Dokument-ID Dokumenttyp Autoren/innen Persönliche Herausgeber/innen Haupttitel Abstract Auflage Verlagsort Verlag Herausgeber (Institution) Erscheinungsjahr Titel des übergeordneten Werkes Jahrgang/Band ISBN Veranstaltung Veranstaltungsort Beginndatum der Veranstaltung Enddatum der Veranstaltung Ausgabe/Heft Erste Seite Letzte Seite URN DOI Lizenz Datum der Freischaltung OPUS4-30571 Zeitschriftenartikel Dimitriev, O.P.; Grytsenko, K.P.; Lytvyn, P.M.; Doroshenko, T.P.; Briks, J.L.; Tolmachev, A.I.; Slominskii, Y.L.; Kudinova, M.A.; Schrader, S.; Schulze, Rolf-Dieter; Friedrich, Jörg Florian Substrate-induced self-assembly of donor-acceptor type compounds with terminal thiocarbonyl groups Two types of conjugated thiocarbonyl-terminated compounds have been synthesized and their ability to be adsorbed on surfaces of the different nature, namely, glass, polytetrafluoroethylene (PTFE), and gold has been studied. Different morphology of the films prepared by thermal vacuum evaporation and drop-casting from solutions has been observed depending on the surface used. It has been found that gold surface has a unique property to influence self-assembly of both monolayer and larger aggregates or crystals of the compounds, in contrast to glass and PTFE substrates. It was found that thiocarbonyl group is able to be chemisorbed to the gold surface. However, it was concluded that in spite of the fact that the thiocarbonyl groups are important for the chemical interaction with the gold surface, physical adsorption on the substrate surface, compound–compound and compound-solvent (when using solution) interactions are of great significance to drive self-assembly of the final film. Amsterdam Elsevier B.V. 2013 Thin solid films 539 127 133 10.1016/j.tsf.2013.05.084 2016-02-20