Liquid solid phase behavior of ternary fatty acid systems of palmitic, stearic, oleic and linoleic acid
- Enrichment of natural unsaturated fractions by melt crystallization processes has already been proved to be effective in prior investigations [1]–[3]. Palmitic, stearic, oleic, linoleic and linolenic acid are the five main fatty acids present in most of these plant based natural oils. There is quite a bit of information about the liquid solid phase behavior of binary mixtures such as palmitic-oleic, stearic-oleic and palmitic-stearic acid mixtures in literature [4]–[6]. Recent investigations have shown phase diagrams of real natural oil based fatty acid systems containing up to 19% saturated content (11% stearic acid and 8% palmitic acid) [7]. Yet, there is hardly any information regarding ternary systems as those of palmitic-stearic-oleic and palmitic-stearic-linoleic acids.
In this work, synthetic mixtures have been used in order to obtain a complete overview of the liquid solid phase diagrams of these ternary mixtures. To imitate naturally occurring mixtures, a mixture with 1:1 ratio of palmitic stearic acid was prepared.Enrichment of natural unsaturated fractions by melt crystallization processes has already been proved to be effective in prior investigations [1]–[3]. Palmitic, stearic, oleic, linoleic and linolenic acid are the five main fatty acids present in most of these plant based natural oils. There is quite a bit of information about the liquid solid phase behavior of binary mixtures such as palmitic-oleic, stearic-oleic and palmitic-stearic acid mixtures in literature [4]–[6]. Recent investigations have shown phase diagrams of real natural oil based fatty acid systems containing up to 19% saturated content (11% stearic acid and 8% palmitic acid) [7]. Yet, there is hardly any information regarding ternary systems as those of palmitic-stearic-oleic and palmitic-stearic-linoleic acids.
In this work, synthetic mixtures have been used in order to obtain a complete overview of the liquid solid phase diagrams of these ternary mixtures. To imitate naturally occurring mixtures, a mixture with 1:1 ratio of palmitic stearic acid was prepared. Varying amounts of either oleic or linoleic acids were added to this mixture in order to obtain the entire range required for the phase diagrams. These mixtures were then subjected to a specific profile with a wide temperature range in a Differential Scanning Calorimeter (DSC) so as to record every phase transition.
This study successfully concludes that these complex mixtures could be treated as binary mixtures of their saturated and unsaturated contents. This is because there were essentially two main peaks noted in the DSC thermograms. It is to be noted that there was a third peak, assumed to represent the solid transition, in mixtures containing oleic acid. This has already been shown in detail and discussed in prior investigations [6], [7]. Another major discovery was that the solidus line depends on the type of the unsaturated content, that is, the degree of unsaturation, in the mixture.…
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