochemically formed passive layers on Fe\/Cr-alloys in 0.5 M H2SO4. Corros. Sci. 46, 1939\u20131952 (2004).","journal-title":"Corros. Sci."},{"key":"637_CR53","doi-asserted-by":"crossref","first-page":"975","DOI":"10.1007\/s12540-012-6009-0","volume":"18","author":"SA Park","year":"2012","unstructured":"Park, S. A., Lee, S. H. &amp; Kim, J. G. Effect of chromium on the corrosion behavior of low alloy steel in sulfuric acid. Met. Mater. Int. 18, 975\u2013987 (2012).","journal-title":"Met. Mater. Int."},{"key":"637_CR54","doi-asserted-by":"crossref","first-page":"5105","DOI":"10.1016\/j.jmrt.2023.08.198","volume":"26","author":"A Ouarga","year":"2023","unstructured":"Ouarga, A. et al. Corrosion of iron and nickel based alloys in sulphuric acid: Challenges and prevention strategies. J. Mater. Res Technol. 26, 5105\u20135125 (2023).","journal-title":"J. Mater. Res Technol."},{"key":"637_CR55","doi-asserted-by":"crossref","first-page":"1550","DOI":"10.1002\/sia.1983","volume":"36","author":"MC Biesinger","year":"2004","unstructured":"Biesinger, M. C., Brown, C., Mycroft, J. R., Davidson, R. D. &amp; McIntyre, N. S. X-ray photoelectron spectroscopy studies of chromium compounds. Surf. Interface Anal. 36, 1550\u20131563 (2004).","journal-title":"Surf. Interface Anal."},{"key":"637_CR56","doi-asserted-by":"crossref","first-page":"974","DOI":"10.1002\/maco.202012191","volume":"72","author":"N Wurzler","year":"2021","unstructured":"Wurzler, N., Sobol, O., Altmann, K., Radnik, J. &amp; Ozcan, O. Preconditioning of AISI 304 stainless steel surfaces in the presence of flavins-Part I: effect on surface chemistry and corrosion behavior. Mater. Corros. Werkst. Korros. 72, 974\u2013982 (2021).","journal-title":"Mater. Corros. Werkst. Korros."},{"key":"637_CR57","doi-asserted-by":"crossref","first-page":"265","DOI":"10.1002\/(SICI)1096-9918(200004)29:4&lt;265::AID-SIA739&gt;3.0.CO;2-3","volume":"29","author":"AA Audi","year":"2000","unstructured":"Audi, A. A. &amp; Sherwood, P. M. A. X-ray photoelectron spectroscopic studies of sulfate and bisulfate interpreted by Xa and band stucture calcualtions. Surf. Interface Anal. 29, 265\u2013275 (2000).","journal-title":"Surf. Interface Anal."},{"key":"637_CR58","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1016\/j.actamat.2017.02.036","volume":"128","author":"G Laplanche","year":"2017","unstructured":"Laplanche, G. et al. Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi. Acta Mater. 128, 292\u2013303 (2017).","journal-title":"Acta Mater."},{"key":"637_CR59","first-page":"2023014","volume":"3","author":"W Tian","year":"2023","unstructured":"Tian, W. et al. The effect of chromium content on the corrosion behavior of ultrafine-grained CrxMnFeCoNi high-entropy alloys in sulfuric acid solution. Microstructures 3, 2023014 (2023).","journal-title":"Microstructures"},{"key":"637_CR60","doi-asserted-by":"crossref","first-page":"1093","DOI":"10.1016\/S0013-4686(02)00841-1","volume":"48","author":"COA Olsson","year":"2003","unstructured":"Olsson, C. O. A. &amp; Landolt, D. Passive films on stainless steels*chemistry, structure and growth. Electrochim. Acta 48, 1093\u20131104 (2003).","journal-title":"Electrochim. Acta"},{"key":"637_CR61","doi-asserted-by":"crossref","first-page":"87","DOI":"10.1016\/0013-4686(96)00170-3","volume":"42","author":"M Keddam","year":"1997","unstructured":"Keddam, M., Kuntz, C., Takenouti, H., Schuster, D. &amp; Zuili, D. Exfoliation corrosion of aluminium alloys examined by electrode impedance. Electrochim. Acta 42, 87\u201397 (1997).","journal-title":"Electrochim. Acta"},{"key":"637_CR62","doi-asserted-by":"crossref","first-page":"1177","DOI":"10.1016\/S0010-938X(01)00145-7","volume":"44","author":"HY Ma","year":"2002","unstructured":"Ma, H. Y., Li, G. Q., Chen, S. C., Zhao, S. Y. &amp; Cheng, X. L. Impedance investigation of the anodic iron dissolution in perchloric acid solution. Corros. Sci. 44, 1177\u20131191 (2002).","journal-title":"Corros. Sci."},{"key":"637_CR63","doi-asserted-by":"crossref","first-page":"673","DOI":"10.1016\/S0010-938X(69)80098-3","volume":"9","author":"G Gilli","year":"1969","unstructured":"Gilli, G., Borea, P. &amp; Zucchi, F. &amp; Trabanel.G. Passivation of Ni caused by layers of salts in concentrated H2SO4. Corros. Sci. 9, 673 (1969). &amp;.","journal-title":"Corros. Sci."},{"key":"637_CR64","doi-asserted-by":"crossref","first-page":"927","DOI":"10.1016\/0013-4686(67)80093-8","volume":"12","author":"U Ebersbach","year":"1967","unstructured":"Ebersbach, U., Schwabe, K. &amp; Ritter, K. On the kinetics of the anodic passivation of iron, cobalt and nickel. Electrochim. Acta 12, 927\u2013938 (1967).","journal-title":"Electrochim. Acta"},{"key":"637_CR65","doi-asserted-by":"crossref","first-page":"3637","DOI":"10.1149\/1.1393952","volume":"147","author":"JR Kish","year":"2000","unstructured":"Kish, J. R., Ives, M. B. &amp; Rodda, J. R. Corrosion mechanism of nickel in hot, concentrated H2SO4. J. Electrochem. Soc. 147, 3637 (2000).","journal-title":"J. Electrochem. Soc."},{"key":"637_CR66","doi-asserted-by":"crossref","first-page":"3812","DOI":"10.1016\/j.corsci.2006.01.009","volume":"48","author":"Y Zhang","year":"2006","unstructured":"Zhang, Y., Macdonald, D. D., Urquidi-Macdonald, M., Engelhardt, G. R. &amp; Dooley, R. B. Passivity breakdown on AISI Type 403 stainless steel in chloride-containing borate buffer solution. Corros. Sci. 48, 3812\u20133823 (2006).","journal-title":"Corros. Sci."},{"key":"637_CR67","doi-asserted-by":"crossref","first-page":"421","DOI":"10.1016\/j.jelechem.2004.05.032","volume":"572","author":"DD Macdonald","year":"2004","unstructured":"Macdonald, D. D., Sun, A., Priyantha, N. &amp; Jayaweera, P. An electrochemical impedance study of alloy-22 in NaCl brine at elevated temperature: II. Reaction mechanism analysis. J. Electroanal. Chem. 572, 421\u2013431 (2004).","journal-title":"J. Electroanal. Chem."},{"key":"637_CR68","volume":"237","author":"MZ Chen","year":"2024","unstructured":"Chen, M. Z. et al. Insights into the passivity and electrochemistry of CoCrFeMnNi high entropy alloy fabricated by underwater laser direct metal deposition. Corros. Sci. 237, 112289 (2024).","journal-title":"Corros. Sci."},{"key":"637_CR69","doi-asserted-by":"crossref","first-page":"338","DOI":"10.1016\/j.actamat.2018.09.040","volume":"161","author":"G Laplanche","year":"2018","unstructured":"Laplanche, G. et al. Phase stability and kinetics of a \u03c3-phase precipitation in CrMnFeCoNi high-entropy alloys. Acta Mater. 161, 338\u2013351 (2018).","journal-title":"Acta Mater."},{"key":"637_CR70","doi-asserted-by":"crossref","first-page":"C563","DOI":"10.1149\/2.1061709jes","volume":"164","author":"YM Chen","year":"2017","unstructured":"Chen, Y. M., Rudawski, N. G., Lambers, E. &amp; Orazem, M. E. Application of impedance spectroscopy and surface analysis to obtain oxide film thickness. J. Electrochem. Soc. 164, C563\u2013C573 (2017).","journal-title":"J. Electrochem. Soc."}],"container-title":["npj Materials Degradation"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.nature.com\/articles\/s41529-025-00637-z.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41529-025-00637-z","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.nature.com\/articles\/s41529-025-00637-z.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,7,13]],"date-time":"2025-07-13T10:14:31Z","timestamp":1752401671000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.nature.com\/articles\/s41529-025-00637-z"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,13]]},"references-count":70,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2025,12]]}},"alternative-id":["637"],"URL":"https:\/\/doi.org\/10.1038\/s41529-025-00637-z","relation":{},"ISSN":["2397-2106"],"issn-type":[{"value":"2397-2106","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,13]]},"assertion":[{"value":"14 February 2025","order":1,"name":"received","label":"Received","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"28 June 2025","order":2,"name":"accepted","label":"Accepted","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"13 July 2025","order":3,"name":"first_online","label":"First Online","group":{"name":"ArticleHistory","label":"Article History"}},{"value":"The authors declare that they have no known competing financial interests or personal relationship that could have appeared to influence the work reported in this paper.","order":1,"name":"Ethics","group":{"name":"EthicsHeading","label":"Competing interests"}}],"article-number":"86"}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://creativecommons.org/licenses/by/4.0</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PublisherName,TitleMain_1,Language,TitleAbstract_1,TitleParent_1,ArticleNumber,Issue,Volume,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="date_peer_review">28.07.2025</enrichment>
    <enrichment key="PaperofMonth">1</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Annica Wetzel</author>
    <author>Ann-Kathrin Hans</author>
    <author>Marcus von der Au</author>
    <author>Izabella Brand</author>
    <author>Gunther Wittstock</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Long-term corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multi-principal element alloys (MPEAs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>X-ray photoelectron spectroscopy (XPS)</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/63689/2025.Wetzel_et_al.npjMaterDeg.9.86.pdf</file>
  </doc>
  <doc>
    <id>62556</id>
    <completedYear/>
    <publishedYear>2025</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>14</pageLast>
    <pageNumber/>
    <edition/>
    <issue>4</issue>
    <volume>15</volume>
    <type>article</type>
    <publisherName>MDPI</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Deposition and Characterization of Cu-Enhanced High-Entropy Alloy Coatings via DC Magnetron Sputtering</title>
    <abstract language="eng">Protection against microbiologically influenced corrosion (MIC) is critical for materials used in aquatic environments, as MIC accelerates material degradation and leads to faster structural failure. Copper (Cu) has the potential to substantially improve the MIC resistance in alloys. In this study, high-entropy alloy (HEA) coatings containing Cu were deposited using DC (Direct Current) magnetron sputtering to enhance the corrosion resistance and mechanical properties of various substrates. Two CuCrFeMnNi HEA compositions in the form of bulk alloys and PVD (Physical Vapor Deposition) coatings, with 5% and 10% Cu, were analyzed for their microstructural, mechanical, and anticorrosive characteristics. Deposition parameters were varied to select the optimal values. Microstructural evaluations using SEM-EDS (scanning electron microscopy and energy dispersive X-ray spectroscopy), XRD (X-ray diffraction), and AFM (atomic force microscopy) revealed uniform, dense coatings with good adhesion composed of dendritic and interdendritic BCC (body-centered cubic) and FCC (face centered cubic) structures, respectively. Microhardness tests indicated improved mechanical properties for the samples coated with developed HEAs. The coatings exhibited improved corrosion resistance in NaCl solution, the 10% Cu composition displaying the highest polarization resistance and lowest corrosion rate. These findings suggest that Cu-containing HEA coatings are promising candidates for applications requiring enhanced corrosion protection.</abstract>
    <parentTitle language="eng">Applied Sciences</parentTitle>
    <identifier type="doi">10.3390/app15041917</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-625561</identifier>
    <identifier type="issn">2076-3417</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,12]],"date-time":"2025-02-12T16:41:40Z","timestamp":1739378500397,"version":"3.37.0"},"reference-count":26,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2025,2,12]],"date-time":"2025-02-12T00:00:00Z","timestamp":1739318400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"European Union\u2014NextGenerationEU","award":["PNRR\/2022\/C9\/MCID\/I8","CF58\/14.11.2022","760105\/23.05.2023"]},{"DOI":"10.13039\/501100000921","name":"COST","doi-asserted-by":"crossref","award":["EU-MACE CA22123"],"id":[{"id":"10.13039\/501100000921","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Applied Sciences"],"abstract":"&lt;jats:p&gt;Protection against microbiologically influenced corrosion (MIC) is critical for materials used in aquatic environments, as MIC accelerates material degradation and leads to faster structural failure. Copper (Cu) has the potential to substantially improve the MIC resistance in alloys. In this study, high-entropy alloy (HEA) coatings containing Cu were deposited using DC (Direct Current) magnetron sputtering to enhance the corrosion resistance and mechanical properties of various substrates. Two CuCrFeMnNi HEA compositions in the form of bulk alloys and PVD (Physical Vapor Deposition) coatings, with 5% and 10% Cu, were analyzed for their microstructural, mechanical, and anticorrosive characteristics. Deposition parameters were varied to select the optimal values. Microstructural evaluations using SEM-EDS (scanning electron microscopy and energy dispersive X-ray spectroscopy), XRD (X-ray diffraction), and AFM (atomic force microscopy) revealed uniform, dense coatings with good adhesion composed of dendritic and interdendritic BCC (body-centered cubic) and FCC (face centered cubic) structures, respectively. Microhardness tests indicated improved mechanical properties for the samples coated with developed HEAs. The coatings exhibited improved corrosion resistance in NaCl solution, the 10% Cu composition displaying the highest polarization resistance and lowest corrosion rate. These findings suggest that Cu-containing HEA coatings are promising candidates for applications requiring enhanced corrosion protection.&lt;\/jats:p&gt;","DOI":"10.3390\/app15041917","type":"journal-article","created":{"date-parts":[[2025,2,12]],"date-time":"2025-02-12T15:25:57Z","timestamp":1739373957000},"page":"1917","source":"Crossref","is-referenced-by-count":0,"title":["Deposition and Characterization of Cu-Enhanced High-Entropy Alloy Coatings via DC Magnetron Sputtering"],"prefix":"10.3390","volume":"15","author":[{"given":"Arcadii","family":"Sobetkii","sequence":"first","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8105-6609","authenticated-orcid":false,"given":"Laurentiu-Florin","family":"Mosinoiu","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7898-8774","authenticated-orcid":false,"given":"Stefania","family":"Caramarin","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8306-9246","authenticated-orcid":false,"given":"Dumitru","family":"Mitrica","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3902-5876","authenticated-orcid":false,"given":"Laura-Madalina","family":"Cursaru","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"given":"Alexandru-Cristian","family":"Matei","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2964-6764","authenticated-orcid":false,"given":"Ioan-Albert","family":"Tudor","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"given":"Beatrice-Adriana","family":"Serban","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"given":"Mihai","family":"Ghita","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"given":"Nicoleta","family":"Vitan","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"}]},{"given":"Julia","family":"Witt","sequence":"additional","affiliation":[{"name":"Federal Institute of Materials Research and Testing (BAM), 12205 Berlin, Germany"}]},{"given":"Ozlem","family":"Ozcan","sequence":"additional","affiliation":[{"name":"Federal Institute of Materials Research and Testing (BAM), 12205 Berlin, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3426-5085","authenticated-orcid":false,"given":"Bogdan","family":"Postolnyi","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"},{"name":"Institute of Physics for Advanced Materials, Nanotechnology and Photonics, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"},{"name":"Faculty of Electronics and Information Technologies, Sumy State University, 116 Kharkivska St., 40007 Sumy, Ukraine"}]},{"given":"Alexander","family":"Pogrebnjak","sequence":"additional","affiliation":[{"name":"National R&amp;D Institute for Non-Ferrous and Rare Metals\u2014IMNR, 102 Biruintei Blvd, 077145 Pantelimon, Romania"},{"name":"Faculty of Electronics and Information Technologies, Sumy State University, 116 Kharkivska St., 40007 Sumy, Ukraine"},{"name":"Faculty of Material Science and Technology in Trnava, Institute Materials, Slovak University of Technology in Bratislava, 91724 Trnava, Slovakia"}]}],"member":"1968","published-online":{"date-parts":[[2025,2,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Knisz, J., Eckert, R., Gieg, L.M., Koerdt, A., Lee, J.S., Silva, E.R., Skovhus, T.L., An Stepec, B.A., and Wade, S.A. (2023). Microbiologically Influenced Corrosion\u2014More than Just Microorganisms. FEMS Microbiol. Rev., 47.","DOI":"10.1093\/femsre\/fuad041"},{"key":"ref_2","unstructured":"Javaherdashti, R. (2008). Microbiologically Influenced Corrosion. An Engineering Insight, Springer."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1016\/j.colsurfb.2011.04.025","article-title":"The Perfect Slime","volume":"86","author":"Flemming","year":"2011","journal-title":"Colloids Surf. B Biointerfaces"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"1226","DOI":"10.1128\/AEM.02848-13","article-title":"Corrosion of Iron by Sulfate-Reducing Bacteria: New Views of an Old Problem","volume":"80","author":"Enning","year":"2014","journal-title":"Appl. Environ. Microbiol."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"542","DOI":"10.1038\/ismej.2014.169","article-title":"The Dual Role of Microbes in Corrosion","volume":"9","author":"Kip","year":"2015","journal-title":"ISME J."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1002\/adem.200300567","article-title":"Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes","volume":"6","author":"Yeh","year":"2004","journal-title":"Adv. Eng. Mater."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"2628","DOI":"10.1016\/j.actamat.2013.01.042","article-title":"Relative Effects of Enthalpy and Entropy on the Phase Stability of Equiatomic High-Entropy Alloys","volume":"61","author":"Otto","year":"2013","journal-title":"Acta Mater."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.pmatsci.2013.10.001","article-title":"Microstructures and Properties of High-Entropy Alloys","volume":"61","author":"Zhang","year":"2014","journal-title":"Prog. Mater. Sci."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"448","DOI":"10.1016\/j.actamat.2016.08.081","article-title":"A Critical Review of High Entropy Alloys and Related Concepts","volume":"122","author":"Miracle","year":"2017","journal-title":"Acta Mater."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Caramarin, S., Badea, I.-C., Mosinoiu, L.-F., Mitrica, D., Serban, B.-A., Vitan, N., Cursaru, L.-M., and Pogrebnjak, A. (2024). Structural Particularities, Prediction, and Synthesis Methods in High-Entropy Alloys. Appl. Sci., 14.","DOI":"10.3390\/app14177576"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1900343","DOI":"10.1002\/adem.201900343","article-title":"A Review on High Entropy Alloys Coatings: Fabrication Processes and Property Assessment","volume":"21","author":"Li","year":"2019","journal-title":"Adv. Eng. Mater."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"022002","DOI":"10.1088\/2752-5724\/ac5e0c","article-title":"Properties and Processing Technologies of High-Entropy Alloys","volume":"1","author":"Yan","year":"2022","journal-title":"Mater. Futures"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1015","DOI":"10.1007\/s12598-018-1161-4","article-title":"Tailoring Strength and Ductility of High-Entropy CrMnFeCoNi Alloy by Adding Al","volume":"41","author":"Xian","year":"2022","journal-title":"Rare Met."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1016\/j.jmst.2021.07.002","article-title":"Fabricating Antibacterial CoCrCuFeNi High-Entropy Alloy via Selective Laser Melting and in-Situ Alloying","volume":"102","author":"Gao","year":"2022","journal-title":"J. Mater. Sci. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"285","DOI":"10.1016\/j.actamat.2016.10.038","article-title":"High-Entropy Al0.3CoCrFeNi Alloy Fibers with High Tensile Strength and Ductility at Ambient and Cryogenic Temperatures","volume":"123","author":"Li","year":"2017","journal-title":"Acta Mater."},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Lin, C., and Yao, Y. (2023). Corrosion-Resistant Coating Based on High-Entropy Alloys. Metals, 13.","DOI":"10.3390\/met13020205"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1027","DOI":"10.1070\/RCR4407","article-title":"The structure and properties of high-entropy alloys and nitride coatings based on them","volume":"83","author":"Pogrebnjak","year":"2014","journal-title":"Russ. Chem. Rev."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"1079","DOI":"10.1016\/j.matchemphys.2014.06.062","article-title":"Microstructure, physical and chemical properties of nanostructured (Ti\u2013Hf\u2013Zr\u2013V\u2013Nb)N coatings under different deposition conditions","volume":"147","author":"Pogrebnjak","year":"2014","journal-title":"Mater. Chem. Phys."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1016\/j.matdes.2018.05.012","article-title":"On the Machining of Selective Laser Melting CoCrFeMnNi High-Entropy Alloy","volume":"153","author":"Guo","year":"2018","journal-title":"Mater. Des."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1016\/S0042-207X(99)00189-X","article-title":"Magnetron Sputtering: A Review of Recent Developments and Applications","volume":"56","author":"Kelly","year":"2000","journal-title":"Vacuum"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"108369","DOI":"10.1016\/j.intermet.2024.108369","article-title":"Effect of Sputtering Power and Substrate Bias on Microstructure, Mechanical Properties and Corrosion Behavior of CoCrFeMnNi High Entropy Alloy Thin Films Deposited by Magnetron Sputtering Method","volume":"172","author":"Obeydavi","year":"2024","journal-title":"Intermetallics"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1016\/j.jallcom.2014.10.030","article-title":"Corrosion and Wear Behavior of Ni60CuMoW Coatings Fabricated by Combination of Laser Cladding and Mechanical Vibration Processing","volume":"621","author":"Liu","year":"2015","journal-title":"J. Alloys Compd."},{"key":"ref_23","doi-asserted-by":"crossref","unstructured":"Wu, X., and Lv, Y. (2022). Study on the Corrosion Resistance of Laser Clad Al0.7FeCoCrNiCux High-Entropy Alloy Coating in Marine Environment. Coatings, 12.","DOI":"10.3390\/coatings12121855"},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Shi, Y., Yang, B., and Liaw, P.K. (2017). Corrosion-Resistant High-Entropy Alloys: A Review. Metals, 7.","DOI":"10.3390\/met7020043"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"110408","DOI":"10.1016\/j.corsci.2022.110408","article-title":"Influence of the Cu Content on the Electrochemical Corrosion Performances of Ni60 Coating","volume":"205","author":"Yang","year":"2022","journal-title":"Corros. Sci."},{"key":"ref_26","unstructured":"(2018). Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements for Localized Corrosion Susceptibility of Iron-, Nickel-, or Cobalt-Based Alloys (Standard No. ASTM G61-86). (Reapproved 2003)."}],"container-title":["Applied Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2076-3417\/15\/4\/1917\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,2,12]],"date-time":"2025-02-12T16:00:40Z","timestamp":1739376040000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2076-3417\/15\/4\/1917"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,12]]},"references-count":26,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2025,2]]}},"alternative-id":["app15041917"],"URL":"https:\/\/doi.org\/10.3390\/app15041917","relation":{},"ISSN":["2076-3417"],"issn-type":[{"value":"2076-3417","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,12]]}}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">10.03.2025</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Arcadii Sobetkii</author>
    <author>Laurentiu-Florin Mosinoiu</author>
    <author>Stefania Caramarin</author>
    <author>Dumitru Mitrica</author>
    <author>Laura-Madalina Cursaru</author>
    <author>Alexandru-Cristian Matei</author>
    <author>Ioan-Albert Tudor</author>
    <author>Beatrice-Adriana Serban</author>
    <author>Mihai Ghita</author>
    <author>Nicoleta Vitan</author>
    <author>Julia Witt</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Bogdan Postolnyi</author>
    <author>Alexander Pogrebnjak</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>High-entropy alloys (HEAs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>DC magnetron sputtering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Cu-enhanced coatings</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion resistance</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microstructural characterization</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/62556/2025.Sobetkii_et_al.ApplSci.15.1917.pdf</file>
  </doc>
  <doc>
    <id>50342</id>
    <completedYear/>
    <publishedYear>2019</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>5749</pageFirst>
    <pageLast>5759</pageLast>
    <pageNumber/>
    <edition/>
    <issue>12</issue>
    <volume>2</volume>
    <type>article</type>
    <publisherName>ACS</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Mussel-Inspired Multivalent Linear Polyglycerol Coatings Outperform Monovalent Polyethylene Glycol Coatings in Antifouling Surface Properties</title>
    <abstract language="eng">Biofouling constitutes a major challenge in the application of biosensors and biomedical implants, as well as for (food) packaging and marine equipment. In this work, an antifouling surface coating based on the combination of mussel-inspired dendritic polyglycerol (MI-dPG) and an amine-functionalized block copolymer of linear polyglycerol (lPG−b−OA11, OA = oligo-amine) was developed. The coating was compared to a MI-dPG surface which was postfunctionalized with commercially available amine-terminated Polyethylene glycol (HO−PEG−NH2) of similar molecular weight. In the current work, These coatings were compared in their chemical stability, protein fouling characteristics, and cell fouling characteristics. The lPG−b−OA11-functionalized coating showed high chemical stability in both phosphate buffered saline (PBS) and sodium dodecyl sulfate (SDS) solutions and reduced the adhesion of fibrinogen from human plasma with 99% and the adhesion of human serum albumin with 96%, in comparison to the bare titanium dioxide substrate. Furthermore, the Proliferation of human umbilical vein endothelial cells (HUVECs) was reduced with 85% when the lPG−b−OA11 system was compared to bare titanium dioxide. Additionally, a reduction of 94% was observed when the lPG−b−OA11 system was compared to tissue culture polystyrene.</abstract>
    <parentTitle language="eng">ACS Applied Biomaterials</parentTitle>
    <identifier type="doi">10.1021/acsabm.9b00786</identifier>
    <author>M. W. Kulka</author>
    <author>Ievgen Donskyi</author>
    <author>Nina Wurzler</author>
    <author>D. Salz</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Wolfgang Unger</author>
    <author>R. Haag</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Antifouling surface coatings</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Human umbilical cell adhesion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Linear polyglycerol</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polyethylene glycol</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Mussel-inspired adhesives</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>47864</id>
    <completedYear/>
    <publishedYear>2019</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>52</pageFirst>
    <pageLast>55</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>101</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Efficient detection of localized corrosion processes on stainless steel by means of scanning electrochemical microscopy (SECM) using a multi-electrode approach</title>
    <abstract language="eng">High resolution analysis of corrosion processes on stainless steels is a challenging task. The application of local electrochemical techniques such as scanning electrochemical microscopy (SECM) has opened new possibilities for the detection of corrosion products and activity on metallic surfaces. However, due to its stochastic nature, the analysis of pitting corrosion requires being at the right place at the right time. Scanning over large areas at a high resolution not only leads to long scan durations but also leaves many short-lived processes undetected. In this paper we present the combined automated operation of SECM and wire multi-electrodes connected to a multi-electrode analyzer (MMA). The inter-electrode currents between 25 wire electrodes connected via zero resistance ammeters (ZRA) are measured by the MMA at open circuit potential (OCP) and the electrodes reporting anodic currents are detected automatically to be analyzed by means of SECM. The results demonstrate the successful application of this methodology for the detection of unstable and stable pitting processes on 304 stainless steel in a corrosive aqueous environment.</abstract>
    <parentTitle language="eng">Electrochemistry Communications</parentTitle>
    <identifier type="doi">10.1016/j.elecom.2019.02.019</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-478646</identifier>
    <enrichment key="date_peer_review">29.04.2019</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Marco Hampel</author>
    <author>Matthias Schenderlein</author>
    <author>Christian Schary</author>
    <author>Matthias Dimper</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Scanning electrochemical microscope (SECM)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Localised corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion monitoring</value>
    </subject>
    <collection role="ddc" number="543">Analytische Chemie</collection>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/47864/Hampel_et_al._EChemCommun_2019.pdf</file>
  </doc>
  <doc>
    <id>50608</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>Article 527</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>11</volume>
    <type>article</type>
    <publisherName>Frontiers in microbiology</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Iron to Gas: Versatile Multiport Flow-Column Revealed Extremely High Corrosion Potential by Methanogen-Induced Microbiologically Influenced Corrosion (Mi-MIC)</title>
    <abstract language="eng">Currently, sulfate-reducing bacteria (SRB) is regarded as the main culprit of microbiologically influenced corrosion (MIC), mainly due to the low reported corrosion rates of other microorganisms. For example, the highest reported corrosion rate for methanogens is 0.065 mm/yr. However, by investigating methanogen-induced microbiologically influenced corrosion (Mi-MIC) using an in-house developed versatile multiport flow test column, extremely high corrosion rates were observed. We analyzed a large set of carbon steel beads, which were sectionally embedded into the test columns as substrates for iron-utilizing methanogen Methanobacterium IM1. After 14 days of operation using glass beads as fillers for section separation, the highest average corrosion rate of Methanobacterium IM1 was 0.2 mm/yr, which doubled that of Desulfovibrio ferrophilus IS5 and Desulfovibrio alaskensis 16109 investigated at the same conditions. At the most corroded region, nearly 80% of the beads lost 1% of their initial weight (fast-corrosion), resulting in an average corrosion rate of 0.2 mm/yr for Methanobacterium IM1-treated columns. When sand was used as filler material to mimic sediment conditions, average corrosion rates for Methanobacterium IM1 increased to 0.3 mm/yr (maximum 0.52 mm/yr) with over 83% of the beads having corrosion rates above 0.3 mm/yr. Scanning electron images of metal coupons extracted from the column showed methanogenic cells were clustered close to the metal surface. Methanobacterium IM1 is a hydrogenotrophic methanogen with higher affinity to metal than H2. Unlike SRB, Methanobacterium IM1 is not restricted to the availability of sulfate concentration in the environment. Thus, the use of the multiport flow column provided a new insight on the corrosion potential of methanogens, particularly in dynamic conditions, that offers new opportunities for monitoring and development of mitigation strategies. Overall, this study shows under certain conditions methanogenic archaea can cause higher corrosion than SRB, specific quantifications, i.e., maximum, average, and minimum corrosion rates can be determined, and that spatial statistical evaluations of MIC can be carried out.</abstract>
    <parentTitle language="eng">Bioleaching and Biocorrosion: Advances in Interfacial Processes</parentTitle>
    <identifier type="doi">10.3389/fmicb.2020.00527</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-506084</identifier>
    <enrichment key="date_peer_review">30.04.2020</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Biwen Annie An</author>
    <author>Sherin Kleinbub</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Andrea Koerdt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microbiologically influenced corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Methanogen</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Methane</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biocorrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Flow system</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Modeling</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multiport</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">4.1 Biologische Materialschädigung und Referenzorganismen</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/50608/Versatile Multiport Flow-Column Revealed Extremely High Corrosion Potential by Mi-MIC.pdf</file>
  </doc>
  <doc>
    <id>50573</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>106673</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>112</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Trained to corrode: Cultivation in the presence of Fe(III) increases the electrochemical activity of iron reducing bacteria – An in situ electrochemical XANES study</title>
    <abstract language="eng">This paper reports results from in situ electrochemical X-ray absorption near-edge spectroscopy (XANES) studies of the corrosion processes on model thin iron films in the presence of iron reducing bacteria Shewanella putrefaciens. Here we investigate the electrochemical activity of two cultures grown in the presence and absence of Fe(III) citrate in the culture medium. The XANES spectra and the OCP data of the Fe sample incubated with the culture grown in absence of Fe(III) did not show any significant changes during twenty hours of monitoring. In the case of the culture grown in Fe(III) containing medium, an accelerated dissolution of the iron film was observed together with the formation of a mixed Fe(II)-Fe(III) hydroxide surface layer. The open circuit potential (OCP) steadily approached the free corrosion potential of iron in neutral chloride containing electrolytes, indicating a continuous dissolution process without passivation.</abstract>
    <parentTitle language="eng">Electrochemistry Communications</parentTitle>
    <identifier type="doi">10.1016/j.elecom.2020.106673</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-505732</identifier>
    <enrichment key="date_peer_review">19.03.2020</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Nina Wurzler</author>
    <author>J. D. Schütter</author>
    <author>R. Wagner</author>
    <author>M. Dimper</author>
    <author>D. Lützenkirchen-Hecht</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microbiologically influenced corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>XANES</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electrochemistry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Iron reducing bacteria</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/50573/Wurzler_Trained to corrode.pdf</file>
  </doc>
  <doc>
    <id>61158</id>
    <completedYear/>
    <publishedYear>2024</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>26</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Wiley</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Materials Acceleration Platforms (MAPs) Accelerating Materials Research and Development to Meet Urgent Societal Challenges</title>
    <abstract language="eng">AbstractClimate Change and Materials Criticality challenges are driving urgent responses from global governments. These global responses drive policy to achieve sustainable, resilient, clean solutions with Advanced Materials (AdMats) for industrial supply chains and economic prosperity. The research landscape comprising industry, academe, and government identified a critical path to accelerate the Green Transition far beyond slow conventional research through Digital Technologies that harness Artificial Intelligence, Smart Automation and High Performance Computing through Materials Acceleration Platforms, MAPs. In this perspective, following the short paper, a broad overview about the challenges addressed, existing projects and building blocks of MAPs will be provided while concluding with a review of the remaining gaps and measures to overcome them.</abstract>
    <parentTitle language="eng">Advanced Materials</parentTitle>
    <identifier type="doi">10.1002/adma.202407791</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-611583</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,9,7]],"date-time":"2024-09-07T00:33:41Z","timestamp":1725669221576},"reference-count":145,"publisher":"Wiley","license":[{"start":{"date-parts":[[2024,9,6]],"date-time":"2024-09-06T00:00:00Z","timestamp":1725580800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"&lt;jats:title&gt;Abstract&lt;\/jats:title&gt;&lt;jats:p&gt;Climate Change and Materials Criticality challenges are driving urgent responses from global governments. These global responses drive policy to achieve sustainable, resilient, clean solutions with Advanced Materials (AdMats) for industrial supply chains and economic\u00a0prosperity. The research landscape comprising industry, academe, and government identified a critical path to accelerate the Green Transition far beyond slow conventional research through Digital Technologies that harness Artificial Intelligence, Smart Automation and High Performance Computing through Materials Acceleration Platforms, MAPs. In this perspective, following the short paper, a broad overview about the challenges addressed, existing projects and building blocks of MAPs will be provided while concluding with a review of the remaining gaps and measures to overcome them.&lt;\/jats:p&gt;","DOI":"10.1002\/adma.202407791","type":"journal-article","created":{"date-parts":[[2024,9,6]],"date-time":"2024-09-06T13:40:28Z","timestamp":1725630028000},"update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Materials Acceleration Platforms (MAPs) Accelerating Materials Research and Development to Meet Urgent Societal Challenges"],"prefix":"10.1002","author":[{"ORCID":"http:\/\/orcid.org\/0000-0003-0410-3616","authenticated-orcid":false,"given":"Simon P.","family":"Stier","sequence":"first","affiliation":[{"name":"Department Digital Transformation TLZ\u2010RT Fraunhofer ISC  Neunerplatz 2 97082 W\u00fcrzburg Germany"}]},{"given":"Christoph","family":"Kreisbeck","sequence":"additional","affiliation":[{"name":"Aixelo Inc.  Cambridge MA 02141 USA"}]},{"given":"Holger","family":"Ihssen","sequence":"additional","affiliation":[{"name":"Helmholtz Association  Rue du Tr\u00f4ne 98 Bruxelles B\u20101050 Belgium"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7620-1245","authenticated-orcid":false,"given":"Matthias Albert","family":"Popp","sequence":"additional","affiliation":[{"name":"Department Digital Transformation TLZ\u2010RT Fraunhofer ISC  Neunerplatz 2 97082 W\u00fcrzburg Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4384-2112","authenticated-orcid":false,"given":"Jens","family":"Hauch","sequence":"additional","affiliation":[{"name":"Forschungszentrum J\u00fclich GmbH, Helmholtz\u2010Institut Erlangen\u2010N\u00fcrnberg for Renewable Energy (HI ERN) Institute of Materials for Electronics and Energy Technology (i\u2010MEET)  91058 Erlangen Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-3021-0813","authenticated-orcid":false,"given":"Kourosh","family":"Malek","sequence":"additional","affiliation":[{"name":"Forschungszentrum J\u00fclich GmbH Theory and Computation of Energy Materials (IEK\u201013) Institute of Energy and Climate Research (IEK)  52428 J\u00fclich Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-0156-8701","authenticated-orcid":false,"given":"Marine","family":"Reynaud","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n Cooperativa de Energ\u00edas Alternativas (CIC energiGUNE) Basque Research and Technology Alliance (BRTA)  Parque Tecnol\u00f3gico de \u00c1lava, Albert Einstein 48 Vitoria\u2010Gasteiz 01510 Spain"}]},{"given":"T.P.M.","family":"Goumans","sequence":"additional","affiliation":[{"name":"Software for Chemistry &amp;amp; Materials BV  De Boelelaan 1083 Amsterdam 1081 HV The Netherlands"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-1596-0923","authenticated-orcid":false,"given":"Johan","family":"Carlsson","sequence":"additional","affiliation":[{"name":"Dassault Systemes Deutschland GmbH  51063 Cologne Germany"}]},{"given":"Ilian","family":"Todorov","sequence":"additional","affiliation":[{"name":"Scientific Computing Department Science and Technology Facilities Council, Daresbury Laboratory  Warrington WA4 4AD UK"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-7444-2969","authenticated-orcid":false,"given":"Lukas","family":"Gold","sequence":"additional","affiliation":[{"name":"Department Digital Transformation TLZ\u2010RT Fraunhofer ISC  Neunerplatz 2 97082 W\u00fcrzburg Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-2673-0832","authenticated-orcid":false,"given":"Andreas","family":"R\u00e4der","sequence":"additional","affiliation":[{"name":"Department Digital Transformation TLZ\u2010RT Fraunhofer ISC  Neunerplatz 2 97082 W\u00fcrzburg Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-9487-4689","authenticated-orcid":false,"given":"Wolfgang","family":"Wenzel","sequence":"additional","affiliation":[{"name":"Institute of Nanotechnology (INT) Karlsruhe Institute of Technology  Hermann\u2010von\u2010Helmholtz\u2010Platz 1 76344 Eggenstein\u2010Leopoldshafen Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-9365-8703","authenticated-orcid":false,"given":"Shahbaz Tareq","family":"Bandesha","sequence":"additional","affiliation":[{"name":"Department Digital Transformation TLZ\u2010RT Fraunhofer ISC  Neunerplatz 2 97082 W\u00fcrzburg Germany"}]},{"given":"Philippe","family":"Jacques","sequence":"additional","affiliation":[{"name":"EMIRI AISBL  Rue de Ransbeek 310 Brussels B\u20101120 Belgium"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6114-0240","authenticated-orcid":false,"given":"Francisco","family":"Garcia\u2010Moreno","sequence":"additional","affiliation":[{"name":"Institute of Applied Materials Helmholtz\u2010Zentrum Berlin f\u00fcr Materialien und Energie  Hahn\u2010Meitner\u2010Platz 1 14109 Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-9075-3820","authenticated-orcid":false,"given":"Oier","family":"Arcelus","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n Cooperativa de Energ\u00edas Alternativas (CIC energiGUNE) Basque Research and Technology Alliance (BRTA)  Parque Tecnol\u00f3gico de \u00c1lava, Albert Einstein 48 Vitoria\u2010Gasteiz 01510 Spain"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-4465-1465","authenticated-orcid":false,"given":"Pascal","family":"Friederich","sequence":"additional","affiliation":[{"name":"Institute of Nanotechnology (INT) Karlsruhe Institute of Technology  Hermann\u2010von\u2010Helmholtz\u2010Platz 1 76344 Eggenstein\u2010Leopoldshafen Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-8758-6109","authenticated-orcid":false,"given":"Simon","family":"Clark","sequence":"additional","affiliation":[{"name":"SINTEF Industry New Energy Solutions  Sem S\u00e6lands vei 12 Trondheim 7034 Norway"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-5747-8879","authenticated-orcid":false,"given":"Mario","family":"Maglione","sequence":"additional","affiliation":[{"name":"Institut de Chimie de la Mati\u00e8re Condens\u00e9e de Bordeaux (ICMCB)\u2010UMR 5026, CNRS Universit\u00e9 de Bordeaux  87 Avenue du Docteur Schweitzer Pessac F\u201033608 France"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-2308-744X","authenticated-orcid":false,"given":"Anssi","family":"Laukkanen","sequence":"additional","affiliation":[{"name":"VTT Technical Research Centre of Finland Ltd.  Espoo 02044 Finland"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-5880-5045","authenticated-orcid":false,"given":"Ivano Eligio","family":"Castelli","sequence":"additional","affiliation":[{"name":"Department of Energy Conversion and Storage Technical University of Denmark  Kgs. Lyngby DK\u20102800 Denmark"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-3117-6933","authenticated-orcid":false,"given":"Javier","family":"Carrasco","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n Cooperativa de Energ\u00edas Alternativas (CIC energiGUNE) Basque Research and Technology Alliance (BRTA)  Parque Tecnol\u00f3gico de \u00c1lava, Albert Einstein 48 Vitoria\u2010Gasteiz 01510 Spain"},{"name":"IKERBASQUE \u2010 Basque Foundation for Science  Plaza Euskadi 5 Bilbao 48009 Spain"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-9298-2333","authenticated-orcid":false,"given":"Montserrat Casas","family":"Cabanas","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n Cooperativa de Energ\u00edas Alternativas (CIC energiGUNE) Basque Research and Technology Alliance (BRTA)  Parque Tecnol\u00f3gico de \u00c1lava, Albert Einstein 48 Vitoria\u2010Gasteiz 01510 Spain"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-3461-0232","authenticated-orcid":false,"given":"Helge S\u00f6ren","family":"Stein","sequence":"additional","affiliation":[{"name":"Technical University of Munich (TUM) Digital Catalysis  Lichtenbergstr. 4 85748 Garching b. M\u00fcnchen Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-1965-7996","authenticated-orcid":false,"given":"Ozlem","family":"Ozcan","sequence":"additional","affiliation":[{"name":"Federal Institute for Materials Research and Testing (BAM)  Unter den Eichen 87 12205 Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-2292-180X","authenticated-orcid":false,"given":"David","family":"Elbert","sequence":"additional","affiliation":[{"name":"Hopkins Extreme Materials Institute Johns Hopkins University  Baltimore MD 21218 USA"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-8473-8659","authenticated-orcid":false,"given":"Karsten","family":"Reuter","sequence":"additional","affiliation":[{"name":"Fritz\u2010Haber\u2010Institut der Max\u2010Planck\u2010Gesellschaf  Faradayweg 4\u20106 14195 Berlin Germany"}]},{"given":"Christoph","family":"Scheurer","sequence":"additional","affiliation":[{"name":"Fritz\u2010Haber\u2010Institut der Max\u2010Planck\u2010Gesellschaf  Faradayweg 4\u20106 14195 Berlin Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-7308-3041","authenticated-orcid":false,"given":"Masahiko","family":"Demura","sequence":"additional","affiliation":[{"name":"National Institute for Materials Science (NIMS)  1\u20102\u20101 Sengen, Tsukuba Ibaraki 305\u20100044 Japan"}]},{"given":"Sang Soo","family":"Han","sequence":"additional","affiliation":[{"name":"Korea Institute of Science and Technology (KIST)  5 Hwarangno 14\u2010gil Seongbuk\u2010gu Seoul 136\u2010791 Republic of Korea"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-1484-0284","authenticated-orcid":false,"given":"Tejs","family":"Vegge","sequence":"additional","affiliation":[{"name":"Department of Energy Conversion and Storage Technical University of Denmark  Kgs. Lyngby DK\u20102800 Denmark"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-9174-3165","authenticated-orcid":false,"given":"Sawako","family":"Nakamae","sequence":"additional","affiliation":[{"name":"Service de physique de l'\u00e9tat condens\u00e9, CEA, CNRS Universit\u00e9 Paris\u2010Saclay  CEA Saclay Gif\u2010sur\u2010Yvette Cedex 91191 France"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-2257-8375","authenticated-orcid":false,"given":"Monica","family":"Fabrizio","sequence":"additional","affiliation":[{"name":"Institute of Condensed Matter and Technologies for Energy National Research Council  Corso Stati Uniti, 4 \u2010 35127 Padua Italy"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-5113-3047","authenticated-orcid":false,"given":"Mark","family":"Kozdras","sequence":"additional","affiliation":[{"name":"Canmet MATERIALS Natural Resources Canada  183 Longwood Road South Hamilton ON L8P 0A5 Canada"}]}],"member":"311","published-online":{"date-parts":[[2024,9,6]]},"reference":[{"key":"e_1_2_9_1_1","author":"Stier S.","year":"2023","journal-title":"Zenodo"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,9,6]]},"assertion":[{"value":"2024-05-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-09-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">01.10.2024</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>S. P. Stier</author>
    <author>C. Kreisbeck</author>
    <author>H. Ihssen</author>
    <author>M. A. Popp</author>
    <author>J. Hauch</author>
    <author>K. Malek</author>
    <author>M. Reynaud</author>
    <author>T.P.M. Goumans</author>
    <author>J. Carlsson</author>
    <author>I. Todorov</author>
    <author>L. Gold</author>
    <author>A. Räder</author>
    <author>W. Wenzel</author>
    <author>S. T. Bandesha</author>
    <author>P. Jacques</author>
    <author>F. Garcia‐Moreno</author>
    <author>O. Arcelus</author>
    <author>P. Friederich</author>
    <author>S. Clark</author>
    <author>M. Maglione</author>
    <author>A. Laukkanen</author>
    <author>I. E. Castelli</author>
    <author>J. Carrasco</author>
    <author>M. C. Cabanas</author>
    <author>H. S. Stein</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>D. Elbert</author>
    <author>K. Reuter</author>
    <author>C. Scheurer</author>
    <author>M. Demura</author>
    <author>S. S. Han</author>
    <author>T. Vegge</author>
    <author>S. Nakamae</author>
    <author>M. Fabrizio</author>
    <author>M. Kozdras</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Advanced materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Artiﬁcial intelligence</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Autonomous labs</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Materials acceleration platforms</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Societal challenges</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>MAPs</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/61158/Advanced Materials-2024-Stier_MAPs_Accelerating_Materials_Research.pdf</file>
  </doc>
  <doc>
    <id>59703</id>
    <completedYear/>
    <publishedYear>2024</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>17</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>229</volume>
    <type>article</type>
    <publisherName>Elsevier Ltd.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Corrosion and passivation of AlCrFe2Ni2Mox high-entropy alloys in sulphuric acid</title>
    <abstract language="eng">Corrosion behaviour of AlCrFe2Ni2Mox (x = 0.0, 0.1, 0.15, 0.3 and 0.6) high-entropy alloys was investigated in a 0.1 M H2SO4 solution. Passive films formed upon anodic polarisation, built of Al-based inner layer and (Cr, Fe, Mo)-based outer layer, had good protective properties. In particular, they prevented corrosion of the (Al, Ni)-rich BCC-B2 phase, which was observed under open-circuit conditions. Moderate amounts of Mo, up to x = 0.3, positively affected the passivation ability of AlCrFe2Ni2. Significant changes in microstructure and phase composition of the alloy at higher Mo concentrations (x = 0.6) resulted in deterioration of its corrosion resistance.</abstract>
    <parentTitle language="eng">Corrosion Science</parentTitle>
    <identifier type="doi">10.1016/j.corsci.2024.111855</identifier>
    <identifier type="issn">0010-938X</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">20.03.2024</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Jakub Czerski</author>
    <author>Marzena Mitoraj-Krolikowska</author>
    <author>Elzbieta Godlewska</author>
    <author>Annica Wetzel</author>
    <author>Julia Witt</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Mateusz Marzec</author>
    <author>Marcin Goly</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>EIS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Alloy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sulphuric acid</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>AFM</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Acid corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Passive films</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>56845</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>11</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>4</volume>
    <type>article</type>
    <publisherName>Cell Press ; Elsevier</publisherName>
    <publisherPlace>Maryland Heights, MO</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Designing durable, sustainable, high-performance materials for clean energy infrastructure</title>
    <abstract language="eng">Civilization and modern societies would not be possible without manmade materials. Considering their production volumes, their supporting role in nearly all industrial processes, and the impact of their sourcing and production on the environment, metals and alloys are and will be of prominent importance for the clean energy transition. The focus of materials discovery must move to more specialized, application-tailored green alloys that outperform the legacy materials not only in performance but also in sustainability and resource efficiency. This white paper summarizes a joint Canadian-German initiative aimed at developing a materials acceleration platform (MAP) focusing on the discovery of new alloy families that will address this challenge. We call our initiative the “Build to Last Materials Acceleration Platform” (B2L-MAP) and present in this perspective our concept of a three-tiered self-driving laboratory that is composed of a simulation-aided pre-selection module (B2L-select), an artificial intelligence (AI)-driven experimental lead generator (B2L-explore), and an upscaling module for durability assessment (B2L-assess). The resulting tool will be used to identify and subsequently demonstrate novel corrosion-resistant alloys at scale for three key applications of critical importance to an offshore, wind-driven hydrogen plant (reusable electrical contacts, offshore infrastructure, and oxygen evolution reaction catalysts).</abstract>
    <parentTitle language="eng">Cell reports. Physical science</parentTitle>
    <identifier type="issn">2666-3864</identifier>
    <identifier type="doi">10.1016/j.xcrp.2022.101200</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-568452</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">24.04.2023</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>J. Hattrick-Simpers</author>
    <author>K. Li</author>
    <author>M. Greenwood</author>
    <author>R. Black</author>
    <author>Julia Witt</author>
    <author>M. Kozdras</author>
    <author>X. Pang</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Material Acceleration Platforms (MAPs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Self-driving-labs (SDLs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Automation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Artificial Intelligence (AI)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Elektrolyse</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Structural Materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/56845/1-s2.0-S2666386422005185-main.pdf</file>
  </doc>
  <doc>
    <id>65415</id>
    <completedYear/>
    <publishedYear>2026</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>14</pageLast>
    <pageNumber/>
    <edition/>
    <issue>Part 1</issue>
    <volume>341</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Multiscale insights into fibroblast growth factor 23 adsorption on polyelectrolyte layers: From molecular properties to biointerfaces</title>
    <abstract language="eng">Fibroblast growth factor 23 (FGF23) is a clinically significant protein hormone regulating phosphate and vitamin D metabolism, with elevated levels linked to chronic kidney disease, cardiovascular disorders, and impaired bone homeostasis. Despite its relevance as both a biomarker and a therapeutic target, its interactions with functional biomaterials remain poorly understood. In this work, we investigate the FGF23 adsorption on polyelectrolyte layers using a combination of theoretical modeling and experimental methods. Theoretical calculations provided insights into the protein's charge distribution and diffusion properties, while experimental measurements quantified its hydrodynamic diameter, electrophoretic mobility, and electrokinetic charge over a broad range of pH values. Microscale thermophoresis revealed quantitative binding affinities of FGF23 to hyaluronic acid, chitosan, and poly(diallyldimethylammonium chloride). Adsorption studies on mica, silica, and polyelectrolyte mono- and bilayers showed that FGF23 binds to both negatively and positively charged substrates, with binding affinities following: hyaluronic acid &lt; poly(diallyldimethylammonium chloride) &lt; chitosan. Desorption occurred more readily from negatively charged surfaces (mica, silica and hyaluronic acid), indicating weaker interactions compared to positively charged layers. These results reveal fundamental aspects of protein –polyelectrolyte interactions and highlight the reversible binding capacity of FGF23 to negatively charged surfaces. Such adsorption behavior provides a physicochemical framework for considering FGF23-polyelectrolyte systems in the design of therapeutic carriers and bioactive materials. However, any direct relevance to wound healing, chronic kidney disease, or cardiovascular disorders remains prospective and requires dedicated biological validation.</abstract>
    <parentTitle language="eng">International Journal of Biological Macromolecules</parentTitle>
    <identifier type="issn">0141-8130</identifier>
    <identifier type="doi">10.1016/j.ijbiomac.2026.150221</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://www.elsevier.com/tdm/userlicense/1.0/</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorFirstName_8,PersonAuthorLastName_8,PublisherName,TitleMain_1,Language,TitleParent_1,ArticleNumber,Volume,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="date_peer_review">28.01.2026</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>A. Pomorska Gawel</author>
    <author>M. Dąbkowska</author>
    <author>D. Kosior</author>
    <author>P. Batys</author>
    <author>A. Szatanik</author>
    <author>Julia Witt</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>A. Michna</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Molecular dynamics</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Streaming potential measurements</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Adsorption</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Stability</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Binding affinity</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
  </doc>
  <doc>
    <id>54054</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>7797</pageFirst>
    <pageLast>7808</pageLast>
    <pageNumber/>
    <edition/>
    <issue>28</issue>
    <volume>125</volume>
    <type>article</type>
    <publisherName>American Chemical Society</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Effect of the Anchoring Layer and Transport Type on the Adsorption Kinetics of Lambda Carrageenan</title>
    <abstract language="eng">The kinetics of lambda carrageenan (λ-car) adsorption/desorption on/from anchoring layers under diffusion- and convection-controlled transport conditions were investigated. The eighth generation of poly(amidoamine) dendrimers and branched polyethyleneimine possessing different shapes and polydispersity indexes were used for anchoring layer formation. Dynamic light scattering, electrophoresis, streaming potential measurements, optical waveguide lightmode spectroscopy, and quartz crystal microbalance were applied to characterize the formation of mono- and bilayers. The unique combination of the employed techniques enabled detailed insights into the mechanism of the λ-car adsorption mainly controlled by electrostatic interactions. The results show that the macroion adsorption efficiency is strictly correlated with the value of the final zeta potentials of the anchoring layers, the transport type, and the initial bulk concentration of the macroions. The type of the macroion forming the anchoring layer had a minor impact on the kinetics of λ-car adsorption. Besides significance to basic science, the results presented in this paper can be used for the development of biocompatible and stable macroion multilayers of well-defined electrokinetic properties and structure.</abstract>
    <parentTitle language="eng">The Journal of Physical Chemistry</parentTitle>
    <identifier type="doi">10.1021/acs.jpcb.1c03550</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-540546</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">16.12.2021</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>A. Michna</author>
    <author>J. Maciejewska-Prończuk</author>
    <author>M. Wasilewska</author>
    <author>Tayfun Kilicer</author>
    <author>Julia Witt</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>AFM</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Dynamic light scattering</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electrophoresis</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/54054/2021.Michna_et_al.JPhysChemB.125.7797.pdf</file>
  </doc>
  <doc>
    <id>57981</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>7</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>226</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Synthesis and characterization of lipopolysaccharide (LPS) anchored polystyrene microparticles as a synthetic model system for attachment studies</title>
    <abstract language="eng">Outer membrane lipopolysaccharides (LPS) play a crucial role in determining attachment behavior and pathogenicity of bacteria. The aim of this study was to develop a simple procedure for anchoring bacterial lipopolysaccharides to polystyrene (PS) microparticles as a model system for in situ attachment studies. By using a swellcapture methodology, commercially available LPS of Pseudomonas aeruginosa (strain ATCC 27316 serotype 10.22) was anchored onto PS microparticles in a proof-of-concept study. A detailed chemical and morphological characterization has proven the success of LPS incorporation. It was shown that the coverage and structure of the LPS film was concentration dependent. The procedure can easily be adapted to LPS of other bacterial strains to generate a synthetic model toolkit for attachment studies.</abstract>
    <parentTitle language="eng">Colloids and Surfaces B: Biointerfaces</parentTitle>
    <identifier type="issn">0927-7765</identifier>
    <identifier type="doi">10.1016/j.colsurfb.2023.113301</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-579818</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">04.09.2023</enrichment>
    <enrichment key="PaperofMonth">1</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Jan David Schutter</author>
    <author>Karl Eberhardt</author>
    <author>Anna Maria Elert</author>
    <author>Jörg Radnik</author>
    <author>Daniel Geißler</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bacterial lipopolysaccharides</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Pseudomonas aeruginosa</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Polystyrene microparticles</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Swell-capture</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biomimicry</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">1 Analytische Chemie; Referenzmaterialien</collection>
    <collection role="institutes" number="">1.2 Biophotonik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="institutes" number="">S Qualitätsinfrastruktur</collection>
    <collection role="institutes" number="">S.2 Digitalisierung der Qualitätsinfrastruktur</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/57981/LPS_Microparticles_Schutter_2023.pdf</file>
  </doc>
  <doc>
    <id>55179</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>427</pageFirst>
    <pageLast>435</pageLast>
    <pageNumber/>
    <edition/>
    <issue>3</issue>
    <volume>73</volume>
    <type>article</type>
    <publisherName>Wiley VHC-Verlag</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Corrosion protection properties of poly(4-vinyl pyridine) containing multilayer polymeric coatings on magnesium alloy AZ31</title>
    <abstract language="eng">The aim of this study is to develop polymeric thin films for corrosion protection of magnesium alloy AZ31. As polymer matrix, poly(4-vinyl pyridine) (P4VP) is selected due to its semiconducting properties and protonic conductivity. Polyacrylic acid is tested as crosslinking layers to improve interfacial adhesion. The macroscopic corrosion properties of the multilayer coatings are investigated by means of electrochemical methods, such as linear sweep voltammetry and electrochemical impedance spectroscopy (EIS), in corrosive media simulating technical and biomedical applications. It is demonstrated that thin multilayer coatings can suppress the corrosion rates of magnesium alloys. To our best knowledge, this is the first demonstration of the use of P4VP as a conducting polymer film with protonic conductivity for corrosion protection of magnesium alloys.</abstract>
    <parentTitle language="eng">Materials and Corrosion</parentTitle>
    <identifier type="doi">10.1002/maco.202112708</identifier>
    <identifier type="issn">0947-5117</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-551799</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">06.07.2022</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>Chayanika Das</author>
    <author>Eleni Kastania</author>
    <author>Julia Witt</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multilayercoatings</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>AZ31</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion protection</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Intrinsically conducting polymers</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Magnesium alloys</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/55179/2021.Das_et_al.MaterCorr.pdf</file>
  </doc>
  <doc>
    <id>55988</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>12</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>4</volume>
    <type>article</type>
    <publisherName>Wiley online library</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Effect of organic conditioning layers adsorbed on stainless steel AISI 304 on the attachment and biofilm formation of electroactive bacteria Shewanella putrefaciens CN32</title>
    <abstract language="eng">The initial attachment and subsequent biofilm formation of electroactive bac-teriaShewanella putrefaciensCN32 was investigated to clarify the influence oforganic conditioning layers. A selection of macromolecules and self-assembledmonolayers (SAMs) of different chain lengths and functional groups were pre-pared and characterized by means of infrared spectroscopy in terms of theirchemistry. Surface energy and Zeta (ζ-) potential of the conditioning layers wasdetermined with contact angle and streaming current measurements. Amongthe studied surface parameters, a high polar component and a high ratio ofpolar-to-disperse components of the surface energy has emerged as a successfulindicator for the inhibition of the initial settlement ofS. putrefacienson stainlesssteel AISI 304 surfaces. Considering the negative surface charge of planktonicS. putrefacienscells, and the strong inhibition of cell attachment by positivelycharged polyethylenimine (PEI) conditioning layers, our results indicate thatelectrostatic interactions do play a subordinate role in controlling the attach-ment of this microorganism on stainless steel AISI 304 surfaces. For the biofilmformation, the organization of the SAMs affected the local distribution of thebiofilms. The formation of three-dimensional and patchy biofilm networks waspromoted with increasing disorder of the SAMs.</abstract>
    <parentTitle language="eng">Engineering Reports</parentTitle>
    <identifier type="doi">10.1002/eng2.12458</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-559887</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">19.10.2022</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Nina Wurzler</author>
    <author>Gundula Hidde</author>
    <author>Matthias Schenderlein</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Bacterial attachment</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Conditioning films</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Self-assembled monolayers</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Stainless steel</value>
    </subject>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Umwelt-Material-Interaktionen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/55988/Engineering Reports -2021_Wurzler.pdf</file>
  </doc>
  <doc>
    <id>54693</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>9</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Wiley VHC-Verlag</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">In Situ Atomic Force Microscopy Analysis of the Corrosion Processes at the Buried Interface of an Epoxy-like Model Organic Film and AA2024-T3 Aluminum Alloy</title>
    <abstract language="eng">The application of characterization methods with high spatial resolution to the analysis of buried coating/metal interfaces requires the design and use of model systems. Herein, an epoxy-like thin film is used as a model coating resembling the epoxy-based coatings and adhesives widely used in technical applications. Spin coating is used for the deposition of a 30 nm-thin bilayer (BL) composed of poly-(ethylenimine) (PEI) and poly[(o-cresyl glycidyl ether)-co-formaldehyde] (CNER). Fourier-transform infrared spectroscopy (FTIR) results confirm that the exposure of coated AA2024-T3 (AA) samples to the corrosive electrolyte solution does not cause the degradation of the polymer layer. In situ atomic force microscopy (AFM) studies are performed to monitor local corrosion processes at the buried interface of the epoxy-like film and the AA2024-T3 aluminum alloy surface in an aqueous electrolyte solution. Hydrogen evolution due to the reduction of water as the cathodic corrosion reaction leads to local blister formation. Based on the results of the complementary energy-dispersive X-ray spectroscopy (EDX) analysis performed at the same region of interest, most of the hydrogen evolved originates at the vicinity of Mg-containing intermetallic particles.</abstract>
    <parentTitle language="eng">Advanced Engineering Materials</parentTitle>
    <identifier type="doi">10.1002/adem.202101342</identifier>
    <identifier type="issn">1438-1656</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-546932</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">27.04.2022</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>A. Almalla</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Scanning Kelvin probe force microscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Aluminum alloys</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Buried interfaces</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>In situ atomic force microscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Local corrosion</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/54693/2022_Almalla_Ozcan_Witt.AdvEngMater.2101342.pdf</file>
  </doc>
  <doc>
    <id>55990</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>10</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>601</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">The comparison of the corrosion behavior of the CrCoNi medium entropy alloy and CrMnFeCoNi high entropy alloy</title>
    <abstract language="eng">This work presents the determination of the corrosion characteristics of CrCoNi (medium entropy alloy) and CrMnFeCoNi (high entropy alloy) in 0.1 M NaCl and 0.1 M H2SO4. The morphology and chemical composition of the oxide layers formed on CrCoNi and CrMnFeCoNi were comparatively analyzed by scanning Kelvin probe microscopy (SKPFM) and scanning electron microscopy (SEM) and supported with chemical analysis by means of inductively coupled plasma mass spectrometry (ICP-MS) and X-Ray photoelectron spectroscopy (XPS). The analysis of the 3p core level peaks showed that the oxide layer (native and after anodic passivation) on CrCoNi consisted mainly of Cr oxides, while the oxide layer on CrMnFeCoNi was primarily composed of a mixture of Cr and Fe oxides. In addition, XPS was utilized to assess the oxide layer thicknesses. These results were compared to the thicknesses obtained by means of electrochemical impedance spectroscopy (EIS), with both approaches yielding values up to about 4 nm depending on the electrolyte and the alloy. Cyclic polarization measurements indicated superior corrosion resistance of CrCoNi in both aqueous environments compared to CrMnFeCoNi, as well as to AISI 304 stainless steel.</abstract>
    <parentTitle language="eng">Applied Surface Science</parentTitle>
    <identifier type="doi">10.1016/j.apsusc.2022.154171</identifier>
    <identifier type="issn">0169-4332</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-559902</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">19.10.2022</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Annica Wetzel</author>
    <author>Marcus von der Au</author>
    <author>P. M. Dietrich</author>
    <author>Jörg Radnik</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Medium entropy alloy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>High entropy alloy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SKPFM</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>XPS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Passivation</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">1 Analytische Chemie; Referenzmaterialien</collection>
    <collection role="institutes" number="">1.1 Anorganische Spurenanalytik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/55990/AppSurfSci_2022_Wetzel.pdf</file>
  </doc>
  <doc>
    <id>51462</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>e49826-1</pageFirst>
    <pageLast>e49826-9</pageLast>
    <pageNumber/>
    <edition/>
    <issue>48</issue>
    <volume>137</volume>
    <type>article</type>
    <publisherName>Wiley</publisherName>
    <publisherPlace>New York, NY</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Development of layer-by-layer assembled thin coatings on aluminium alloy AA2024-T3 for high resolution studies of local corrosion processes</title>
    <abstract language="eng">The aim of this study is to develop nanometer-thin epoxy-based films on aluminium alloy AA2024-T3 as a model coating system for high resolution corrosion studies. Spin coating was used for the layer-by-layer (LbL) deposition of poly-(ethylenimine) (PEI) and poly([o-cresyl glycidyl ether]-co-formaldehyde) (CNER) bilayers. The film chemistry and the cross-linking process were characterized by means of Fourier-transform infrared spectroscopy (FTIR).&#13;
Ellipsometric data confirmed the linear increase of film thickness. The potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) results indicate the improvement of the film barrier properties with increasing film thickness. Mapping of the topography and the volta potential was performed by means of scanning Kelvin probe force microscopy (SKPFM).&#13;
The results indicate the presence of a homogeneous film structure, while the intermetallic phases can still be identified below the coating. The SKPFM Analysis confirmed that the model films are suitable for investigation of corrosion processes at the coating/metal interface.</abstract>
    <parentTitle language="eng">Journal of applied polymer science</parentTitle>
    <identifier type="doi">10.1002/app.49826</identifier>
    <identifier type="issn">0021-8995</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-514627</identifier>
    <enrichment key="date_peer_review">28.10.2020</enrichment>
    <author>A. Almalla</author>
    <author>Andreas Hertwig</author>
    <author>Daniel Fischer</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Spectroscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Coatings</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electrochemistry</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Microscopy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Resins</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="institutes" number="">6.7 Materialsynthese und Design</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="institutes" number="">6.0 Abteilungsleitung und andere</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/51462/2020.Almalla_et_al.JApplPolymSci.137.e49826.pdf</file>
  </doc>
  <doc>
    <id>59704</id>
    <completedYear/>
    <publishedYear>2024</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>8</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume/>
    <type>article</type>
    <publisherName>Wiley VHC-Verlag</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Transpassive Metal Dissolution vs. Oxygen Evolution Reaction: Implication for Alloy Stability and Electrocatalysis</title>
    <title language="deu">Transpassive Metallauflösung vs. Sauerstoffentwicklung:&#13;
Auswirkungen auf Legierungsstabilität und Elektrokatalyse</title>
    <abstract language="eng">Multi-principal element alloys (MPEAs) are gaining interest in corrosion and electrocatalysis research due to their electrochemical stability across a broad pH range and the design flexibility they offer. Using the equimolar CrCoNi alloy, we observe significant metal dissolution in a corrosive electrolyte (0.1 M NaCl, pH 2) concurrently with the oxygen evolution reaction (OER) in the transpassive region despite the absence of hysteresis in polarization curves or other obvious corrosion indicators. We present a characterization scheme to delineate the contribution of OER and alloy dissolution, using scanning electrochemical microscopy (SECM) for OER-onset detection, and quantitative chemical analysis with inductively coupled-mass spectrometry (ICP-MS) and ultraviolet visible light (UV-Vis) spectroscopy to elucidate metal dissolution processes. In-situ electrochemical atomic force microscopy (EC-AFM) revealed that the transpassive metal dissolution on CrCoNi is dominated by intergranular corrosion. These results have significant implications for the stability of MPEAs in corrosion systems, emphasizing the necessity of analytically determining metal ions released from MPEA electrodes into the electrolyte when evaluating Faradaic efficiencies of OER catalysts. The release of transition metal ions not only reduces the Faradaic efficiency of electrolyzers but may also cause poisoning and degradation of membranes in electrochemical reactors.</abstract>
    <abstract language="deu">Multi-Hauptelement-Legierungen (MPEAs) gewinnen in der Korrosions- und Elektrokatalyseforschung aufgrund ihrer elektrochemischen Stabilität über einen breiten pH-Bereich und der Vielfalt der möglichen chemischen Zusammensetzungen zunehmend an Interesse. In unseren Untersuchungen mit der äquimolaren CrCoNi-Legierung in einem sauren Elektrolyten (0.1 M NaCl, pH 2) beobachteten wir eine signifikante Metallauflösung, die mit der Sauerstoffentwicklungsreaktion (OER) im transpassiven Bereich einhergeht, obwohl in zyklischen Polarisationskurven keine Hysterese auftrat oder andere offensichtliche Korrosionsindikatoren vorlagen. In diesem Artikel wird ein Charakterisierungskonzept eingeführt, dass die Beiträge der OER und der Legierungsauflösung differenziert. Hierfür kommt die elektrochemische Rastermikroskopie (SECM) zum Nachweis des Beginns der OER und die quantitative chemische Analyse mit induktiv gekoppelter Massenspektrometrie (ICP-MS) und UV/Vis-Spektrometrie zur Aufklärung der Metallauflösungsprozesse zum Einsatz. Die elektrochemische In situ-Atomkraftmikroskopie (EC-AFM) zeigte, dass die intergranulare Korrosion der dominierende Mechanismus der transpassive Metallauflösung von CrCoNi ist. Diese Ergebnisse besitzen erhebliche Auswirkungen für die Beurteilung der Stabilität von MPEAs in Korrosionssystemen und der Stromausbeute von OER-Katalysatoren auf der Basis von MPEAs. Die Daten unterstreichen die Notwendigkeit der analytischen Bestimmung von Metallionen, die von MPEA-Elektroden freigesetzt werden. Die Freisetzung von Übergangsmetallionen verringert nicht nur die Stromausbeute von Elektrolyseuren, sondern kann zu einer Schädigung von Membranen in elektrochemischen Reaktoren führen.</abstract>
    <parentTitle language="eng">Angewandte Chemie International Edition</parentTitle>
    <identifier type="doi">10.1002/anie.202317058</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-597045</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">20.03.2024</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Annica Wetzel</author>
    <author>Daniel Morell</author>
    <author>Marcus von der Au</author>
    <author>Gunther Wittstock</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Transpassive dissolution</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multi-prinicpal element alloys (MPEAs)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Passivation</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">1 Analytische Chemie; Referenzmaterialien</collection>
    <collection role="institutes" number="">1.4 Non-Target-Analytik</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/59704/2024.Wetzel_et_al.AngewChemIntEd.e202317058_DE.pdf</file>
    <file>https://opus4.kobv.de/opus4-bam/files/59704/2024.Wetzel_et_al.AngewChemIntEd.e202317058.pdf</file>
  </doc>
  <doc>
    <id>52600</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>102812</pageFirst>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>106</volume>
    <type>article</type>
    <publisherName>Elsevier Ltd.</publisherName>
    <publisherPlace>Amsterdam</publisherPlace>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Effect of PAA-induced surface etching on the adhesion properties of ZnO nanostructured films</title>
    <abstract language="eng">Zinc oxide - polymer interfaces are known to exhibit interesting properties regarding molecular adhesion. This work is aimed at the investigation of the effect of the morphology and surface chemistry on the macroscopic adhesion of a model epoxy-based adhesive to nanorod (ZnO NR) and nanocrystalline (ZnO NC) ZnO-modified surfaces. Both ZnO films have been prepared using hydrothermal synthesis on hot-dip galvanized steel (HDG) surfaces by varying the precursor chemistry in order to control the film morphology. Poly (acrylic acid) (PAA) was used to improve the interfacial adhesion by modifying the morphology and surface chemistry of ZnO nanostructured films. The strong interaction of PAA from a dilute and neutral aqueous solution with the ZnO nanocrystallites was shown to significantly improve the interfacial adhesion by means of a nanoetching process.&#13;
It was shown that the wet peel-forces correlate well with the considered morphology and surface chemistry.</abstract>
    <parentTitle language="eng">International Journal of Adhesion &amp; Adhesives</parentTitle>
    <identifier type="issn">0143-7496</identifier>
    <identifier type="doi">10.1016/j.ijadhadh.2021.102812</identifier>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">06.05.2021</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>D. Meinderink</author>
    <author>C. Kielar</author>
    <author>Oded Sobol</author>
    <author>L. Ruhm</author>
    <author>F. Rieker</author>
    <author>K. Nolkemper</author>
    <author>A. G. Orive</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>G. Grundmeier</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Interfacial stability</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Morphology control</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Poly(acrylic acid)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Adhesion by mechanical interlocking</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>ZnO films</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>ZnO nanorods Nanocrystalline</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="institutes" number="">9 Komponentensicherheit</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
    <collection role="institutes" number="">9.0 Abteilungsleitung und andere</collection>
  </doc>
  <doc>
    <id>38196</id>
    <completedYear/>
    <publishedYear>2016</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1020</pageFirst>
    <pageLast>1026</pageLast>
    <pageNumber/>
    <edition/>
    <issue>10</issue>
    <volume>67</volume>
    <type>article</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Adhesion and corrosive delamination of epoxy films on chemically etched ZnMgAl-alloy coatings</title>
    <abstract language="eng">The effect of alkaline and acidic pretreatment steps on the surface chemical&#13;
composition and adhesion properties of ZnMgAl-alloy coated steel was&#13;
investigated by means of spectroscopic methods, scanning Kelvin probe (SKP)&#13;
and peel test measurements.The spectroscopic results indicate that the surface&#13;
film composition can be adjusted by the wet-chemical treatment. To study the&#13;
corresponding surface adhesive properties, the samples were coated with an&#13;
epoxy amine adhesive. Peel tests under humid conditions indicated an&#13;
increased interaction between the acidic pre-treated surface and the adhesive.&#13;
The results of the SKP analysis show that the acidic cleaned substrates have the&#13;
highest resistance to delamination, which can be explained by the shift of the&#13;
interfacial electrode potential.</abstract>
    <parentTitle language="eng">Materials and Corrosion</parentTitle>
    <identifier type="issn">0947-5117</identifier>
    <identifier type="issn">1521-4176</identifier>
    <identifier type="doi">10.1002/maco.201608968</identifier>
    <enrichment key="date_peer_review">11.11.2016</enrichment>
    <author>K. Pohl</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>M. Voigt</author>
    <author>G. Grundmeier</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>ZnMgAl-alloy coatings</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>XPS</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Scanning Kelvin probe</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>65416</id>
    <completedYear/>
    <publishedYear>2026</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>13</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>522</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Influence of the BF3·O(C2H5)2 on the corrosion resistance of hybrid silica sol-gel coatings deposited on flash-PEO-treated Mg alloy</title>
    <abstract language="eng">Achieving highly cross-linked sol-gel coatings to provide effective corrosion protection of Mg alloys remains a challenging task. The aim of this work is to evaluate the effect boron trifluoride diethyl etherate (BF3·O(C2H5)2) as catalyst to epoxy group in a GPTMS/TEOS/SiO2 sol and assesses its effect on the structure and corrosion resistance properties of Flash-PEO coated pre-treated Mg alloy. 29Si MAS NMR and 13C CPMAS-NMR demonstrated that (BF3·O(C2H5)2) efficiently promotes the epoxy polymerization of the GPTMS and the formation of a hybrid silica network. However, the amount of (BF3·O(C2H5)2) should be optimized to minimize the formation of undesirable byproducts such as ethyl ether terminal units. Therefore, GPTMS/TEOS/SiO2 sols containing different amounts of (BF3·O(C2H5)2) were synthesized and deposited onto the Flash-PEO coated Mg alloy, leading to bilayer systems with a total thickness of ⁓8 μm. The corrosion behavior of the bilayer coatings in 3.5 wt% NaCl solution was evaluated by electrochemical impedance spectroscopy (EIS) and Scanning Kelvin probe microscope (SKPFM). The results revealed that the barrier properties of the coatings with enhanced cross-linked structure showed impedance modulus (│Z│f:0.1 Hz) approximately four orders of magnitude higher than the bare magnesium alloy and two orders of magnitude higher than the F-PEO coated sample. A suitable compromise between (BF3·O(C2H5)2) amount and sol-gel film structure is required to obtain a more durable barrier coating capable to extend the protective lifespan of the magnesium alloy.</abstract>
    <parentTitle language="eng">Surface and Coatings Technology</parentTitle>
    <identifier type="issn">0257-8972</identifier>
    <identifier type="doi">10.1016/j.surfcoat.2025.133055</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://www.elsevier.com/tdm/userlicense/1.0/</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PublisherName,TitleMain_1,Language,TitleParent_1,ArticleNumber,Volume,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <author>E. Merino</author>
    <author>S. Cere</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Matthias Dimper</author>
    <author>I. Sobrados</author>
    <author>A. Durán</author>
    <author>Y. Castro</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Sol-gel</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Corrosion</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>AZ31B Mg alloy</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Chemical structure</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SKPFM</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei im Netzwerk der BAM verfügbar ("Closed Access")</collection>
  </doc>
  <doc>
    <id>58821</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>9434</pageFirst>
    <pageLast>9440</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>24</volume>
    <type>article</type>
    <publisherName>Elsevier B.V.</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation</title>
    <abstract language="eng">Noble metal-free nanoparticles (NPs) based on multi-principal element alloys (MPEAs) were synthesized using a one-step pulsed laser ablation in liquids (PLALs) method for the electrochemical reduction of CO2. Laser ablation was performed in pure water or poly-(diallyldimethylammonium chloride) (PDADMAC)-containing an aqueous solution of Al8Cr17Co17Cu8Fe17Ni33 MPEA targets. Transmission electron microscopy (TEM) measurements combined with energy dispersive X-ray (EDX) mapping were used to characterize the structure and composition of the laser-generated MPEA nanoparticles (MPEA-NPs). These results confirmed the presence of a characteristic elemental distribution of a core-shell phase structure as the predominant NP species. The electrocatalytic performance of the laser-generated MPEA-NPs was characterized by linear sweep voltammetry (LSV) demonstrating an enhanced electrocatalytic CO2 activity for PDADMAC-stabilized NPs. The findings of these investigations indicate that MPEAs have great potential to replace conventional, expensive noble metal electrocatalysts.</abstract>
    <parentTitle language="eng">Journal of Materials Research and Technology</parentTitle>
    <identifier type="doi">10.1016/j.jmrt.2023.05.143</identifier>
    <identifier type="issn">2238-7854</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-588218</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2023,11,6]],"date-time":"2023-11-06T05:22:20Z","timestamp":1699248140313},"reference-count":44,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2023,5,1]],"date-time":"2023-05-01T00:00:00Z","timestamp":1682899200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2023,5,16]],"date-time":"2023-05-16T00:00:00Z","timestamp":1684195200000},"content-version":"vor","delay-in-days":15,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100010790","name":"Erasmus+","doi-asserted-by":"publisher"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Materials Research and Technology"],"published-print":{"date-parts":[[2023,5]]},"DOI":"10.1016\/j.jmrt.2023.05.143","type":"journal-article","created":{"date-parts":[[2023,5,19]],"date-time":"2023-05-19T07:54:56Z","timestamp":1684482896000},"page":"9434-9440","update-policy":"http:\/\/dx.doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":1,"title":["High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation"],"prefix":"10.1016","volume":"24","author":[{"given":"H.","family":"P\u00e9rez Blanes","sequence":"first","affiliation":[]},{"given":"P.","family":"Ghiasi","sequence":"additional","affiliation":[]},{"given":"J.","family":"Sandk\u00fchler","sequence":"additional","affiliation":[]},{"given":"Y.","family":"Yesilcicek","sequence":"additional","affiliation":[]},{"given":"S.","family":"Pentzien","sequence":"additional","affiliation":[]},{"given":"A.","family":"Conradi","sequence":"additional","affiliation":[]},{"given":"C.","family":"Prinz","sequence":"additional","affiliation":[]},{"given":"D.","family":"Al-Sabbagh","sequence":"additional","affiliation":[]},{"given":"A.F.","family":"Th\u00fcnemann","sequence":"additional","affiliation":[]},{"given":"O.","family":"Ozcan","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-2733-1470","authenticated-orcid":false,"given":"J.","family":"Witt","sequence":"additional","affiliation":[]}],"member":"78","reference":[{"key":"10.1016\/j.jmrt.2023.05.143_bib1","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1002\/cey2.228","volume":"4","author":"Yu","year":"2022","journal-title":"Carbon Energy"},{"key":"10.1016\/j.jmrt.2023.05.143_bib2","doi-asserted-by":"crossref","first-page":"11280","DOI":"10.1021\/acscatal.0c03617","volume":"10","author":"Xin","year":"2020","journal-title":"ACS Catal"},{"key":"10.1016\/j.jmrt.2023.05.143_bib3","volume":"8","author":"L\u00f6ffler","year":"2018","journal-title":"Adanced Energy Materials"},{"key":"10.1016\/j.jmrt.2023.05.143_bib4","doi-asserted-by":"crossref","first-page":"4011","DOI":"10.1038\/s41467-019-11848-9","volume":"10","author":"Xie","year":"2019","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib5","doi-asserted-by":"crossref","first-page":"3658","DOI":"10.1021\/acscatal.9b04302","volume":"10","author":"Nellaiappan","year":"2020","journal-title":"ACS Catal"},{"key":"10.1016\/j.jmrt.2023.05.143_bib6","doi-asserted-by":"crossref","first-page":"D174","DOI":"10.1149\/2.0811504jes","volume":"162","author":"Koenen","year":"2015","journal-title":"J Electrochem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib7","doi-asserted-by":"crossref","first-page":"1012","DOI":"10.1002\/cphc.201601139","volume":"18","author":"Jendrzej","year":"2017","journal-title":"ChemPhysChem"},{"key":"10.1016\/j.jmrt.2023.05.143_bib8","doi-asserted-by":"crossref","volume":"90","author":"Crivellaro","year":"2019","journal-title":"Rev Sci Instrum","DOI":"10.1063\/1.5083811"},{"key":"10.1016\/j.jmrt.2023.05.143_bib9","doi-asserted-by":"crossref","volume":"6","author":"Wagener","year":"2016","journal-title":"Sci Rep","DOI":"10.1038\/srep23352"},{"key":"10.1016\/j.jmrt.2023.05.143_bib10","doi-asserted-by":"crossref","first-page":"1582","DOI":"10.3390\/nano10081582","volume":"10","author":"Dittrich","year":"2020","journal-title":"Nanomaterials"},{"key":"10.1016\/j.jmrt.2023.05.143_bib11","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1016\/j.jcis.2016.10.023","volume":"489","author":"Amendola","year":"2017","journal-title":"J Colloid Interface Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib12","doi-asserted-by":"crossref","first-page":"951","DOI":"10.1070\/QE2004v034n10ABEH002756","volume":"34","author":"Kazakevich","year":"2004","journal-title":"Quant Electron"},{"key":"10.1016\/j.jmrt.2023.05.143_bib13","doi-asserted-by":"crossref","first-page":"13228","DOI":"10.1021\/jp502327c","volume":"118","author":"Malviya","year":"2014","journal-title":"J Phys Chem C"},{"key":"10.1016\/j.jmrt.2023.05.143_bib14","doi-asserted-by":"crossref","first-page":"2362","DOI":"10.3390\/nano10122362","volume":"10","author":"Nadarajah","year":"2020","journal-title":"Nanomaterials"},{"key":"10.1016\/j.jmrt.2023.05.143_bib15","doi-asserted-by":"crossref","first-page":"3123","DOI":"10.1007\/s11051-010-9949-7","volume":"12","author":"Mahfouz","year":"2010","journal-title":"J Nanoparticle Res"},{"key":"10.1016\/j.jmrt.2023.05.143_bib16","doi-asserted-by":"crossref","first-page":"18547","DOI":"10.1039\/C9RA03254A","volume":"9","author":"Waag","year":"2019","journal-title":"RSC Adv"},{"key":"10.1016\/j.jmrt.2023.05.143_bib17","doi-asserted-by":"crossref","first-page":"9135","DOI":"10.1002\/anie.202016898","volume":"60","author":"Song","year":"2021","journal-title":"Angew Chem, Int Ed Engl"},{"key":"10.1016\/j.jmrt.2023.05.143_bib18","doi-asserted-by":"crossref","first-page":"946","DOI":"10.1038\/s41929-018-0168-4","volume":"1","author":"Zhuang","year":"2018","journal-title":"Nature Catalysis"},{"key":"10.1016\/j.jmrt.2023.05.143_bib19","doi-asserted-by":"crossref","first-page":"4614","DOI":"10.1038\/s41467-018-07032-0","volume":"9","author":"Li","year":"2018","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib20","doi-asserted-by":"crossref","first-page":"4028","DOI":"10.1039\/D0SC05990K","volume":"12","author":"Wilde","year":"2021","journal-title":"Chem Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib21","doi-asserted-by":"crossref","first-page":"764","DOI":"10.1038\/s41929-018-0139-9","volume":"1","author":"Morales-Guio","year":"2018","journal-title":"Nature Catalysis"},{"key":"10.1016\/j.jmrt.2023.05.143_bib22","doi-asserted-by":"crossref","first-page":"3340","DOI":"10.1038\/s41467-019-11292-9","volume":"10","author":"Zhang","year":"2019","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib23","doi-asserted-by":"crossref","first-page":"19283","DOI":"10.1021\/jacs.0c09458","volume":"142","author":"Castilla-Amoros","year":"2020","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib24","doi-asserted-by":"crossref","first-page":"1449","DOI":"10.1038\/s41467-021-21750-y","volume":"12","author":"Ren","year":"2021","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib25","doi-asserted-by":"crossref","first-page":"7610","DOI":"10.1021\/acs.chemrev.8b00705","volume":"119","author":"Nitopi","year":"2019","journal-title":"Chem Rev"},{"key":"10.1016\/j.jmrt.2023.05.143_bib26","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1038\/nchem.121","volume":"1","author":"Norskov","year":"2009","journal-title":"Nat Chem"},{"key":"10.1016\/j.jmrt.2023.05.143_bib27","doi-asserted-by":"crossref","first-page":"8256","DOI":"10.1021\/acssuschemeng.0c01475","volume":"8","author":"Wang","year":"2020","journal-title":"ACS Sustainable Chem Eng"},{"key":"10.1016\/j.jmrt.2023.05.143_bib28","doi-asserted-by":"crossref","first-page":"2169","DOI":"10.1021\/acscatal.9b04343","volume":"10","author":"Pedersen","year":"2020","journal-title":"ACS Catal"},{"key":"10.1016\/j.jmrt.2023.05.143_bib29","doi-asserted-by":"crossref","first-page":"218","DOI":"10.1107\/S0021889899015216","volume":"33","author":"Orthaber","year":"2000","journal-title":"J Appl Crystallogr"},{"key":"10.1016\/j.jmrt.2023.05.143_bib30","doi-asserted-by":"crossref","first-page":"1587","DOI":"10.1107\/S1600576715016544","volume":"48","author":"Bressler","year":"2015","journal-title":"J Appl Crystallogr"},{"key":"10.1016\/j.jmrt.2023.05.143_bib31","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1002\/adem.200300567","volume":"6","author":"Yeh","year":"2004","journal-title":"Adv Eng Mater"},{"key":"10.1016\/j.jmrt.2023.05.143_bib32","doi-asserted-by":"crossref","first-page":"7039","DOI":"10.1007\/s10853-011-5672-8","volume":"46","author":"Zhou","year":"2011","journal-title":"J Mater Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib33","doi-asserted-by":"crossref","first-page":"6203","DOI":"10.1007\/s10853-011-5612-7","volume":"46","author":"Cao","year":"2011","journal-title":"J Mater Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib34","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/j.actamat.2020.04.034","volume":"193","author":"Fantin","year":"2020","journal-title":"Acta Mater"},{"key":"10.1016\/j.jmrt.2023.05.143_bib35","doi-asserted-by":"crossref","first-page":"1280","DOI":"10.1107\/S160057671701010X","volume":"50","author":"Pauw","year":"2017","journal-title":"J Appl Crystallogr"},{"key":"10.1016\/j.jmrt.2023.05.143_bib36","doi-asserted-by":"crossref","first-page":"11128","DOI":"10.1021\/acs.chemrev.5b00690","volume":"116","author":"Li","year":"2016","journal-title":"Chem Rev"},{"key":"10.1016\/j.jmrt.2023.05.143_bib37","doi-asserted-by":"crossref","first-page":"6892","DOI":"10.1021\/la101014g","volume":"26","author":"Jakobi","year":"2010","journal-title":"Langmuir"},{"key":"10.1016\/j.jmrt.2023.05.143_bib38","doi-asserted-by":"crossref","volume":"22","author":"Jakobi","year":"2011","journal-title":"Nanotechnology","DOI":"10.1088\/0957-4484\/22\/14\/145601"},{"key":"10.1016\/j.jmrt.2023.05.143_bib39","doi-asserted-by":"crossref","first-page":"16434","DOI":"10.1039\/C8NR03962C","volume":"10","author":"Tymoczko","year":"2018","journal-title":"Nanoscale"},{"key":"10.1016\/j.jmrt.2023.05.143_bib40","doi-asserted-by":"crossref","first-page":"1326","DOI":"10.1039\/C9NH00332K","volume":"4","author":"Tymoczko","year":"2019","journal-title":"Nanoscale Horizons"},{"key":"10.1016\/j.jmrt.2023.05.143_bib41","doi-asserted-by":"crossref","first-page":"1438","DOI":"10.1021\/ar500029y","volume":"47","author":"Schoenbaum","year":"2014","journal-title":"Acc Chem Res"},{"key":"10.1016\/j.jmrt.2023.05.143_bib42","doi-asserted-by":"crossref","first-page":"2122","DOI":"10.1021\/jacs.6b10978","volume":"139","author":"Liu","year":"2017","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib43","doi-asserted-by":"crossref","first-page":"2829","DOI":"10.1021\/jacs.1c11500","volume":"144","author":"Zhu","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib44","doi-asserted-by":"crossref","first-page":"10356","DOI":"10.1039\/C9SC04439F","volume":"10","author":"Pankhurst","year":"2019","journal-title":"Chem Sci"}],"container-title":["Journal of Materials Research and Technology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2238785423011080?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2238785423011080?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2023,11,6]],"date-time":"2023-11-06T03:36:43Z","timestamp":1699241803000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2238785423011080"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,5]]},"references-count":44,"alternative-id":["S2238785423011080"],"URL":"http:\/\/dx.doi.org\/10.1016\/j.jmrt.2023.05.143","relation":{},"ISSN":["2238-7854"],"issn-type":[{"value":"2238-7854","type":"print"}],"subject":["Metals and Alloys","Surfaces, Coatings and Films","Biomaterials","Ceramics and Composites"],"published":{"date-parts":[[2023,5]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation","name":"articletitle","label":"Article Title"},{"value":"Journal of Materials Research and Technology","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jmrt.2023.05.143","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2023 The Author(s). Published by Elsevier B.V.","name":"copyright","label":"Copyright"}]}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="date_peer_review">15.11.2023</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>H. Pérez Blanes</author>
    <author>Pouria Ghiasi</author>
    <author>J. Sandkühler</author>
    <author>Yasemin Yesilcicek</author>
    <author>Simone Pentzien</author>
    <author>Andrea Conradi</author>
    <author>Carsten Prinz</author>
    <author>Dominik Al-Sabbagh</author>
    <author>Andreas Thünemann</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Metals and Alloys</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Surfaces</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biomaterials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ceramics and Composites</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Coatings and Films</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="institutes" number="">6.0 Abteilungsleitung und andere</collection>
    <collection role="themenfelder" number="">Advanced Materials</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/58821/Blanes_Journal_of_Materials_Research_and_Technology_2023_24_9434-9440.pdf</file>
  </doc>
  <doc>
    <id>59401</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>9434</pageFirst>
    <pageLast>9440</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>24</volume>
    <type>article</type>
    <publisherName>Elsevier BV</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation</title>
    <abstract language="eng">Noble metal-free nanoparticles (NPs) based on multi-principal element alloys (MPEAs) were synthesized using a one-step pulsed laser ablation in liquids (PLALs) method for the electrochemical reduction of CO2. Laser ablation was performed in pure water or poly-(diallyldimethylammonium chloride) (PDADMAC)-containing an aqueous solution of Al8Cr17Co17Cu8Fe17Ni33 MPEA targets. Transmission electron microscopy (TEM) measurements combined with energy dispersive X-ray (EDX) mapping were used to characterize the structure and composition of the laser-generated MPEA nanoparticles (MPEA-NPs). These results confirmed the presence of a characteristic elemental distribution of a core-shell phase structure as the predominant NP species. The electrocatalytic performance of the laser-generated MPEA-NPs was characterized by linear sweep voltammetry (LSV) demonstrating an enhanced electrocatalytic CO2 activity for PDADMAC-stabilized NPs. The findings of these investigations indicate that MPEAs have great potential to replace conventional, expensive noble metal electrocatalysts.</abstract>
    <parentTitle language="eng">Journal of Materials Research and Technology</parentTitle>
    <identifier type="doi">10.1016/j.jmrt.2023.05.143</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-594018</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_import_data">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,1,7]],"date-time":"2024-01-07T00:08:37Z","timestamp":1704586117864},"reference-count":44,"publisher":"Elsevier BV","license":[{"start":{"date-parts":[[2023,5,1]],"date-time":"2023-05-01T00:00:00Z","timestamp":1682899200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/www.elsevier.com\/tdm\/userlicense\/1.0\/"},{"start":{"date-parts":[[2023,5,16]],"date-time":"2023-05-16T00:00:00Z","timestamp":1684195200000},"content-version":"vor","delay-in-days":15,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100010790","name":"Erasmus+","doi-asserted-by":"publisher"}],"content-domain":{"domain":["elsevier.com","sciencedirect.com"],"crossmark-restriction":true},"short-container-title":["Journal of Materials Research and Technology"],"published-print":{"date-parts":[[2023,5]]},"DOI":"10.1016\/j.jmrt.2023.05.143","type":"journal-article","created":{"date-parts":[[2023,5,19]],"date-time":"2023-05-19T07:54:56Z","timestamp":1684482896000},"page":"9434-9440","update-policy":"http:\/\/dx.doi.org\/10.1016\/elsevier_cm_policy","source":"Crossref","is-referenced-by-count":1,"title":["High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation"],"prefix":"10.1016","volume":"24","author":[{"given":"H.","family":"P\u00e9rez Blanes","sequence":"first","affiliation":[]},{"given":"P.","family":"Ghiasi","sequence":"additional","affiliation":[]},{"given":"J.","family":"Sandk\u00fchler","sequence":"additional","affiliation":[]},{"given":"Y.","family":"Yesilcicek","sequence":"additional","affiliation":[]},{"given":"S.","family":"Pentzien","sequence":"additional","affiliation":[]},{"given":"A.","family":"Conradi","sequence":"additional","affiliation":[]},{"given":"C.","family":"Prinz","sequence":"additional","affiliation":[]},{"given":"D.","family":"Al-Sabbagh","sequence":"additional","affiliation":[]},{"given":"A.F.","family":"Th\u00fcnemann","sequence":"additional","affiliation":[]},{"given":"O.","family":"Ozcan","sequence":"additional","affiliation":[]},{"ORCID":"http:\/\/orcid.org\/0000-0002-2733-1470","authenticated-orcid":false,"given":"J.","family":"Witt","sequence":"additional","affiliation":[]}],"member":"78","reference":[{"key":"10.1016\/j.jmrt.2023.05.143_bib1","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1002\/cey2.228","volume":"4","author":"Yu","year":"2022","journal-title":"Carbon Energy"},{"key":"10.1016\/j.jmrt.2023.05.143_bib2","doi-asserted-by":"crossref","first-page":"11280","DOI":"10.1021\/acscatal.0c03617","volume":"10","author":"Xin","year":"2020","journal-title":"ACS Catal"},{"key":"10.1016\/j.jmrt.2023.05.143_bib3","volume":"8","author":"L\u00f6ffler","year":"2018","journal-title":"Adanced Energy Materials"},{"key":"10.1016\/j.jmrt.2023.05.143_bib4","doi-asserted-by":"crossref","first-page":"4011","DOI":"10.1038\/s41467-019-11848-9","volume":"10","author":"Xie","year":"2019","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib5","doi-asserted-by":"crossref","first-page":"3658","DOI":"10.1021\/acscatal.9b04302","volume":"10","author":"Nellaiappan","year":"2020","journal-title":"ACS Catal"},{"key":"10.1016\/j.jmrt.2023.05.143_bib6","doi-asserted-by":"crossref","first-page":"D174","DOI":"10.1149\/2.0811504jes","volume":"162","author":"Koenen","year":"2015","journal-title":"J Electrochem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib7","doi-asserted-by":"crossref","first-page":"1012","DOI":"10.1002\/cphc.201601139","volume":"18","author":"Jendrzej","year":"2017","journal-title":"ChemPhysChem"},{"key":"10.1016\/j.jmrt.2023.05.143_bib8","doi-asserted-by":"crossref","volume":"90","author":"Crivellaro","year":"2019","journal-title":"Rev Sci Instrum","DOI":"10.1063\/1.5083811"},{"key":"10.1016\/j.jmrt.2023.05.143_bib9","doi-asserted-by":"crossref","volume":"6","author":"Wagener","year":"2016","journal-title":"Sci Rep","DOI":"10.1038\/srep23352"},{"key":"10.1016\/j.jmrt.2023.05.143_bib10","doi-asserted-by":"crossref","first-page":"1582","DOI":"10.3390\/nano10081582","volume":"10","author":"Dittrich","year":"2020","journal-title":"Nanomaterials"},{"key":"10.1016\/j.jmrt.2023.05.143_bib11","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1016\/j.jcis.2016.10.023","volume":"489","author":"Amendola","year":"2017","journal-title":"J Colloid Interface Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib12","doi-asserted-by":"crossref","first-page":"951","DOI":"10.1070\/QE2004v034n10ABEH002756","volume":"34","author":"Kazakevich","year":"2004","journal-title":"Quant Electron"},{"key":"10.1016\/j.jmrt.2023.05.143_bib13","doi-asserted-by":"crossref","first-page":"13228","DOI":"10.1021\/jp502327c","volume":"118","author":"Malviya","year":"2014","journal-title":"J Phys Chem C"},{"key":"10.1016\/j.jmrt.2023.05.143_bib14","doi-asserted-by":"crossref","first-page":"2362","DOI":"10.3390\/nano10122362","volume":"10","author":"Nadarajah","year":"2020","journal-title":"Nanomaterials"},{"key":"10.1016\/j.jmrt.2023.05.143_bib15","doi-asserted-by":"crossref","first-page":"3123","DOI":"10.1007\/s11051-010-9949-7","volume":"12","author":"Mahfouz","year":"2010","journal-title":"J Nanoparticle Res"},{"key":"10.1016\/j.jmrt.2023.05.143_bib16","doi-asserted-by":"crossref","first-page":"18547","DOI":"10.1039\/C9RA03254A","volume":"9","author":"Waag","year":"2019","journal-title":"RSC Adv"},{"key":"10.1016\/j.jmrt.2023.05.143_bib17","doi-asserted-by":"crossref","first-page":"9135","DOI":"10.1002\/anie.202016898","volume":"60","author":"Song","year":"2021","journal-title":"Angew Chem, Int Ed Engl"},{"key":"10.1016\/j.jmrt.2023.05.143_bib18","doi-asserted-by":"crossref","first-page":"946","DOI":"10.1038\/s41929-018-0168-4","volume":"1","author":"Zhuang","year":"2018","journal-title":"Nature Catalysis"},{"key":"10.1016\/j.jmrt.2023.05.143_bib19","doi-asserted-by":"crossref","first-page":"4614","DOI":"10.1038\/s41467-018-07032-0","volume":"9","author":"Li","year":"2018","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib20","doi-asserted-by":"crossref","first-page":"4028","DOI":"10.1039\/D0SC05990K","volume":"12","author":"Wilde","year":"2021","journal-title":"Chem Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib21","doi-asserted-by":"crossref","first-page":"764","DOI":"10.1038\/s41929-018-0139-9","volume":"1","author":"Morales-Guio","year":"2018","journal-title":"Nature Catalysis"},{"key":"10.1016\/j.jmrt.2023.05.143_bib22","doi-asserted-by":"crossref","first-page":"3340","DOI":"10.1038\/s41467-019-11292-9","volume":"10","author":"Zhang","year":"2019","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib23","doi-asserted-by":"crossref","first-page":"19283","DOI":"10.1021\/jacs.0c09458","volume":"142","author":"Castilla-Amoros","year":"2020","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib24","doi-asserted-by":"crossref","first-page":"1449","DOI":"10.1038\/s41467-021-21750-y","volume":"12","author":"Ren","year":"2021","journal-title":"Nat Commun"},{"key":"10.1016\/j.jmrt.2023.05.143_bib25","doi-asserted-by":"crossref","first-page":"7610","DOI":"10.1021\/acs.chemrev.8b00705","volume":"119","author":"Nitopi","year":"2019","journal-title":"Chem Rev"},{"key":"10.1016\/j.jmrt.2023.05.143_bib26","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1038\/nchem.121","volume":"1","author":"Norskov","year":"2009","journal-title":"Nat Chem"},{"key":"10.1016\/j.jmrt.2023.05.143_bib27","doi-asserted-by":"crossref","first-page":"8256","DOI":"10.1021\/acssuschemeng.0c01475","volume":"8","author":"Wang","year":"2020","journal-title":"ACS Sustainable Chem Eng"},{"key":"10.1016\/j.jmrt.2023.05.143_bib28","doi-asserted-by":"crossref","first-page":"2169","DOI":"10.1021\/acscatal.9b04343","volume":"10","author":"Pedersen","year":"2020","journal-title":"ACS Catal"},{"key":"10.1016\/j.jmrt.2023.05.143_bib29","doi-asserted-by":"crossref","first-page":"218","DOI":"10.1107\/S0021889899015216","volume":"33","author":"Orthaber","year":"2000","journal-title":"J Appl Crystallogr"},{"key":"10.1016\/j.jmrt.2023.05.143_bib30","doi-asserted-by":"crossref","first-page":"1587","DOI":"10.1107\/S1600576715016544","volume":"48","author":"Bressler","year":"2015","journal-title":"J Appl Crystallogr"},{"key":"10.1016\/j.jmrt.2023.05.143_bib31","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1002\/adem.200300567","volume":"6","author":"Yeh","year":"2004","journal-title":"Adv Eng Mater"},{"key":"10.1016\/j.jmrt.2023.05.143_bib32","doi-asserted-by":"crossref","first-page":"7039","DOI":"10.1007\/s10853-011-5672-8","volume":"46","author":"Zhou","year":"2011","journal-title":"J Mater Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib33","doi-asserted-by":"crossref","first-page":"6203","DOI":"10.1007\/s10853-011-5612-7","volume":"46","author":"Cao","year":"2011","journal-title":"J Mater Sci"},{"key":"10.1016\/j.jmrt.2023.05.143_bib34","doi-asserted-by":"crossref","first-page":"329","DOI":"10.1016\/j.actamat.2020.04.034","volume":"193","author":"Fantin","year":"2020","journal-title":"Acta Mater"},{"key":"10.1016\/j.jmrt.2023.05.143_bib35","doi-asserted-by":"crossref","first-page":"1280","DOI":"10.1107\/S160057671701010X","volume":"50","author":"Pauw","year":"2017","journal-title":"J Appl Crystallogr"},{"key":"10.1016\/j.jmrt.2023.05.143_bib36","doi-asserted-by":"crossref","first-page":"11128","DOI":"10.1021\/acs.chemrev.5b00690","volume":"116","author":"Li","year":"2016","journal-title":"Chem Rev"},{"key":"10.1016\/j.jmrt.2023.05.143_bib37","doi-asserted-by":"crossref","first-page":"6892","DOI":"10.1021\/la101014g","volume":"26","author":"Jakobi","year":"2010","journal-title":"Langmuir"},{"key":"10.1016\/j.jmrt.2023.05.143_bib38","doi-asserted-by":"crossref","volume":"22","author":"Jakobi","year":"2011","journal-title":"Nanotechnology","DOI":"10.1088\/0957-4484\/22\/14\/145601"},{"key":"10.1016\/j.jmrt.2023.05.143_bib39","doi-asserted-by":"crossref","first-page":"16434","DOI":"10.1039\/C8NR03962C","volume":"10","author":"Tymoczko","year":"2018","journal-title":"Nanoscale"},{"key":"10.1016\/j.jmrt.2023.05.143_bib40","doi-asserted-by":"crossref","first-page":"1326","DOI":"10.1039\/C9NH00332K","volume":"4","author":"Tymoczko","year":"2019","journal-title":"Nanoscale Horizons"},{"key":"10.1016\/j.jmrt.2023.05.143_bib41","doi-asserted-by":"crossref","first-page":"1438","DOI":"10.1021\/ar500029y","volume":"47","author":"Schoenbaum","year":"2014","journal-title":"Acc Chem Res"},{"key":"10.1016\/j.jmrt.2023.05.143_bib42","doi-asserted-by":"crossref","first-page":"2122","DOI":"10.1021\/jacs.6b10978","volume":"139","author":"Liu","year":"2017","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib43","doi-asserted-by":"crossref","first-page":"2829","DOI":"10.1021\/jacs.1c11500","volume":"144","author":"Zhu","year":"2022","journal-title":"J Am Chem Soc"},{"key":"10.1016\/j.jmrt.2023.05.143_bib44","doi-asserted-by":"crossref","first-page":"10356","DOI":"10.1039\/C9SC04439F","volume":"10","author":"Pankhurst","year":"2019","journal-title":"Chem Sci"}],"container-title":["Journal of Materials Research and Technology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2238785423011080?httpAccept=text\/xml","content-type":"text\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.elsevier.com\/content\/article\/PII:S2238785423011080?httpAccept=text\/plain","content-type":"text\/plain","content-version":"vor","intended-application":"text-mining"}],"deposited":{"date-parts":[[2024,1,6]],"date-time":"2024-01-06T08:58:43Z","timestamp":1704531523000},"score":1,"resource":{"primary":{"URL":"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S2238785423011080"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,5]]},"references-count":44,"alternative-id":["S2238785423011080"],"URL":"http:\/\/dx.doi.org\/10.1016\/j.jmrt.2023.05.143","relation":{},"ISSN":["2238-7854"],"issn-type":[{"value":"2238-7854","type":"print"}],"subject":["Metals and Alloys","Surfaces, Coatings and Films","Biomaterials","Ceramics and Composites"],"published":{"date-parts":[[2023,5]]},"assertion":[{"value":"Elsevier","name":"publisher","label":"This article is maintained by"},{"value":"High CO2 reduction activity on AlCrCoCuFeNi multi-principal element alloy nanoparticle electrocatalysts prepared by means of pulsed laser ablation","name":"articletitle","label":"Article Title"},{"value":"Journal of Materials Research and Technology","name":"journaltitle","label":"Journal Title"},{"value":"https:\/\/doi.org\/10.1016\/j.jmrt.2023.05.143","name":"articlelink","label":"CrossRef DOI link to publisher maintained version"},{"value":"article","name":"content_type","label":"Content Type"},{"value":"\u00a9 2023 The Author(s). Published by Elsevier B.V.","name":"copyright","label":"Copyright"}]}}</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">true</enrichment>
    <enrichment key="date_peer_review">23.01.2024</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>H. Pérez Blanes</author>
    <author>P. Ghiasi</author>
    <author>J. Sandkühler</author>
    <author>Yasemin Yesilcicek</author>
    <author>Simone Pentzien</author>
    <author>Andrea Conradi</author>
    <author>Carsten Prinz</author>
    <author>Dominik Al-Sabbagh</author>
    <author>Andreas Thünemann</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Julia Witt</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Multi-principal element alloys</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Chemically Complex Materials</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>CCMat</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Electrocatalysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Carbon dioxide reduction</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Pulsed laser ablation</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="institutes" number="">6.3 Strukturanalytik</collection>
    <collection role="institutes" number="">6.5 Synthese und Streuverfahren nanostrukturierter Materialien</collection>
    <collection role="themenfelder" number="">Energie</collection>
    <collection role="themenfelder" number="">Elektrische Energiespeicher und -umwandlung</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="themenfelder" number="">Materialdesign</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/59401/Witt_2023.pdf</file>
  </doc>
  <doc>
    <id>65501</id>
    <completedYear/>
    <publishedYear>2026</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1</pageFirst>
    <pageLast>14</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>10</volume>
    <type>article</type>
    <publisherName>Springer Science and Business Media LLC</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">A 30-year-old diesel tank: Fungal-dominated biofilms cause local corrosion of galvanised steel</title>
    <abstract language="eng">The increased use of biodiesel is expected to lead to more microbial corrosion, fouling and fuel degradation issues. In this context, we have analysed the metal, fuel and microbiology of a fouled diesel tank which had been in service for over 30 years. The fuel itself, a B7 biodiesel blend, was not degraded, and—although no free water phase was visible—contained a water content of ~60 ppm. The microbial community was dominated by the fungus  Amorphotheca resinae, which formed thick, patchy biofilms on the tank bottom and walls. The tank sheets, composed of galvanised carbon steel, were locally corroded underneath the biofilms, up to a depth of a third of the sheet thickness. On the biofilm-free surfaces, Zn coatings could still be observed. Taken together, A. resinae was shown to thrive in these water-poor conditions, likely enhancing corrosion through the removal of the protective Zn coatings.</abstract>
    <parentTitle language="eng">npj Materials Degradation</parentTitle>
    <identifier type="issn">2397-2106</identifier>
    <identifier type="doi">10.1038/s41529-025-00731-2</identifier>
    <identifier type="urn">urn:nbn:de:kobv:b43-655014</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="local_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="local_crossrefLicence">https://creativecommons.org/licenses/by/4.0</enrichment>
    <enrichment key="local_import_origin">crossref</enrichment>
    <enrichment key="local_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorFirstName_8,PersonAuthorLastName_8,PersonAuthorFirstName_9,PersonAuthorLastName_9,PersonAuthorFirstName_10,PersonAuthorLastName_10,PersonAuthorFirstName_11,PersonAuthorLastName_11,PersonAuthorFirstName_12,PersonAuthorLastName_12,PersonAuthorFirstName_13,PersonAuthorLastName_13,PersonAuthorFirstName_14,PersonAuthorLastName_14,PersonAuthorFirstName_15,PersonAuthorLastName_15,PersonAuthorFirstName_16,PersonAuthorLastName_16,PersonAuthorFirstName_17,PersonAuthorLastName_17,PersonAuthorFirstName_18,PersonAuthorLastName_18,PersonAuthorFirstName_19,PersonAuthorLastName_19,PersonAuthorFirstName_20,PersonAuthorLastName_20,PersonAuthorFirstName_21,PersonAuthorLastName_21,PersonAuthorFirstName_22,PersonAuthorLastName_22,PersonAuthorFirstName_23,PersonAuthorLastName_23,PersonAuthorFirstName_24,PersonAuthorLastName_24,PublisherName,TitleMain_1,Language,TitleAbstract_1,TitleParent_1,ArticleNumber,Issue,Volume,PublishedYear,IdentifierIssn,Enrichmentlocal_crossrefLicence</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="date_peer_review">23.02.2026</enrichment>
    <licence>Creative Commons - CC BY - Namensnennung 4.0 International</licence>
    <author>Ruben Gerrits</author>
    <author>Biwen An Stepec</author>
    <author>Ralph Bäßler</author>
    <author>Roland Becker</author>
    <author>Matthias Dimper</author>
    <author>Ines Feldmann</author>
    <author>Kira L. Goff</author>
    <author>Jens Günster</author>
    <author>Andrea Hofmann</author>
    <author>René Hesse</author>
    <author>Sarah Kirstein</author>
    <author>Ulrich Klein</author>
    <author>Tatjana Mauch</author>
    <author>Meina Neumann-Schaal</author>
    <author>Özlem Özcan Sandikcioglu</author>
    <author>Nicole M. Taylor</author>
    <author>Julia Schumacher</author>
    <author>Yin Shen</author>
    <author>Heike Strehlau</author>
    <author>Matthias Weise</author>
    <author>Jacqueline Wolf</author>
    <author>Andrey Yurkov</author>
    <author>Lisa M. Gieg</author>
    <author>Anna Gorbushina</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Fungal biofilms</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Biodiesel degradation mechanisms</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="628">Sanitär- und Kommunaltechnik; Umwelttechnik</collection>
    <collection role="institutes" number="">1 Analytische Chemie; Referenzmaterialien</collection>
    <collection role="institutes" number="">1.7 Organische Spuren- und Lebensmittelanalytik</collection>
    <collection role="institutes" number="">4 Material und Umwelt</collection>
    <collection role="institutes" number="">6 Materialchemie</collection>
    <collection role="institutes" number="">6.1 Oberflächen- und Dünnschichtanalyse</collection>
    <collection role="institutes" number="">6.2 Material- und Oberflächentechnologien</collection>
    <collection role="institutes" number="">7 Bauwerkssicherheit</collection>
    <collection role="themenfelder" number="">Umwelt</collection>
    <collection role="themenfelder" number="">Material</collection>
    <collection role="themenfelder" number="">Degradationsmechanismen</collection>
    <collection role="institutes" number="">7.6 Korrosion und Korrosionsschutz</collection>
    <collection role="literaturgattung" number="">Verlagsliteratur</collection>
    <collection role="fulltextaccess" number="">Datei für die Öffentlichkeit verfügbar ("Open Access")</collection>
    <collection role="unnumberedseries" number="">Wissenschaftliche Artikel der BAM</collection>
    <collection role="institutes" number="">4.0 Abteilungsleitung und andere</collection>
    <collection role="themenfelder" number="">Biokorrosion</collection>
    <thesisPublisher>Bundesanstalt für Materialforschung und -prüfung (BAM)</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-bam/files/65501/2025 Gerrits et al_30 year old diesel tank.pdf</file>
  </doc>
</export-example>
