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Temperature Initiated P-Polymerization in Solid [Cd3Cu]CuP10

  • [Cd3Cu]CuP10 is the first representative of a class of compounds featuring polyphosphidic adamantine-analogous [P10] units, which tend to be fragmented and polymerized to [P6] rings and tubular [P26] units in the solid state. A new polyphosphide with nominal composition Cd15Cu10P46 results, featuring isolated and polymerized polyanions. Thermoanalytic experiments and phase analytic measurements substantiated the consecutive loss of P4 and Cd of the starting material via different intermediate steps. After P4 loss, the new polyphosphide occurred followed by various binary copper phosphides to the final product Cu3P.

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Metadaten
Author: Melanie Bawohl, Tom Nilges, Peer SchmidtORCiD
URL:http://pubs.acs.org/doi/abs/10.1021/ic401508n
DOI:https://doi.org/10.1021/ic401508n
ISSN:1520-510X
Title of the source (English):Inorganic chemistry
Document Type:Scientific journal article peer-reviewed
Language:English
Year of publication:2013
Tag:Thermal Analysis, Solid State Synthesis, Crystal Structure, Polyphosphide
Volume/Year:52
Issue number:20
First Page:11895
Last Page:11901
Faculty/Chair:Fakultät 2 Umwelt und Naturwissenschaften / FG Anorganische Chemie
Institution name at the time of publication:Fakultät für Naturwissenschaften (eHL) / Prof. Anorganische Chemie
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