TY - JOUR A1 - Kathan, M. A1 - Kovaricek, P. A1 - Jurissek, Ch. A1 - Senf, A. A1 - Dallmann, A. A1 - Thünemann, Andreas A1 - Hecht, S. T1 - Control of Imine Exchange Kinetics with Photoswitches to Modulate Self-Healing in Polysiloxane Networks by Light Illumination T2 - Angewandte Chemie International Edition N2 - Various aldehyde-containing photoswitches have been developed whose reactivity toward amines can be controlled externally. A thermally stable bifunctional diarylethene, which in its ring-closed form exhibits imine formation accelerated by one order of magnitude, was used as a photoswitchable crosslinker and mixed with a commercially available amino-functionalized polysiloxane to yield a rubbery material with viscoelastic and self-healing properties that can be reversibly tuned by irradiation. PB - Wiley-VCH Verlag GmbH CY - Weinheim KW - Polymer KW - Self-healing KW - Rheology KW - Nanotechnology PY - 2016 UR - https://opus4.kobv.de/opus4-bam/frontdoor/index/index/docId/37904 AN - OPUS4-37904 SN - 1433-7851 (print) SN - 1521-3773 (online) VL - 55 IS - 44 SP - 13882 EP - 13886 AD - Bundesanstalt fuer Materialforschung und -pruefung (BAM), Berlin, Germany