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Institute
Im vorgestellten Projekt wurden werkstoff- und konstuktionsgerechte Knotenformen aus Aluminiumschaumsandwich (engl. Aluminium Foam Sandwich, AFS) gestaltet und mit unterschiedlichen Schweißverfahren wie dem Metall-Inertgasschweißen und dem Rührreibschweißen gefügt und geprüft. Im Rahmen der Arbeiten stand dabei die schweißtechnische Verarbeitung von AFS mit anderen Produkten, wie den Strangpressprofilen oder dem Aluminiumvollmaterial, und deren Beanspruchbarkeit im Vordergrund. In umfangreichen Untersuchungen wurden hierzu sowohl die Verbindugsknoten selbst als auch der Sandwichverbund und die Einzelkomponenten des Sandwich, Schaum und Decklagen, anhand der statischen Festigkeit und Schwingfestigkeit bewertet. Zusätzlich wurden innere Schädigungsmechanismen betrachtet. Mit experimentellen und numerischen Nachweismethoden konnte die anwendungssichere Knotengestaltung, -anbindung und -berechnung der unterschiedlichen Verbindungstypen umgesetzt werden. Die Ergebnisse wurden im Rahmen der Nachweisführung gegenübergestellt und hinsichtlich eines praxisgerechten Einsatzes nach FKM-Richtlinie bzw. Eurocode9 bewertet. Mit den ermittelten Ergebnissen wurde die bisherige Gestaltungs- und Fügerichtlinie um neue Verbindungstypen erweitert.
Efficient recycling pathway of bio-based composite polyurethane foams via sustainable diamine
(2024)
Aminolysis is widely recognized as a valuable chemical route for depolymerizing polymeric materials containing ester, amide, or urethane functional groups, including polyurethane foams. Bio-based polyurethane foams, pristine and reinforced with 40 wt% of sustainable fillers, were depolymerized in the presence of bio-derived butane-1,4-diamine, BDA. A process comparison was made using fossil-derived ethane-1,2-diamine, EDA, by varying amine/polyurethane ratio (F/A, 1:1 and 1:0.6). The obtained depolymerized systems were analyzed by FTIR and NMR characterizations to understand the effect of both diamines on the degradation pathway. The use of bio-based BDA seemed to be more effective with respect to conventional EDA, owing to its stronger basicity (and thus higher nucleophilicity), corresponding to faster depolymerization rates. BDA-based depolymerized systems were then employed to prepare second-generation bio-based composite polyurethane foams by partial replacement of isocyanate components (20 wt%). The morphological, mechanical, and thermal conductivity properties of the second-generation polyurethane foams were evaluated. The best performances (σ10 %=71 ± 9 kPa, λ = 0.042 ± 0.015 W∙ m-1 ∙K-1) were attained by employing the lowest F/A ratio (1:0.6); this demonstrates their potential application in different sectors such as packaging or construction, fulfilling the paradigm of the circular economy.
In this work we present the progress in regard to the integration of a surface plasmon resonance refractive index sensor into a CMOS compatible 200 mm wafer silicon-based technology. Our approach pursues the combination of germanium photodetectors with metallic nanohole arrays. The paper is focused on the technology development to fabricate large area photodetectors based on a modern design concept. In a first iteration we achieved a leakage current density of 82 mA/cm2 at reverse bias of 0.5 V and a maximum optical responsivity of 0.103 A/W measured with TE polarized light at λ = 1310 nm and a reversed bias of 1 V. For the realization of nanohole arrays we used thin Titanium nitride (TiN) layers deposited by a sputtering process. We were able to produce very homogenous TiN layers with a thickness deviation of around 10 % and RMS of 1.413 nm for 150 nm thick TiN layers.
A slow-fast trait continuum at the whole community level in relation to land-use intensification
(2024)
AbstractOrganismal functional strategies form a continuum from slow- to fast-growing organisms, in response to common drivers such as resource availability and disturbance. However, whether there is synchronisation of these strategies at the entire community level is unclear. Here, we combine trait data for 2800 above- and belowground taxa from 14 trophic guilds spanning a disturbance and resource availability gradient in German grasslands. The results indicate that most guilds consistently respond to these drivers through both direct and trophically mediated effects, resulting in a ‘slow-fast’ axis at the level of the entire community. Using 15 indicators of carbon and nutrient fluxes, biomass production and decomposition, we also show that fast trait communities are associated with faster rates of ecosystem functioning. These findings demonstrate that ‘slow’ and ‘fast’ strategies can be manifested at the level of whole communities, opening new avenues of ecosystem-level functional classification.