TY - JOUR A1 - Darlatt, Erik A1 - Traulsen, C.H.-H. A1 - Poppenberg, J. A1 - Richter, S. A1 - Kühn, Julius A1 - Schalley, C.A. A1 - Unger, Wolfgang T1 - Evidence of click and coordination reactions on a self-assembled monolayer by synchrotron radiation based XPS and NEXAFS T2 - Journal of electron spectroscopy and related phenomena N2 - An ethynylterpyridine was 'clicked' to an azide-terminated self-assembled monolayer on gold and characterized by synchrotron radiation based surface analysis as NEXAFS and XPS. The detection of azide and terpyridine signatures confirmed a partial click reaction at room temperature. The absence of the azides after reaction at 50 °C indicates an almost complete conversion. For the latter case successful Pd(II) coordination has been proven. The Au–S interface of the SAMs has been characterized by S 1s and S 2p XPS. PB - Elsevier CY - Amsterdam KW - Synchrotron radiation XPS KW - NEXAFS spectroscopy KW - Surface click chemistry KW - Self-assembled monolayer KW - HAXPES KW - XANES PY - 2012 UR - https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/25596 AN - OPUS4-25596 SN - 0368-2048 SN - 1873-2526 VL - 185 IS - 3-4 SP - 85 EP - 89 AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany