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Capacitive sensors based on photografted molecularly imprinted polymers

  • The reversible chemosensors to creatinine and desmetryn based on artificial chemoreceptors are described. A grafted photopolymerization combined with a technique of molecular imprinting was used for the receptor layer preparation. After polymer deposition and intensive washing from templates, the electrodes were investigated by impedance spectrometry. Creatinine and desmetryn binding were detected as a decrease in the electrode capacitance. Sensor response to creatining was highly selective. No response to the addition of sodium chloride, creatine, urea or glucose were observed. The electrodes coated with the molecularly imprinted polymers selective to desmetryn displayed specific binding of this herbicide: only small capacitive effects were observed to addition of terbumeton or atrazine, while metribuzine displayed capacitance decrease similar to desmetryn.

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Metadaten
Author: Tanya Panasyuk-Delaney, Vladimir M. MirskyORCiDGND, Otto S. WolfbeisGND
ISSN:0208-5216
Title of the source (English):Biocybernetics and Biomedical Engineering
Document Type:Scientific journal article peer-reviewed
Language:English
Year of publication:2001
Tag:atrazine; capacitive sensor; chemical sensor; creatinine; photografted polymerization
Volume/Year:21
Issue number:3
First Page:43
Last Page:54
Faculty/Chair:Fakultät 2 Umwelt und Naturwissenschaften / FG Nanobiotechnologie
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