TY - JOUR A1 - Batzdorf, Lisa A1 - Zimathies, Annett A1 - Panne, Ulrich A1 - Emmerling, Franziska T1 - Mechanochemical synthesis of [Zn3(C2O4)3(4,4'-bipy)4] and its reorganization at high temperatures JF - Zeitschrift für physikalische Chemie N2 - The metal organic layered structure catena-(bis(µ2-4,4'-bipyridine)-tris(µ2-oxalato)-bis(4,4'-bipyridine)-tri-zinc(ii)) ([Zn3(C2O4)3(4,4'-bipy)4]) was synthesized mechanochemically applying three different routes. The synthesis succeeded by i) simultaneously neat grinding the three starting materials zinc acetate dihydrate, oxalic acid dihydrate and 4,4'bipyridine, ii) grinding two compounds and adding the third afterwards, independent of the sequence. The products were characterized using powder X-ray diffraction, Raman spectroscopy, gas adsorption measurements, and scanning electron microscopy. Temperature-dependent synchrotron XRD measurements revealed that the monoclinic structure of [Zn3(C2O4)3(4,4'-bipy)4] rearranges reversibly to a higher ordered orthorhombic structure [Zn(C2O4)(4,4'-bipy)] at high temperatures. KW - Mechanochemistry KW - Metal organic compounds KW - Synchrotron radiation KW - Reorganization PY - 2014 DO - https://doi.org/10.1515/zpch-2014-0445 SN - 0942-9352 SN - 2196-7156 SN - 0044-3336 SN - 0044-3328 SN - 0942-9352 N1 - Geburtsname von Batzdorf, Lisa: Tröbs, L. - Birth name of Batzdorf, Lisa: Tröbs, L. VL - 228 IS - 4-5 SP - 575 EP - 585 PB - Oldenbourg CY - München AN - OPUS4-30628 LA - eng AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany ER -