TY - CONF A1 - Nehrig, Marko A1 - Wille, Frank A1 - Feldkamp, Martin A1 - Rolle, Annette T1 - Aspects of gas generation caused by residual water inside ILW packages T2 - RAMTRANS 2015 - 10th International conference on radioactive materials transport and storage (Proceedings) N2 - Packages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. Water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behaviour of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. Pressure build-up, a changed thermal behaviour and content chemistry, and especially the risk of accumulation of combustible gases exceeding the limiting concentration for inflammability has to be considered in the safety assessment. Approaches to ensure the transportability of stored packages due to radiolysis will be discussed. T2 - RAMTRANS 2015 - 10th International conference on radioactive materials transport and storage CY - Oxford, UK DA - 19.05.2015 KW - Typ-B KW - ILW package KW - Gas generation KW - Radiolysis KW - Wet content PY - 2015 SP - 1 EP - 7 AN - OPUS4-33429 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -