TY - JOUR A1 - Unger, Brita A1 - Bücker, Michael A1 - Reinsch, Stefan A1 - Hübert, Thomas T1 - Chemical aspects of wood modification by sol-gel-derived silica T2 - Wood science and technology N2 - It has been shown that tetraethoxysilane-derived precursors are suitable solutions for impregnating pine sapwood to improve its dimensional stability. Tailored sol–gel syntheses result in precursors with nano-scaled silica species which are able to penetrate into the cell walls of wood. The physical fixation of those species inside the cell walls was verified by ESEM/EDX investigations. There is evidence that the silica species are chemically bonded to wood components. Nonreacted alkoxy groups can exist in the wood composites after impregnation. The amount of these organic residues depends on the composition of the precursors, especially their condensation degree and reactivity. Treatments for finishing the composites after the impregnation step to get clean products and stable properties are discussed in this context. An explanation of the complex relationship between solids content in the impregnation solutions and percentage weight gain and bulking of the composites is given. It can be demonstrated that high WPG values (>20 %) are pre-conditions for an effective protection of the resulting composites but they only guarantee efficient improvements if connected with the incorporation of the inorganic component inside the cell walls. Therefore, the sol–gel syntheses have to be carried out in such a manner that very small (<2 nm) as well as reactive species are sufficiently available. This demands syntheses using sub-stoichiometric water contents (H2O/TEOS <4, better <2). PB - Springer CY - Berlin KW - Silica-wood composites KW - Sol-gel derived precursors KW - Curing KW - Fixation of silica KW - Dimensional stability PY - 2013 UR - https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/26258 AN - OPUS4-26258 SN - 0043-7719 SN - 1432-5225 VL - 47 IS - 1 SP - 83 EP - 104 AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany