TY - CONF A1 - Heinekamp, Christian A1 - Guiherme Buzanich, Ana A1 - Ahrens, Mike A1 - Emmerling, Franziska A1 - Braun, Thomas T1 - Zirconium chloro fluoride as catalyst for C-F bond activation and HF transfer of fluoroalkanes N2 - In this work, we successfully synthesized amorphous zirconium chloro fluoride (ZCF), which exhibits medium lewis acidity. In addition to investigating the local coordination sphere around the Zr atoms and the material properties, we were able to establish a catalytic behavior of ZCF in C-F bond activation reactions. We present a heterogeneous catalyst that performs dehydrofluorination of a fluoroalkane and consecutive hydrofluorination of an alkyne at room temperature. T2 - MC 16 CY - Dublin, Ireland DA - 03.07.2023 KW - ZCF KW - Heterogeneous catalysis KW - C-F bond activation PY - 2023 AN - OPUS4-58052 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -