TY  - JOUR
A1  - Rohde, H.
A1  - Menzel, Michael
A1  - Renz, F.
A1  - Filippou, A.C.
T1  - Investigation of Mo- and W-stannylidyne complexes by Mössbauer spectroscopy
JF  - Hyperfine Interactions
N2  - Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
KW  - Molybdenum
KW  - Tungsten
KW  - Stannylidyne complexes
KW  - Phosphane complexes
KW  - 119mSn-Mössbauer spectroscopy
PY  - 2008
DO  - https://doi.org/10.1007/s10751-008-9821-7
SN  - 0304-3843
SN  - 1572-9540
VL  - 185
IS  - 1-3
SP  - 129
EP  - 132
PB  - Kluwer
CY  - Dordrecht
AN  - OPUS4-18623
LA  - eng
AD  - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany
ER  -